The kinetics of protonolysis of o-substituted phenylmercuric chlorides, o-XC6H4HgCl (X = H, CH3, CH3O, C2H5O, CF3, COOC2H5, Cl, Br, F, NO2), by hydrochloric acid in the presence of sodium iodide as catalyst have been ...The kinetics of protonolysis of o-substituted phenylmercuric chlorides, o-XC6H4HgCl (X = H, CH3, CH3O, C2H5O, CF3, COOC2H5, Cl, Br, F, NO2), by hydrochloric acid in the presence of sodium iodide as catalyst have been studied in ethanol. The reaction has been found to be second order overall, first order in each reactant. The rate constants k measured at the same temperature may be arranged in the following order: C2H5O > CH3O > CH3 > H > CO2C2H5 > F > Cl > Br > CF3 > NO2.展开更多
文摘The kinetics of protonolysis of o-substituted phenylmercuric chlorides, o-XC6H4HgCl (X = H, CH3, CH3O, C2H5O, CF3, COOC2H5, Cl, Br, F, NO2), by hydrochloric acid in the presence of sodium iodide as catalyst have been studied in ethanol. The reaction has been found to be second order overall, first order in each reactant. The rate constants k measured at the same temperature may be arranged in the following order: C2H5O > CH3O > CH3 > H > CO2C2H5 > F > Cl > Br > CF3 > NO2.
