In this work,the solubility data and liquid-phase mass transfer coefficients of hydrogen(H2),methane(CH4)and their mixtures in vacuum gas oil(VGO)at temperatures(353.15-453.15 K)and pressures(1-7 MPa)were measured,whi...In this work,the solubility data and liquid-phase mass transfer coefficients of hydrogen(H2),methane(CH4)and their mixtures in vacuum gas oil(VGO)at temperatures(353.15-453.15 K)and pressures(1-7 MPa)were measured,which are necessary for catalytic cracking process simulation and design.The solubility of H2 and CH4 in VGO increases with the increase of pressure,but decreases with the increase of temperature.Henry’s constants of H2 and CH4 follow the relation of In H=-413.05/T+5.27 and In H=-990.67/T+5.87,respectively.The molar fractions of H2 and system pressures at different equilibrium time were measured to estimate the liquid-phase mass transfer coefficients.The results showed that with the increase of pressure,the liquid-phase mass transfer coefficients increase.Furthermore,the solubility of H2 and CH4 in VGO was predicted by the predictive COSMO-RS model,and the predicted values agree well with experimental data.In addition,the gas-liquid equilibrium(GLE)for H2+CH4+VGO system at different feeding gas ratios in volume fraction(i.e.,H285%+CH415%and H290%+CH410%)was measured.The selectivity of H2 to CH4 predicted by the COSMO-RS model agrees well with experimental data.This work provides the basic thermodynamic and dynamic data for fuel oil catalytic cracking processes.展开更多
On the basis of the analysis of field thermogeochemical data along abnormal zones of a thermal stream in the Bukhara-Khiva, oil-and-gas region of the Turan (Tegermen, Chagakul, Shimoly Alat, Beshtepa) was succeeded to...On the basis of the analysis of field thermogeochemical data along abnormal zones of a thermal stream in the Bukhara-Khiva, oil-and-gas region of the Turan (Tegermen, Chagakul, Shimoly Alat, Beshtepa) was succeeded to obtain important data on a deep structure of sites. Data of gas-chemical and geothermal observations show about confinedness of abnormal concentration of methane to zones of the increased values of the temperature field the measured values of temperatures (Tegermen Square and others). On geoelectric section mines 2-D of inversion of the MT-field depth of 4000 m are lower, among very high-resistance the chemogenic and carbonate deposits of the Paleozoic is traced the subvertical carrying-out abnormal zone. This zone is identified as the channel of a deep heat and mass transfer with which hydrocarbon (HC) deposits are connected. It is shown that electro-investigation when using a geophysical complex can and has to become “advancing” at exploration by oil and gas.展开更多
Carbon dioxide(CO_(2))is one of the main factors contributing to the greenhouse effect.The dependence on fossil fuels has led to increasing levels of carbon dioxide in the atmosphere every year.And it is far from enou...Carbon dioxide(CO_(2))is one of the main factors contributing to the greenhouse effect.The dependence on fossil fuels has led to increasing levels of carbon dioxide in the atmosphere every year.And it is far from enough to solve the climate problem by reducing the consumption of fossil fuels to cut down carbon dioxide emissions.In recent years,a series of researches on Carbon Capture,Utilization and Storage(CCUS)have been carried out in various countries around the world.CO_(2) is a nontoxic,tasteless and stable gas at normal temperature.However,when it reaches supercritical state after rising temperature and pressure,it has the characteristics of low viscosity,high diffusivity and high density,and is widely used in green,pollution-free and efficient development technology.Because of these unique properties,supercritical carbon dioxide(sCO_(2))has attracted more and more attention from researchers.sCO_(2) has been widely used in many aspects by virtue of its high solubility and easy compression.Different from previous reviews which only introduced the application of sCO_(2) property,this paper introduces the current research status of the application of the thermodynamic property of carbon dioxide in extraction,dyeing,pharmaceutical,power generation,heat transfer and exploitation of unconventional oil and gas,and mainly analyzes each application in detail from the aspects of working mechanism and improving working efficiency.Finally,the research direction and problems needed to be solved for the application of CO_(2) thermal physics are proposed,which pave the way for other new applications.展开更多
油气集输系统中的风险因素数量庞杂,各风险因素相互关联,且对系统整体的安全功能作用不同。因此,对风险因素进行层次筛选是提高风险评价效率和准确性的有效途径。首先采用事故树分析(Fault Tree Analysis,FTA)系统辨识风险因素,根据Del...油气集输系统中的风险因素数量庞杂,各风险因素相互关联,且对系统整体的安全功能作用不同。因此,对风险因素进行层次筛选是提高风险评价效率和准确性的有效途径。首先采用事故树分析(Fault Tree Analysis,FTA)系统辨识风险因素,根据Delphi方法进行风险因素初次筛选,并对筛选出的风险因素进行聚簇。然后,利用模糊认知图(Fuzzy Cognition Maps,FCM)对风险因素进行二次筛选,基于权重排序得到风险评价因素集。最后,利用模糊综合评价方法(Fuzzy Comprehensive Evaluation,FCE)进行风险等级的定量计算,并对风险评价方法过程进行了分析设计。结果表明,该研究提高了油气集输系统风险评估工作的科学性,对制定较强针对性的风险控制策略具有重要意义。展开更多
基金Supported by the National Natural Science Foundation of China(U1862103).
文摘In this work,the solubility data and liquid-phase mass transfer coefficients of hydrogen(H2),methane(CH4)and their mixtures in vacuum gas oil(VGO)at temperatures(353.15-453.15 K)and pressures(1-7 MPa)were measured,which are necessary for catalytic cracking process simulation and design.The solubility of H2 and CH4 in VGO increases with the increase of pressure,but decreases with the increase of temperature.Henry’s constants of H2 and CH4 follow the relation of In H=-413.05/T+5.27 and In H=-990.67/T+5.87,respectively.The molar fractions of H2 and system pressures at different equilibrium time were measured to estimate the liquid-phase mass transfer coefficients.The results showed that with the increase of pressure,the liquid-phase mass transfer coefficients increase.Furthermore,the solubility of H2 and CH4 in VGO was predicted by the predictive COSMO-RS model,and the predicted values agree well with experimental data.In addition,the gas-liquid equilibrium(GLE)for H2+CH4+VGO system at different feeding gas ratios in volume fraction(i.e.,H285%+CH415%and H290%+CH410%)was measured.The selectivity of H2 to CH4 predicted by the COSMO-RS model agrees well with experimental data.This work provides the basic thermodynamic and dynamic data for fuel oil catalytic cracking processes.
文摘On the basis of the analysis of field thermogeochemical data along abnormal zones of a thermal stream in the Bukhara-Khiva, oil-and-gas region of the Turan (Tegermen, Chagakul, Shimoly Alat, Beshtepa) was succeeded to obtain important data on a deep structure of sites. Data of gas-chemical and geothermal observations show about confinedness of abnormal concentration of methane to zones of the increased values of the temperature field the measured values of temperatures (Tegermen Square and others). On geoelectric section mines 2-D of inversion of the MT-field depth of 4000 m are lower, among very high-resistance the chemogenic and carbonate deposits of the Paleozoic is traced the subvertical carrying-out abnormal zone. This zone is identified as the channel of a deep heat and mass transfer with which hydrocarbon (HC) deposits are connected. It is shown that electro-investigation when using a geophysical complex can and has to become “advancing” at exploration by oil and gas.
文摘Carbon dioxide(CO_(2))is one of the main factors contributing to the greenhouse effect.The dependence on fossil fuels has led to increasing levels of carbon dioxide in the atmosphere every year.And it is far from enough to solve the climate problem by reducing the consumption of fossil fuels to cut down carbon dioxide emissions.In recent years,a series of researches on Carbon Capture,Utilization and Storage(CCUS)have been carried out in various countries around the world.CO_(2) is a nontoxic,tasteless and stable gas at normal temperature.However,when it reaches supercritical state after rising temperature and pressure,it has the characteristics of low viscosity,high diffusivity and high density,and is widely used in green,pollution-free and efficient development technology.Because of these unique properties,supercritical carbon dioxide(sCO_(2))has attracted more and more attention from researchers.sCO_(2) has been widely used in many aspects by virtue of its high solubility and easy compression.Different from previous reviews which only introduced the application of sCO_(2) property,this paper introduces the current research status of the application of the thermodynamic property of carbon dioxide in extraction,dyeing,pharmaceutical,power generation,heat transfer and exploitation of unconventional oil and gas,and mainly analyzes each application in detail from the aspects of working mechanism and improving working efficiency.Finally,the research direction and problems needed to be solved for the application of CO_(2) thermal physics are proposed,which pave the way for other new applications.
