Pollution source identification methods and remediation technologies of groundwater: A review

Groundwater is an important source of drinking water.Groundwater pollution severely endangers drinking water safety and sustainable social development.In the case of groundwater pollution,the top priority is to identify pollution sources,and accurate information on pollution sources is the premise of efficient remediation.Then,an appropriate pollution remediation scheme should be developed according to information on pollution sources,site conditions,and economic costs.The methods for identifying pollution sources mainly include geophysical exploration,geochemistry,isotopic tracing,and numerical modeling.Among these identification methods,only the numerical modeling can recognize various information on pollution sources,while other methods can only identify a certain aspect of pollution sources.The remediation technologies of groundwater can be divided into in-situ and ex-situ remediation technologies according to the remediation location.The in-situ remediation technologies enjoy low costs and a wide remediation range,but their remediation performance is prone to be affected by environmental conditions and cause secondary pollution.The ex-situ remediation technologies boast high remediation efficiency,high processing capacity,and high treatment concentration but suffer high costs.Different methods for pollution source identification and remediation technologies are applicable to different conditions.To achieve the expected identification and remediation results,it is feasible to combine several methods and technologies according to the actual hydrogeological conditions of contaminated sites and the nature of pollutants.Additionally,detailed knowledge about the hydrogeological conditions and stratigraphic structure of the contaminated site is the basis of all work regardless of the adopted identification methods or remediation technologies.

Numerical Simulation of the Settling Flux of Biodeposition in a Bay with Cage Culture Through Similarity Theory and a Simplified Pollution Source

The settling flux of biodeposition affects the environmental quality of cage culture areas and determines their environmental carrying capacity.Simple and effective simulation of the settling flux of biodeposition is extremely important for determining the spatial distribution of biodeposition.Theoretically,biodeposition in cage culture areas without specific emission rules can be simplified as point source pollution.Fluent is a fluid simulation software that can simulate the dispersion of particulate matter simply and efficiently.Based on the simplification of pollution sources and bays,the settling flux of biodeposition can be easily and effectively simulated by Fluent fluid software.In the present work,the feasibility of this method was evaluated by simulation of the settling flux of biodeposition in Maniao Bay,Hainan Province,China,and 20 sampling sites were selected for determining the settling fluxes.At sampling sites P1,P2,P3,P4,P5,Z1,Z2,Z3,Z4,A1,A2,A3,A4,B1,B2,C1,C2,C3 and C4,the measured settling fluxes of biodeposition were 26.02,15.78,10.77,58.16,6.57,72.17,12.37,12.11,106.64,150.96,22.59,11.41,18.03,7.90,19.23,7.06,11.84,5.19 and 2.57 g d^(−1)m^(−2),respectively.The simulated settling fluxes of biodeposition at the corresponding sites were 16.03,23.98,8.87,46.90,4.52,104.77,16.03,8.35,180.83,213.06,39.10,17.47,20.98,9.78,23.25,7.84,15.90,6.06 and 1.65 g d^(−1)m^(−2),respectively.There was a positive correlation between the simulated settling fluxes and measured ones(R=0.94,P=2.22×10^(−9)<0.05),which implies that the spatial differentiation of biodeposition flux was well simulated.Moreover,the posterior difference ratio of the simulation was 0.38,and the small error probability was 0.94,which means that the simulated results reached an acceptable level from the perspective of relative error.Thus,if nonpoint source pollution is simplified to point source pollution and open waters are simplified based on similarity theory,the setting flux of biodeposition in the open waters can be simply and effectively simulated by the fluid simulation software Fluent.

Ecological Remediation Measures for Non-point Source Pollution Based on Source-Sink Landscape Theory: A Case Study of Huanghou Basin

The growth of society and population has led to a range of water pollution issues.Among these,non-point source pollution assessment and treatment pose a particular challenge due to its formation mechanism.This has become a focal point and challenge in water pollution treatment research.The study area for this research was the Huanghou basin in Guizhou Province,southwest China.The land use type of the basin was analyzed using remote sensing technology,and water quality data was collected by distributing points throughout the basin,based on source-sink landscape theory.The distribution map of the basin’s source-sink landscape and the results of water quality data accurately and efficiently identified the areas with high risk of non-point source pollution in the western and southwestern residential and agricultural areas of the upper basin.Hence,a strategy of“increasing sinks and decreasing sources”was proposed.The strategy was implemented at both macro and micro levels to address non-point source pollution in the basin using ecological remediation techniques.The work to control karst rocky desertification should continue at a macro level.The rocky desertification area in the basin should gradually transform into grassland and forested land,while increasing the overall area of the sink landscape.Ecological restoration techniques,such as slope planting,riparian zone vegetation restoration,increasing plant abundance,and restoring aquatic plants,can effectively control non-point source pollution at the micro level.Compared to traditional control methods,this remediation strategy focuses on source and process control.It is more effective and does not require large-scale water pollution control projects,which can save a lot of environmental control funds and management costs.Therefore,it has greater research significance and application value.

Integrating stable isotopes and factor analysis to delineate the groundwater provenance and pollution sources in the northwestern part of the Amman-Al Zarqa Basin, Jordan

Globally,groundwater contamination by nitrate is one of the most widespread environmental problems,particularly in arid and semiarid areas,which are characterized by low amounts of rainfall and groundwater recharge.The stable isotope composition of groundwater(δ2H-H2O andδ18O-H2O)and dissolved nitrate(δ15N-NO3–andδ18O-NO3–)and factor analysis(FA)were applied to explore groundwater provenance,pollution,and chemistry evolution in the northwestern part of the Amman-Al Zarqa Basin,Jordan.In this study,we collected 23 samples from the Lower Ajloun aquifer in 2021,including 1 sample from a groundwater well and 22 samples from springs.These samples were tested for electrical conductivity,total dissolved solids,pH,temperature,dissolved oxygen,the concentration of major ions(Ca2+,Mg2+,Na+,K+,HCO3–,Cl–,SO42–,and NO3–),and the stable isotope composition of groundwater and dissolved nitrate.The results revealed that groundwater in the study area is mainly Ca–Mg–HCO3 type and can be classified as fresh water,hard water,and very hard water.The range and average concentration of NO3–were 3.5–230.8 and 50.9 mg/L,respectively.Approximately 33%of the sampling points showed NO3–levels above the maximum allowable concentration of 50.0 mg/L set by the World Health Organization(WHO)guidelines for drinking water quality.The values ofδ18O-H2O andδ2H-H2O showed that groundwater in the study area is part of the current water cycle,originating in the Mediterranean Sea,with significant evaporation,orographic,and amount effects.The values of the stable isotope composition of NO3–corresponded toδ15N-NO3–andδ18O-NO3–values produced by the nitrification process of manure or septic waste and soil NH4+.The FA performed on the hydrochemical parameters and isotope data resulted in three main factors,with Factor 1,Factor 2,and Factor 3,accounting for 50%,21%,and 11%of the total variance,respectively.Factor 1 was considered human-induced factor,named"pollution factor",whereas Factor 2,named"conservative fingerprint factor",and Factor 3,named"hardness factor",were considered natural factors.This study will help local researchers manage groundwater sustainably in the study area and other similar arid and semiarid areas in the world.

Analysis on the Pollution Load of Non-point Source Pollution and Surface Runoff of A Typical Village in Baiyangdian Lake Basin

[Objective] The characteristic of non-point source pollution of a typical village in Baiyangdian Lake basin was studied.[Method] The discharge of domestic sewage and solid wastes of the typical village was investigated,and both pollutant and nutrient element content were monitored,as well as the water quality and quantity of rainfall runoff.[Result] The non-point source pollution of livestock manure was far more serious than the sum of domestic sewage and domestic waste in this village,and the annual emission of total organic carbon(TOC),total nitrogen(TN) and total phosphorus(TP) was 37 794.0,4 102.9 and 1 923.7 kg,respectively.The event mean concentration(EMC)of chemical oxygen demand COD,TN and TP in rainfall runoff was 44.5,78.8,1.3 mg/L,respectively,and annual pollution load was 7.6,13.4 and 0.2 kg/hm2,respectively,while the annual pollution load of COD accounted for 5.1% of standard farmland,and that of TN and TP occupied 4.5% and 0.49% of slope farmland.[Conclusion] Livestock manure was the main source of non-point source pollution in the village and the annual pollution load of non-point source pollution was obtained.

Seasonal Impact of Agricultural Non-point Source Pollution on Water Environment of Dianshan Lake Basin in Shanghai City

Taken the Dalian lake region as the study area,which represents the typical agriculture production mode and agricultural non-point source pollution （ANSP） in Dianshan lake area in Shanghai City,basis on the characteristics of regional ANSP and combing with the seasonal water quality monitoring of Dalian Lake and reaches of its main influents,the laws of seasonal impact on the water environment were investigated.The results showed that,the seasonal change of TN and COD concentration of regional water had no significant correlation with the local ANSP emissions,while the seasonal changes of TP was consistent with seasonal emissions of regional TP pollution,and it had a significant correlation with Chl.a in four seasons,indicating that regional TP pollutant was the constriction factor influenced the eutrophication degree of Dalian lake.Because more than 80% of TP emissions came from the drainage of intensive pounds in winter,summer and fall,TP pollutant control should be adopted as the control target of regional ANSP control.

Analysis on the Status of Agricultural Non-point Source Pollution in Xinan River Basin

Taking Xinan River basin as research object,the status of agricultural non-point source pollution was analyzed based on field survey,as well as the effect of fertilizer and pesticide leaching and runoff,livestock and poultry breeding and rural domestic pollution on non-point source TN and TP.At last,some technical countermeasures of controlling non-point source pollution were put forward according to the characteristics of agricultural non-point source pollution in Xinan River basin.

Reviews on Agricultural Nonpoint Source Pollution Monitoring Techniques and Methods

Farmland nutrient loss has become one of the main reason causing agri- cultural nonpoint source pollution and water nitrogen, phosphorus eutrophication. Agricultural nonpoint source pollution monitoring techniques and methods are very important in agricultural nonpoint source pollution control. This paper reviews the various monitoring techniques of agricultural non-point source pollution, including runoff pollutant monitoring, leaching pollutant monitoring and on-line monitoring. The runoff pollutant monitoring methods are mainly included artificial simulation of rain- fall runoff method, flow meter method, weir method and volumetric method. The leaching pollutant monitoring methods are mainly included leaching plate method, leaching gutter method, leakage pooling method, pumping filter pipe method and simulating soil column method. Although online monitoring of farmland nutrient loss still exists some technical bottlenecks and economic limitations, it is the future di- rection of development.

Controlling effects of forest belts on non-point source pollution of agricultural lands in Taihu Lake area, China

Taihu Lake area is one of the most developed areas in agricultural production. Application of fertilizers and pesticides in large quantities greatly aggravate environmental pollution of this area, and water pollution has worsened to an unbearable condition. Two sampling farms (respectively 1 hm2) under rape-rice rotation and wheat-rice rotation were selected as studied ecosystem and a 5-yr-old Poplar forest and 8-yr-old Metasequoia forest were chosen in the selected areas. By collecting samples of Nitrogen, Phosphorus in water, crops and underground of forest, the transfer and loss of N and P (main water pollutants) in faming ecosystem were studied, and the effects of forest belts on non-point source pollution of agricultural lands was analyzed. The results indicated that the transfer and loss of N and P vary with means of rotation, types of crops and the amount of fertilizer application. Buffering forest belts betweens farmlands and ditches can effectively stop and purify such elements as N and P in soil runoffs, thus controlling non-point source pollution of agricultural lands. When the width ratio of farmland to forest belt is 100 to 40, 50.05% losing N, 29.37% losing P can be absorbed by forest under rape-rice rotation and 30.98% N, 86.73% P can be absorbed by forest under wheat-rice rotation. When the width ratio of farmland to forest belt is 150 to 40, 33.37% losing N, 19.58% losing P can be absorbed by the forest under rape-rice rotation, and under wheat-rice rotation 20.65% lost N and 57.82% lost P can be absorbed. There is only some purification effect when the width ration of farmland to forest belt is 200 to 40. Based on model of buffering forest belts, the width ratio of farmland to forest is determined between 100 to 40 and 150 to 40, because it not only can purify water, but also occupy less farmland. It is suggested that Poplars, with the characteristics of fast-growing and high value, are suitable to be planted as shelter-forest in Taihu Lake Watershed.

Advances in Microbial Remediation on the Application of Heavy Metal Pollution in Agricultural Water Resources

Heavy metal pollution in agricultural water resources is very serious in re- cent years, resulting in large losses of the agricultural economy and endangering human life and health. Due to the advantages of low cost, high efficiency and less secondary pollution, microbial ramediation technology is widely used in the treatment of heavy metal pollution in agricultural water resources. At present, with the progress of modern biotechnology, microbial remediation of heavy metals in agricul- tural water resources has grown rapidly. The sources and status quo of heavy met- al pollution in agricultural water resources at home and aboard, and the principles of microbial remediation of heavy metals pollution in agricultural water resources were reviewed in this paper, as well as the several common microbial remediation technology of heavy metals in agricultural water resources. Additionally, the further research work of heavy metal contaminated agricultural water resources by microbial ramediation were prospected.

Analysis on Strategic Future of Application of Agricultural Ecological Source in Control on Agricultural Nonpoint Source Pollution in Xi River Area in Guangxi

Non-point source pollution has become a hot issue on aquatic ecological environment at home and abroad. The research analyzed the challenges confronted by Xi River and proposed to construct agricultural ecological source in middle and upper reaches of the Xi River from the perspectives of scientific layout, legal construction, routine monitoring, technology integration, and coordination system in order to promote sustainable development of eco-environment in Xi River.

Determination of pollution point source in parabolic system model

This paper considers an inverse problem for a partial differential equation to identify a pollution point source in a watershed. The mathematical model of the problem is a weakly coupled system of two linear parabolic equations for the concentrations u（x, t） and v（x, t） with an unknown point source F（x, t） = A（ t）δ（x- s） related to the concentration u（x, t）, where s is the point source location and A（t） is the amplitude of the pollution point source. Assuming that source F becomes inactive after time T＊, it is proved that it can be uniquely determined by the indirect measurements { v（0, t）, v（ a, t）, v（ b, t）, v（ l, t）, 0 〈 t ≤ T, T＊ 〈 T}, and, thus, the local Lipschitz stability for this inverse source problem is obtained. Based on the proof of its uniqueness, an inversion scheme is presented to determine the point source. Finally, two numerical examples are given to show the feasibility of the inversion scheme.

A distributed non-point source pollution model: calibration and validation in the Yellow River Basin

The applicability of a non-point source pollution model—SWAT(soil and water assessment tools) in a large river basin with high sediment runoff modulus(770 t/km2 in the Yellow River) was examined. The basic database, which includes DEM, soil and landuse map, weather data, and land management data, was established for the study area using GIS. A two-stage “Brute Force' optimization method was used to calibrate the parameters with the observed monthly flow and sediment data from 1992 to 1997. In the process of calibration automated digital filter technique was used to separate direct runoff and base flow. The direct runoff was firstly calibrated, and the base flow, then the total runoff was matched. The sediment yield was calibrated to match well. Keeping input parameters set during the calibration process unchanged, the model was validated with 1998—1999's observed monthly flow and sediment. The evaluation coefficients for simulated and observed flow and sediment showed that SWAT was successfully applied in the study area: relative error was within 20%, coefficient of determination and Nash-Suttcliffe simulation efficiency were all equal to or above 0.70 during calibration and validation period.

Progress in the research on aquatic environmental nonpoint source pollution in China

In this paper, the authors reviewed the development process of China's research on aquatic environmental nonpoint pollution, and the situation of nonpoint source pollution in east China was also analyzed.

Validation of an agricultural non-point source(AGNPS)pollution model for a catchment in the Jiulong River watershed,China

This study tested and evaluated the agricultural non-point source （AGNPS） model for the Wuchuan catchment, a typical agricultural area in the Jiulong River watershed, Fujian Province, China. The AGNPS model was calibrated and validated for the study area with observed data on ten storms. The data on eight storms in 2002 were used for calibration while data on two storms were used for validation of the model. Considering the lack of water quality data over a long-term series, a novel method, comparing an internal nested catchment with its surrounding catchment, was used to supplement the less long-term series data. Dual calibration and validation of the AGNPS model was obtained by this comparison. The results indicate that the correlation coefficients were 0.99 and 0.98 for runoff, 0.94 and 0.95 for the peak runoff rate of the large catchment and the small catchment, respectively, and 0.76 for the sediment of the small catchment only. Each pair of correlation coefficients is homogeneous for the same event for the two catchments. With the exception of the sediment yield and particulate phosphorus, the peak runoff rate and other nutrients were well predicted. Sensitivity analysis showed that the Soil Conservation Service curve number and rainfall quantity were the most sensitive parameters, which resulted in high output variations. Erosivity and other parameters had little influence on the hydrological and quality outputs.

An improved genetic algorithm for searching for pollution sources

As an optimization method that has experienced rapid development over the past 20 years, the genetic algorithm has been successfully applied in many fields, but it requires repeated searches based on the characteristics of high-speed computer calculation and conditions of the known relationship between the objective function and independent variables. There are several hundred generations of evolvement, but the functional relationship is unknown in pollution source searches. Therefore, the genetic algorithm cannot be used directly. Certain improvements need to be made based on the actual situation, so that the genetic algorithm can adapt to the actual conditions of environmental problems, and can be used in environmental monitoring and environmental quality assessment. Therefore, a series of methods are proposed for the improvement of the genetic algorithm： （1） the initial generation of individual groups should be artificially set and move from lightly polluted areas to heavily polluted areas; （2） intervention measures should be introduced in the competition between individuals; （3） guide individuals should be added; and （4） specific improvement programs should be put forward. Finally, the scientific rigor and rationality of the improved genetic algorithm are proven through an example.

Assessment of Point and Nonpoint Sources Pollution in Songhua River Basin,Northeast China by Using Revised Water Quality Model

Individual participation of pollutants in the pollution load should be estimated even if roughly for the appropriate environmental management of a river basin.It is difficult to identify the sources and to quantify the load, especially in modeling nonpoint source.In this study a revised model was established by integrating point and nonpoint sources into one-dimensional Streeter-Phelps(S-P) model on the basis of real-time hydrologic data and surface water quality monitoring data in the Jilin Reach of the Songhua River Basin.Chemical oxygen demand(COD) and ammonia nitrogen(NH 3-N) loads were estimated.Results showed that COD loads of point source and nonpoint source were 134 958 t/yr and 86 209 t/yr, accounting for 61.02% and 38.98% of total loads, respectively.NH 3-N loads of point source and nonpoint source were 16 739 t/yr and 14 272 t/yr, accounting for 53.98% and 46.02%, respectively.Point source pollution was stronger than nonpoint source pollution in the study area at present.The water quality of upstream was better than that of downstream of the rivers and cities.It is indispensable to treat industrial wastewater and municipal sewage out of point sources, to adopt the best management practices to control diffuse pollutants from agricultural land and urban surface runoff in improving water quality of the Songhua River Basin.The revised S-P model can be successfully used to identify pollution source and quantify point source and nonpoint source loads by calibrating and validating.

Estimation of non-point source pollution loads with flux method in Danjiangkou Reservoir area,China

The estimation of non-point source pollution loads into the Danjiangkou Reservoir is highly significant to environmental protection in the watershed. In order to overcome the drawbacks of traditional watershed numerical models, a base flow separation method was established coupled with a digital filtering method and a flux method. The digital filtering method has been used to separate the base flows of the Hanjiang,Tianhe, Duhe, Danjiang, Laoguan, and Qihe rivers. Based on daily discharge, base flow, and pollutant concentration data, the flux method was used to calculate the point source pollution load and non-point source pollution load. The results show that:(1) In the year 2013, the total inflow of the six rivers mentioned above accounted for 95.9% of the total inflow to the Danjiangkou Reservoir. The total pollution loads of chemical oxygen demand(CODMn) and total phosphorus(TP) from the six rivers were 58.20 103 t and 1.863 10~3 t, respectively, and the non-point source pollution loads were 39.82 10~3 t and 1.544 10~3 t, respectively, indicating that the non-point source pollution is a major factor(with a contribution rate of 68.4% for CODMnand 82.9% for TP).(2) The Hanjiang River is the most significant contributor of pollution loads to the Danjiangkou Reservoir, and its CODMnand TP contribution rates reached 79.3% and 83.2%, respectively. The Duhe River took the second place.(3) Non-point source pollution mainly occurred in the wet season in 2013, accounting for 80.8% and 90.9% of the total pollution loads of CODMnand TP, respectively. It is concluded that the emphasis of pollution control should be placed on non-point source pollution.

Assessing effects of “source-sink” landscape on non-point source pollution based on cell units of a small agricultural catchment

Ascertaining the relationship between "source-sink" landscape and non-point source(NPS) pollution is crucial for reducing NPS pollution, however, it is not easy to realize this target on cell unit scale. To reveal the relationships between "sourcesink" landscape and NPS pollution based on cell units of a small catchment in the Three Gorges Reservoir Region(TGRR), the runoff and nutrient yields were simulated first by rainfall events on a cell unit scale based on the Annualized AGricultural Non-Point Source Pollution Model(AnnAGNPS). Landscape structure and pattern were quantified with "sourcesink" landscape indicators based on cell units including landscape area indices and locationweighted landscape indices. The results showed that:the study case of small Wangjiagou catchment highlighted a good prediction capability of runoff and nutrient export by the AnnAGNPS model. Throughout the catchment, the spatial distribution trends of four location-weighted landscape indices were similar to the trends of simulated total nitrogen(TN) and total phosphorus(TP), which highlighted the importance of spatial arrangement of "source" and "sink" landscape types in a catchment when estimating pollutant loads. Results by Pearson correlation analysis indicated that the location-weighted landscape index provided a more comprehensive account of multiple factors, and can better reflect NPS-related nutrient loss than other landscape indices applied in single-factor analysis. This study provides new findings for applying the "source-sink" landscape indices based on cell units in small catchments to explain the effect of "source-sink" landscape on nutrient export based on cell unit, and helps improve the understanding of the correlation between "source-sink" landscape and NPS pollution.

Discussion on the Green Tax Stimulation Measure of Nitrogen Fertilizer Non-Point Source Pollution Control-Taking the Dongting Lake Area in China as a Case

A study on designing the tax of nitrogen fertilizer can provide a new method for controlling nitrogen fertilizer non-point source pollution. The tax design of nitrogen fertilizer was discussed by utilizing the external theory and the demand elasticity theory. The results indicated that the coefficient of price elasticity of nitrogen fertilizer demand is -0.21, which instructed that the market demand is in lack of elasticity in the short period and the impact of nitrogen fertilizer manufacturers is subtle. The 11 counties （cities and boroughs） in the Dongting Lake area in China, where the farmland nitrogen application surpassed the average ecological fertilization dosage, is listed to the taxation scope of nitrogen fertilizer tax. The environment loss will reduce 0.07 hundred million RMB yuan and the revenue will increase 0.89 hundred million RMB yuan in the country after levying on nitrogen fertilizer. The loss, which was brought by the decreasing food supplies production, will be 0.58 hundred million RMB yuan and the net social benefit will be 0.38 hundred million RMB yuan following revenue collection. The variation scope of the increasing expenditure of farmers will range from 0.95 to 1.49%. The variation scope of the income of farmers will range from -8.41 to 6.44%. The 5 areas, Yunxi Borough, Junshan Borough, Hanshou County, Jinshi City, and Ziyang Borough, had an increase in food supplies production after the revenue collection. The environment loss will reduce 0.01 hundred million RMB yuan and the revenue will increase 0.16 hundred million RMB yuan in the country after levying on nitrogen fertilizer. The economic benefits, which was brought by the increasing cereals production, will be 0.67 hundred million RMB yuan and the net social benefit will be 0.84 hundred million RMB yuan after revenue collection. The variation scope of the increasing expenditure of farmers will range from 0.95 to 1.06%. The variation scope of the increasing income of farmers will range from 0.69 to 6.44%. Considering the entire social welfare, taxation of nitrogen fertilizer will have more advantages than disadvantages in the Dongting Lake area.