The structural studies of noncrystalline rocks by total radial distribution function (RDF) which was derived from the wide angular X-ray scattering (WAXS) have been reported. In order to make a further study of the st...The structural studies of noncrystalline rocks by total radial distribution function (RDF) which was derived from the wide angular X-ray scattering (WAXS) have been reported. In order to make a further study of the structural features shown by RDF, the unsymmetric peaks in total RDF were separated into the approximately symmetric peaks by the multi-peaks separation processing. By analyzing the relationship of the peak parameters with the compositions, the information of further structures has been discussed.展开更多
In this experiment, strontium borate glasses were prepared using the conventional quenching method in air atmosphere. Optical absorption, photoluminescence excitation and emission spectra, X-ray excited luminescence ...In this experiment, strontium borate glasses were prepared using the conventional quenching method in air atmosphere. Optical absorption, photoluminescence excitation and emission spectra, X-ray excited luminescence （XEL）, and luminescence decay curve of the as-prepared glasses were investigated at room temperature. The as-prepared glasses had two kinds of Eu ions, i.e., Eu^2＋ and Eu^2＋. Compared with the reported results of strontium borate glasses, Eu^2＋ luminescence was enhanced in the studied strontium borate glasses coprepared with F^- and Li^＋ ions. The coexisting of Li^＋ or F^- in the borate glasses could create more negative defect Vsr″ and stabilize Eu^2＋ ions, which might act as donor of electrons; For the F^- doping, the new center of B（O, F）4 （or BO3F） and BO2F2 units could be considered to be the distorted （BO4）, which were needed as a rigid framework to stabilize the divalent rare earth ions.展开更多
Limited information is available concerning the mineralogy of paddy soils in the southeastern China.Using chemical methods in conjunction with X-ray diffractometry, we studied the mineral composition of three paddy so...Limited information is available concerning the mineralogy of paddy soils in the southeastern China.Using chemical methods in conjunction with X-ray diffractometry, we studied the mineral composition of three paddy soils: Jinghua (paddy soil on Quaternary red clay), Fuyang (Hapl-percogenic loamy paddy soil), and Shaoxing (gleyic clayey paddy soil). All the soils contained quartz, mica, vermiculite, chlorite and kaolinite, and the distribution of these minerals varied with soil particle size fractions. The clay fraction of the F’uyang and Shaoxing soils also contained smectite. Although X-ray data did not show the presence of smectite in the Jinghua soil, this mineral was identified by the chemical method, suggesting a transitional property of the mineral in the soil. Hydroxy-Al interlayered minerals were also present in the clay fraction.The amount of smectite in the soils was 31.6 (Shaoxing), 16.5 (Fuyang), and 21.4 (Jinghua) g kg-1; for vermiculite it was 33.3 (Shaoxing), 16.5 (Fuyang), and 8.5 (Jinghua) g kg-1. Smectite was only found in the clay fraction. In contrast, amounts of vermiculite in soil particle size fractions were 3.0～11.4 (sand),2.1～6.0 (coarse silt), 4.6～18.9 (medium silt), 0.9～40.0 (fine silt), and 17.0～108 (clay) g kg-1. The amount of noncrystalline aluminosilicates in the soils in g kg-1 decreased in the order: Shaoxing (2.4) > Jinghua (1.9) > Fuyang (1.7). This study has provided useful mineralogical information that is fundamental in future developmellt of management strategies of the soils.展开更多
文摘The structural studies of noncrystalline rocks by total radial distribution function (RDF) which was derived from the wide angular X-ray scattering (WAXS) have been reported. In order to make a further study of the structural features shown by RDF, the unsymmetric peaks in total RDF were separated into the approximately symmetric peaks by the multi-peaks separation processing. By analyzing the relationship of the peak parameters with the compositions, the information of further structures has been discussed.
基金Jiangsu Provincial Natural Science Foundation of China (BK-2007053) the Second Stage of Brain Korea 21 Project Corporations at Changwon National University
文摘In this experiment, strontium borate glasses were prepared using the conventional quenching method in air atmosphere. Optical absorption, photoluminescence excitation and emission spectra, X-ray excited luminescence （XEL）, and luminescence decay curve of the as-prepared glasses were investigated at room temperature. The as-prepared glasses had two kinds of Eu ions, i.e., Eu^2＋ and Eu^2＋. Compared with the reported results of strontium borate glasses, Eu^2＋ luminescence was enhanced in the studied strontium borate glasses coprepared with F^- and Li^＋ ions. The coexisting of Li^＋ or F^- in the borate glasses could create more negative defect Vsr″ and stabilize Eu^2＋ ions, which might act as donor of electrons; For the F^- doping, the new center of B（O, F）4 （or BO3F） and BO2F2 units could be considered to be the distorted （BO4）, which were needed as a rigid framework to stabilize the divalent rare earth ions.
文摘Limited information is available concerning the mineralogy of paddy soils in the southeastern China.Using chemical methods in conjunction with X-ray diffractometry, we studied the mineral composition of three paddy soils: Jinghua (paddy soil on Quaternary red clay), Fuyang (Hapl-percogenic loamy paddy soil), and Shaoxing (gleyic clayey paddy soil). All the soils contained quartz, mica, vermiculite, chlorite and kaolinite, and the distribution of these minerals varied with soil particle size fractions. The clay fraction of the F’uyang and Shaoxing soils also contained smectite. Although X-ray data did not show the presence of smectite in the Jinghua soil, this mineral was identified by the chemical method, suggesting a transitional property of the mineral in the soil. Hydroxy-Al interlayered minerals were also present in the clay fraction.The amount of smectite in the soils was 31.6 (Shaoxing), 16.5 (Fuyang), and 21.4 (Jinghua) g kg-1; for vermiculite it was 33.3 (Shaoxing), 16.5 (Fuyang), and 8.5 (Jinghua) g kg-1. Smectite was only found in the clay fraction. In contrast, amounts of vermiculite in soil particle size fractions were 3.0～11.4 (sand),2.1～6.0 (coarse silt), 4.6～18.9 (medium silt), 0.9～40.0 (fine silt), and 17.0～108 (clay) g kg-1. The amount of noncrystalline aluminosilicates in the soils in g kg-1 decreased in the order: Shaoxing (2.4) > Jinghua (1.9) > Fuyang (1.7). This study has provided useful mineralogical information that is fundamental in future developmellt of management strategies of the soils.
