The East China Sea （ECS）, one of the largest continental seas, has dynamic hydrology and complex optical characteristics that make ocean color remote-sensing retrieval difficult. The distributions and proportions of...The East China Sea （ECS）, one of the largest continental seas, has dynamic hydrology and complex optical characteristics that make ocean color remote-sensing retrieval difficult. The distributions and proportions of the light absorption coefficients of major ocean color components based on two large-scale investigations in the ECS are presented, showing these features in typical summer and winter seasons. The absorption coefficient aCDOM, aNAp and aphy of colored dissolved organic matter, non-algal particle, and pigment of phytoplankton show a decreasing trend from the coast to the outer shelf. According to the aeDOM distribution at 440 nm, the Changjiang River plume shows an abnormal southeastward transport. An extremely high aNaP value patch at 440 nm is present in the middle coast. The chlorophyll-a-specific phytoplankton pigment absorption （a^hy） is much higher in winter than in summer, which may cause serious underestimated results when applying the averaged aphy into remote-sensing algorithms for chlorophyll concentration retrieval. The importance of phytoplankton size was evident in outer shelf waters. The absorption of aCDOM （440） is a dominant component accounting for over half of the total seawater absorption in summer. The aNAP（440） accounts for 64% of the absorption of the ECS coastal area in winter.展开更多
The removal of algal organic matter(AOM) is a growing concern for the water treatment industry worldwide. The current study investigates coagulation of non-proteinaceous AOM(AOM after protein separation), which has be...The removal of algal organic matter(AOM) is a growing concern for the water treatment industry worldwide. The current study investigates coagulation of non-proteinaceous AOM(AOM after protein separation), which has been minimally explored compared with proteinaceous fractions. Jar tests with either aluminum sulphate(alum) or polyaluminium chloride(PACl) were performed at doses of 0.2–3.0 mg Al per 1 mg of dissolved organic carbon in the p H range 3.0–10.5. Additionally, non-proteinaceous matter was characterized in terms of charge, molecular weight and carbohydrate content to assess the treatability of its different fractions. Results showed that only up to 25% of non-proteinaceous AOM can be removed by coagulation under optimized conditions. The optimal coagulation p H(6.6–8.0 for alum and 7.5–9.0 for PACl) and low surface charge of the removed fraction indicated that the prevailing coagulation mechanism was adsorption of non-proteinaceous matter onto aluminum hydroxide precipitates. The lowest residual Al concentrations were achieved in very narrow p H ranges, especially in the case of PACl. High-molecular weight saccharidelike organics were amenable to coagulation compared to low-molecular weight(< 3 k Da)substances. Their high content in non-proteinaceous matter(about 67%) was the reason for its low removal. Comparison with our previous studies implies that proteinaceous and nonproteinaceous matter is coagulated under different conditions due to the employment of diverse coagulation mechanisms. The study suggests that further research should focus on the removal of low-molecular weight AOM, reluctant to coagulate, with other treatment processes to minimize its detrimental effect on water safety.展开更多
基金The National Basic Research Program ("973" Program) of China under contract No.2009CB421202the National Natural Science Foundation of China under contract Nos 40976110 and 40706061the National High Technology Research and Development Program ("863" Program) of China under contract No.2008AA09Z104
文摘The East China Sea （ECS）, one of the largest continental seas, has dynamic hydrology and complex optical characteristics that make ocean color remote-sensing retrieval difficult. The distributions and proportions of the light absorption coefficients of major ocean color components based on two large-scale investigations in the ECS are presented, showing these features in typical summer and winter seasons. The absorption coefficient aCDOM, aNAp and aphy of colored dissolved organic matter, non-algal particle, and pigment of phytoplankton show a decreasing trend from the coast to the outer shelf. According to the aeDOM distribution at 440 nm, the Changjiang River plume shows an abnormal southeastward transport. An extremely high aNaP value patch at 440 nm is present in the middle coast. The chlorophyll-a-specific phytoplankton pigment absorption （a^hy） is much higher in winter than in summer, which may cause serious underestimated results when applying the averaged aphy into remote-sensing algorithms for chlorophyll concentration retrieval. The importance of phytoplankton size was evident in outer shelf waters. The absorption of aCDOM （440） is a dominant component accounting for over half of the total seawater absorption in summer. The aNAP（440） accounts for 64% of the absorption of the ECS coastal area in winter.
基金supported by the Czech Science Foundation (No. GA18-14445S)by the institutional support of the Czech Academy of Sciences (RVO: 67985874)
文摘The removal of algal organic matter(AOM) is a growing concern for the water treatment industry worldwide. The current study investigates coagulation of non-proteinaceous AOM(AOM after protein separation), which has been minimally explored compared with proteinaceous fractions. Jar tests with either aluminum sulphate(alum) or polyaluminium chloride(PACl) were performed at doses of 0.2–3.0 mg Al per 1 mg of dissolved organic carbon in the p H range 3.0–10.5. Additionally, non-proteinaceous matter was characterized in terms of charge, molecular weight and carbohydrate content to assess the treatability of its different fractions. Results showed that only up to 25% of non-proteinaceous AOM can be removed by coagulation under optimized conditions. The optimal coagulation p H(6.6–8.0 for alum and 7.5–9.0 for PACl) and low surface charge of the removed fraction indicated that the prevailing coagulation mechanism was adsorption of non-proteinaceous matter onto aluminum hydroxide precipitates. The lowest residual Al concentrations were achieved in very narrow p H ranges, especially in the case of PACl. High-molecular weight saccharidelike organics were amenable to coagulation compared to low-molecular weight(< 3 k Da)substances. Their high content in non-proteinaceous matter(about 67%) was the reason for its low removal. Comparison with our previous studies implies that proteinaceous and nonproteinaceous matter is coagulated under different conditions due to the employment of diverse coagulation mechanisms. The study suggests that further research should focus on the removal of low-molecular weight AOM, reluctant to coagulate, with other treatment processes to minimize its detrimental effect on water safety.
