To sensitize polyaniline with dyes by electrochemical polymerization, HClO 4 is employed as the dopant and oxidant, and the polyaniline with different sensitive properties is synthesized. The effect of sensitized emer...To sensitize polyaniline with dyes by electrochemical polymerization, HClO 4 is employed as the dopant and oxidant, and the polyaniline with different sensitive properties is synthesized. The effect of sensitized emeraldine salt on the absorption spectrum is discussed in details. The maximum conductivity of sensitized films reaches 1.22 S/cm, and investigation on dye sensitizing of the polymer reveals that C.I. Direct Blue 71, C.I. Direct Blue 84, C.I. Direct Black 19 and CuPc-(COOH) 4 may enhance the photoconductivity of polyaniline greatly.展开更多
The IC 50 values of 20 nitroaromatics were determined by the activity of ATPase of carp ( Cyprinus carpio ) kidney in vitro, and used to develop the quantitative structure activity relationship (QSAR) wi...The IC 50 values of 20 nitroaromatics were determined by the activity of ATPase of carp ( Cyprinus carpio ) kidney in vitro, and used to develop the quantitative structure activity relationship (QSAR) with 6 descriptors of 1 X v, Σσ -, I , 1 Ka , E LUMO , log P . A best equation was obtained by multiple regression analysis -log IC 50 =1 306 Σσ -+0 657 I +0 584E LUMO +2 852( r =0 925). Σσ - is the sum of substituent constants. I is the indicator variable. E LUMO is the energy of the lowest unoccupied orbital. Results showed that the Σσ -, I and E LUMO were closely correlated with toxicity of nitroaromatics. Some toxicity mechanisms by nitroaromatics are also discussed in this paper.展开更多
Temperature-dependence and excitation-intensity-dependence of photoluminescence spectra for both disordered and ordered Ga 0.52 In 0.48 P are measured. The disordered sample is characterized by its single peak photolu...Temperature-dependence and excitation-intensity-dependence of photoluminescence spectra for both disordered and ordered Ga 0.52 In 0.48 P are measured. The disordered sample is characterized by its single peak photoluminescence spectrum which is excitation-intensity independent and has different activation energy at different temperature region. The ordered sample shows double peaks, the intensity of the high-energy peak has an anomalous increase firstly and quenches afterwards. The relative phenomena are reasonably explained in terms of lattice ordering and orientation superlattice model.展开更多
Polyparaphenylene(PPP) is prepared by AlCl 3-CuCl 2 catalysts with benzene as the monomer and is doped by chemical method and N + ion implantation. The influences of the concentration, temperature and time of chemi...Polyparaphenylene(PPP) is prepared by AlCl 3-CuCl 2 catalysts with benzene as the monomer and is doped by chemical method and N + ion implantation. The influences of the concentration, temperature and time of chemical doping and the dose, energy and temperature of ion implantation, on PPP conductivity are investigated. The results showed that the conductivity of PPP can be improved 4～5 orders of magnitude by ion implantation and the conductivity of PPP can reach about 0.11 S·cm -1 by chemical doping. The comparison of stability of the material conductive behavior by using the two doping methods is presented. It shows that ion implantation is better than chemical doping in stabilizing the electric conductive behavior for the material.展开更多
Photoelectric property of polyaniline doped with dodecyl-benzene sulphonic acid (DBSA) is studied. The result shows that the concentration of carrier increases obviously, when polyaniline doped with DBSA is irradiated...Photoelectric property of polyaniline doped with dodecyl-benzene sulphonic acid (DBSA) is studied. The result shows that the concentration of carrier increases obviously, when polyaniline doped with DBSA is irradiated with light. Mixture of sensitive material is advantageous to the absorption of polyaniline in visible light spectrum, and the conductivity is also improved. The results of dielectric measurements on polyaniline doped with DBSA in an Al-PAn-DBSA-Al configuration as function of frequency and temperature are reported. The space-charge polarization phenomenon is observed. Carrier lifetime is microsecond magnitude and mobility is (0.001～0.1) cm 2/V·s, which are obtained by calculation or experiment. The active energy is obtained from the relation between conductivity and temperature. The conducting mechanism of PAn-DBSA is analyzed.展开更多
An easy and practical system of feeble fluctuation of liquid electrical conductivity is described. The system, which increases a precision on the three orders magnitude as compared with that of the recent domestic con...An easy and practical system of feeble fluctuation of liquid electrical conductivity is described. The system, which increases a precision on the three orders magnitude as compared with that of the recent domestic conductivity meter, is used to measure the feeble fluctuation of the conductivity by means of compensation and comparison, so that it solves the problem of measuring the feeble fluctuation.展开更多
A low turn-on field electron emission from diamond-like carbon films has been observed for the first time to author’s knowledge.Carbon films were prepared by microwave plasma chemical vapor deposition (CVD).Special p...A low turn-on field electron emission from diamond-like carbon films has been observed for the first time to author’s knowledge.Carbon films were prepared by microwave plasma chemical vapor deposition (CVD).Special pretreatment ceramic substrates were used. The characteristics of the film have been identified by using X-ray diffraction(XRD),and Raman spectrum. The field emission experiment has been performed in a vacuum chamber with a base pressure of about 10 -5 Pa. The turn-on field of 1.2 V/μm,and the current density of 1.25 mA/cm 2 at electric field of 6 V/μm were obtained.展开更多
A new organic semiconductor tartaric acid doped salt of emeraldine polyaniline (PANI-C 4H 6O 6) has been obtained by the method of oxidative polymerization of monomeric aniline with ammonium persulfate in acidic solut...A new organic semiconductor tartaric acid doped salt of emeraldine polyaniline (PANI-C 4H 6O 6) has been obtained by the method of oxidative polymerization of monomeric aniline with ammonium persulfate in acidic solution. The structure was characterized by Fourier Transform Infrared technique (FTIR) and X-ray diffraction (XRD). The temperature dependence dc conductivity δ dc ( T ) shows a semiconductor behavior and follows the quasi one dimensional variable range hopping (Q1D-VRH) model. Data on δ dc ( T ) are also discussed.展开更多
文摘To sensitize polyaniline with dyes by electrochemical polymerization, HClO 4 is employed as the dopant and oxidant, and the polyaniline with different sensitive properties is synthesized. The effect of sensitized emeraldine salt on the absorption spectrum is discussed in details. The maximum conductivity of sensitized films reaches 1.22 S/cm, and investigation on dye sensitizing of the polymer reveals that C.I. Direct Blue 71, C.I. Direct Blue 84, C.I. Direct Black 19 and CuPc-(COOH) 4 may enhance the photoconductivity of polyaniline greatly.
文摘The IC 50 values of 20 nitroaromatics were determined by the activity of ATPase of carp ( Cyprinus carpio ) kidney in vitro, and used to develop the quantitative structure activity relationship (QSAR) with 6 descriptors of 1 X v, Σσ -, I , 1 Ka , E LUMO , log P . A best equation was obtained by multiple regression analysis -log IC 50 =1 306 Σσ -+0 657 I +0 584E LUMO +2 852( r =0 925). Σσ - is the sum of substituent constants. I is the indicator variable. E LUMO is the energy of the lowest unoccupied orbital. Results showed that the Σσ -, I and E LUMO were closely correlated with toxicity of nitroaromatics. Some toxicity mechanisms by nitroaromatics are also discussed in this paper.
文摘Temperature-dependence and excitation-intensity-dependence of photoluminescence spectra for both disordered and ordered Ga 0.52 In 0.48 P are measured. The disordered sample is characterized by its single peak photoluminescence spectrum which is excitation-intensity independent and has different activation energy at different temperature region. The ordered sample shows double peaks, the intensity of the high-energy peak has an anomalous increase firstly and quenches afterwards. The relative phenomena are reasonably explained in terms of lattice ordering and orientation superlattice model.
文摘Polyparaphenylene(PPP) is prepared by AlCl 3-CuCl 2 catalysts with benzene as the monomer and is doped by chemical method and N + ion implantation. The influences of the concentration, temperature and time of chemical doping and the dose, energy and temperature of ion implantation, on PPP conductivity are investigated. The results showed that the conductivity of PPP can be improved 4～5 orders of magnitude by ion implantation and the conductivity of PPP can reach about 0.11 S·cm -1 by chemical doping. The comparison of stability of the material conductive behavior by using the two doping methods is presented. It shows that ion implantation is better than chemical doping in stabilizing the electric conductive behavior for the material.
文摘Photoelectric property of polyaniline doped with dodecyl-benzene sulphonic acid (DBSA) is studied. The result shows that the concentration of carrier increases obviously, when polyaniline doped with DBSA is irradiated with light. Mixture of sensitive material is advantageous to the absorption of polyaniline in visible light spectrum, and the conductivity is also improved. The results of dielectric measurements on polyaniline doped with DBSA in an Al-PAn-DBSA-Al configuration as function of frequency and temperature are reported. The space-charge polarization phenomenon is observed. Carrier lifetime is microsecond magnitude and mobility is (0.001～0.1) cm 2/V·s, which are obtained by calculation or experiment. The active energy is obtained from the relation between conductivity and temperature. The conducting mechanism of PAn-DBSA is analyzed.
文摘An easy and practical system of feeble fluctuation of liquid electrical conductivity is described. The system, which increases a precision on the three orders magnitude as compared with that of the recent domestic conductivity meter, is used to measure the feeble fluctuation of the conductivity by means of compensation and comparison, so that it solves the problem of measuring the feeble fluctuation.
基金The National Advanced Material Com mittee of China
文摘A low turn-on field electron emission from diamond-like carbon films has been observed for the first time to author’s knowledge.Carbon films were prepared by microwave plasma chemical vapor deposition (CVD).Special pretreatment ceramic substrates were used. The characteristics of the film have been identified by using X-ray diffraction(XRD),and Raman spectrum. The field emission experiment has been performed in a vacuum chamber with a base pressure of about 10 -5 Pa. The turn-on field of 1.2 V/μm,and the current density of 1.25 mA/cm 2 at electric field of 6 V/μm were obtained.
文摘A new organic semiconductor tartaric acid doped salt of emeraldine polyaniline (PANI-C 4H 6O 6) has been obtained by the method of oxidative polymerization of monomeric aniline with ammonium persulfate in acidic solution. The structure was characterized by Fourier Transform Infrared technique (FTIR) and X-ray diffraction (XRD). The temperature dependence dc conductivity δ dc ( T ) shows a semiconductor behavior and follows the quasi one dimensional variable range hopping (Q1D-VRH) model. Data on δ dc ( T ) are also discussed.
