The small and scattered enterprise pattern in the county economy has formed numerous sporadic pollution sources, hindering the centralized treatment of the water environment, increasing the cost and difficulty of trea...The small and scattered enterprise pattern in the county economy has formed numerous sporadic pollution sources, hindering the centralized treatment of the water environment, increasing the cost and difficulty of treatment. How enterprises can make reasonable decisions on their water environment behavior based on the external environment and their own factors is of great significance for scientifically and effectively designing water environment regulation mechanisms. Based on optimal control theory, this study investigates the design of contractual mechanisms for water environmental regulation for small and medium-sized enterprises. The enterprise is regarded as an independent economic entity that can adopt optimal control strategies to maximize its own interests. Based on the participation of multiple subjects including the government, enterprises, and the public, an optimal control strategy model for enterprises under contractual water environmental regulation is constructed using optimal control theory, and a method for calculating the amount of unit pollutant penalties is derived. The water pollutant treatment cost data of a paper company is selected to conduct empirical numerical analysis on the model. The results show that the increase in the probability of government regulation and public participation, as well as the decrease in local government protection for enterprises, can achieve the same regulatory effect while reducing the number of administrative penalties per unit. Finally, the implementation process of contractual water environmental regulation for small and medium-sized enterprises is designed.展开更多
Alumina-magnesia dry materials are widely used in induction furnace linings, but they show different kinds of damage when melting different kinds of alloy steel. In this paper, the chemical composition, phase composit...Alumina-magnesia dry materials are widely used in induction furnace linings, but they show different kinds of damage when melting different kinds of alloy steel. In this paper, the chemical composition, phase composition, and microstructure of the post-use dry materials for the working liners melting different kinds of steel were evaluated. Furthermore, the corrosion mechanism of the steel on the furnace lining materials was comprehensively analyzed. The findings reveal a significant ability of the Mn element in the molten steel to diffuse and penetrate into the refractories. Mn oxidizes to form MnO at the steel-refractory interface, and then forms a liquid phase with Al_(2)O_(3). The Cr element is dissolved into corundum and spinel of the refractories, resulting in lattice defects and structural damage of the materials. TiO2reacts with Al_(2)O_(3) to form Al_(2)TiO_(5), which plays a crucial role in preventing crack formation and propagation. Part of Ti4+dissolves into magnesia-alumina(MA), densifying the materials. TiO2also slows down the reaction between the Cr element and refractory components, further improving the corrosion resistance of the materials.展开更多
This paper presents the ductility characterization for a medium carbon steel, for two microstructural conditions, that has been evaluated using the continuum damage mechanics theory, as proposed by Kachanov and develo...This paper presents the ductility characterization for a medium carbon steel, for two microstructural conditions, that has been evaluated using the continuum damage mechanics theory, as proposed by Kachanov and developed by Lemaitre. Tensile tests were carried out using loading-unloading cycles in order to capture the gradual deterioration of the elastic modulus, which may be linked to the ductile damage increase with increasing plastic strain. The mechanical parameters for the isotropic damage evolution equation were obtained and then used as inputs for a plasticity-damage coupled nu- merical algorithm, validated through numerical simulations of the experimental tensile tests. A comparison between the SAE 1050 steels studied and two carbon steel alloys (obtained from the literature), provided some basic understanding of the influence of the carbon level on the evolution of the damage parameters. An empiric relationship for this set of parameters, which can provide useful data for preliminary studies envisaging prediction of ductile failure in carbon steels, is also presented.展开更多
For developing new binder phase with high performance, Co-Ni-Fe alloy was used as binder in cemented carbides. The mechanical properties of WC-CoNiFe and WC-Co cemented carbides with different grain sizes were studied...For developing new binder phase with high performance, Co-Ni-Fe alloy was used as binder in cemented carbides. The mechanical properties of WC-CoNiFe and WC-Co cemented carbides with different grain sizes were studied. The results show that the reprecipitation of WC-CoNiFe is inhibited compared with that of WC-Co during sintering process, and the grains in WC-CoNiFe cemented carbides are more of smooth shape, resulting in a slightly lower hardness and higher transverse rupture strength. With the increase of the grain size, the hardness of the two cemented carbides decreases, and the transverse rupture strength increases. However, the slope values of K in Hall-Petch relationship are higher in WC-CoNiFe than those in WC-Co, indicating the high toughness of medium entropy alloy Co-Ni-Fe.展开更多
In order to obtain good strength−plasticity synergy for a medium entropy alloy(MEA)CrCoNi,cold rolling,asymmetric rolling,cryorolling and asymmetric-cryorolling with subsequent annealing at different temperatures were...In order to obtain good strength−plasticity synergy for a medium entropy alloy(MEA)CrCoNi,cold rolling,asymmetric rolling,cryorolling and asymmetric-cryorolling with subsequent annealing at different temperatures were conducted.The results showed that the asymmetric-cryorolled alloy achieved a high strength of over 1.6 GPa.After annealing at 1073 K,it retained a high strength of~1 GPa while the elongation reached nearly 60%.After annealing,the heterogeneous characteristics were formed in asymmetric-cryorolled samples,which were found to be more distinct than those of the samples subjected to asymmetric rolling.This resulted in the generation of high strength and ductility.展开更多
The influence of soaking time in deep cryogenic treatment on the tensile and impact properties of low-alloy medium-carbon HY-TUF steel was investigated in this study. Microstructural studies based on phase distributio...The influence of soaking time in deep cryogenic treatment on the tensile and impact properties of low-alloy medium-carbon HY-TUF steel was investigated in this study. Microstructural studies based on phase distribution mapping by electron backscatter diffraction show that the deep cryogenic process causes a decrease in the content of retained austenite and an increase in the volume fraction of η-carbide with increasing soaking time up to 48 h. The decrease in the content of retained austenite from ~1.23vol% to 0.48vol% suggests an isothermal martensitic transformation at 77 K. The η-type precipitates formed in deep cryogenic-treated martensite over 48 h have the Hirotsu and Nagakura orientation relation with the martensitic matrix. Furthermore, a high coherency between η-carbide and the martensitic matrix is observed by high-resolution transmission electron microscopy. The variations in macrohardness, yield strength, ultimate tensile strength, and ductility with soaking time in the deep cryogenic process show a peak/plateau trend.展开更多
The mechanism of beneficiation with air dense fluidized bed has been theoretically studied in the paper. Focusing attention on the misplacing resources in separation process, the misplacing effects are divided into t...The mechanism of beneficiation with air dense fluidized bed has been theoretically studied in the paper. Focusing attention on the misplacing resources in separation process, the misplacing effects are divided into two parts called respectively as misplacing effect of viscosity and misplacing effect of motion. The proposed separation theory can reasonably explain the results of separation in different fluidization states. Experimental results in pilot and commercial plants showed that the air dense medium fluidized bed is a high efficiency dry cleaning technique. The dynamic stability of fluidized bed density is directly affected by the variation of fine coal content in fluidized bed and can be controlled in expected range through measurement of fluidized bed density and adjusting of split flow rate. With air dense medium fluidized bed, various coals of size 50—6 mm can be efficiently beneficiated. The separation density can be adjusted between 1.2—2.2 g/cm 3, and the probable error E p value is about 0.06.展开更多
The slope stability of Ya’an expressway in Sichuan dominated by mudstone strata,is influenced greatly by both the mechanical properties and stressstrain relationship of mudstone.In this paper,the mechanical propertie...The slope stability of Ya’an expressway in Sichuan dominated by mudstone strata,is influenced greatly by both the mechanical properties and stressstrain relationship of mudstone.In this paper,the mechanical properties of the Ya’an mudstone samples under triaxial compression conditions were studied,based on an established constitutive model under the framework of breakage mechanics to simulate the mechanical properties of mudstone.Firstly,triaxial compression tests and SEM tests at the confining pressures of 0.5 MPa,1.0 MPa,and 2.0 MPa were carried out on the mudstone samples,and it was found that the mudstone sample undergoes strain softening and dilatancy followed by the volumetric compaction.Then,based on analysis on the breakage mechanism of the above test results,we idealized the mudstone sample as a binary medium material consisting of the bonded elements and frictional elements,of which the bonded elements are composed of solid matrix and pores,and the frictional elements are composed of broken aggregates.During the loading process,the cementation between clay minerals and non-clay minerals in the mudstone sample is first destroyed,leading to the formation of micro-cracks within the particle aggregate,that is,the bonded elements are gradually damaged during the loading process and gradually turned into the frictional elements,and the two jointly bear the external load.The bonded elements are composed of mudstone matrix and pores,which have the cementitious characteristics of mudstone,and the frictional elements are composed of the broken aggregate with the frictional characteristics of the broken particles.Based on the homogenization theory,the constitutive model for the mudstone is established,and the determining method for model parameters is also given.Finally,the results of the triaxial compression tests of the mudstone samples are predicted by the constitutive model proposed here,which can reflect the main mechanical properties of the mudstone samples.展开更多
We studied the effects of nanoparticles of organo-silane（NOS） compounds in the size range of20–80 nm on physical and mechanical properties in medium density fiberboard,and used NOS at four consumption levels of 0,5...We studied the effects of nanoparticles of organo-silane（NOS） compounds in the size range of20–80 nm on physical and mechanical properties in medium density fiberboard,and used NOS at four consumption levels of 0,50,100,and 150 g kg-1dry wood fibers.Density of all treatments was kept constant at 0.67 g cm-3.The water-repellent property of organo-silane significantly reduced water absorption（WA） and thickness swelling but mechanical properties declined due to the reduced proportion of wood-fiber as organo-silane was added to the matrix：the compression ratio of MDF panels and the integrity among wood-fibers both declined,resulting in reduced mechanical properties.We recommend use of 50 g of NOS/kg wood-fiber to improve WA and thickness swelling while retaining acceptable mechanical properties.展开更多
As a necessary factor for a successful business,entrepreneurial spirit is an important means for enterprises to survive in the unstable environment of fierce competition. Under the circumstance of mass entrepreneurshi...As a necessary factor for a successful business,entrepreneurial spirit is an important means for enterprises to survive in the unstable environment of fierce competition. Under the circumstance of mass entrepreneurship and innovation,a large number of small and medium-sized private enterprises have emerged in all walks of life in China. This paper examines the differences in the definition of entrepreneurial spirit by different scholars,the influence of Chinese entrepreneurship on the development of small and medium-sized private enterprises,the origin of the spirit of private entrepreneurs with Chinese characteristics,and the disadvantages of the spirit of small and medium-sized private entrepreneurs in China. It is necessary to further improve entrepreneurial spirit to contribute to the development of small and medium-sized private enterprises and help China to build the national economic system.展开更多
文摘The small and scattered enterprise pattern in the county economy has formed numerous sporadic pollution sources, hindering the centralized treatment of the water environment, increasing the cost and difficulty of treatment. How enterprises can make reasonable decisions on their water environment behavior based on the external environment and their own factors is of great significance for scientifically and effectively designing water environment regulation mechanisms. Based on optimal control theory, this study investigates the design of contractual mechanisms for water environmental regulation for small and medium-sized enterprises. The enterprise is regarded as an independent economic entity that can adopt optimal control strategies to maximize its own interests. Based on the participation of multiple subjects including the government, enterprises, and the public, an optimal control strategy model for enterprises under contractual water environmental regulation is constructed using optimal control theory, and a method for calculating the amount of unit pollutant penalties is derived. The water pollutant treatment cost data of a paper company is selected to conduct empirical numerical analysis on the model. The results show that the increase in the probability of government regulation and public participation, as well as the decrease in local government protection for enterprises, can achieve the same regulatory effect while reducing the number of administrative penalties per unit. Finally, the implementation process of contractual water environmental regulation for small and medium-sized enterprises is designed.
基金the National Natural Science Foundation of China(52272022)Key Program of Natural Science Foundation of Hubei Province(2021CFA071).
文摘Alumina-magnesia dry materials are widely used in induction furnace linings, but they show different kinds of damage when melting different kinds of alloy steel. In this paper, the chemical composition, phase composition, and microstructure of the post-use dry materials for the working liners melting different kinds of steel were evaluated. Furthermore, the corrosion mechanism of the steel on the furnace lining materials was comprehensively analyzed. The findings reveal a significant ability of the Mn element in the molten steel to diffuse and penetrate into the refractories. Mn oxidizes to form MnO at the steel-refractory interface, and then forms a liquid phase with Al_(2)O_(3). The Cr element is dissolved into corundum and spinel of the refractories, resulting in lattice defects and structural damage of the materials. TiO2reacts with Al_(2)O_(3) to form Al_(2)TiO_(5), which plays a crucial role in preventing crack formation and propagation. Part of Ti4+dissolves into magnesia-alumina(MA), densifying the materials. TiO2also slows down the reaction between the Cr element and refractory components, further improving the corrosion resistance of the materials.
基金The authors would like to thanks Brasmetal Waeholtz for providing the material samples for the tests GMSIE- POLI/USP for the tensile test machine and CAPES for the scholarship of SPT provided for the development of this study.
文摘This paper presents the ductility characterization for a medium carbon steel, for two microstructural conditions, that has been evaluated using the continuum damage mechanics theory, as proposed by Kachanov and developed by Lemaitre. Tensile tests were carried out using loading-unloading cycles in order to capture the gradual deterioration of the elastic modulus, which may be linked to the ductile damage increase with increasing plastic strain. The mechanical parameters for the isotropic damage evolution equation were obtained and then used as inputs for a plasticity-damage coupled nu- merical algorithm, validated through numerical simulations of the experimental tensile tests. A comparison between the SAE 1050 steels studied and two carbon steel alloys (obtained from the literature), provided some basic understanding of the influence of the carbon level on the evolution of the damage parameters. An empiric relationship for this set of parameters, which can provide useful data for preliminary studies envisaging prediction of ductile failure in carbon steels, is also presented.
基金Project(51671217)supported by the National Natural Science Foundation of ChinaProject(2016YFB0700302)supported by the National Key Research and Development Plan of China。
文摘For developing new binder phase with high performance, Co-Ni-Fe alloy was used as binder in cemented carbides. The mechanical properties of WC-CoNiFe and WC-Co cemented carbides with different grain sizes were studied. The results show that the reprecipitation of WC-CoNiFe is inhibited compared with that of WC-Co during sintering process, and the grains in WC-CoNiFe cemented carbides are more of smooth shape, resulting in a slightly lower hardness and higher transverse rupture strength. With the increase of the grain size, the hardness of the two cemented carbides decreases, and the transverse rupture strength increases. However, the slope values of K in Hall-Petch relationship are higher in WC-CoNiFe than those in WC-Co, indicating the high toughness of medium entropy alloy Co-Ni-Fe.
基金supported by the Hunan High-Tech Industry Science and Technology Innovation Leading Plan,China(No.2020GK2032)the Huxiang High-Level Talent Gathering Project of Hunan Province,China(No.2018RS3015)+1 种基金the Innovation Driven Program of Central South University,China(No.2019CX006)the Research Fund of the Key Laboratory of High Performance Complex Manufacturing at Central South University,China。
文摘In order to obtain good strength−plasticity synergy for a medium entropy alloy(MEA)CrCoNi,cold rolling,asymmetric rolling,cryorolling and asymmetric-cryorolling with subsequent annealing at different temperatures were conducted.The results showed that the asymmetric-cryorolled alloy achieved a high strength of over 1.6 GPa.After annealing at 1073 K,it retained a high strength of~1 GPa while the elongation reached nearly 60%.After annealing,the heterogeneous characteristics were formed in asymmetric-cryorolled samples,which were found to be more distinct than those of the samples subjected to asymmetric rolling.This resulted in the generation of high strength and ductility.
文摘The influence of soaking time in deep cryogenic treatment on the tensile and impact properties of low-alloy medium-carbon HY-TUF steel was investigated in this study. Microstructural studies based on phase distribution mapping by electron backscatter diffraction show that the deep cryogenic process causes a decrease in the content of retained austenite and an increase in the volume fraction of η-carbide with increasing soaking time up to 48 h. The decrease in the content of retained austenite from ~1.23vol% to 0.48vol% suggests an isothermal martensitic transformation at 77 K. The η-type precipitates formed in deep cryogenic-treated martensite over 48 h have the Hirotsu and Nagakura orientation relation with the martensitic matrix. Furthermore, a high coherency between η-carbide and the martensitic matrix is observed by high-resolution transmission electron microscopy. The variations in macrohardness, yield strength, ultimate tensile strength, and ductility with soaking time in the deep cryogenic process show a peak/plateau trend.
文摘The mechanism of beneficiation with air dense fluidized bed has been theoretically studied in the paper. Focusing attention on the misplacing resources in separation process, the misplacing effects are divided into two parts called respectively as misplacing effect of viscosity and misplacing effect of motion. The proposed separation theory can reasonably explain the results of separation in different fluidization states. Experimental results in pilot and commercial plants showed that the air dense medium fluidized bed is a high efficiency dry cleaning technique. The dynamic stability of fluidized bed density is directly affected by the variation of fine coal content in fluidized bed and can be controlled in expected range through measurement of fluidized bed density and adjusting of split flow rate. With air dense medium fluidized bed, various coals of size 50—6 mm can be efficiently beneficiated. The separation density can be adjusted between 1.2—2.2 g/cm 3, and the probable error E p value is about 0.06.
基金supported by Highway Planning,Survey and Design Research Institute,Sichuan Provincial Transport Department(Grant No.2020WX-15)the funding of National Natural Science Foundation of China(NSFC)(Grant No.U22A20596)。
文摘The slope stability of Ya’an expressway in Sichuan dominated by mudstone strata,is influenced greatly by both the mechanical properties and stressstrain relationship of mudstone.In this paper,the mechanical properties of the Ya’an mudstone samples under triaxial compression conditions were studied,based on an established constitutive model under the framework of breakage mechanics to simulate the mechanical properties of mudstone.Firstly,triaxial compression tests and SEM tests at the confining pressures of 0.5 MPa,1.0 MPa,and 2.0 MPa were carried out on the mudstone samples,and it was found that the mudstone sample undergoes strain softening and dilatancy followed by the volumetric compaction.Then,based on analysis on the breakage mechanism of the above test results,we idealized the mudstone sample as a binary medium material consisting of the bonded elements and frictional elements,of which the bonded elements are composed of solid matrix and pores,and the frictional elements are composed of broken aggregates.During the loading process,the cementation between clay minerals and non-clay minerals in the mudstone sample is first destroyed,leading to the formation of micro-cracks within the particle aggregate,that is,the bonded elements are gradually damaged during the loading process and gradually turned into the frictional elements,and the two jointly bear the external load.The bonded elements are composed of mudstone matrix and pores,which have the cementitious characteristics of mudstone,and the frictional elements are composed of the broken aggregate with the frictional characteristics of the broken particles.Based on the homogenization theory,the constitutive model for the mudstone is established,and the determining method for model parameters is also given.Finally,the results of the triaxial compression tests of the mudstone samples are predicted by the constitutive model proposed here,which can reflect the main mechanical properties of the mudstone samples.
基金conducted as a joint research projectfinanced by SRTTU(Iran)UPM(Malaysia)
文摘We studied the effects of nanoparticles of organo-silane（NOS） compounds in the size range of20–80 nm on physical and mechanical properties in medium density fiberboard,and used NOS at four consumption levels of 0,50,100,and 150 g kg-1dry wood fibers.Density of all treatments was kept constant at 0.67 g cm-3.The water-repellent property of organo-silane significantly reduced water absorption（WA） and thickness swelling but mechanical properties declined due to the reduced proportion of wood-fiber as organo-silane was added to the matrix：the compression ratio of MDF panels and the integrity among wood-fibers both declined,resulting in reduced mechanical properties.We recommend use of 50 g of NOS/kg wood-fiber to improve WA and thickness swelling while retaining acceptable mechanical properties.
基金Supported by Special Youth Project"A Comparative Study on the Cultivation Mode of Innovative Entrepreneurship Talents in China and South Korea"(120-1452226)
文摘As a necessary factor for a successful business,entrepreneurial spirit is an important means for enterprises to survive in the unstable environment of fierce competition. Under the circumstance of mass entrepreneurship and innovation,a large number of small and medium-sized private enterprises have emerged in all walks of life in China. This paper examines the differences in the definition of entrepreneurial spirit by different scholars,the influence of Chinese entrepreneurship on the development of small and medium-sized private enterprises,the origin of the spirit of private entrepreneurs with Chinese characteristics,and the disadvantages of the spirit of small and medium-sized private entrepreneurs in China. It is necessary to further improve entrepreneurial spirit to contribute to the development of small and medium-sized private enterprises and help China to build the national economic system.
基金the financial supports from the National Natural Science Foundation of China (No. 52103360)the Basic and Applied Basic Research Foundation of Guangdong Province, China (No. 2020A1515111104)+1 种基金the Key-Area Research and Development Program of Guangdong Province (No. 2018B090905002)the technical support of Sinoma Institute of Materials Research (Guangzhou) Co., Ltd. (China)。
