The enlarged production scale of underground non-ferrous metal mines is affected by many uncertain factors difficult to describe mathematically with any level of accuracy.The problem can be solved by a synthesis of ar...The enlarged production scale of underground non-ferrous metal mines is affected by many uncertain factors difficult to describe mathematically with any level of accuracy.The problem can be solved by a synthesis of artificial intelligence.Based on the analysis of the major factors affecting the scale of enlarged production,we first interpreted in detail the design principles and structure of the intelligent system.Secondly,we introduced an ANN subsystem.In order to ensure technological and scale efficien- cies of the training samples for ANN,we filtrated the samples with a DEA method.Finally,we trained the intelligent system,which was proved to be very efficient.展开更多
Spectral analysis was a method of identifying substances, determining their chemical composition and calculating their content based on their spectral characteristics. This paper mainly discussed the application of va...Spectral analysis was a method of identifying substances, determining their chemical composition and calculating their content based on their spectral characteristics. This paper mainly discussed the application of various spectroscopic techniques, mainly including atomic absorption spectrometry (AAS) inductively coupled plasma emission spectrometry (ICP-AES) X-ray fluorescence spectroscopy (XRF) atomic fluorescence spectroscopy (AFS) direct reading spectroscopy (OES) glow discharge emission spectroscopy (GD-OSE) laser-induced breakdown spectroscopy (LIBS), in the formulation of non-ferrous metal standards in China. The AAS method was the most widely used single-element microanalysis method among the non-ferrous metal standards. The ICP-AES method was good at significant advantages in the simultaneous detection of multiple elements. The XRF method was increasingly used in the determination of primary and secondary trace elements due to its simple sample preparation and high efficiency. The AFS was mostly detected by single-element trace analysis. OES GD-OES and LIBS were playing an increasingly important role in the new demand area for non-ferrous metals. This paper discussed matrix elimination, sample digestion, sample preparation, instrument categories and other aspects of some standards, and summarized the advantages of spectral analysis and traditional chemical analysis methods. The new methods of future spectroscopic technology had been illustrated in the process of developing non-ferrous metal standards.展开更多
To acquire non-ferrous metals related news from different countries’internet,we proposed a cross-lingual non-ferrous metals related news recognition method based on CNN with a limited bilingual dictionary.Firstly,con...To acquire non-ferrous metals related news from different countries’internet,we proposed a cross-lingual non-ferrous metals related news recognition method based on CNN with a limited bilingual dictionary.Firstly,considering the lack of related language resources of non-ferrous metals,we use a limited bilingual dictionary and CCA to learn cross-lingual word vector and to represent news in different languages uniformly.Then,to improve the effect of recognition,we use a variant of the CNN to learn recognition features and construct the recognition model.The experimental results show that our proposed method acquires better results.展开更多
The bottom ashes resulted annually from the incineration of municipal solid waste in Europe contain about 400,000 tonnes of metallic aluminium and 200,000 tonnes of heavy non-ferrous metals, such as copper and zinc. E...The bottom ashes resulted annually from the incineration of municipal solid waste in Europe contain about 400,000 tonnes of metallic aluminium and 200,000 tonnes of heavy non-ferrous metals, such as copper and zinc. Efficient recovery of this non-ferrous metal resource requires state-of-the-art separation technologies and a continuous feedback of laboratory analyses of the metal products and the depleted bottom ash to the operators of the bottom ash treatment plants. A methodology is presented for the optimization of the production of non-ferrous metal value from Municipal Solid Waste Incinerator bottom ash. Results for an incineration plant in the Netherlands show that efficient recycling can have a significant impact on value recovery as well as on non-ferrous metal recycling rates, producing up to 8% more revenue and 25% more metals from the ash.展开更多
Transition metal phosphides(TMPs)have been regarded as alternative hydrogen evolution reaction(HER)and oxygen evolution reaction(OER)catalysts owing to their comparable activity to those of noble metal-based catalysts...Transition metal phosphides(TMPs)have been regarded as alternative hydrogen evolution reaction(HER)and oxygen evolution reaction(OER)catalysts owing to their comparable activity to those of noble metal-based catalysts.TMPs have been produced in various morphologies,including hollow and porous nanostructures,which are features deemed desirable for electrocatalytic materials.Templated synthesis routes are often responsible for such morphologies.This paper reviews the latest advances and existing challenges in the synthesis of TMP-based OER and HER catalysts through templated methods.A comprehensive review of the structure-property-performance of TMP-based HER and OER catalysts prepared using different templates is presented.The discussion proceeds according to application,first by HER and further divided among the types of templates used-from hard templates,sacrificial templates,and soft templates to the emerging dynamic hydrogen bubble template.OER catalysts are then reviewed and grouped according to their morphology.Finally,prospective research directions for the synthesis of hollow and porous TMP-based catalysts,such as improvements on both activity and stability of TMPs,design of environmentally benign templates and processes,and analysis of the reaction mechanism through advanced material characterization techniques and theoretical calculations,are suggested.展开更多
The metal-organic framework(MOF)derived Ni–Co–C–N composite alloys(NiCCZ)were“embedded”inside the carbon cloth(CC)strands as opposed to the popular idea of growing them upward to realize ultrastable energy storag...The metal-organic framework(MOF)derived Ni–Co–C–N composite alloys(NiCCZ)were“embedded”inside the carbon cloth(CC)strands as opposed to the popular idea of growing them upward to realize ultrastable energy storage and conversion application.The NiCCZ was then oxygen functionalized,facilitating the next step of stoichiometric sulfur anion diffusion during hydrothermal sulfurization,generating a flower-like metal hydroxysulfide structure(NiCCZOS)with strong partial implantation inside CC.Thus obtained NiCCZOS shows an excellent capacity when tested as a supercapacitor electrode in a three-electrode configuration.Moreover,when paired with the biomass-derived nitrogen-rich activated carbon,the asymmetric supercapacitor device shows almost 100%capacity retention even after 45,000 charge–discharge cycles with remarkable energy density(59.4 Wh kg^(-1)/263.8μWh cm^(–2))owing to a uniquely designed cathode.Furthermore,the same electrode performed as an excellent bifunctional water-splitting electrocatalyst with an overpotential of 271 mV for oxygen evolution reaction(OER)and 168.4 mV for hydrogen evolution reaction(HER)at 10 mA cm−2 current density along with 30 h of unhinged chronopotentiometric stability performance for both HER and OER.Hence,a unique metal chalcogenide composite electrode/substrate configuration has been proposed as a highly stable electrode material for flexible energy storage and conversion applications.展开更多
Supercapacitors(SCs)are considered promising energy storge systems because of their outstanding power density,fast charge and discharge rate and long-term cycling stability.The exploitation of cheap and efficient elec...Supercapacitors(SCs)are considered promising energy storge systems because of their outstanding power density,fast charge and discharge rate and long-term cycling stability.The exploitation of cheap and efficient electrode materials is the key to improve the performance of supercapacitors.As the battery-type materials,transition metal phosphides(TMPs)possess high theoretical specific capacity,good electrical conductivity and superior structural stability,which have been extensively studied to be electrode materials for supercapacitors.In this review,we summarize the up-to-date progress on TMPs materials from diversified synthetic methods,diverse nanostructures and several prominent TMPs and their composites in application of supercapacitors.In the end,we also propose the remaining challenges toward the rational discovery and synthesis of high-performance TMP electrodes materials for energy storage.展开更多
The geopolymer samples were prepared with smelting waste slag of non-ferrous metal as the raw material and water glass as the activator. The effect of modulus of water glass and water binder ratio on the compressive s...The geopolymer samples were prepared with smelting waste slag of non-ferrous metal as the raw material and water glass as the activator. The effect of modulus of water glass and water binder ratio on the compressive strength was studied. The results show that the strength of the geopolymer activated by water glass with modulus of 1.1 and water binder ratio of 0.28 can maintain an increasing trend in the 90 curing days. Through the analyses with XRD, SEM(EDS), and FTIR, the main reaction products are found to be geopolymer gels, which bond the crystalline minerals to provide strength. The molecular chains of amorphous phase in slag become shorter after depolymerization-polycondensation.展开更多
The Rare Earths Research Institute(the former Rare Earths Research Laboratory)under the GRINM,the first institute to conduct R&D for rare earths(RE)industry in China,was founded in 1958.The Institutewas mainly eng...The Rare Earths Research Institute(the former Rare Earths Research Laboratory)under the GRINM,the first institute to conduct R&D for rare earths(RE)industry in China,was founded in 1958.The Institutewas mainly engaged in the research work of comprehensive utilization of the mine at Baiyun-ebo,the largest展开更多
The Rare Earths Research Institute(the former Rare Earths Research Laboratory)under the GRINM,the first institute to conduct R&D for rare earths(RE)industry in China,was founded in 1958.The Institutewas mainly eng...The Rare Earths Research Institute(the former Rare Earths Research Laboratory)under the GRINM,the first institute to conduct R&D for rare earths(RE)industry in China,was founded in 1958.The Institutewas mainly engaged in the research work of comprehensive utilization of the mine at Baiyun-ebo,the largestRE mine in the world,and the ion adsorption type RE mineral in southern China.The ore decomposition,展开更多
Improving the long-term cycling stability and energy density of all-solid-state lithium(Li)-metal batteries(ASSLMBs)at room temperature is a severe challenge because of the notorious solid–solid interfacial contact l...Improving the long-term cycling stability and energy density of all-solid-state lithium(Li)-metal batteries(ASSLMBs)at room temperature is a severe challenge because of the notorious solid–solid interfacial contact loss and sluggish ion transport.Solid electrolytes are generally studied as two-dimensional(2D)structures with planar interfaces,showing limited interfacial contact and further resulting in unstable Li/electrolyte and cathode/electrolyte interfaces.Herein,three-dimensional(3D)architecturally designed composite solid electrolytes are developed with independently controlled structural factors using 3D printing processing and post-curing treatment.Multiple-type electrolyte films with vertical-aligned micro-pillar(p-3DSE)and spiral(s-3DSE)structures are rationally designed and developed,which can be employed for both Li metal anode and cathode in terms of accelerating the Li+transport within electrodes and reinforcing the interfacial adhesion.The printed p-3DSE delivers robust long-term cycle life of up to 2600 cycles and a high critical current density of 1.92 mA cm^(−2).The optimized electrolyte structure could lead to ASSLMBs with a superior full-cell areal capacity of 2.75 mAh cm^(−2)(LFP)and 3.92 mAh cm^(−2)(NCM811).This unique design provides enhancements for both anode and cathode electrodes,thereby alleviating interfacial degradation induced by dendrite growth and contact loss.The approach in this study opens a new design strategy for advanced composite solid polymer electrolytes in ASSLMBs operating under high rates/capacities and room temperature.展开更多
The concentration difference in the near-surface region of lithium metal is the main cause of lithium dendrite growth.Resolving this issue will be key to achieving high-performance lithium metal batteries(LMBs).Herein...The concentration difference in the near-surface region of lithium metal is the main cause of lithium dendrite growth.Resolving this issue will be key to achieving high-performance lithium metal batteries(LMBs).Herein,we construct a lithium nitrate(LiNO_(3))-implanted electroactiveβphase polyvinylidene fluoride-co-hexafluoropropylene(PVDF-HFP)crystalline polymorph layer(PHL).The electronegatively charged polymer chains attain lithium ions on the surface to form lithium-ion charged channels.These channels act as reservoirs to sustainably release Li ions to recompense the ionic flux of electrolytes,decreasing the growth of lithium dendrites.The stretched molecular channels can also accelerate the transport of Li ions.The combined effects enable a high Coulombic efficiency of 97.0%for 250 cycles in lithium(Li)||copper(Cu)cell and a stable symmetric plating/stripping behavior over 2000 h at 3 mA cm^(-2)with ultrahigh Li utilization of 50%.Furthermore,the full cell coupled with PHL-Cu@Li anode and Li Fe PO_(4) cathode exhibits long-term cycle stability with high-capacity retention of 95.9%after 900 cycles.Impressively,the full cell paired with LiNi_(0.87)Co_(0.1)Mn_(0.03)O_(2)maintains a discharge capacity of 170.0 mAh g^(-1)with a capacity retention of 84.3%after 100 cycles even under harsh condition of ultralow N/P ratio of 0.83.This facile strategy will widen the potential application of LiNO_(3)in ester-based electrolyte for practical high-voltage LMBs.展开更多
In the last ten years (1982~1991) 2.26 Mt of 10 kinds of nonferrous metals had been pro-duced in Hunan Province. Up to date the mining capacity achieves 6.52 Mt, ore-dressing capacity--7.25 Mt, smelt capacity--334 kt...In the last ten years (1982~1991) 2.26 Mt of 10 kinds of nonferrous metals had been pro-duced in Hunan Province. Up to date the mining capacity achieves 6.52 Mt, ore-dressing capacity--7.25 Mt, smelt capacity--334 kt and the processing capacity--113 kt. In 1991 the output of10 kinds of nonferrous metals amounted to 292.8 kt. At present Hunan Province produces alloys,oxides and other compounds for copper, aluminium, lead, zinc, antimony and mercury. Species ofrare-earth metals and its alloys produced in Hunan Province amount to 160 and more. In this展开更多
According to the Ninth Five-year Plan and 2010 Long-term Goal Program, the non-ferrous metal industry will focus on revamping and expanding its existing enterprises. Through systematic technical renovation, the indust...According to the Ninth Five-year Plan and 2010 Long-term Goal Program, the non-ferrous metal industry will focus on revamping and expanding its existing enterprises. Through systematic technical renovation, the industry will expand production capability, increase varieties, improve the recovery of waste metals, and do a good job of展开更多
China’s non-ferrous metals industry has constantly maintained a steady, rapid and healthy development since the reform and opening to the outside world. By the end of 1994, the annual output often kinds of common non...China’s non-ferrous metals industry has constantly maintained a steady, rapid and healthy development since the reform and opening to the outside world. By the end of 1994, the annual output often kinds of common non-ferrous metals such as copper, aluminium, lead, and zinc had reached 3.701 million tons, a 12.2 percent increase over the previous year; the qualification rate of principal products and the output value rate of good quality products all achieved an increase over the previous year. China has展开更多
Since its founding in April 1983, the China National Non-ferrous Metal Industrial Corporation has developed into a giant enterprise group engaged in the production of non-ferrous metal mineral products, smelting produ...Since its founding in April 1983, the China National Non-ferrous Metal Industrial Corporation has developed into a giant enterprise group engaged in the production of non-ferrous metal mineral products, smelting products, processing products and recovery products, as well as geological prospecting, engineering survey, design, construction, equipment manufacture, the research and development of hi-tech prod-展开更多
Since the China Non-Ferrous Metal Industry Corporation was founded, it has always adhered to the development principle of "Science and technology are a production force" and "Economic construction must ...Since the China Non-Ferrous Metal Industry Corporation was founded, it has always adhered to the development principle of "Science and technology are a production force" and "Economic construction must rely on science and technology progress and science and technology must serve economic construction in return" to enhance the reform in the scientific research system. With support from the State and展开更多
In the city Guangyuan,sited in the north of Sichuan Province,the Guangyuan Non-ferrousMetal Company had been established recently.The city plans to enter the non-ferrous metal indus-try in a list of key enterprises an...In the city Guangyuan,sited in the north of Sichuan Province,the Guangyuan Non-ferrousMetal Company had been established recently.The city plans to enter the non-ferrous metal indus-try in a list of key enterprises and to develop aluminium,lead and gold mainly.Some middle-scaleenterprices have been established,for example;Wuzhou Aluminium-electrolysis plant,Jialing展开更多
Vice president of China National Nonferrous Metals Industries Corporation Mr. WoTingshu said:"The output of 10 kinds of nonferrous metals amounted to 2.45 Mt." This factmean1s that the national plan for nonf...Vice president of China National Nonferrous Metals Industries Corporation Mr. WoTingshu said:"The output of 10 kinds of nonferrous metals amounted to 2.45 Mt." This factmean1s that the national plan for nonferrous metals production fulfiled earlier. The 10 kinds ofnonferrous metals are aluminium, magnesium, lead, zinc, copper, tin, nickel, antimony mercuryand titanium.展开更多
基金Project 50374005 supported by the National Natural Science Foundation of China
文摘The enlarged production scale of underground non-ferrous metal mines is affected by many uncertain factors difficult to describe mathematically with any level of accuracy.The problem can be solved by a synthesis of artificial intelligence.Based on the analysis of the major factors affecting the scale of enlarged production,we first interpreted in detail the design principles and structure of the intelligent system.Secondly,we introduced an ANN subsystem.In order to ensure technological and scale efficien- cies of the training samples for ANN,we filtrated the samples with a DEA method.Finally,we trained the intelligent system,which was proved to be very efficient.
文摘Spectral analysis was a method of identifying substances, determining their chemical composition and calculating their content based on their spectral characteristics. This paper mainly discussed the application of various spectroscopic techniques, mainly including atomic absorption spectrometry (AAS) inductively coupled plasma emission spectrometry (ICP-AES) X-ray fluorescence spectroscopy (XRF) atomic fluorescence spectroscopy (AFS) direct reading spectroscopy (OES) glow discharge emission spectroscopy (GD-OSE) laser-induced breakdown spectroscopy (LIBS), in the formulation of non-ferrous metal standards in China. The AAS method was the most widely used single-element microanalysis method among the non-ferrous metal standards. The ICP-AES method was good at significant advantages in the simultaneous detection of multiple elements. The XRF method was increasingly used in the determination of primary and secondary trace elements due to its simple sample preparation and high efficiency. The AFS was mostly detected by single-element trace analysis. OES GD-OES and LIBS were playing an increasingly important role in the new demand area for non-ferrous metals. This paper discussed matrix elimination, sample digestion, sample preparation, instrument categories and other aspects of some standards, and summarized the advantages of spectral analysis and traditional chemical analysis methods. The new methods of future spectroscopic technology had been illustrated in the process of developing non-ferrous metal standards.
基金The Major Technologies R&D Special Program of Anhui,China(Grant No.16030901060)The National Natural Science Foundation of China(Grant No.61502010)+1 种基金The Natural Science Foundation of Anhui Province(Grant No.1608085QF146)The Natural Science Foundation of China(Grant No.61806004).
文摘To acquire non-ferrous metals related news from different countries’internet,we proposed a cross-lingual non-ferrous metals related news recognition method based on CNN with a limited bilingual dictionary.Firstly,considering the lack of related language resources of non-ferrous metals,we use a limited bilingual dictionary and CCA to learn cross-lingual word vector and to represent news in different languages uniformly.Then,to improve the effect of recognition,we use a variant of the CNN to learn recognition features and construct the recognition model.The experimental results show that our proposed method acquires better results.
文摘The bottom ashes resulted annually from the incineration of municipal solid waste in Europe contain about 400,000 tonnes of metallic aluminium and 200,000 tonnes of heavy non-ferrous metals, such as copper and zinc. Efficient recovery of this non-ferrous metal resource requires state-of-the-art separation technologies and a continuous feedback of laboratory analyses of the metal products and the depleted bottom ash to the operators of the bottom ash treatment plants. A methodology is presented for the optimization of the production of non-ferrous metal value from Municipal Solid Waste Incinerator bottom ash. Results for an incineration plant in the Netherlands show that efficient recycling can have a significant impact on value recovery as well as on non-ferrous metal recycling rates, producing up to 8% more revenue and 25% more metals from the ash.
基金the support from the CIPHER Project(IIID 2018-008)funded by the Commission on Higher Education-Philippine California Advanced Research Institutes(CHED-PCARI)。
文摘Transition metal phosphides(TMPs)have been regarded as alternative hydrogen evolution reaction(HER)and oxygen evolution reaction(OER)catalysts owing to their comparable activity to those of noble metal-based catalysts.TMPs have been produced in various morphologies,including hollow and porous nanostructures,which are features deemed desirable for electrocatalytic materials.Templated synthesis routes are often responsible for such morphologies.This paper reviews the latest advances and existing challenges in the synthesis of TMP-based OER and HER catalysts through templated methods.A comprehensive review of the structure-property-performance of TMP-based HER and OER catalysts prepared using different templates is presented.The discussion proceeds according to application,first by HER and further divided among the types of templates used-from hard templates,sacrificial templates,and soft templates to the emerging dynamic hydrogen bubble template.OER catalysts are then reviewed and grouped according to their morphology.Finally,prospective research directions for the synthesis of hollow and porous TMP-based catalysts,such as improvements on both activity and stability of TMPs,design of environmentally benign templates and processes,and analysis of the reaction mechanism through advanced material characterization techniques and theoretical calculations,are suggested.
基金supported by the Basic Science Research Program through the National Research Foundation of Korea(NRF)grant funded by the Korean government(MSIT)(2021R1A4A2000934).
文摘The metal-organic framework(MOF)derived Ni–Co–C–N composite alloys(NiCCZ)were“embedded”inside the carbon cloth(CC)strands as opposed to the popular idea of growing them upward to realize ultrastable energy storage and conversion application.The NiCCZ was then oxygen functionalized,facilitating the next step of stoichiometric sulfur anion diffusion during hydrothermal sulfurization,generating a flower-like metal hydroxysulfide structure(NiCCZOS)with strong partial implantation inside CC.Thus obtained NiCCZOS shows an excellent capacity when tested as a supercapacitor electrode in a three-electrode configuration.Moreover,when paired with the biomass-derived nitrogen-rich activated carbon,the asymmetric supercapacitor device shows almost 100%capacity retention even after 45,000 charge–discharge cycles with remarkable energy density(59.4 Wh kg^(-1)/263.8μWh cm^(–2))owing to a uniquely designed cathode.Furthermore,the same electrode performed as an excellent bifunctional water-splitting electrocatalyst with an overpotential of 271 mV for oxygen evolution reaction(OER)and 168.4 mV for hydrogen evolution reaction(HER)at 10 mA cm−2 current density along with 30 h of unhinged chronopotentiometric stability performance for both HER and OER.Hence,a unique metal chalcogenide composite electrode/substrate configuration has been proposed as a highly stable electrode material for flexible energy storage and conversion applications.
基金supported by National Undergraduate Training Programs for Innovations[grant number 202210225259]the Outstanding Youth Project of Natural Science Foundation in Heilongjiang Province(YQ2022E040)+3 种基金the Shandong Provincial Natural Science Foundation(ZR2022ME166)the Postdoctoral Scientific Research Developmental Fund of Heilongjiang Province(LBH-Q20023)the University Nursing Program for Young Scholars with Creative Talents in Heilongjiang Province(UNPYSCT-2020197)the 111 Project(B20088).
文摘Supercapacitors(SCs)are considered promising energy storge systems because of their outstanding power density,fast charge and discharge rate and long-term cycling stability.The exploitation of cheap and efficient electrode materials is the key to improve the performance of supercapacitors.As the battery-type materials,transition metal phosphides(TMPs)possess high theoretical specific capacity,good electrical conductivity and superior structural stability,which have been extensively studied to be electrode materials for supercapacitors.In this review,we summarize the up-to-date progress on TMPs materials from diversified synthetic methods,diverse nanostructures and several prominent TMPs and their composites in application of supercapacitors.In the end,we also propose the remaining challenges toward the rational discovery and synthesis of high-performance TMP electrodes materials for energy storage.
基金Funded by the Key Project of National Natural Science Foundation of China(No.51472040)
文摘The geopolymer samples were prepared with smelting waste slag of non-ferrous metal as the raw material and water glass as the activator. The effect of modulus of water glass and water binder ratio on the compressive strength was studied. The results show that the strength of the geopolymer activated by water glass with modulus of 1.1 and water binder ratio of 0.28 can maintain an increasing trend in the 90 curing days. Through the analyses with XRD, SEM(EDS), and FTIR, the main reaction products are found to be geopolymer gels, which bond the crystalline minerals to provide strength. The molecular chains of amorphous phase in slag become shorter after depolymerization-polycondensation.
文摘The Rare Earths Research Institute(the former Rare Earths Research Laboratory)under the GRINM,the first institute to conduct R&D for rare earths(RE)industry in China,was founded in 1958.The Institutewas mainly engaged in the research work of comprehensive utilization of the mine at Baiyun-ebo,the largest
文摘The Rare Earths Research Institute(the former Rare Earths Research Laboratory)under the GRINM,the first institute to conduct R&D for rare earths(RE)industry in China,was founded in 1958.The Institutewas mainly engaged in the research work of comprehensive utilization of the mine at Baiyun-ebo,the largestRE mine in the world,and the ion adsorption type RE mineral in southern China.The ore decomposition,
基金This work was financially supported by Stable Support Plan Program for Higher Education Institutions(20220815094504001)Shenzhen Key Laboratory of Advanced Energy Storage(ZDSYS20220401141000001)+1 种基金This work was also financially supported by the Shenzhen Science and Technology Innovation Commission(GJHZ20200731095606021,20200925155544005)the Project of Hetao Shenzhen-Hong Kong Science and Technology Innovation Cooperation Zone(HZQB-KCZYB-2020083)。
文摘Improving the long-term cycling stability and energy density of all-solid-state lithium(Li)-metal batteries(ASSLMBs)at room temperature is a severe challenge because of the notorious solid–solid interfacial contact loss and sluggish ion transport.Solid electrolytes are generally studied as two-dimensional(2D)structures with planar interfaces,showing limited interfacial contact and further resulting in unstable Li/electrolyte and cathode/electrolyte interfaces.Herein,three-dimensional(3D)architecturally designed composite solid electrolytes are developed with independently controlled structural factors using 3D printing processing and post-curing treatment.Multiple-type electrolyte films with vertical-aligned micro-pillar(p-3DSE)and spiral(s-3DSE)structures are rationally designed and developed,which can be employed for both Li metal anode and cathode in terms of accelerating the Li+transport within electrodes and reinforcing the interfacial adhesion.The printed p-3DSE delivers robust long-term cycle life of up to 2600 cycles and a high critical current density of 1.92 mA cm^(−2).The optimized electrolyte structure could lead to ASSLMBs with a superior full-cell areal capacity of 2.75 mAh cm^(−2)(LFP)and 3.92 mAh cm^(−2)(NCM811).This unique design provides enhancements for both anode and cathode electrodes,thereby alleviating interfacial degradation induced by dendrite growth and contact loss.The approach in this study opens a new design strategy for advanced composite solid polymer electrolytes in ASSLMBs operating under high rates/capacities and room temperature.
基金the financial support from the National Natural Science Foundation of China(Nos.22205191 and 52002346)the Science and Technology Innovation Program of Hunan Province(No.2021RC3109)+1 种基金the Natural Science Foundation of Hunan Province,China(No.2022JJ40446)Guangxi Key Laboratory of Low Carbon Energy Material(No.2020GXKLLCEM01)。
文摘The concentration difference in the near-surface region of lithium metal is the main cause of lithium dendrite growth.Resolving this issue will be key to achieving high-performance lithium metal batteries(LMBs).Herein,we construct a lithium nitrate(LiNO_(3))-implanted electroactiveβphase polyvinylidene fluoride-co-hexafluoropropylene(PVDF-HFP)crystalline polymorph layer(PHL).The electronegatively charged polymer chains attain lithium ions on the surface to form lithium-ion charged channels.These channels act as reservoirs to sustainably release Li ions to recompense the ionic flux of electrolytes,decreasing the growth of lithium dendrites.The stretched molecular channels can also accelerate the transport of Li ions.The combined effects enable a high Coulombic efficiency of 97.0%for 250 cycles in lithium(Li)||copper(Cu)cell and a stable symmetric plating/stripping behavior over 2000 h at 3 mA cm^(-2)with ultrahigh Li utilization of 50%.Furthermore,the full cell coupled with PHL-Cu@Li anode and Li Fe PO_(4) cathode exhibits long-term cycle stability with high-capacity retention of 95.9%after 900 cycles.Impressively,the full cell paired with LiNi_(0.87)Co_(0.1)Mn_(0.03)O_(2)maintains a discharge capacity of 170.0 mAh g^(-1)with a capacity retention of 84.3%after 100 cycles even under harsh condition of ultralow N/P ratio of 0.83.This facile strategy will widen the potential application of LiNO_(3)in ester-based electrolyte for practical high-voltage LMBs.
文摘In the last ten years (1982~1991) 2.26 Mt of 10 kinds of nonferrous metals had been pro-duced in Hunan Province. Up to date the mining capacity achieves 6.52 Mt, ore-dressing capacity--7.25 Mt, smelt capacity--334 kt and the processing capacity--113 kt. In 1991 the output of10 kinds of nonferrous metals amounted to 292.8 kt. At present Hunan Province produces alloys,oxides and other compounds for copper, aluminium, lead, zinc, antimony and mercury. Species ofrare-earth metals and its alloys produced in Hunan Province amount to 160 and more. In this
文摘According to the Ninth Five-year Plan and 2010 Long-term Goal Program, the non-ferrous metal industry will focus on revamping and expanding its existing enterprises. Through systematic technical renovation, the industry will expand production capability, increase varieties, improve the recovery of waste metals, and do a good job of
文摘China’s non-ferrous metals industry has constantly maintained a steady, rapid and healthy development since the reform and opening to the outside world. By the end of 1994, the annual output often kinds of common non-ferrous metals such as copper, aluminium, lead, and zinc had reached 3.701 million tons, a 12.2 percent increase over the previous year; the qualification rate of principal products and the output value rate of good quality products all achieved an increase over the previous year. China has
文摘Since its founding in April 1983, the China National Non-ferrous Metal Industrial Corporation has developed into a giant enterprise group engaged in the production of non-ferrous metal mineral products, smelting products, processing products and recovery products, as well as geological prospecting, engineering survey, design, construction, equipment manufacture, the research and development of hi-tech prod-
文摘Since the China Non-Ferrous Metal Industry Corporation was founded, it has always adhered to the development principle of "Science and technology are a production force" and "Economic construction must rely on science and technology progress and science and technology must serve economic construction in return" to enhance the reform in the scientific research system. With support from the State and
文摘In the city Guangyuan,sited in the north of Sichuan Province,the Guangyuan Non-ferrousMetal Company had been established recently.The city plans to enter the non-ferrous metal indus-try in a list of key enterprises and to develop aluminium,lead and gold mainly.Some middle-scaleenterprices have been established,for example;Wuzhou Aluminium-electrolysis plant,Jialing
文摘Vice president of China National Nonferrous Metals Industries Corporation Mr. WoTingshu said:"The output of 10 kinds of nonferrous metals amounted to 2.45 Mt." This factmean1s that the national plan for nonferrous metals production fulfiled earlier. The 10 kinds ofnonferrous metals are aluminium, magnesium, lead, zinc, copper, tin, nickel, antimony mercuryand titanium.