The radical polymerization of maleic anhydride（MA）,styrene（ST）with the vinyl groups introduced onto the surface of the nano-sized silica via solution polymerization method was developed.The methacryloxypropyl nano...The radical polymerization of maleic anhydride（MA）,styrene（ST）with the vinyl groups introduced onto the surface of the nano-sized silica via solution polymerization method was developed.The methacryloxypropyl nano-sized silica（MPNS）was used as macromonomer and polymerized with maleic anhydride and styrene by initiating with BPO in toluene.The structure and properties of MPNS/SMA nano-composite were characterized by FT-IR spectra and TEM.Meanwhile,it was applied as tanning agent compared with the traditional styrene-maleic anhydride copolymer in leather.It was found that the applied leather had better quality characteristics with the addition of the nano-sized silica.展开更多
The use of vegetable tanning materials in leather processing has drawn attention as an alternative to basic chromium sulphate for its natural abundance and environmental aspects.In this work,an attempt has been made t...The use of vegetable tanning materials in leather processing has drawn attention as an alternative to basic chromium sulphate for its natural abundance and environmental aspects.In this work,an attempt has been made to extract vegetable tannins from Xylocarpus granatum bark using different solvents(e.g.,water,methanol,ethanol,and chloroform)and compare with conventional vegetable tanning agents such as mimosa and quebracho.The highest extraction efficiency was observed 31.22%by methanol.The presence of tannin content and polyphenolic compounds,e.g.(-)epicatechin(503 mg/100 g dry extract),catechin hydrate(218 mg/100 g dry extract),catechol(29 mg/100 g dry extract)were ensured by UV-Vis,FT-IR spectroscopy and HPLC.Again,condensed tannins,moisture content,and pH of the methanol extracted tannin were found 47.80%,5.82%,and 3.97 respectively.The leather tanned by Xylocarpus granatum tannin showed a shrinkage temperature of 86.34±1.52℃.Other properties such as tensile strength,tear strength,grain cracking load,and distention at grain cracking were comparable to conventional vegetable-tanned leather.The cross-sectional morphology of the tanned leathers was also characterized by scanning electron microscopy(SEM)which revealed a compact structure of the leather fibers.In light of the findings from the study,X.granatum bark tannin could be a well alternative to chromium and a new source of vegetable tannin for the leather industry.展开更多
The use of vegetable tanning materials in leather processing has drawn attention as an alternative to basic chromium sulphate for its natural abundance and environmental aspects. In this work, an attempt has been made...The use of vegetable tanning materials in leather processing has drawn attention as an alternative to basic chromium sulphate for its natural abundance and environmental aspects. In this work, an attempt has been made to extract veg-etable tannins from Xylocarpus granatum bark using different solvents (e.g., water, methanol, ethanol, and chloroform) and compare with conventional vegetable tanning agents such as mimosa and quebracho. The highest extraction efficiency was observed 31.22% by methanol. The presence of tannin content and polyphenolic compounds, e.g. (-)epicatechin (503 mg/100 g dry extract), catechin hydrate (218 mg/100 g dry extract), catechol (29 mg/100 g dry extract) were ensured by UV-Vis, FT-IR spectroscopy and HPLC. Again, condensed tannins, moisture content, and pH of the methanol extracted tannin were found 47.80%, 5.82%, and 3.97 respectively. The leather tanned by Xylocar-pus granatum tannin showed a shrinkage temperature of 86.34 ± 1.52 °C. Other properties such as tensile strength, tear strength, grain cracking load, and distention at grain cracking were comparable to conventional vegetable- tanned leather. The cross-sectional morphology of the tanned leathers was also characterized by scanning electron microscopy (SEM) which revealed a compact structure of the leather fibers. In light of the findings from the study, X. granatum bark tannin could be a well alternative to chromium and a new source of vegetable tannin for the leather industry.展开更多
文摘The radical polymerization of maleic anhydride（MA）,styrene（ST）with the vinyl groups introduced onto the surface of the nano-sized silica via solution polymerization method was developed.The methacryloxypropyl nano-sized silica（MPNS）was used as macromonomer and polymerized with maleic anhydride and styrene by initiating with BPO in toluene.The structure and properties of MPNS/SMA nano-composite were characterized by FT-IR spectra and TEM.Meanwhile,it was applied as tanning agent compared with the traditional styrene-maleic anhydride copolymer in leather.It was found that the applied leather had better quality characteristics with the addition of the nano-sized silica.
基金funded by the Ministry of Science and Technology,Bangladesh by the National Science and Technology(NST)fellowship(Group:Physical Science,Reg.No:317).
文摘The use of vegetable tanning materials in leather processing has drawn attention as an alternative to basic chromium sulphate for its natural abundance and environmental aspects.In this work,an attempt has been made to extract vegetable tannins from Xylocarpus granatum bark using different solvents(e.g.,water,methanol,ethanol,and chloroform)and compare with conventional vegetable tanning agents such as mimosa and quebracho.The highest extraction efficiency was observed 31.22%by methanol.The presence of tannin content and polyphenolic compounds,e.g.(-)epicatechin(503 mg/100 g dry extract),catechin hydrate(218 mg/100 g dry extract),catechol(29 mg/100 g dry extract)were ensured by UV-Vis,FT-IR spectroscopy and HPLC.Again,condensed tannins,moisture content,and pH of the methanol extracted tannin were found 47.80%,5.82%,and 3.97 respectively.The leather tanned by Xylocarpus granatum tannin showed a shrinkage temperature of 86.34±1.52℃.Other properties such as tensile strength,tear strength,grain cracking load,and distention at grain cracking were comparable to conventional vegetable-tanned leather.The cross-sectional morphology of the tanned leathers was also characterized by scanning electron microscopy(SEM)which revealed a compact structure of the leather fibers.In light of the findings from the study,X.granatum bark tannin could be a well alternative to chromium and a new source of vegetable tannin for the leather industry.
基金the Ministry of Science and Technology,Bangladesh by the National Science and Technology(NST)fellowship(Group:Physical Science,Reg.No:317).
文摘The use of vegetable tanning materials in leather processing has drawn attention as an alternative to basic chromium sulphate for its natural abundance and environmental aspects. In this work, an attempt has been made to extract veg-etable tannins from Xylocarpus granatum bark using different solvents (e.g., water, methanol, ethanol, and chloroform) and compare with conventional vegetable tanning agents such as mimosa and quebracho. The highest extraction efficiency was observed 31.22% by methanol. The presence of tannin content and polyphenolic compounds, e.g. (-)epicatechin (503 mg/100 g dry extract), catechin hydrate (218 mg/100 g dry extract), catechol (29 mg/100 g dry extract) were ensured by UV-Vis, FT-IR spectroscopy and HPLC. Again, condensed tannins, moisture content, and pH of the methanol extracted tannin were found 47.80%, 5.82%, and 3.97 respectively. The leather tanned by Xylocar-pus granatum tannin showed a shrinkage temperature of 86.34 ± 1.52 °C. Other properties such as tensile strength, tear strength, grain cracking load, and distention at grain cracking were comparable to conventional vegetable- tanned leather. The cross-sectional morphology of the tanned leathers was also characterized by scanning electron microscopy (SEM) which revealed a compact structure of the leather fibers. In light of the findings from the study, X. granatum bark tannin could be a well alternative to chromium and a new source of vegetable tannin for the leather industry.
