采用热压法制备了奇–奇数聚酰胺(PA)1111铁电薄膜,研究了PA1111的铁电性,并通过探讨极化温度(Tp)、极化时间(tp)和极化电场强度(Ep)对PA1111压电应变常数(d33)的影响来研究PA1111的压电性。结果表明,在频率0.1 Hz,外加电场150 MV/m的...采用热压法制备了奇–奇数聚酰胺(PA)1111铁电薄膜,研究了PA1111的铁电性,并通过探讨极化温度(Tp)、极化时间(tp)和极化电场强度(Ep)对PA1111压电应变常数(d33)的影响来研究PA1111的压电性。结果表明,在频率0.1 Hz,外加电场150 MV/m的条件下,PA1111的矫顽电场(Ec)约为75 MV/m,剩余极化强度(Pr)达47 m C/m2。在相同的测试条件下,PA1111的Ec接近于PA11,但Pr比PA11的低,两者的压电性能相差不大。极化工艺研究表明,随着tp增加,PA1111的d33先迅速增大后趋于稳定;随着Ep的增加和Tp的升高,PA1111的d33随之增大。在Tp为75℃,tp为30 min,Ep为50 MV/m的条件下,PA1111的d33达-3.9 p C/N,压电电压常数达-169 m V·m/N。展开更多
In situ, compatibilization of low density polyethylene (LDPE) (30%) and nylon-6 (70%) blends through one-step reactive extrusion using t-BuOOH as an initiator and low molecular weight interfacial agents as compatibili...In situ, compatibilization of low density polyethylene (LDPE) (30%) and nylon-6 (70%) blends through one-step reactive extrusion using t-BuOOH as an initiator and low molecular weight interfacial agents as compatibilizers was studied. The compatibilizer contained a long chain hydrocarbon, double bond and two polar functional groups which was capable of reacting with both LDPE and nylon-6 in the presence of initiator to form a copolymer at the interface of the two polymer phases. The extruded blends exhibited significant enhancement in their compatibility based on morphological, thermal analysis and mechanical studies. The effect of the hydrocarbon chain length and structure of the functional group of the compatibilizer was also examined. It was found that blends prepared by using the compatibilizer containing longer hydrocarbon chain and amide group had better mechanical properties.展开更多
Based on the X-ray scattering intensity theory and using the atomic scattering factorapproximate expression,the correction factors for three main crystalline peaks and an amorphouspeak of Nylon-1010 were calculated an...Based on the X-ray scattering intensity theory and using the atomic scattering factorapproximate expression,the correction factors for three main crystalline peaks and an amorphouspeak of Nylon-1010 were calculated and the formula of degree of crystallinity of Nylon-1010 wasderived by graphic multipeak resolution method. The results calculated are compatible with the density measurement and calorimetry.展开更多
The kineties of non-isothermal crystallization of Nylon-1010 has been investigated by using differential scanning calorimetry(DSC), DSC curves were obtained under cooling rate(R): 2. 5, 5, 10, 20, 40K/min. Applying Ma...The kineties of non-isothermal crystallization of Nylon-1010 has been investigated by using differential scanning calorimetry(DSC), DSC curves were obtained under cooling rate(R): 2. 5, 5, 10, 20, 40K/min. Applying Mandelkern and Ziabicki theories, the values of the Z kinetic parameter and G the kinetic crystalllzab- ility have been determined. Expenents of Avrami obtained in this work decrease with increase of cooling rate and then level off. The experimental results show disagreements with the Ozawa equation.展开更多
The structures of Nylon-1010 with different draw ratios have been investigated by using Small-Angle X-ray Scattering(SAXS).It is shown that by using a simple geometrical construction the following structure parameters...The structures of Nylon-1010 with different draw ratios have been investigated by using Small-Angle X-ray Scattering(SAXS).It is shown that by using a simple geometrical construction the following structure parameters can be directly derived from the correlation function,the long period(L),the thickness of the crystal amorphous interphase(dtr),the lamellar thickness(do),the“invariant”(Q),the specific inner surface(Os), and the electron density difference between the core of the crystallites and the amorphous matrix(η_ε-η_ω)。展开更多
From Wide-Angle X-ray Scattering (WAXS) pattern of uniaxially orientated fibers, the crystal structure of Nylon-1010 was determined. The Nylon-1010 crystallizes in the triclinic system, with lattice dimensions: a=4.9A...From Wide-Angle X-ray Scattering (WAXS) pattern of uniaxially orientated fibers, the crystal structure of Nylon-1010 was determined. The Nylon-1010 crystallizes in the triclinic system, with lattice dimensions: a=4.9A, b=5.4A, c=27.8, α=49 °, β=77 °,γ=63.5 °, the unit cell contains one monomeric unit and the space group is P. The degree of crystallinity of polymer was deter mined as about 60%, using Ruland's method.The structures of Nylon-1010 with different draw ratio have been investigated by using Small-Angle X-ray Scattering (SAXS). The results indicate that the draw ratio of samples has a significant effect on microstructure of Nylon-1010. The long period and thickness of amorphous layer obviously increase but the invariant, average lameUar and interphase zone show almost independent of draw ratio, long period increases because amorphous layer increases with draw ratio. The electron density fluctuation values increased with draw ratio, but inner surface O_s is drecreased.展开更多
The structure of aggregation state and isothermal crystallization behavior of Nylon-1010 have been studied by WAXD, DSE, Variance-Range Function and density measurement. The results show that crystallization of Nylon-...The structure of aggregation state and isothermal crystallization behavior of Nylon-1010 have been studied by WAXD, DSE, Variance-Range Function and density measurement. The results show that crystallization of Nylon-1010 has the most suitable annealing temperature, the crystals of the Nxlon-1010 are two-dimension heterogeneous nucleation. Both low treatment temperature and high crystallization te, temperature are disadvantageous for Nylon-1010 crystal growth.展开更多
文摘采用热压法制备了奇–奇数聚酰胺(PA)1111铁电薄膜,研究了PA1111的铁电性,并通过探讨极化温度(Tp)、极化时间(tp)和极化电场强度(Ep)对PA1111压电应变常数(d33)的影响来研究PA1111的压电性。结果表明,在频率0.1 Hz,外加电场150 MV/m的条件下,PA1111的矫顽电场(Ec)约为75 MV/m,剩余极化强度(Pr)达47 m C/m2。在相同的测试条件下,PA1111的Ec接近于PA11,但Pr比PA11的低,两者的压电性能相差不大。极化工艺研究表明,随着tp增加,PA1111的d33先迅速增大后趋于稳定;随着Ep的增加和Tp的升高,PA1111的d33随之增大。在Tp为75℃,tp为30 min,Ep为50 MV/m的条件下,PA1111的d33达-3.9 p C/N,压电电压常数达-169 m V·m/N。
文摘In situ, compatibilization of low density polyethylene (LDPE) (30%) and nylon-6 (70%) blends through one-step reactive extrusion using t-BuOOH as an initiator and low molecular weight interfacial agents as compatibilizers was studied. The compatibilizer contained a long chain hydrocarbon, double bond and two polar functional groups which was capable of reacting with both LDPE and nylon-6 in the presence of initiator to form a copolymer at the interface of the two polymer phases. The extruded blends exhibited significant enhancement in their compatibility based on morphological, thermal analysis and mechanical studies. The effect of the hydrocarbon chain length and structure of the functional group of the compatibilizer was also examined. It was found that blends prepared by using the compatibilizer containing longer hydrocarbon chain and amide group had better mechanical properties.
基金This project was supported by the National Natural Science Foundation of China and the National Basic Research Project Macromolecular Condensed State.
文摘Based on the X-ray scattering intensity theory and using the atomic scattering factorapproximate expression,the correction factors for three main crystalline peaks and an amorphouspeak of Nylon-1010 were calculated and the formula of degree of crystallinity of Nylon-1010 wasderived by graphic multipeak resolution method. The results calculated are compatible with the density measurement and calorimetry.
文摘The kineties of non-isothermal crystallization of Nylon-1010 has been investigated by using differential scanning calorimetry(DSC), DSC curves were obtained under cooling rate(R): 2. 5, 5, 10, 20, 40K/min. Applying Mandelkern and Ziabicki theories, the values of the Z kinetic parameter and G the kinetic crystalllzab- ility have been determined. Expenents of Avrami obtained in this work decrease with increase of cooling rate and then level off. The experimental results show disagreements with the Ozawa equation.
文摘The structures of Nylon-1010 with different draw ratios have been investigated by using Small-Angle X-ray Scattering(SAXS).It is shown that by using a simple geometrical construction the following structure parameters can be directly derived from the correlation function,the long period(L),the thickness of the crystal amorphous interphase(dtr),the lamellar thickness(do),the“invariant”(Q),the specific inner surface(Os), and the electron density difference between the core of the crystallites and the amorphous matrix(η_ε-η_ω)。
文摘From Wide-Angle X-ray Scattering (WAXS) pattern of uniaxially orientated fibers, the crystal structure of Nylon-1010 was determined. The Nylon-1010 crystallizes in the triclinic system, with lattice dimensions: a=4.9A, b=5.4A, c=27.8, α=49 °, β=77 °,γ=63.5 °, the unit cell contains one monomeric unit and the space group is P. The degree of crystallinity of polymer was deter mined as about 60%, using Ruland's method.The structures of Nylon-1010 with different draw ratio have been investigated by using Small-Angle X-ray Scattering (SAXS). The results indicate that the draw ratio of samples has a significant effect on microstructure of Nylon-1010. The long period and thickness of amorphous layer obviously increase but the invariant, average lameUar and interphase zone show almost independent of draw ratio, long period increases because amorphous layer increases with draw ratio. The electron density fluctuation values increased with draw ratio, but inner surface O_s is drecreased.
文摘The structure of aggregation state and isothermal crystallization behavior of Nylon-1010 have been studied by WAXD, DSE, Variance-Range Function and density measurement. The results show that crystallization of Nylon-1010 has the most suitable annealing temperature, the crystals of the Nxlon-1010 are two-dimension heterogeneous nucleation. Both low treatment temperature and high crystallization te, temperature are disadvantageous for Nylon-1010 crystal growth.
