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sol-gel法制备多孔纳米SiO_2薄膜 被引量:6
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作者 李智 姚熹 张良莹 《电子元件与材料》 CAS CSCD 北大核心 2005年第2期32-34,37,共4页
以NH3·H2O为催化剂,用正硅酸乙酯(TEOS)溶胶–凝胶工艺制备纳米多孔二氧化硅薄膜.强碱催化使二氧化硅胶粒溶解度增大并增大了体系的离子强度;丙三醇的加入,与水解中间体结合,有效抑制了二氧化硅溶胶胶粒的长大;PVA(聚乙烯醇)对二... 以NH3·H2O为催化剂,用正硅酸乙酯(TEOS)溶胶–凝胶工艺制备纳米多孔二氧化硅薄膜.强碱催化使二氧化硅胶粒溶解度增大并增大了体系的离子强度;丙三醇的加入,与水解中间体结合,有效抑制了二氧化硅溶胶胶粒的长大;PVA(聚乙烯醇)对二氧化硅胶粒有强的吸附作用,使胶粒聚联成大的网络结构,增加了成膜性能.通过改变反应物的剂量,调节添加剂的用量,可以制得折射率1.18~1.42,对应孔率60.50%~7.75%并且孔径小于100 nm的纳米多孔二氧化硅薄膜,.单层薄膜厚度在3 μm以内精确可控. 展开更多
关键词 无机非金属材料 多孔纳米二氧化硅薄膜 溶胶-凝胶工艺 孔率 厚度控制 SOL-GEL法
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Monodisperse silica nanoparticle suspension for developing latent blood fingermarks 被引量:3
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作者 Liang Meng Yifei Ren +3 位作者 Zhilong Zhou Congxiang Li Chen Wang Shanlin Fu 《Forensic Sciences Research》 CSCD 2020年第1期38-46,共9页
Traditional fingermark developing methods are unsuitable for developing and extracting latent blood fingermarks on dark surfaces at crime scene because of their ineffectiveness or tedious operation procedures.In the p... Traditional fingermark developing methods are unsuitable for developing and extracting latent blood fingermarks on dark surfaces at crime scene because of their ineffectiveness or tedious operation procedures.In the present work,an effective and simple method was developed to serve this purpose using a suspension of monodisperse silica nanoparticles(MSNs).A suspension of 0.1 g/mL of MSNs was prepared by dispersing MSNs ultrasonically into an ethanol solution containing 1.0%Tween 80 and then uniformly sprayed onto the latent blood fingermarks on black plastic bags.Approximately 20 s later,ethanol was sprayed to clean the superfluous developing liquid.After the ethanol had evaporated,the latent fin-germarks became visible as a result of the photonic crystal effect produced by the MSNs that had adsorbed to the fingermark ridges.The developed fingermarks were then photo-graphed using a digital camera under a white or monospectral light source,revealing fine ridges and clear fingermark details.This novel,simple and effective method uses the pho-tonic crystal effect of MSNs to develop latent blood fingermarks without the need for sur-face functionalization and conjugation to dye or fluorescently label molecules.The method can detect latent blood fingermarks that have been retained on a black plastic bag surface for at least 30 d.Given the simplicity and effectiveness of the developed method,MSNs may be a useful alternative material for use in developing latent fingermarks.Further research on the topic is warranted. 展开更多
关键词 Forensic SCIENCES MONODISPERSE silica nanoparticles photonic crystal LATENT BLOOD fingermarks FINGERMARK development DARK non-porous substrate
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