Evaluation of the Oxidation Reactivity and Behavior of Exhaust Soot Particles from Diesel Engines with Different Emission Levels

The aim of this study was to investigate the oxidation reactivity and behavior of exhaust particulate matter(PM)from diesel engines.PM samples from two diesel engines(1K,CY4102)with different emission levels were collected by a thermophoretic system and a quartz filter.The oxidation reactivity,oxidation behaviors,and physicochemical properties of the PM samples were analyzed using thermogravimetric analysis(TGA),high-resolution transmission electron microscopy(HRTEM),Fourier-transform infrared spectrometry(FTIR),and Raman spectroscopy.The results showed that there was a great difference in the oxidation reactivity of soot particles emitted by the two different diesel engines.A qualitative analysis of the factors influencing oxidation reactivity showed that the nanostructure,degree of graphitization,and relative concentration of aliphatic C—H functional groups were the most important factors,whereas no significant correlation was found between the primary particle size and activation energy of the diesel soot.Based on the oxidation behavior analysis,the diesel soot particles exhibited both internal and surface oxidation modes during the oxidation process.Surface oxidation was dominant during the initial stage,and as oxidation progressed,the mode gradually changed to internal oxidation.Internal oxidation mode of soot particles from the 1K engine was significantly higher than that of CY4102.

Performance, Combustion and Emission Characteristics of Oxygenated Diesel in DI Engines: A Critical Review

The transition from non-renewable to renewable energy sources is a significant challenge of our time. In the fuel industry, oxygenated additives such as butanol are transforming conventional fuels into renewable biofuels. This technology has been utilized in reciprocating engines for decades. This paper reviews the viability of using an n-butanol blend as a short-term replacement for diesel by analyzing its physical and chemical properties, combustion, performance, and emission characteristics in compression ignition (CI) engines under various conditions, including variable load, speed, acceleration, and both stationary and transient cycles. N-Butanol exhibits higher viscosity, better lubricity, higher heating value, improved blend stability, enhanced cold-flow properties, and higher density. These factors influence spray formation, injection timing, atomization, and combustion characteristics. Its higher oxygen content improves the diffusion combustion stage and efficiency. Adding 5% and 10% n-butanol to diesel increases pressure and apparent heat release rate, slightly reduces temperature, and improves thermal efficiency, with mixed effects on CO and THC emissions and a notable decrease in particulate matter emissions. Fuel consumption increases, while the impact on NOx emissions varies. A 10% butanol blend is considered optimal for enhancing performance and reducing particulate emissions without significantly affecting NOx emissions. Blending up to 40% butanol with diesel does not require engine modifications or ECU recalibrations in engines calibrated for pure diesel. Due to its advantageous properties and performance, n-butanol is recommended as a superior alcohol-diesel blend than ethanol for short-term diesel replacement.

Comparative Study of Exhaust Emissions from Diesel and Syngas Powered 3.5 kW Compression Ignition Engine with and without Load

Despite diesel engines being highly efficient, with low fuel consumption and reduced carbon dioxide emissions, they emit relatively high levels of particulate matter and oxides of nitrogen (NOx) due to high exhaust gas temperatures. Engine emissions show the quality and completeness of combustion. This paper aims to present the results of a study comparing exhaust emissions from a diesel and syngas powered engine. Syngas was produced from co-firing coal and biomass in a gasifier then cleaned, cooled and applied as an alternative fuel in an engine operated from 0 - 100% load. Exhaust-emissions were monitored at this load conditions. The exhaust-temperature was measured using thermocouples and the emission gases were analyzed using Testo 350. The emissions were lower and decreased as the engine load increased, except for sulphur dioxide and NOx. The study shows that levels of carbon monoxide, were higher in a range of 46.5 - 80.2%, while carbon dioxide was 3.3 - 18% higher compared to those from diesel. Hydrocarbon emissions were 480 and 1250 ppm for diesel and syngas respectively. The study reveals that the engine operates optimally at higher loads since hydrocarbons and oxides of carbon are low due to complete combustion at higher temperatures. Exhaust gas temperature was higher in the syngas fuel and increased as the engine load increased in the range of 455.83 - 480.03˚C which influenced the formation of NOx. NOx from diesel was found to be higher, ranging from 32.5 - 40.5%, compared to those from syngas with an engine load of 75%. The study observed that relative to diesel, the emissions of sulfur dioxide at 50% engine load were lower in a range of 23.7 - 57.1%. Emissions of hydrocarbons depended on the degree of substitution of diesel and engine load. The study therefore shows that, relative to diesel, emissions decreased when syngas was used with upgraded syngas from Prosporis juliflora presenting as the best alternative followed by Hyphanae compressa, and lastly rice husk. For optimal performance of the syngas fuelled engine, the study reports that the engine should be operated at engine loads above 50% with strategies on NOx emissions considered.

Optimization of the Performance of Marine Diesel Engines to Minimize the Formation of SO_x Emissions

Optimization procedures are required to minimize the amount of fuel consumption and exhaust emissions from marine engines.This study discusses the procedures to optimize the performance of any marine engine implemented in a 0D/1D numerical model in order to achieve lower values of exhaust emissions.From that point,an extension of previous simulation researches is presented to calculate the amount of SOx emissions from two marine diesel engines along their load diagrams based on the percentage of sulfur in the marine fuel used.The variations of SOx emissions are computed in g/k W·h and in parts per million(ppm)as functions of the optimized parameters:brake specific fuel consumption and the amount of air-fuel ratio respectively.Then,a surrogate model-based response surface methodology is used to generate polynomial equations to estimate the amount of SOx emissions as functions of engine speed and load.These developed non-dimensional equations can be further used directly to assess the value of SOx emissions for different percentages of sulfur of the selected or similar engines to be used in different marine applications.

Analysis of the Emissions and Performance of a Diesel Engine Using Pumpkin Seed Oil Methyl Ester with Different Injection Pressures

Biodiesel fuel is a potential alternative energy source for diesel engines due to its physiochemical characteristics relatively similar to those of traditional diesel fuel.In this study,the performance,emission,and combustion features of a mono cylinder DI diesel engine are assessed using 20%Pumpkin seed methyl ester(PSOME20)and considering varying injection pressures(200,220,240,and 260 bar).The considered Pumpkin seed oil is converted into pumpkin biodiesel by transesterification and then used as fuel.The findings demonstrate that the Brake Thermal Efficiency(BTE)of PSOME20 can be raised by 1.68%,and the carbon monoxide(CO),hydrocarbon(HC),and smoke emanations can be lowered,while oxides of nitrogen(NOx)emissions are increased at an injection pressure(IP)of 240 bar compared to the standard IP of 200 bar.The cylinder pressure and the Heat Release Rate(HRR)become higher at 240 bar,whereas the ignition delay is shortened with respect to PSOME20 at a normal IP of 200 bar.

Influence of Urea Uneven Injection on the Performances of a Diesel Engine

The influence of heterogeneous flow injection of urea at different velocities and temperatures on NO x conversion efficiency,ammonia storage and ammonia leakage is investigated experimentally.A diesel engine employing a selective catalytic reduction(SCR)technology is considered.It is found that for a fixed injection velocity,the degree of ammonia leakage changes depending on the temperature.The higher the temperature,the faster the catalytic reduction reaction and the smaller the degree of ammonia leakage.The temperature has a great influence on the catalytic reduction reaction rate.At an injection velocity of 10000/h,the average reaction rate at 420℃ is 12 times higher than that at 180℃.The injection velocity has a weak influence on the reaction rate.When the injection velocity changes from 10000/h to 40000/h at the same temperature,the average reaction rate does not change appreciably.However,increasing the space velocity can accelerate the leakage of ammonia,thereby miti-gating the benefits associated with the NO_(x) conversion.

HC-PM COUPLING MODEL FOR PARTICULATE MATTER EMISSION OF DIESEL ENGINES

A rapid, phenomenological model that predicts paniculate matter (PM) emissionof diesel engines is developed and formulated. The model is a chemical equilibrium compositionmodel, and is based on the formation mechanisms of PM and unburned hydrocarbon (HC) emissions ofdiesel engines. It can evaluate the emission concentration of PM via the emission concentration ofHC. To validate the model, experiments are carried out in two research diesel engines. Comparisonsof the model results with the experimental data show good agreement. The model can be used toevaluate the concentration of PM emission of diesel engines under lack of PM measuring instruments.In addition, the model is useful for computer simulations of diesel engines, as well as electroniccontrol unit (ECU) designs for electronically controlled diesel engines.

A Strategy to Control the Turbocharger Energy of a Diesel Engine at Different Altitudes

Power deterioration is a major problem for diesel engines operating at high altitudes.This problem stems from the limited availability of turbocharger energy,which is not enough to increase the boost pressure to the required level.In this study,a control strategy is introduced in order to achieve engine power recovery at different altitudes.It is shown that as the altitude increases from 0 to 4500 m,the required boost pressure ratio increases from 2.4 to 4.3.The needed turbocharger energy should be increased accordingly by 240%,and the TCC(turbine characterization coefficient)should be adjusted within wide ranges.A 12%decrease in the TCC can lead to a rise of the intake air pressure,which can compensate the pressure decrease due to a 1000 m altitude increase.The fluctuation range of boost pressure was within 14.5 kPa for variations in altitude from 0 to 4500 m.

Investigating the Effects of Eichhornia Crassipes Biodiesel and Liquefied Petroleum Gas on the Performance and Emissions of a Dual-Fuel Engine

This study considers the effect of Eichhornia Crassipes Biodiesel(ECB)blends on the performances,combustion,and emission characteristics of a direct injection compression ignition engine operated in a dual-fuel mode(DFM)and equipped with an Exhaust gas recirculation technique(EGR).In particular,a single-cylinder,four-stroke,water-cooled diesel engine was utilized and four modes of fuel operation were considered:mode I,the engine operated with an ordinary diesel fuel;mode II,the engine operated with the addition of 2.4 L/min of lique-fied petroleum gas(LPG)and 20%EGR;mode III,20%ECB with 2.4 L/min LPG and 20%EGR;mode IV,40%ECB with 2.4 L/min LPG and 20%EGR.The operation conditions were constant engine speed(1500 rpm),var-iation of load(25%,50%,75%,and 100%),full load,with a compression ratio of 18,and a time injection of 23°BTDC(Before top died center).With regard to engine emissions,carbon dioxide(CO_(2)),carbon monoxide(CO),hydrocarbons(UHC),and nitrogen oxide(NOX)were measured using a gas analyzer.The smoke opacity was measured using an OPABOX smoke meter.By comparing the results related to the different modes with mode I at full load,the BTE(Brake thermal efficiency)increased by 20.17%,11.45%,and 12.66%with modes II,III,and IV,respectively.In comparison to the results for mode II,the BTE decreased due to the combustion of ECB blends by 7.26%and 6.24%for mode III and mode IV,respectively,at full load.In comparison to mode II,the Brake specific energy consumption(BSEC)increased with the ECB substitution.With ECB blends,there is a noticeable decrease in the CO,CO_(2),and UHC emissions at a partial load.Furthermore,the 20%ECB has no effect on CO emissions at full load.For modes II and IV,the CO_(2)increased by 33.33%and 19%,respectively,while the UHC emissions were reduced by 14.49%for mode III and 26.08%for mode IV.The smoke of mode III was lower by 7.21%,but for mode IV,it was higher by 12.37%.In addition,with mode III and mode IV,the NOx emissions increased by 30.50%and 18.80%,respectively.

Test Research on the Knock of a Common-Rail Diesel Engine Fueled with Diesel-Methanol Dual-Fuel

Experiments were conducted on a diesel-methanol dual-fuel(DMDF)engine modified by a six-cylinder,turbocharged,inter-cooled diesel engine.According to the number of diesel injection,the experiments are divided to two parts:the single injectionmode and double injectionmode.The results show that,at the double injectionmode,themaximumof pressure rise rate is small and the engine runs smoothly,however,knock still occurswhen the cocombustion ratio(CCR)is big enough.Under knock status,the power density of the block vibration concentrating at some special frequencies rises dramatically,and the special frequency of single injection mode(about 4.1 kHz)is lower than that of double injection mode(7–9 kHz).The cylinder pressure oscillations of knock status are very different fromthe non-knock status.Under knock status,cylinder pressure oscillations become more concentrated and fiercer at some special frequencies,and the same as the block vibration.The special frequency of single injection mode(3–6 kHz)is lower than that of double injection mode(above 9 kHz).

Hardware-in-the-Loop Research on the Electronic Control Unit for Diesel Engines

A hardware-in-the-loop simulating platform is developed to avoid designing defects caused by the complicated logical structure and multiple-functional buildup of the dectronic control unit（ECU）in modem diesel engines, and to diminish potential damages on components or human exposure to dangers in R＆D en- deavor. This plat-form consists of a computer installed with software Matlab/Simulink/RTW and dSPACE/ ControlDesk; a diesel engine ECU, and a dSPACE autobox which runs a real-time diesel engine model. A typical model of diesel engine with turbocharger and intercooler is presented. Based on this model our research is carried out with a real ECU to test its software control strategies. Results show that by using the diesel engine model downloaded inside, the hardware-in-the-loop platform can simulate diesel engine＇s working conditions and generate all kinds of sensor signals which ECU needs on a real-time basis. So the ECU control strategies can be validated and relevant parameters roughly calibrated.

Optimal Mixture Ratios of Biodiesel Ethanol Diesel for Diesel Engines

In this paper, we study the best-mixture ratio of biodiesel-ethanol-diesel for diesel engines. The simulation results show that the integrated indexes including engine power, cost-effectiveness and emission properties are rather better with different optimizing index when the ratio of bio-diesel, ethanol and diesel are 71.58:2.72:25.70 and 50:2.4127:47.5873.

Experiment Study on the Exhaust-Gas Heat Exchanger for Small and Medium-Sized Marine Diesel Engine

This paper aims to design a special exchanger to recover the exhaust gas heat of marine diesel engines used in small and medium-sized fishing vessels,which can then be used to heat water up to 55°C–85°C for membrane desalination devices to produce fresh water.A new exhaust-gas heat exchanger of fins and tube,with a reinforced heat transfer tube section,unequal spacing fins,a mixing zone between the fin groups and four routes tube bundle,was designed.Numerical simulations were also used to provide reference information for structural design.Experiments were carried out for exhaust gas waste heat recovery from a marine diesel engine in an engine test bench utilizing the heat exchanger.The experimental results show that the difference between heat absorption by water and heat reduction of exhaust gas is less than 6.5%.After the water flow rate was adjusted,the exhaust gas waste heat recovery efficiency was higher than 70%,and the exhaust-gas heat exchanger’s outlet water temperature was 55°C–85°C at different engine loads.This means that the heat recovery from the exhaust gas of a marine diesel engine meets the requirement to drive a membrane desalination device to produce fresh water for fishers working in small and medium-sized fishing vessels.

Optimizing the Exhaust System of Marine Diesel Engines to Improve Low-speed Performances and Cylinder Working Conditions

Proper design of exhaust systems in marine high-power turbocharged diesel engines can contribute to improve the low-speed performance of these engines and make the working conditions of the cylinders more uniform.Here a high-power marine 16-cylinder V-type turbocharged diesel engine is simulated using the GT-Power software.The results reveal the differences induced by different exhaust system structures,such as an 8-cylinder-inpipe exhaust system with single/double superchargers and a 4-cylinder-in-pipe exhaust system with a single supercharger.After a comparative analysis,the 8-cylinder type with double superchargers is determined to be the optimal solution,and the structure of the exhaust system is further optimized.The simulations show that the optimized maximum exhaust temperature difference among cylinders is reduced by 66%.Finally,the simulation results and the optimized performance of the designed exhaust system are verified through experiments.

Miller Cycle with Early Intake Valve Closing in Marine Medium-Speed Diesel Engines

In this study,a one-dimensional simulation was performed to evaluate the performance of in-cylinder combustion to control NO_(x) emissions on a four-stroke,six-cylinder marine medium-speed diesel engine.Reducing the combustion temperature is an important in-cylinder measure to decrease NO_(x) emissions of marine diesel engines.The Miller cycle is an effective method used to reduce the maximum combustion temperature in a cylinder and accordingly decrease NO_(x) emissions.Therefore,the authors of this study designed seven different early intake valve closing(EIVC)Miller cycles for the original engine,and analyzed the cycle effects on combustions and emissions in high-load conditions.The results indicate that the temperature in the cylinder was significantly reduced,whereas fuel consumption was almost unchanged.When the IVC was properly advanced,the ignition delay period increased and the premixed combustion accelerated,but the in-cylinder average pressure,temperature and NO_(x) emissions in the cylinder were lower than the original engine.However,closing the intake valve too early led to high fuel consumption.In addition,the NO_(x) emissions,in-cylinder temperature,and heat release rate remarkably increased.Therefore,the optimal timing of the EIVC varied with different loads.The higher the load was,the earlier the best advance angle appeared.Therefore,the Miller cycle is an effective method for in-engine NO_(x) purification and does not entail significant cost.

Assessment of the Application of Subcooled Fluid Boiling to Diesel Engines for Heat Transfer Enhancement

The increasing demand of cooling in internal combustion engines(ICE)due to engine downsizing may require a shift in the heat removal method from the traditional single phase liquid convection to the application of new technologies based on subcooled fluid boiling.Accordingly,in the present study,experiments based on subcooled flow boiling of 50/50 by volume mixture of ethylene glycol and water coolant(EG/W)in a rectangular channel heated by a cast iron block are presented.Different degrees of subcooling,velocity and pressure conditions are examined.Comparison of three empirical reference models shows that noticeable deviations occur especially when low bulk subcooling and velocity conditions are considered.On the basis of the experimental data,a modified power-type wall heat flux model is developed and its ability to represent adequately reality is tested through numerical simulations against a reference rig case and a practical diesel engine.Computational results show that this modified model can effectively be used for practical engine cooling system design.

Effect of Palm Oil Biodiesel Blends on Engine Emission and Performance Characteristics in an Internal Combustion Engine

Increasing global environmental issues and depleting fossil fuel reserves has necessitated the need for alternative and sustainable fuel. In this paper, the effects of biodiesel and its blend on engine emission and performance characteristics in an internal combustion engine were analyzed. Biodiesel derived from the transesterification of raw palm oil was blended with diesel fuel at different proportions designated as PO5 (5% Biodiesel and 95% Diesel), PO10 (10% Biodiesel and 90% Diesel), PO15 (15% Biodiesel and 85% Diesel), PO20 (20% Biodiesel and 80% Diesel), PO50 (50% Biodiesel and 50% Diesel), PO85 (85% Biodiesel and 15% Diesel), and PO100 (100% Biodiesel). A Lombardini 2-cylinder, four-stroke direct injection diesel engine with a compression ratio of 22.8 was developed using Ricardo Wave software in which diesel, palm oil biodiesel blends and pure biodiesel are used in the model, and the obtained results were analysed and presented. The simulation was done under varying engine speeds of 1200 rpm to 3200 rpm at full load condition. Biodiesel and its blends are more environment-friendly and non-toxic when compared to diesel fuel;it also improves the mechanical efficiency of the engines, and above all can also lead to a reduction in poverty among rural dwellers. The obtained results showed that brake specific fuel consumption and brake thermal efficiency increased with palm oil biodiesel blends as compared to diesel fuel which might be a result of biodiesel’s lower heating value, and the increase in thermal energy may be a result of the oxygenation of the biodiesel blend as compared to pure diesel. In terms of brake torque, palm oil biodiesel blends were lesser than diesel fuel. The CO, HC, and NOx emissions of palm oil biodiesel blends decreased significantly compared to that of pure diesel. From this study, palm oil biodiesel emits lesser emissions than diesel fuel and its performance characteristics are similar to diesel fuel. Therefore, palm oil biodiesel can be used without any modifications directly in a diesel engine. In addition, it can also be used as blends as an alternative and sustainable fuel, decreasing air pollution, and increasing environmental sustainability.

A New Method for Computing Radiation Heat Flow of In-Cylinder Soot of Diesel Engines

A concise formula for computing radiation heat flow of in-cylinder soot is presented, based on the assumptions that in-cylinder heat transfer of diesel engines is a quasi-equilibrium process and in-cylinder soot particles are spherical. That in this formula there consist neither constants needing adjustments nor variables related to engine types or operating conditions makes it universal and easy to use. Also it can be seen from the formula that radiation heat transfer is proportional to the quotient of in-cylinder soot mass over the average radius of primary particles. Besides, with the help of different algorithms it can be used for predicting cylinders＇ global as well as local radiation heat flows. As a demonstrative application on its global facet, a three-dimension simulation study about the soot-radiation-related heat flow in the combustion chamber of a diesel engine is carried out. Results show that the range of the soot-radiation-related heat flow computed by this formula agrees well with other researcher＇s earlier theoretic reasoning and experimental measurements.

A Review and Comparison on Recent Optimization Methodologies for Diesel Engines and Diesel Power Generators

The electrical instability that frequently distinguishes the isolated networks and depends on diesel generators to supply their energy requirements leads to an operation of the diesel generator in a transient dynamic condition and/or at low loads. In addition, extended operation of the diesel generator at partial load develops the condensation of combustion residues on the engine cylinder walls, which, after a certain time, increases friction, reduces the efficiency of the equipment and increases its fuel consumption. On the other hand, recent regulatory changes have led to ever more stringent and evolving emission standards. Among these, the International Maritime Organization (IMO) and the Environmental Protection Agency (EPA) have implemented emission standards in order to reduce exhaust gas emitted by marine diesel engines. To phase lower emission engines as soon as possible, a Tier system was adopted. This paper presents a literature review of existing technologies available to optimize the energy performance of diesel engines and diesel generators in order to reduce the cost of electricity, to increase the diesel engine efficiency and to decrease their fuel consumption and greenhouse gases (GHG) emissions. The proposed optimization methodologies are based on the application of Pre-treatment, Internal treatment and Post-treatment technologies for diesel engines and on the application of mechanical and electrical technologies for diesel power generators (DPGs). The list of references given at the end of the paper should offer aids for students and researchers working in this field.

An Evaluation of Human Error Probabilities for Critical Failures in Auxiliary Systems of Marine Diesel Engines

Human error,an important factor,may lead to serious results in various operational fields.The human factor plays a critical role in the risks and hazards of the maritime industry.A ship can achieve safe navigation when all operations in the engine room are conducted vigilantly.This paper presents a systematic evaluation of 20 failures in auxiliary systems of marine diesel engines that may be caused by human error.The Cognitive Reliability Error Analysis Method(CREAM)is used to determine the potentiality of human errors in the failures implied thanks to the answers of experts.Using this method,the probabilities of human error on failures were evaluated and the critical ones were emphasized.The measures to be taken for these results will make significant contributions not only to the seafarers but also to the ship owners.