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Effect of process parameters on the morphology of aluminum/copper alloy lap joints by red and blue hybrid laser welding
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作者 宋曜祥 肖梦智 +4 位作者 黄德才 张瑞华 尹燕 茹恩光 吴怡霖 《China Welding》 CAS 2024年第2期23-30,共8页
In order to overcome the problems of many pores,large deformation and unstable weld quality of traditional laser welded aluminumcopper alloy joints,a red-blue dual-beam laser source and a swinging laser were introduce... In order to overcome the problems of many pores,large deformation and unstable weld quality of traditional laser welded aluminumcopper alloy joints,a red-blue dual-beam laser source and a swinging laser were introduced for welding.T2 copper and 6063 aluminum thin plates were lap welded by coaxial dual-beam laser welding.The morphology of weld cross section was compared to explore the influence of process parameters on the formation of lap joints.The microstructure characteristics of the weld zone were observed and compared by optical microscope.The results show that the addition of laser beam swing can eliminate the internal pores of the weld.With the increase of the swing width,the weld depth decreases,and the weld width increases first and then decreases.The influence of welding speed on the weld cross section morphology is similar to that of swing width.With the increase of welding speed,the weld width increases first and then decreases,while the weld depth decreases all the time.This is because that the red laser is used as the main heat source to melt the base metals,with the increase of red laser power,the weld depth increases.As an auxiliary laser source,blue laser reduces the total energy consumption,consequently,the effective heat input increases and the spatter is restrained effectively.As a result,the increase of red laser power has an enhancement effect on the weld width and weld depth.When the swing width is 1.2 mm,the red laser power is 550 W,the blue laser power is 500 W,and the welding speed is 35 mm/s,the weld forming is the best.The lap joint of T2 copper and 6063 aluminum alloy thin plate can be connected stably with the hybrid of blue laser.The effect rules of laser beam swing on the weld formation were obtained,which improved the quality of the joints. 展开更多
关键词 laser welding aluminum/copper alloy dual beam process parameters weld morphology
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Superplastic solid state welding of steel and copper alloy based on laser quenching of steel surface 被引量:6
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作者 张柯柯 韩彩霞 +3 位作者 权淑丽 程光辉 杨洁 杨蕴林 《中国有色金属学会会刊:英文版》 CSCD 2005年第2期384-388,共5页
Based on the feasibility of isothermal superplastic solid state welding of steel and copper alloy, the welded surface of steel surface was ultra-fined through laser quenching, and then the welding process tests betwee... Based on the feasibility of isothermal superplastic solid state welding of steel and copper alloy, the welded surface of steel surface was ultra-fined through laser quenching, and then the welding process tests between different base metals of 40Cr and QCr0.5 were made under the condition of non vacuum and non shield gas. The experimental results show that, with the sample surface of steel after laser quenching and that of copper alloy carefully cleaned, and under the pre-pressed stress of 56.684.9 MPa, at the welding temperature of 750800 ℃ and at initial strain rate of (2.57.5)×10-4 s-1, the solid state welding can be finished in 120180 s so that the strength of the joint is up to that of QCr0.5 base metal and the expansion rate of the joint does not exceed 6%. The plastic deformation of the joint was further analysed. The superplastic deformation of the copper alloy occurs in welding process and the deformation of steel are little. 展开更多
关键词 铜合金 钢材 激光淬火 超塑性形变 固态焊接
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Microstructural evolution and mechanical properties of friction stir-welded C71000 copper–nickel alloy and 304 austenitic stainless steel 被引量:6
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作者 Hamed Jamshidi Aval 《International Journal of Minerals,Metallurgy and Materials》 SCIE EI CAS CSCD 2018年第11期1294-1303,共10页
Dissimilar joints comprised of copper–nickel and steel alloys are a challenge for manufacturers in modern industries, as these metals are not thermomechanically or chemically well matched. The present study investiga... Dissimilar joints comprised of copper–nickel and steel alloys are a challenge for manufacturers in modern industries, as these metals are not thermomechanically or chemically well matched. The present study investigated the effects of tool rotational speed and linear speed on the microstructure and mechanical properties of friction stir-welded C71000 copper–nickel and 340 stainless steel alloys using a tungsten carbide tool with a cylindrical pin. The results indicated that a rotational-to-linear speed ratio of 12.5 r/mm did not cause any macro defects, whereas some tunneling defects and longitudinal cracks were found at other ratios that were lower and higher. Furthermore, chromium carbide was formed on the grain boundaries of the 304 stainless steel near the shoulder zone and inside the joint zone, directing carbon and chromium penetration toward the grain boundaries. Tensile strength and elongation percentages were 84% and 65% of the corresponding values in the copper–nickel base metal, respectively. 展开更多
关键词 dissimilar FRICTION STIR welding copper–nickel alloy AUSTENITIC STAINLESS steel microstructure MECHANICAL properties
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Microstructures and properties analysis of dissimilar metal joint in the friction stir welded copper to aluminum alloy 被引量:9
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作者 王希靖 张忠科 +1 位作者 达朝炳 李晶 《China Welding》 EI CAS 2007年第1期57-62,共6页
This paper mainly concentrated on the feasibility of friction stir welding of dissimilar metal of aluminum alloy to copper (I2) and a preliminary analysis of welding parameters influencing on the microstructures and... This paper mainly concentrated on the feasibility of friction stir welding of dissimilar metal of aluminum alloy to copper (I2) and a preliminary analysis of welding parameters influencing on the microstructures and properties of joint was carried out. The results indicated that the thickness of workpiece played an important role in the welding parameters which could succeed in the friction stir welding of dissimilar metal of copper to aluminum alloy, and the parameters were proved to be a narrow choice. The interfacial region between copper and aluminum in the dissimilar joint was not uniformly mixed, constituted with part of incomplete mixing zone, complete mixing zone, dispersion zone and the most region' s boundary was obvious. Meantime a kind banded structure with inhomogeneous width was formed. The intermetallic compounds generated during friction stir welding in the interfacial region were mainly CugAl4, Al2Cu etc, and their hardness was higher than oihers. 展开更多
关键词 friction stir welding dissimilar metals copper aluminum alloy
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Effect of Fe content on the friction and abrasion properties of copper base overlay on steel substrate by TIG welding 被引量:1
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作者 吕世雄 宋建岭 +1 位作者 刘磊 杨士勤 《China Welding》 EI CAS 2009年第3期55-59,共5页
Copper base alloy was overlaid onto 35CrMnSiA steel plate by tungsten inert gas (TIG) welding method. The heat transfer process was simulated, the microstructures of the copper base overlay were analyzed by scanning... Copper base alloy was overlaid onto 35CrMnSiA steel plate by tungsten inert gas (TIG) welding method. The heat transfer process was simulated, the microstructures of the copper base overlay were analyzed by scanning electron microscopy (SEM) and energy dispersive spectrometer (EDS), and the friction and abrasion properties of the overlay were measured. The results show that the Fe content increases in the overlay with increasing the welding current. And with the increase of Fe content in the overlay, the friction coefficient increases and the wear mechanism changes from oxidation wear to abrasive wear and plough wear, which is related to the size and quantity of Fe grains in the overlay. While with the increase of Fe content in the overlay, the protection of oxidation layer against the oxidation wear on the melted metal decreases. 展开更多
关键词 Fe content copper base alloy TIG welding overlay friction and abrasion
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Refill Friction Stir Spot Welding Al Alloy to Copper via Pure Metallurgical Joining Mechanism
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作者 Zhikang Shen Yuquan Ding +6 位作者 Wei Guo Wentao Hou Xiaochao Liu Haiyan Chen Fenjun Liu Wenya Li Adrian Gerlich 《Chinese Journal of Mechanical Engineering》 SCIE EI CAS CSCD 2021年第4期90-97,共8页
The current investigation of refill friction stir spot welding(refill FSSW)Al alloy to copper primarily involved plunging the tool into bottom copper sheet to achieve both metallurgical and mechanical interfacial bond... The current investigation of refill friction stir spot welding(refill FSSW)Al alloy to copper primarily involved plunging the tool into bottom copper sheet to achieve both metallurgical and mechanical interfacial bonding.Compared to conventional FSSW and pinless FSSW,weld strength can be significantly improved by using this method.Nevertheless,tool wear is a critical issue during refill FSSW.In this study,defect-free Al/copper dissimilar welds were successfully fabricated using refill FSSW by only plunging the tool into top Al alloy sheet.Overall,two types of continuous and ultra-thin intermetallic compounds(IMCs)layers were identified at the whole Al/copper interface.Also,strong evidence of melting and resolidification was observed in the localized region.The peak temperature obtained at the center of Al/copper interface was 591℃,and the heating rate reached up to 916℃/s during the sleeve penetration phase.A softened weld region was produced via refill FSSW process,the hardness profile exhibited a W-shaped appearance along middle thickness of top Al alloy.The weld lap shear load was insensitive to the welding condition,whose scatter was rather small.The fracture path exclusively propagated along the IMCs layer of Cu_(9)Al_(4) under the external lap shear loadings,both CuAl_(2) and Cu_(9)Al_(4) were detected on the fractured surface on the copper side.This research indicated that acceptable weld strength can be achieved via pure metallurgical joining mechanism,which has significant potential for the industrial applications. 展开更多
关键词 Refill friction stir spot welding Al alloy copper Interfacial microstructure Mechanical properties
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Microstructure of deep cryogenic treatment electrode for resistance spot welding of aluminium alloy
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作者 吴志生 高珊 +3 位作者 赵菲 陈晓燕 阴旭 王晓峰 《China Welding》 EI CAS 2010年第4期49-53,共5页
Cr-Zr-Cu alloy electrodes for resistance spot welding of aluminium alloy are treated by deep cryogenic treatment processes. The Cr-Zr-Cu alloy electrodes are analyzed by transmission electron microscope( TEM ) , and... Cr-Zr-Cu alloy electrodes for resistance spot welding of aluminium alloy are treated by deep cryogenic treatment processes. The Cr-Zr-Cu alloy electrodes are analyzed by transmission electron microscope( TEM ) , and results show that the common dislocation in Cr-Zr-Cu alloy electrodes is changed into the dislocation loop, and twin crystal is found after deep cryogenic treatment. The parallel twin crystal band is observed by selected electron diffraction(SED) and the twin crystal plane is marked as ( 111 ). The Cr-Zr-Cu alloy electrode is studied by X-ray diffraction( XRD ) and results show that the intensity of diffraction peak is obviously changed after deep cryogenic treatment, and the grain rotates to preferred orientation. The Cr-Zr- Cu alloy electrode is studied by positron annihilation technique (PAT) and results indicate that the amount of vacancy defects is less than that of Cr-Zr-Cu alloy before deep cryogenic treatment. The main elements in Cr-Zr-Cu alloy are studied with X- ray photoelctron spectroscopy( XPS ) and the intensity of spectrum peak is increased after deep cryogenic treatment. 展开更多
关键词 MICROSTRUCTURE deep cryogenic treatment copper alloy ELECTRODE resistance spot welding
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Research on microstructures and properties of electron beam welding joints of Ti-Ni-Cu
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作者 陈国庆 张秉刚 +1 位作者 左跃 冯吉才 《China Welding》 EI CAS 2011年第2期51-55,共5页
This paper reports research into the microstructures and technology of electron beam butt welding joints between copper alloy and titanium alloy sheet. Ni was introduced as an interlayer for electron beam welding test... This paper reports research into the microstructures and technology of electron beam butt welding joints between copper alloy and titanium alloy sheet. Ni was introduced as an interlayer for electron beam welding test. The structure of the joint and phases present were analyzed, as well as the fracture mechanism and fracture site of the joint. When the Ni interlayer was added, the most of the weld was composed of a copper and nickel based solid solution. Only a small amount of the brittle TiCu phase was present, replaced by Ti-Ni-Cu compounds with better performance. Compared with welds without the added interlayer, the tensile strength of the joint was improved significantly. 展开更多
关键词 titanium alloy copper alloy electron beam welding INTERLAYER
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Microstructure and performance of dissimilar joint QCr0.8/TC4 welded by uncentered electron beam 被引量:5
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作者 LIU Wei,ZHANG Binggang,HE Jingshan and ZHAO Haisheng State Key Laboratory of Advanced Welding Production Technology,Harbin Institute of Technology,Harbin 150001,China 《Rare Metals》 SCIE EI CAS CSCD 2007年第S1期344-348,共5页
The mechanical property of dissimilar metal joint between QCr0.8 and TC4 alloy made with centered electron beam is bad and the highest tensile strength of the joint is only about 82.1 MPa.The bad mechanical property i... The mechanical property of dissimilar metal joint between QCr0.8 and TC4 alloy made with centered electron beam is bad and the highest tensile strength of the joint is only about 82.1 MPa.The bad mechanical property is mainly caused by the asymmetric fusion of the two base metals and the generation of the brittle Ti-Cu intermetallic compounds.The finite element analysis shows that the amount of the melted QCr0.8 copper alloy can be added to reduce the amount of the brittle intermetallic compounds.The bias distance to the copper alloy hc has obvious effect on the tensile strength.When hc=0.8 mm,the tensile strength of the joint can reach 270.5 MPa.The reaction layer near the fusion line on the TC4 side consists of the intermetallic compound and the melted base metal which does not react.The joint fractures at the reaction layer and presents quasi-cleavage or transcrystalline rupture in tensile tests. 展开更多
关键词 QCr0.8 copper alloy TC4 alloy uncentered electron beam welding
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Mechanical Properties of Laser Welded Joint of Copper and Steel Dissimilar Metals
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作者 REN Yiwen TAO Junhui +8 位作者 LI Jie CHEN Xinqi ZHANG Lin WANG Chuanhui JIN Haiqin QI Hongyan WANG Zhuo XIE Xing PAN Jie 《Wuhan University Journal of Natural Sciences》 CAS CSCD 2023年第1期68-76,共9页
In this research project,copper and stainless steel were connected by two laser welding methods:straight seam welding and swing welding.Then,electronic tensile test machine,X-ray diffractometer,scanning electron micro... In this research project,copper and stainless steel were connected by two laser welding methods:straight seam welding and swing welding.Then,electronic tensile test machine,X-ray diffractometer,scanning electron microscope and metallographic microscope were used to analyze the tensile properties,macroscopic and microscopic structure morphology and phase of the welded joint.Based on the experimental results,we determined that the strength of the straight seam welded joint was higher.Because of the intermetallic compound near the weld in the swing welding process,it leads to stress concentration,crack cracking and strength reduction.In addition,the oscillating laser beam also leads to the disorderly direction of columnar crystal and coarse structure,which makes the joint strength decrease. 展开更多
关键词 copper steel dissimilar alloy laser welding mechanical properties
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Dissimilar Joining of Pure Copper to Aluminum Alloy via Friction Stir Welding 被引量:7
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作者 Farhad Bakhtiari Argesi Ali Shamsipur Seyyed Ehsan Mirsalehi 《Acta Metallurgica Sinica(English Letters)》 SCIE EI CAS CSCD 2018年第11期1183-1196,共14页
In this study, the dissimilar friction stir welding (FSW) butt joints between aluminum alloy 5754-H114 and commerciallypure copper were investigated. The thickness of welded plates was 4 mm and the aluminum plate wa... In this study, the dissimilar friction stir welding (FSW) butt joints between aluminum alloy 5754-H114 and commerciallypure copper were investigated. The thickness of welded plates was 4 mm and the aluminum plate was placed on theadvancing side. In order to obtain a suitable flow and a better material mixing, a 1-mm offset was considered for thealuminum plate, toward the butt centerline. For investigating the microstructure and mechanical properties of FSWedjoints, optical microscopy and mechanical tests (i.e., uniaxial tensile test and microhardness) were used, respectively.Furthermore, the analysis of intermetallic compounds and fracture surface was examined by scanning electron microscopyand X-ray diffraction. The effect of heat generation on the mechanical properties and microstructure of the FSWed jointswas investigated. The results showed that there is an optimum amount of heat input. The intermetallic compounds formedin FSWed joints were A14Cu9 and AI2Cu. The best results were found in joints with 1000 rpm rotational speed and100 mm/min travel speed. The tensile strength was found as 219 MPa, which reached 84% of the aluminum base strength.Moreover, maximum value of the microhardness of the stir zone (SZ) was attained as about 120 HV, which was greatlydepended on the grain size, intermetallic compounds and copper pieces in SZ. 展开更多
关键词 Friction stir welding 5754-H114 aluminum alloy Pure copper Heat generation MICROSTRUCTURE Intermetallic compounds
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铝合金与镀铜钢CMT熔钎焊技术研究
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作者 单琪 张超 +1 位作者 谢鹏 何兵 《热加工工艺》 北大核心 2024年第1期48-52,57,共6页
采用Al Si12药芯焊丝作为填充材料,对2 mm厚的6082铝合金与Q235B镀铜钢进行对接冷金属过渡(CMT)熔钎焊接试验,研究不同焊接速度和镀铜层厚度对接头焊缝成型、界面组织和力学性能的影响,探讨Cu元素对金属间化合物层(IMC)生长的影响。结... 采用Al Si12药芯焊丝作为填充材料,对2 mm厚的6082铝合金与Q235B镀铜钢进行对接冷金属过渡(CMT)熔钎焊接试验,研究不同焊接速度和镀铜层厚度对接头焊缝成型、界面组织和力学性能的影响,探讨Cu元素对金属间化合物层(IMC)生长的影响。结果表明:当焊接速度为350 mm/min时,铝在钢板正反面均有良好的润湿铺展,焊缝成型美观;IMC层厚度过大或过小均会对接头性能产生不利影响,当镀铜层厚度为10μm时,IMC层厚度为2.38μm,接头抗拉强度达到峰值138.7 MPa,相较于未镀铜接头的提高了31.9%,接头断裂于铝侧热影响区。镀铜层可以抑制界面层中θ-Fe(Al,Si)_(3)相的生成,阻碍Al、Fe反应,降低IMC层厚度。适当的镀铜层厚度可以有效改善接头的力学性能。镀铜层厚度过大促使Al_(2)Cu相产生,成为接头的薄弱区域。 展开更多
关键词 铝合金 镀铜钢 CMT熔钎焊 金属间化合物(IMC)
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铜/钛异种金属焊接微观组织及力学性能研究 被引量:2
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作者 潘明财 周杰 +1 位作者 郭顺 兰司 《铜业工程》 CAS 2023年第2期1-7,共7页
研究采用电子束偏置铜侧的方法完成了T2铜和TC4的异种金属焊接,并采用光学显微镜(OM)、扫描电镜(SEM)、显微硬度及抗拉强度测试等方式分析其微观组织及力学性能特征。研究结果表明:铜侧焊接具有成形较好的焊缝,焊缝表面鱼鳞纹较均匀,成... 研究采用电子束偏置铜侧的方法完成了T2铜和TC4的异种金属焊接,并采用光学显微镜(OM)、扫描电镜(SEM)、显微硬度及抗拉强度测试等方式分析其微观组织及力学性能特征。研究结果表明:铜侧焊接具有成形较好的焊缝,焊缝表面鱼鳞纹较均匀,成形较好,无明显的微裂纹、气孔以及夹渣现象,电子束焊接可实现单侧焊接双面成形。钛合金侧焊缝可观察到宽度25~40μm的金属间化合物层,金属间化合物层由多种反应产物组成,金属间化合物层的存在将恶化接头的力学性能。在偏铜侧1.5 mm焊接时,抗拉强度可达到152 MPa,相当于T2 Cu抗拉强度的66%,拉伸断口表现为脆性解理断裂,引起断裂的主要物相为CuTi相。 展开更多
关键词 钛合金 铜合金 电子束焊接 微观组织 力学性能
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钛合金/铜-镍/不锈钢焊接接头的组织与性能
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作者 常敬欢 余刚 +3 位作者 曹睿 闫英杰 隋然 席筱蓓 《焊接学报》 EI CAS CSCD 北大核心 2023年第7期48-55,I0005,I0006,共10页
采用铜-镍复合填充金属进行了钛合金和不锈钢的冷金属过渡焊接,借助扫描电子显微镜、X射线衍射仪研究铜-镍复合填充金属对钛合金/不锈钢焊接接头微观组织和力学性能的影响.结果表明,添加铜-镍复合填充金属后得到了无焊接缺陷的钛合金/... 采用铜-镍复合填充金属进行了钛合金和不锈钢的冷金属过渡焊接,借助扫描电子显微镜、X射线衍射仪研究铜-镍复合填充金属对钛合金/不锈钢焊接接头微观组织和力学性能的影响.结果表明,添加铜-镍复合填充金属后得到了无焊接缺陷的钛合金/不锈钢焊接接头.接头中形成了硬度相对Ti-Fe,Ti-Cu金属间化合物较低的Ti-Ni金属间化合物,改善了钛合金/不锈钢焊接接头的拉伸性能.当焊接电流为182 A时,钛合金/不锈钢接头的拉剪强度最大为348 MPa.钛合金/不锈钢接头由不锈钢-焊缝金属界面、不锈钢-纯镍-钛合金界面、钛合金-焊缝金属界面和焊缝金属组成,接头中形成了Ti-Cu,Ti-Ni,Al-Cu-Ti和Al-Ni-Ti-Fe-Cu金属间化合物.随着焊接电流的增大,钛合金侧界面反应层的显微硬度逐渐增大,且反应层的宽度也逐渐变宽.创新点:研究铜-镍复合填充金属对Ti-6Al-4V(TC4)钛合金/304不锈钢焊接接头的微观组织、化合物组成以及力学性能的影响. 展开更多
关键词 冷金属过渡焊 钛合金/不锈钢焊接接头 铜-镍复合填充金属 拉剪强度
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铜及铜合金搅拌摩擦焊接工艺研究 被引量:1
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作者 周挺 《科技资讯》 2023年第21期116-119,共4页
铜及铜合金的焊接是工业应用的重点和难点。如何解决铜在焊接中的难溶与热裂问题是研究铜焊接技术的关键,摩擦焊是一种利用金属熔融进行焊接的一种工艺技术,然而对于铜及铜合金的研究较少。通过分析现有技术的优缺点和研究进展,对摩擦... 铜及铜合金的焊接是工业应用的重点和难点。如何解决铜在焊接中的难溶与热裂问题是研究铜焊接技术的关键,摩擦焊是一种利用金属熔融进行焊接的一种工艺技术,然而对于铜及铜合金的研究较少。通过分析现有技术的优缺点和研究进展,对摩擦焊接的关键工艺进行了设计分析,并通过试验验证,做出了工艺参与焊接质量的相关图,确定了合理可行的工艺方案,为铜与铜合金的摩擦焊接应用提供了理论的补充。 展开更多
关键词 铜及铜合金 摩擦焊 工艺技术 试验分析
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水下搅拌摩擦焊对铝/铜接头组织与性能的影响
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作者 周立成 冯志军 +3 位作者 谢广明 吴华锋 李泽华 胡大川 《精密成形工程》 北大核心 2023年第3期97-104,共8页
目的采用搅拌摩擦焊,对比分析大气环境和水下环境下铝/铜接头的组织与性能,以期获得力学性能更优异的铝/铜焊接接头。方法利用搅拌摩擦焊,在焊接速度为40 mm/min、旋转速度为1000 r/min的条件下,分别在大气环境和水下环境下对厚度为9 mm... 目的采用搅拌摩擦焊,对比分析大气环境和水下环境下铝/铜接头的组织与性能,以期获得力学性能更优异的铝/铜焊接接头。方法利用搅拌摩擦焊,在焊接速度为40 mm/min、旋转速度为1000 r/min的条件下,分别在大气环境和水下环境下对厚度为9 mm的6061铝合金板和T2纯铜板进行焊接。然后,对铝/铜界面、焊核区进行扫描电镜及能谱分析,并对铝/铜界面及焊核区进行物相分析,确定产物相组成。最后,对铝/铜试样进行拉伸及硬度检测。结果铝/铜接头均无裂纹、气孔等缺陷。铜颗粒弥散分布在焊核区,铝/铜界面形成金属间化合物层。水下搅拌摩擦焊下界面元素扩散距离明显变短,且金属间化合物厚度更薄。铝/铜接头的金属间化合物为AlCu和Al_(4)Cu_(9)。大气环境焊接下接头的抗拉强度为130.6 MPa,断裂方式为脆性断裂;水下焊接下接头的抗拉强度为199.5 MPa,断裂方式为韧性断裂。水下环境下的接头硬度值更高,其中热影响区的硬度最低值约为65HV。结论水下搅拌摩擦焊铝/铜接头无裂纹、气孔等缺陷。组织上,水下搅拌摩擦焊的铝/铜接头界面元素扩散距离更短,硬脆的金属间化合物更少;性能上,水下搅拌摩擦焊的铝/铜接头强度更高,抗拉强度达到199.5 MPa,达到母材的74.4%。 展开更多
关键词 铝合金 铜合金 水下搅拌摩擦焊接 金属间化合物 力学性能
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Sn-1.5Ag-2Zn低银无铅焊料与取向铜界面研究
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作者 肖金 屈福康 +1 位作者 程伟 李武初 《表面技术》 EI CAS CSCD 北大核心 2023年第8期406-412,共7页
目的高密度封装技术能减少焊盘尺寸和焊盘里面所含晶粒的数量,当多晶焊盘转为单晶焊盘时,晶粒的取向会对界面处金属间化合物的形成产生重要影响。选取具有发展前景的Sn-1.5Ag-2Zn作为焊料合金,研究焊料与单晶(111)铜基板界面反应,得到... 目的高密度封装技术能减少焊盘尺寸和焊盘里面所含晶粒的数量,当多晶焊盘转为单晶焊盘时,晶粒的取向会对界面处金属间化合物的形成产生重要影响。选取具有发展前景的Sn-1.5Ag-2Zn作为焊料合金,研究焊料与单晶(111)铜基板界面反应,得到金属间化合物的生长动力学规律。方法将Sn-1.5Ag-2Zn无铅焊料分别与单晶(111)铜基板及多晶紫铜基板在250℃下进行回流焊接5 min,将焊接后的样品在160℃下分别进行20 h,100 h,300 h,600 h热处理。用扫描电子显微镜背散射电子成像和二次电子成像、X射线衍射仪(XRD)、能谱仪等研究焊接界面处的显微组织、金属间化合物成分以及性能。结果合金焊料与铜基板接触迅速生长出凹凸不平类似扇贝状Cu_(6)Sn_(5)金属间化合物层,与单晶铜表面形成的Cu_(6)Sn_(5)晶粒尺寸比多晶铜的大,单晶铜无晶界阻挡原子扩散,影响晶粒形核与长大。合金焊料与单晶(111)铜焊点在160℃下热处理20 h快速形成的Cu_(6)Sn_(5)生长速度是多晶铜上焊点的2倍左右。而后随热处理时间增加增长缓慢,热处理600 h后厚层Cu_(6)Sn_(5)由于裂纹扩散出现溃断,金属间化合物的厚度维持在3.5μm。焊料与多晶铜焊点在热处理过程中生成的Cu_(5)Zn_(8)起到阻挡层的作用,阻挡焊料与铜基板接触,抑制Cu_(6)Sn_(5)生成,热处理300 h后Cu_(5)Zn_(8)破碎分解,Cu_(6)Sn_(5)在阻挡层消失后快速生长,厚度约为2.8μm。结论单晶铜上焊点金属间化合物的厚度比多晶铜上金属间化合物的厚度多0.7μm,热处理后合金焊料与单晶铜界面形成的金属间化合物致密性更好,基本没有孔隙,而合金焊料与多晶铜界面上金属间化合物晶粒间存在明显孔隙,可以预测合金焊料与单晶铜界面的焊接质量更好。 展开更多
关键词 Sn-1.5Ag-2Zn 单晶铜 合金焊料 焊接 扩散
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化学气相沉积法及机械混合法添加石墨烯对铜铬触头性能的影响
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作者 陈华强 陶应啟 +4 位作者 李晓静 吴云洪 王吉应 叶墨稼 余贤旺 《功能材料》 CAS CSCD 北大核心 2023年第12期12148-12153,12162,共7页
随着电力系统发展,其主要电气控制设备断路器的功率不断提升。作为断路器的核心部件,电触头材料的研究得到了越来越广泛的关注。本文以铜粉、铬粉和石墨烯为原料,分别通过机械混合法和化学气相沉积法添加石墨烯,再通过压制-烧结-复压-... 随着电力系统发展,其主要电气控制设备断路器的功率不断提升。作为断路器的核心部件,电触头材料的研究得到了越来越广泛的关注。本文以铜粉、铬粉和石墨烯为原料,分别通过机械混合法和化学气相沉积法添加石墨烯,再通过压制-烧结-复压-复烧工艺制成石墨烯增强铜铬复合材料。研究了不同工艺添加石墨烯对铜铬复合材料组织及性能的影响。研究发现,通过化学气相沉积法添加的石墨烯在基体中分布均匀,电导率提升至40.64 MS/s、平均燃弧时间为5.37 ms、熔焊力变化范围为13.550~13.636 N,电导率、抗熔焊性能和耐烧蚀性能等得到了明显的提高,有利于其进一步扩大在电接触材料领域的应用范围。 展开更多
关键词 铜铬合金 石墨烯 熔焊力 燃弧时间 开断试验
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基于高熵合金中间层的铜/钢TIG焊接头组织与性能
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作者 蒋淑英 张军利 赵明 《中国石油大学学报(自然科学版)》 EI CAS CSCD 北大核心 2023年第6期154-161,共8页
铜/钢复合结构不仅能够满足不同环境对材料性能的要求,还可减少铜材的消耗,将大大降低构件的成本;但铜与钢之间物化性能差异较大,其中极差的相溶性会导致焊后出现液相分离或缺陷。基于焊缝金属固溶-高熵化思路,设计Fe_(5)Co_(30)Cr_(30)... 铜/钢复合结构不仅能够满足不同环境对材料性能的要求,还可减少铜材的消耗,将大大降低构件的成本;但铜与钢之间物化性能差异较大,其中极差的相溶性会导致焊后出现液相分离或缺陷。基于焊缝金属固溶-高熵化思路,设计Fe_(5)Co_(30)Cr_(30)Ni_(30)Cu_(5)高熵合金作为中间层,对T2紫铜和Q235钢进行TIG焊接,并对中间层及接头的组织与性能进行分析。结果表明:Fe_(5)Co_(30)Cr_(30)Ni_(30)Cu_(5)高熵合金为单相FCC固溶体结构,具有良好的强度和塑韧性;采用该中间层材料,利用TIG焊方法可实现T2紫铜和Q235钢的可靠连接,焊缝成形良好且无气孔、裂纹等缺陷;焊缝区组织为单相FCC固溶体结构,具有显著的高熵化特征;焊接接头平均抗拉强度为225 MPa,达到铜母材强度的91%,平均断后延伸率达到44%;接头断裂发生在紫铜侧热影响区,且断口表面呈现有大量的韧窝结构,具有显著的韧性断裂特征。 展开更多
关键词 T2紫铜 Q235钢 TIG焊 高熵合金中间层 组织 性能
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镍铜合金薄壁管现场焊接作业的总结与建议
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作者 童朝刚 《硫磷设计与粉体工程》 CAS 2023年第3期17-19,I0001,共4页
以沙特Wasit项目镍铜合金薄壁管焊接为例,分析了母材及焊丝化学成分,介绍了镍铜合金的焊接特性和焊接工艺参数,总结了现场施工的焊接设备、环境要求、坡口选用,以及焊接作业中的注意事项,并针对镍铜合金焊接特点提出了建议。
关键词 管道焊接 焊接工艺 镍铜合金 注意事项
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