Based on Schaaff＇s collision factor theory （CFT） in liquids, the equations for nonlinear ultrasonic parameters in both organic liquid and binary organic liquid mixtures are deduced. The nonlinear ultrasonic paramet...Based on Schaaff＇s collision factor theory （CFT） in liquids, the equations for nonlinear ultrasonic parameters in both organic liquid and binary organic liquid mixtures are deduced. The nonlinear ultrasonic parameters, including pressure coefficient, temperature coefficients of ultrasonic velocity, and nonlinear acoustic parameter B/A in both organic liquid and binary organic liquid mixtures, are evaluated for comparison with the measured results and data from other sources. The equations show that the coefficient of ultrasonic velocity and nonlinear acoustic parameter B/A are closely related to molecular interactions. These nonlinear ultrasonic parameters reflect some information of internal structure and outside status of the medium or mixtures. From the exponent of repulsive forces of the molecules, several thermodynamic parameters, pressure and temperature of the medium, the nonlinear ultrasonic parameters and ultrasonic nature of the medium can be evaluated. When evaluating and studying nonlinear acoustic parameter B/A of binary organic liquid mixtures, there is no need to know the nonlinear acoustic parameter B/A of the components. Obviously, the equation reveals the connection between the nonlinear ultrasonic nature and internal structure and outside status of the mixtures more directly and distinctly than traditional mixture law for B/A, e.g. Apfel＇s and Sehgal＇s laws for liquid binary mixtures.展开更多
Based on Jacobson’s molecular free length theory in liquids and the relationship between the ultrasonic velocity and the molecular free length in organic liquids, the equation of the acoustic nonlinearity parameter i...Based on Jacobson’s molecular free length theory in liquids and the relationship between the ultrasonic velocity and the molecular free length in organic liquids, the equation of the acoustic nonlinearity parameter in organic liquid binary mixtures is derived. The calculated values from the equation are in good agreement both with those from Apfel’s and from Sehgal’s mixture laws.展开更多
文摘Based on Schaaff＇s collision factor theory （CFT） in liquids, the equations for nonlinear ultrasonic parameters in both organic liquid and binary organic liquid mixtures are deduced. The nonlinear ultrasonic parameters, including pressure coefficient, temperature coefficients of ultrasonic velocity, and nonlinear acoustic parameter B/A in both organic liquid and binary organic liquid mixtures, are evaluated for comparison with the measured results and data from other sources. The equations show that the coefficient of ultrasonic velocity and nonlinear acoustic parameter B/A are closely related to molecular interactions. These nonlinear ultrasonic parameters reflect some information of internal structure and outside status of the medium or mixtures. From the exponent of repulsive forces of the molecules, several thermodynamic parameters, pressure and temperature of the medium, the nonlinear ultrasonic parameters and ultrasonic nature of the medium can be evaluated. When evaluating and studying nonlinear acoustic parameter B/A of binary organic liquid mixtures, there is no need to know the nonlinear acoustic parameter B/A of the components. Obviously, the equation reveals the connection between the nonlinear ultrasonic nature and internal structure and outside status of the mixtures more directly and distinctly than traditional mixture law for B/A, e.g. Apfel＇s and Sehgal＇s laws for liquid binary mixtures.
文摘Based on Jacobson’s molecular free length theory in liquids and the relationship between the ultrasonic velocity and the molecular free length in organic liquids, the equation of the acoustic nonlinearity parameter in organic liquid binary mixtures is derived. The calculated values from the equation are in good agreement both with those from Apfel’s and from Sehgal’s mixture laws.
