Elements can be classified into metals,nonmetals,or metalloids based on their chemical and physical properties.Precious metals are rare and expensive.There are ten known precious metals,three of which are of interest ...Elements can be classified into metals,nonmetals,or metalloids based on their chemical and physical properties.Precious metals are rare and expensive.There are ten known precious metals,three of which are of interest to investors,silver,gold,and platinum.The goal is to find physical methods to identify the presence of precious metals,silver,and gold in the metal components of the computer motherboard,and to confirm its presence by chemical methods for its use and its selling to the jewelry industry after it is physically separated from the computer motherboards.Physical and chemical tests were identified.Physical tests include inscription test,magnet test and specific gravity test for both silver and gold metal pieces and chemical tests include bleach test,nitric acid test,test karat solution kit,and jewelry test kits.展开更多
As a carbon-free energy carrier,hydrogen has become the pivot for future clean energy,while efficient hydrogen production and combustion still require precious metal-based catalysts.Single-atom catalysts(SACs)with hig...As a carbon-free energy carrier,hydrogen has become the pivot for future clean energy,while efficient hydrogen production and combustion still require precious metal-based catalysts.Single-atom catalysts(SACs)with high atomic utilization open up a desirable perspective for the scale applications of precious metals,but the general and facile preparation of various precious metal-based SACs remains challenging.Herein,a general movable printing method has been developed to synthesize various precious metal-based SACs,such as Pd,Pt,Rh,Ir,and Ru,and the features of highly dispersed single atoms with nitrogen coordination have been identified by comprehensive characterizations.More importantly,the synthesized Pt-and Ru-based SACs exhibit much higher activities than their corresponding nanoparticle counterparts for hydrogen oxidation reaction and hydrogen evolution reaction(HER).In addition,the Pd-based SAC delivers an excellent activity for photocatalytic hydrogen evolution.Especially for the superior mass activity of Ru-based SACs toward HER,density functional theory calculations confirmed that the adsorption of the hydrogen atom has a significant effect on the spin state and electronic structure of the catalysts.展开更多
With the increasing awareness of environmental protection, people’s concern of pollution issues arising. Vehicles, as the most important means of transportation, its exhaust emission has received considerable attenti...With the increasing awareness of environmental protection, people’s concern of pollution issues arising. Vehicles, as the most important means of transportation, its exhaust emission has received considerable attention. The catalytic converter is able to purify harmful substances in exhaust gas. The absolute content of precious metals in the catalytic converter dominates the exhaust gas purification effect. Accurate detection of precious metal content is of great significance for controlling the cost of catalysts, ensuring catalytic performance and recovering precious metals from spent catalysts. We herein summarized several instruments for precious metals content exploration, such as X-ray fluorescence spectrometer (XRF), atomic absorption spectrometer (AAS), inductively coupled plasma emission spectrometer (ICP) and spectrophotometer. In this thesis, the feasibility of using various devices for characterizing precious metal content in catalytic converters is analyzed and their strengths or weaknesses are elaborated.展开更多
The recovery of precious metals from the secondary resources by microwave technology has emerged in recent years. Microwave technology as a new method for the recovery of precious metals has shown significant advantag...The recovery of precious metals from the secondary resources by microwave technology has emerged in recent years. Microwave technology as a new method for the recovery of precious metals has shown significant advantages against the conventional recovery procedures. This paper presents a review of the advances in microwave technology applied to the recovery of precious metals from the secondary resources. Many different applications are considered, including microwave-assisted leaching, microwave augmented ashing and microwave pyrolysis. In general, microwave enhanced recovery of precious metals from secondary resources.展开更多
This study reveals the time-varying spillover effects of higher moments(realized volatility,realized skewness and realized kurtosis)and jumps between China’s precious metals and industrial metals markets.Using 5-min ...This study reveals the time-varying spillover effects of higher moments(realized volatility,realized skewness and realized kurtosis)and jumps between China’s precious metals and industrial metals markets.Using 5-min high-frequency data from May 10,2012 to October 21,2021,the dynamic effects of spillovers are uncovered using the time-frequency domain spillover index framework.The results show that the system connectedness weakens as the moment order gets higher whereas the total jumps connectedness is the smallest,and the spillovers of all estimators are more evident in the short term.The overall information spillovers are time-varying and influenced by major market events.Specifically,for realized volatility,copper is the largest net transmitter and silver is always a net transmitter,while zinc is the largest net receiver.For realized skewness,copper is the largest net transmitter and silver is always a net transmitter,while lead is the largest net receiver.For realized kurtosis and jumps,copper is the largest net transmitter,while aluminum is the largest net receiver.Overall,copper and silver play dominant roles in China’s precious and industrial metals markets system.展开更多
Aimed at high content of valuable metals, complicated composition, difficult to separation of precious metals six component alloy wastes, the present paper proposed a new technology of high efficient separation and pu...Aimed at high content of valuable metals, complicated composition, difficult to separation of precious metals six component alloy wastes, the present paper proposed a new technology of high efficient separation and purification. Using fragmentation technology realizes fast dissolution of palladium, silver, copper and zinc in the wastes, and high efficient and complete separation of them from gold and platinum; using evaporation thermal decomposition technology of mixed solution produced by nitric acid dissolving palladium, silver, copper and zinc, complete and high efficient separation of silver from palladium was realized; by control of solution acidity, using hydrazine reduction method, high efficient and complete separation of gold from platinum was realized. Using this new technology, the recovery rates of palladium and silver are above 99%, and gold and platinum above 98%, the grade of pure metals are above 99.95%.展开更多
Situated in Kunming,Yunnan Province,the institute is a scientific research organiza-tion with a history of fifty years.It is nowaffiliated with the China National NonferrousMetals Industry Corporation.At the beginning...Situated in Kunming,Yunnan Province,the institute is a scientific research organiza-tion with a history of fifty years.It is nowaffiliated with the China National NonferrousMetals Industry Corporation.At the beginning of the nineteen sixties,the institute commenced research workin the field of precious metals.It has sincethen developed and extended greatly,andits activities now cover various fields ofprecious metals science and technology,including the comprehensive utilization展开更多
The region of existence of phases in equilibrium with the solid solution based on palladium. Presented to analyze the current situation in the market of precious metals in Russia. Provides information about the produc...The region of existence of phases in equilibrium with the solid solution based on palladium. Presented to analyze the current situation in the market of precious metals in Russia. Provides information about the production and processing of precious metals. Prospects for the most likely path of development of the Russian market of precious metals.展开更多
The work concentrates on extraction of precious metals (Au, Ag, Pd, Pt) and As, Sb, Cu, Pb, Zn, and Fe which are bound to sulfide-ore minerals in sedimentary rocks, using a two-step sequential extraction experiment wi...The work concentrates on extraction of precious metals (Au, Ag, Pd, Pt) and As, Sb, Cu, Pb, Zn, and Fe which are bound to sulfide-ore minerals in sedimentary rocks, using a two-step sequential extraction experiment with two chemical reagents (hydrogen peroxide and aqua regia) on three rock specimens from the black shale formation in Bakyrchik gold-sulfide deposit in North-East Kazakhstan. The experiment allows to determine the speciation of hardly accessible precious metals and to identify the most productive ore-forming stage from the three identified ones. Analytical methods are used for determining polysulfide mineral textures (optical microscopy), mineralogical (XRPD) and chemical compositions (XRF), and for measuring extracted metals concentrations (ICP-OES) in experimental procedures. The analytical results show that the first stage is more productive in gold (total extraction 2.8 ppm) than others and the second stage is more productive in Ag (total 1.6 ppm) and Pd (total 0.01 ppm), while the last stage is more productive in Pt (0.019 ppm) in the deposit.展开更多
In June 2012,the UN conference on sustainable development "Rio+20" summarized the work of the world community in this direction for last 20 years and outlined the tasks for the future.The UN website contains...In June 2012,the UN conference on sustainable development "Rio+20" summarized the work of the world community in this direction for last 20 years and outlined the tasks for the future.The UN website contains enough information to estimate the importance of global problems and "green economy," taking into account a very complicated state of the global and Russian markets which are balancing on the verge of crisis.Unfortunately,the website does not contain the materials of the 6th civilization forum "Long-Term Strategy for Sustainable Development on the Basis of Partnership of Civilizations:Concepts,Strategy,Programs and Projects" within the bounds of "Rio+20" which has considered the problems of a dialogue and partnership in conditions of extensive globalization.These problems are covered in the Partnership of Civilizations Journal which is issued in the Russian,English and Arabian languages,including its Internet version.The International Informatization Academy (it has the general consultative status at the Economic and Social Council of the UN) and its 20-year activity in the sphere of informatization of the world and Russia on the way to the partnership of civilizations,are presented there[1].展开更多
The enrichment mechanisms of precious metals by base metals or their mattes in pyro-metallurgical processes are discussed at the atomic level in this paper.The reasons brought forward for a trace amount of precious me...The enrichment mechanisms of precious metals by base metals or their mattes in pyro-metallurgical processes are discussed at the atomic level in this paper.The reasons brought forward for a trace amount of precious metals to be trapped into base metals or mattes are that the melted slag phases possess different chemical structures and properties from that of the melted base metal or matte phases.As for the melted slag phase,its formation is thought to depend on the covalent bonds and the ionic bonds between Si,O atoms and Ca2+,Mg2+,Fe2+ ions to tie up each other.Because the bridging electrons in the slag phase are all thought as the localized electrons,the precious metal atoms are not stable among them.However,as for the metal phase,its formation is thought depend on the metal bonds to bind up the metal atoms.Because the electrons in the metal phases can move freely among the atoms,the precious metal atoms that enter the metal phase can cause the system's free energy to decrease.For the melted mattes phase,because it has high electrical conductivities(between 103~104 s·cm-1) at higher temperatures,and its temperature coefficients presents the negative values,its conductance mechanism belongs with the electronic conduction.The property of the mattes is in fact similar to that of the metal at their melted state,so the precious metal atoms will enter the matte phase instead of the slag phase in a matte-smelting process.展开更多
From the perspective of long-term and short-term, the methods of TY causality test, generalized impulse response function, variance decomposition were used to investigate the impacts of international oil prices and ma...From the perspective of long-term and short-term, the methods of TY causality test, generalized impulse response function, variance decomposition were used to investigate the impacts of international oil prices and macroeconomic variables on Chinese gold, silver and platinum prices, but also the feedback effects of Chinese precious metal prices under this impact. The results show that international oil prices play an important role in precious metal price variation both in long-term and short-term, and exchange rate only has an effect in short-term, while interest rate is ineffective in predicting precious metal prices. In addition, precious metal prices have some feedback effects on international oil prices and interest rate in short-term.展开更多
The mitigation of environmental and energy crises could be advanced by reclaiming platinum group precious metals(PGMs) from decommissioned air purification catalysts. However, the complexity of catalyst composition an...The mitigation of environmental and energy crises could be advanced by reclaiming platinum group precious metals(PGMs) from decommissioned air purification catalysts. However, the complexity of catalyst composition and the high chemical inertness of PGMs significantly impede this process. Consequently,recovering PGMs from used industrial catalysts is crucial and challenging. This study delves into an environmentally friendly approach to selectively recover PGMs from commercial air purifiers using photocatalytic redox technology. Our investigation focuses on devising a comprehensive strategy for treating three-way catalysts employed in automotive exhaust treatment. By meticulously pretreating and modifying reaction conditions, we achieved noteworthy results, completely dissolving and separating rhodium(Rh), palladium(Pd), and platinum(Pt) within a 12-h time frame. Importantly, the solubility selectivity persists despite the remarkably similar physicochemical properties of Rh, Pd, and Pt. To bolster the environmental sustainability of our method, we harness sunlight as the energy source to activate the photocatalysts, facilitating the complete dissolution of precious metals under natural light irradiation. This ecofriendly recovery approach demonstrated on commercial air purifiers, exhibits promise for broader application to a diverse range of deactivated air purification catalysts, potentially enabling implementation on a large scale.展开更多
Based on the in-situ self-reduction and chemical stability,graphdiyne(GDY)and graphdiyne oxide(GDYO)are used as trapping agents to investigate the ability for recovering Au^(3+),Ag^+,and Pd^(2+)under different pH valu...Based on the in-situ self-reduction and chemical stability,graphdiyne(GDY)and graphdiyne oxide(GDYO)are used as trapping agents to investigate the ability for recovering Au^(3+),Ag^+,and Pd^(2+)under different pH values and interfering ions.Under strong acidity at pH=1,these two agents demonstrate high select recovery towards the three precious metal ions,which could be insitu reduced to nanoparticles(NPs).In addition,superparamagnetic Fe_(3)O_(4)NPs are deposited on the surfaces of GDY and GDYO.The magnetic responses enable GDYFe_(3)O_(4)to recover precious metals conveniently and efficiently by the aid of an external magnetic field.This study also confirms the antibacterial activity of the as-recovered NPs deposited on GDY and GDYO against Escherichia coli and Staphylococcus aureus(1×10^(5)colony-forming unit(CFU)·mL^(-1)),and the antibacterial rates are 100%.This strategy of recovering precious metals and subsequently reusing to combat pathogens will be of great significance for environmental remediation and biomedical applications.展开更多
A new technique of swelling oxidizing roasting and alkaline leaching was proposed for deselenization and detellurization of pre- cious-metal ore concentrates. Alkali-metal and alkaline-earth-metal chlorides and carbon...A new technique of swelling oxidizing roasting and alkaline leaching was proposed for deselenization and detellurization of pre- cious-metal ore concentrates. Alkali-metal and alkaline-earth-metal chlorides and carbonates were preliminarily selected as swelling agents. The roasting removal rate and alkaline leaching rate of selenium and tellurium were investigated, and NaCl was selected as an appropriate swelling agent. Furthermore, the effects of various factors on the selenium gasification rate and leaching rate of selenium and tellurium were investigated. The results show that the selenium gasification rate reaches 88.41% after swelling oxidizing roasting for 2 h at 510~C using an NaC1 dosage coefficient of 100 and a sulfuric acid dosage coefficient of 1.3; the amorphous elemental tellurium is completely transformed into TeO2. The roasted product is subjected to alkaline leaching using a 100 g/L NaOH solution, which results in a selenium leaching rate of 10.51%, a total selenium removal rate of 98.92%, and a tellurium leaching rate of 97.64%. In the alkaline leaching residue, the contents of selenium, tellurium, gold, platinum, and palladium are 0.7825%, 5.492%, 8.333%, 0.2587%, and 1.113%, respectively; the precious metals are enriched approximately sixfold.展开更多
In recent years JSC "Krastsvetmet" has successfully developed the production of chemically pure compounds of precious metals.Currently methods have been developed and facilities have been provided for indust...In recent years JSC "Krastsvetmet" has successfully developed the production of chemically pure compounds of precious metals.Currently methods have been developed and facilities have been provided for industrial production of the following platinum metals compounds:Rhodium(Ⅲ) chloride hydrate,rhodium(Ⅲ) chloride solution,rhodium(Ⅲ) nitrate solution,rhodium(Ⅲ) iodide,rhodium(Ⅲ) sulfate,hydrated rhodium(Ⅲ) oxide,ammonium hexachlororodiate,rhodium(Ⅲ) phosphate solution,rhodium electrolytes;Iridium(Ⅳ) chloride hydrate,iridium(Ⅲ) chloride hydrate,ammonium hexachloroiridate(Ⅳ),hexa chloriridium acid solution,hexachloriridium crystalline acid;Ruthenium(Ⅲ) chloride hydrate,ruthenium(Ⅳ) hydroxide chloride,ruthenium(Ⅳ) hydroxide chloride solution,ammonium hexachlororuthenate,ruthenium(Ⅲ) chloride solution,potassium,diaquaoctachloronitrido diruthenate.The quality of the production meets the requirements of Russian and foreign consumers.展开更多
The activities of ZrO_2-supported precious metal catalysts for simultaneous removal of soot and NO_x in the presence of rich O_2and H_2O as well as SO_2 have been studied by keeping loose contact between catalyst and ...The activities of ZrO_2-supported precious metal catalysts for simultaneous removal of soot and NO_x in the presence of rich O_2and H_2O as well as SO_2 have been studied by keeping loose contact between catalyst and soot.The results show that only Ru,Ir and Rh have catalytic activity for simultaneous removal of soot and NO_x and the order of catalytic activity is Ru > Ir > Rh.Pt has the catalytic activity only for the removal of soot,and Ag,Pd,and Au have hardly any catalytic activities for the removal of soot and NO_x.The relationships between catalytic activity of precious metal catalysts and various reaction conditions were discussed.展开更多
On the basis of reviewing the progress in the high efficient enrichment from secondary resources of low grade precious metals at home and abroad, a process route of the high efficient enrichment precious metals from s...On the basis of reviewing the progress in the high efficient enrichment from secondary resources of low grade precious metals at home and abroad, a process route of the high efficient enrichment precious metals from secondary resources of low-grade metals by adding iron oxide as the trapping agent, reducing agent, additive, mixing uniformly and grinding, pelletizing, reduction, grinding and separation, and selectively acid leaching iron has been put forward in this paper. The experiments of reduction, grinding and separation, and selectively acid leaching iron were carried out mainly. Under the decided experiment parameters and conditions, iron generated during the reduction can trap precious metals during reduction, high active alloy powders were obtained from the reduced products by grinding and separation, the concentration of precious metals was obtained by acid leaching high active alloy powders. The better enrichment effect was obtained by adopting the technical route of processing. Other low grade noble metal materials and enrichment ratio of precious metals from the materials to acid products was high through acid leaching. This process has the advantages of simple process, environmental-friendly, strong adaptability of raw materials, high concentration ratio, which was regarded as a kind of the general efficient enrichment technology of low grade precious metal materials.展开更多
A survey about OJSC "SIC Supermetal'" as a processor of secondary precious metal raw materials and a manufacturer of precious metal products for technical purposes,has been presented.Brief information ha...A survey about OJSC "SIC Supermetal'" as a processor of secondary precious metal raw materials and a manufacturer of precious metal products for technical purposes,has been presented.Brief information has been given about the basic technologies and materials used in production,including dispersion strengthened materials on the basis of platinum alloys and laminar composites.展开更多
This study examines the role of market sentiment in predicting the price bubbles of four strategic metal commodities(gold,silver,palladium,and platinum)from January 1985 to August 2020.It is the first to investigate t...This study examines the role of market sentiment in predicting the price bubbles of four strategic metal commodities(gold,silver,palladium,and platinum)from January 1985 to August 2020.It is the first to investigate this topic using sentiment indices,including news-based economic and consumer-based sentiments developed using different methods.We observed the role of sentiment as a reliable indicator of future bubbles for some metal commodities and found that bubbles were regularly concomi-tant with bearish sentiments for gold and platinum.Moreover,gold and palladium were the only commodities that experienced a bubble during the COVID-19 pandemic.Overall,our findings suggest inclusion of sentiment to the model that predicts the price bubbles of precious metals.展开更多
文摘Elements can be classified into metals,nonmetals,or metalloids based on their chemical and physical properties.Precious metals are rare and expensive.There are ten known precious metals,three of which are of interest to investors,silver,gold,and platinum.The goal is to find physical methods to identify the presence of precious metals,silver,and gold in the metal components of the computer motherboard,and to confirm its presence by chemical methods for its use and its selling to the jewelry industry after it is physically separated from the computer motherboards.Physical and chemical tests were identified.Physical tests include inscription test,magnet test and specific gravity test for both silver and gold metal pieces and chemical tests include bleach test,nitric acid test,test karat solution kit,and jewelry test kits.
基金National Natural Science Foundation of China,Grant/Award Numbers:62105083,22109034,22109035,52164028Start-up Research Foundation of Hainan University,Grant/Award Numbers:KYQD(ZR)-20008,KYQD(ZR)-20082,KYQD(ZR)-20083,KYQD(ZR)-20084,KYQD(ZR)-21065,KYQD(ZR)-21124,KYQD(ZR)-21125+4 种基金Basic and Applied Basic Research Foundation of Guangdong Province,Grant/Award Number:2019A1515110558Hainan Provincial Postdoctoral Science Foundation,Grant/Award Number:RZ2100007123Hainan Province Science and Technology Special Fund,Grant/Award Numbers:ZDYF2020037,ZDYF2020207Hainan Provincial Natural Science Foundation,Grant/Award Numbers:222MS009,222RC548The specific research fund of The Innovation Platform for Academicians of Hainan Province。
文摘As a carbon-free energy carrier,hydrogen has become the pivot for future clean energy,while efficient hydrogen production and combustion still require precious metal-based catalysts.Single-atom catalysts(SACs)with high atomic utilization open up a desirable perspective for the scale applications of precious metals,but the general and facile preparation of various precious metal-based SACs remains challenging.Herein,a general movable printing method has been developed to synthesize various precious metal-based SACs,such as Pd,Pt,Rh,Ir,and Ru,and the features of highly dispersed single atoms with nitrogen coordination have been identified by comprehensive characterizations.More importantly,the synthesized Pt-and Ru-based SACs exhibit much higher activities than their corresponding nanoparticle counterparts for hydrogen oxidation reaction and hydrogen evolution reaction(HER).In addition,the Pd-based SAC delivers an excellent activity for photocatalytic hydrogen evolution.Especially for the superior mass activity of Ru-based SACs toward HER,density functional theory calculations confirmed that the adsorption of the hydrogen atom has a significant effect on the spin state and electronic structure of the catalysts.
文摘With the increasing awareness of environmental protection, people’s concern of pollution issues arising. Vehicles, as the most important means of transportation, its exhaust emission has received considerable attention. The catalytic converter is able to purify harmful substances in exhaust gas. The absolute content of precious metals in the catalytic converter dominates the exhaust gas purification effect. Accurate detection of precious metal content is of great significance for controlling the cost of catalysts, ensuring catalytic performance and recovering precious metals from spent catalysts. We herein summarized several instruments for precious metals content exploration, such as X-ray fluorescence spectrometer (XRF), atomic absorption spectrometer (AAS), inductively coupled plasma emission spectrometer (ICP) and spectrophotometer. In this thesis, the feasibility of using various devices for characterizing precious metal content in catalytic converters is analyzed and their strengths or weaknesses are elaborated.
文摘The recovery of precious metals from the secondary resources by microwave technology has emerged in recent years. Microwave technology as a new method for the recovery of precious metals has shown significant advantages against the conventional recovery procedures. This paper presents a review of the advances in microwave technology applied to the recovery of precious metals from the secondary resources. Many different applications are considered, including microwave-assisted leaching, microwave augmented ashing and microwave pyrolysis. In general, microwave enhanced recovery of precious metals from secondary resources.
基金the financial support from the National Natural Science Foundation of China(No.72172107)。
文摘This study reveals the time-varying spillover effects of higher moments(realized volatility,realized skewness and realized kurtosis)and jumps between China’s precious metals and industrial metals markets.Using 5-min high-frequency data from May 10,2012 to October 21,2021,the dynamic effects of spillovers are uncovered using the time-frequency domain spillover index framework.The results show that the system connectedness weakens as the moment order gets higher whereas the total jumps connectedness is the smallest,and the spillovers of all estimators are more evident in the short term.The overall information spillovers are time-varying and influenced by major market events.Specifically,for realized volatility,copper is the largest net transmitter and silver is always a net transmitter,while zinc is the largest net receiver.For realized skewness,copper is the largest net transmitter and silver is always a net transmitter,while lead is the largest net receiver.For realized kurtosis and jumps,copper is the largest net transmitter,while aluminum is the largest net receiver.Overall,copper and silver play dominant roles in China’s precious and industrial metals markets system.
文摘Aimed at high content of valuable metals, complicated composition, difficult to separation of precious metals six component alloy wastes, the present paper proposed a new technology of high efficient separation and purification. Using fragmentation technology realizes fast dissolution of palladium, silver, copper and zinc in the wastes, and high efficient and complete separation of them from gold and platinum; using evaporation thermal decomposition technology of mixed solution produced by nitric acid dissolving palladium, silver, copper and zinc, complete and high efficient separation of silver from palladium was realized; by control of solution acidity, using hydrazine reduction method, high efficient and complete separation of gold from platinum was realized. Using this new technology, the recovery rates of palladium and silver are above 99%, and gold and platinum above 98%, the grade of pure metals are above 99.95%.
文摘Situated in Kunming,Yunnan Province,the institute is a scientific research organiza-tion with a history of fifty years.It is nowaffiliated with the China National NonferrousMetals Industry Corporation.At the beginning of the nineteen sixties,the institute commenced research workin the field of precious metals.It has sincethen developed and extended greatly,andits activities now cover various fields ofprecious metals science and technology,including the comprehensive utilization
文摘The region of existence of phases in equilibrium with the solid solution based on palladium. Presented to analyze the current situation in the market of precious metals in Russia. Provides information about the production and processing of precious metals. Prospects for the most likely path of development of the Russian market of precious metals.
文摘The work concentrates on extraction of precious metals (Au, Ag, Pd, Pt) and As, Sb, Cu, Pb, Zn, and Fe which are bound to sulfide-ore minerals in sedimentary rocks, using a two-step sequential extraction experiment with two chemical reagents (hydrogen peroxide and aqua regia) on three rock specimens from the black shale formation in Bakyrchik gold-sulfide deposit in North-East Kazakhstan. The experiment allows to determine the speciation of hardly accessible precious metals and to identify the most productive ore-forming stage from the three identified ones. Analytical methods are used for determining polysulfide mineral textures (optical microscopy), mineralogical (XRPD) and chemical compositions (XRF), and for measuring extracted metals concentrations (ICP-OES) in experimental procedures. The analytical results show that the first stage is more productive in gold (total extraction 2.8 ppm) than others and the second stage is more productive in Ag (total 1.6 ppm) and Pd (total 0.01 ppm), while the last stage is more productive in Pt (0.019 ppm) in the deposit.
文摘In June 2012,the UN conference on sustainable development "Rio+20" summarized the work of the world community in this direction for last 20 years and outlined the tasks for the future.The UN website contains enough information to estimate the importance of global problems and "green economy," taking into account a very complicated state of the global and Russian markets which are balancing on the verge of crisis.Unfortunately,the website does not contain the materials of the 6th civilization forum "Long-Term Strategy for Sustainable Development on the Basis of Partnership of Civilizations:Concepts,Strategy,Programs and Projects" within the bounds of "Rio+20" which has considered the problems of a dialogue and partnership in conditions of extensive globalization.These problems are covered in the Partnership of Civilizations Journal which is issued in the Russian,English and Arabian languages,including its Internet version.The International Informatization Academy (it has the general consultative status at the Economic and Social Council of the UN) and its 20-year activity in the sphere of informatization of the world and Russia on the way to the partnership of civilizations,are presented there[1].
文摘The enrichment mechanisms of precious metals by base metals or their mattes in pyro-metallurgical processes are discussed at the atomic level in this paper.The reasons brought forward for a trace amount of precious metals to be trapped into base metals or mattes are that the melted slag phases possess different chemical structures and properties from that of the melted base metal or matte phases.As for the melted slag phase,its formation is thought to depend on the covalent bonds and the ionic bonds between Si,O atoms and Ca2+,Mg2+,Fe2+ ions to tie up each other.Because the bridging electrons in the slag phase are all thought as the localized electrons,the precious metal atoms are not stable among them.However,as for the metal phase,its formation is thought depend on the metal bonds to bind up the metal atoms.Because the electrons in the metal phases can move freely among the atoms,the precious metal atoms that enter the metal phase can cause the system's free energy to decrease.For the melted mattes phase,because it has high electrical conductivities(between 103~104 s·cm-1) at higher temperatures,and its temperature coefficients presents the negative values,its conductance mechanism belongs with the electronic conduction.The property of the mattes is in fact similar to that of the metal at their melted state,so the precious metal atoms will enter the matte phase instead of the slag phase in a matte-smelting process.
基金Project(13&ZD169)supported by the Major Program of the National Social Science Foundation,ChinaProject(13YJAZH149)supported by Research Project in Humanities and Social Sciences Conducted by the Ministry of Education,China+2 种基金Project(2011ZK2043)supported by the Key Program of the Soft Science Research Project of Hunan Province,ChinaProject(2015JJ2182)supported by Natural Science Foundation of Hunan Province of ChinaProject(2009JYJR035)supported by Emergency Project "The Study of International Financial Crisis" of Ministry of Education of China
文摘From the perspective of long-term and short-term, the methods of TY causality test, generalized impulse response function, variance decomposition were used to investigate the impacts of international oil prices and macroeconomic variables on Chinese gold, silver and platinum prices, but also the feedback effects of Chinese precious metal prices under this impact. The results show that international oil prices play an important role in precious metal price variation both in long-term and short-term, and exchange rate only has an effect in short-term, while interest rate is ineffective in predicting precious metal prices. In addition, precious metal prices have some feedback effects on international oil prices and interest rate in short-term.
基金supported by the National Key Research and Development Program of China (2020YFA0211004)the National Natural Science Foundation of China (22176128 and 22236005)+7 种基金the Innovation Program of Shanghai Municipal Education Commission (2023ZKZD50)Program of Shanghai Academic Research Leader (21XD1422800)Shanghai Government (22dz1205400 and 23520711100)Chinese Education Ministry Key Laboratory and International Joint Laboratory on Resource ChemistryShanghai Eastern Scholar Programthe “111 Innovation and Talent Recruitment Base on Photochemical and Energy Materials” (D18020)Shanghai Engineering Research Center of Green Energy Chemical Engineering (18DZ2254200)Shanghai Frontiers Science Center of Biomimetic Catalysis。
文摘The mitigation of environmental and energy crises could be advanced by reclaiming platinum group precious metals(PGMs) from decommissioned air purification catalysts. However, the complexity of catalyst composition and the high chemical inertness of PGMs significantly impede this process. Consequently,recovering PGMs from used industrial catalysts is crucial and challenging. This study delves into an environmentally friendly approach to selectively recover PGMs from commercial air purifiers using photocatalytic redox technology. Our investigation focuses on devising a comprehensive strategy for treating three-way catalysts employed in automotive exhaust treatment. By meticulously pretreating and modifying reaction conditions, we achieved noteworthy results, completely dissolving and separating rhodium(Rh), palladium(Pd), and platinum(Pt) within a 12-h time frame. Importantly, the solubility selectivity persists despite the remarkably similar physicochemical properties of Rh, Pd, and Pt. To bolster the environmental sustainability of our method, we harness sunlight as the energy source to activate the photocatalysts, facilitating the complete dissolution of precious metals under natural light irradiation. This ecofriendly recovery approach demonstrated on commercial air purifiers, exhibits promise for broader application to a diverse range of deactivated air purification catalysts, potentially enabling implementation on a large scale.
基金financially supported by the National Natural Science Foundation of China(Nos.22062017 and 22164015)Inner Mongolia Autonomous Region Program for Key Science and Technology(No.2020GG0161)+3 种基金Ordos City Program for Key Science and Technology(No.2022YY003)the Program of Higher-Level Talents of Inner Mongolia University(No.10000-22311201/035)the Research Program of science and technology at Universities of Inner Mongolia Autonomous Region(No.NJZZ23091)the Program for Innovative Research Team in Universities of Inner Mongolia Autonomous Region(No.NMGIRT2210)。
文摘Based on the in-situ self-reduction and chemical stability,graphdiyne(GDY)and graphdiyne oxide(GDYO)are used as trapping agents to investigate the ability for recovering Au^(3+),Ag^+,and Pd^(2+)under different pH values and interfering ions.Under strong acidity at pH=1,these two agents demonstrate high select recovery towards the three precious metal ions,which could be insitu reduced to nanoparticles(NPs).In addition,superparamagnetic Fe_(3)O_(4)NPs are deposited on the surfaces of GDY and GDYO.The magnetic responses enable GDYFe_(3)O_(4)to recover precious metals conveniently and efficiently by the aid of an external magnetic field.This study also confirms the antibacterial activity of the as-recovered NPs deposited on GDY and GDYO against Escherichia coli and Staphylococcus aureus(1×10^(5)colony-forming unit(CFU)·mL^(-1)),and the antibacterial rates are 100%.This strategy of recovering precious metals and subsequently reusing to combat pathogens will be of great significance for environmental remediation and biomedical applications.
文摘A new technique of swelling oxidizing roasting and alkaline leaching was proposed for deselenization and detellurization of pre- cious-metal ore concentrates. Alkali-metal and alkaline-earth-metal chlorides and carbonates were preliminarily selected as swelling agents. The roasting removal rate and alkaline leaching rate of selenium and tellurium were investigated, and NaCl was selected as an appropriate swelling agent. Furthermore, the effects of various factors on the selenium gasification rate and leaching rate of selenium and tellurium were investigated. The results show that the selenium gasification rate reaches 88.41% after swelling oxidizing roasting for 2 h at 510~C using an NaC1 dosage coefficient of 100 and a sulfuric acid dosage coefficient of 1.3; the amorphous elemental tellurium is completely transformed into TeO2. The roasted product is subjected to alkaline leaching using a 100 g/L NaOH solution, which results in a selenium leaching rate of 10.51%, a total selenium removal rate of 98.92%, and a tellurium leaching rate of 97.64%. In the alkaline leaching residue, the contents of selenium, tellurium, gold, platinum, and palladium are 0.7825%, 5.492%, 8.333%, 0.2587%, and 1.113%, respectively; the precious metals are enriched approximately sixfold.
文摘In recent years JSC "Krastsvetmet" has successfully developed the production of chemically pure compounds of precious metals.Currently methods have been developed and facilities have been provided for industrial production of the following platinum metals compounds:Rhodium(Ⅲ) chloride hydrate,rhodium(Ⅲ) chloride solution,rhodium(Ⅲ) nitrate solution,rhodium(Ⅲ) iodide,rhodium(Ⅲ) sulfate,hydrated rhodium(Ⅲ) oxide,ammonium hexachlororodiate,rhodium(Ⅲ) phosphate solution,rhodium electrolytes;Iridium(Ⅳ) chloride hydrate,iridium(Ⅲ) chloride hydrate,ammonium hexachloroiridate(Ⅳ),hexa chloriridium acid solution,hexachloriridium crystalline acid;Ruthenium(Ⅲ) chloride hydrate,ruthenium(Ⅳ) hydroxide chloride,ruthenium(Ⅳ) hydroxide chloride solution,ammonium hexachlororuthenate,ruthenium(Ⅲ) chloride solution,potassium,diaquaoctachloronitrido diruthenate.The quality of the production meets the requirements of Russian and foreign consumers.
基金the Special Fund for the Development of Strategic and New Industry in Shenzhen,China(No.JCYJ20130329162012793)National Natural Science Foundation for Young Scholars,China(Nos.20907012,ZYC201105160189A)the Basic Research Plan in Shenzhen City,China(No.JC201105160593A)
文摘The activities of ZrO_2-supported precious metal catalysts for simultaneous removal of soot and NO_x in the presence of rich O_2and H_2O as well as SO_2 have been studied by keeping loose contact between catalyst and soot.The results show that only Ru,Ir and Rh have catalytic activity for simultaneous removal of soot and NO_x and the order of catalytic activity is Ru > Ir > Rh.Pt has the catalytic activity only for the removal of soot,and Ag,Pd,and Au have hardly any catalytic activities for the removal of soot and NO_x.The relationships between catalytic activity of precious metal catalysts and various reaction conditions were discussed.
基金The National Basic Research Program( 973 Plan) of China(2012CB724201)
文摘On the basis of reviewing the progress in the high efficient enrichment from secondary resources of low grade precious metals at home and abroad, a process route of the high efficient enrichment precious metals from secondary resources of low-grade metals by adding iron oxide as the trapping agent, reducing agent, additive, mixing uniformly and grinding, pelletizing, reduction, grinding and separation, and selectively acid leaching iron has been put forward in this paper. The experiments of reduction, grinding and separation, and selectively acid leaching iron were carried out mainly. Under the decided experiment parameters and conditions, iron generated during the reduction can trap precious metals during reduction, high active alloy powders were obtained from the reduced products by grinding and separation, the concentration of precious metals was obtained by acid leaching high active alloy powders. The better enrichment effect was obtained by adopting the technical route of processing. Other low grade noble metal materials and enrichment ratio of precious metals from the materials to acid products was high through acid leaching. This process has the advantages of simple process, environmental-friendly, strong adaptability of raw materials, high concentration ratio, which was regarded as a kind of the general efficient enrichment technology of low grade precious metal materials.
文摘A survey about OJSC "SIC Supermetal'" as a processor of secondary precious metal raw materials and a manufacturer of precious metal products for technical purposes,has been presented.Brief information has been given about the basic technologies and materials used in production,including dispersion strengthened materials on the basis of platinum alloys and laminar composites.
基金financed by United Arab Emirates University(Grand Number 31B135-UPAR-3-2020)。
文摘This study examines the role of market sentiment in predicting the price bubbles of four strategic metal commodities(gold,silver,palladium,and platinum)from January 1985 to August 2020.It is the first to investigate this topic using sentiment indices,including news-based economic and consumer-based sentiments developed using different methods.We observed the role of sentiment as a reliable indicator of future bubbles for some metal commodities and found that bubbles were regularly concomi-tant with bearish sentiments for gold and platinum.Moreover,gold and palladium were the only commodities that experienced a bubble during the COVID-19 pandemic.Overall,our findings suggest inclusion of sentiment to the model that predicts the price bubbles of precious metals.