Coal is a solid combustible mineral,and coal-bearing strata have important hydrocarbon generation potential and contribute to more than 12%of the global hydrocarbon resources.However,the deposition and hydrocarbon evo...Coal is a solid combustible mineral,and coal-bearing strata have important hydrocarbon generation potential and contribute to more than 12%of the global hydrocarbon resources.However,the deposition and hydrocarbon evolution process of ancient coal-bearing strata is characterized by multiple geological times,leading to obvious distinctions in their hydrocarbon generation potential,geological processes,and production,which affect the evaluation and exploration of hydrocarbon resources derived from coaly source rocks worldwide.This study aimed to identify the differences on oil-generated parent macerals and the production of oil generated from different coaly source rocks and through different oil generation processes.Integrating with the analysis of previous tectonic burial history and hydrocarbon generation history,high-temperature and high-pressure thermal simulation experiments,organic geochemistry,and organic petrology were performed on the Carboniferous-Permian(C-P)coaly source rocks in the Huanghua Depression,Bohai Bay Basin.The oil-generated parent macerals of coal's secondary oil generation process(SOGP)were mainly hydrogen-rich collotelinite,collodetrinite,sporinite,and cutinite,while the oil-generated parent macerals of tertiary oil generation process(TOGP)were the remaining small amount of hydrogen-rich collotelinite,sporinite,and cutinite,as well as dispersed soluble organic matter and unexhausted residual hydrocarbons.Compared with coal,the oil-generated parent macerals of coaly shale SOGP were mostly sporinite and cutinite.And part of hydrogen-poor vitrinite,lacking hydrocarbon-rich macerals,and macerals of the TOGP,in addition to some remaining cutinite and a small amount of crude oil and bitumen from SOGP contributed to the oil yield.The results indicated that the changes in oil yield had a good junction between SOGP and TOGP,both coal and coaly shale had higher SOGP aborted oil yield than TOGP starting yield,and coaly shale TOGP peak oil yield was lower than SOGP peak oil yield.There were significant differences in saturated hydrocarbon and aromatic parameters in coal and coaly shale.Coal SOGP was characterized by a lower Ts/Tm and C31-homohopane22S/(22S+22R)and a higher Pr/n C17compared to coal TOGP,while the aromatic parameter methyl dibenzothiophene ratio(MDR)exhibited coaly shale TOGP was higher than coaly shale SOGP than coaly TOGP than coaly SOGP,and coal trimethylnaphthalene ratio(TNR)was lower than coaly shale TNR.Thus,we established oil generation processes and discriminative plates.In this way,we distinguished the differences between oil generation parent maceral,oil generation time,and oil production of coaly source rocks,and therefore,we provided important support for the evaluation,prediction,and exploration of oil resources from global ancient coaly source rocks.展开更多
The theory of ＂source rock control＂ has evolved from source-rock-control hydrocarbon accumulation, to effective source-rock-control hydrocarbon accumulation, and to high-quality source- rock-control hydrocarbon accu...The theory of ＂source rock control＂ has evolved from source-rock-control hydrocarbon accumulation, to effective source-rock-control hydrocarbon accumulation, and to high-quality source- rock-control hydrocarbon accumulation. However, there are problems, such as whether high-quality source rocks exist or not？ What high-quality source rocks are, and how to identify them, are yet to be agreed upon. Aimed at this issue of concern to explorationists, and taking the Beier Sag in the Hailaer Basin as an example, this paper defines the high-quality source rocks and the lower limit for evaluation of high-quality source rocks, by using the inflection point on the relationship curve of hydrocarbon （oil） expulsion, which is calculated by the material balance principle, versus total organic carbon （TOC）. The results show that when TOC is low, all source rocks have limited hydrocarbon expulsion and slow growth rate, thus they cannot be high-quality source rocks. However, when TOC rises to some threshold, hydrocarbon expulsion increases significantly with TOC. This inflection point should be the lower limit of high-quality source rocks： those with TOC greater than the inflection-point value are high-quality source rocks. In addition, the lower limit of high-quality source rocks is also related to the type and maturity of organic matters in the source rocks, as well as the mineral components of the source rocks affecting the residual hydrocarbons. Theoretically, the lower limit of high-quality source rocks depends on geological conditions rather than being a constant value. However, for the sake of simplicity and practicability, in this paper TOC=2.0% is regarded as the lower limit of high-quality source rocks. The examination of such standard in the work area indicates that the high-quality source rocks in members K^n2 and K^n~ of the Nantun formation contribute 76% and 82% to oil generation, and 96% and 91% to oil expulsion, respectively. The distribution of high-quality source rocks is also closely related to the distribution of hydrocarbon reservoirs in the region, demonstrating that high-quality source rocks control hydrocarbon accumulation.展开更多
Based on the transitional background of the global energy structure, exploration and development of unconventional oil and gas, and investigation of key basins, the unconventional oil and gas resources are divided int...Based on the transitional background of the global energy structure, exploration and development of unconventional oil and gas, and investigation of key basins, the unconventional oil and gas resources are divided into three types: source rock oil and gas, tight oil and gas, and retention and accumulated oil and gas. Source rock oil and gas resources are the global strategic supplies of oil and gas, the key resource components in the second 150-year life cycle of the future petroleum industry, and the primary targets for "exploring petroleum inside source kitchen". The geological connotation of source rock oil and gas was proposed, and the models of source rock oil and gas generation, expulsion and accumulation were built, and five source rock oil and gas generation sections were identified, which may determine the actual resource potential under available technical conditions. The formation mechanism of the "sweet sections" was investigated, that is, shale oil is mainly accumulated in the shale section that is close to the oil generation section and has higher porosity and permeability, while the "sweet sections" of coal-bed methane(CBM) and shale gas have self-contained source and reservoir and they are absorbed in coal seams or retained in the organic-rich black shale section, so evaluation and selection of good "sweet areas(sections)" is the key to "exploring petroleum inside source kitchen". Source rock oil and gas resources have a great potential and will experience a substantial growth for over ten world-class large "coexistence basins" of conventional-unconventional oil and gas in the future following North America, and also will be the primary contributor to oil stable development and the growth point of natural gas production in China, with expected contribution of 15% and 30% to oil and gas, respectively, in 2030. Challenges in source rock oil and gas development should be paid more attention to, theoretical innovation is strongly recommended, and a development pilot zone can be established to strengthen technology and promote national support. The source rock oil and gas geology is the latest progress of the "source control theory" at the stage of unconventional oil and gas. It will provide a new theoretical basis for the new journey of the upstream business in the post-industry age.展开更多
Based on the geological and geochemical analysis of potential source rocks in different formations and the classification of crude oil types,combined with the hydrocarbon generation thermal simulation experiments,the ...Based on the geological and geochemical analysis of potential source rocks in different formations and the classification of crude oil types,combined with the hydrocarbon generation thermal simulation experiments,the source,genesis,and distribution of different types of oils in the Mahu large oil province of the Junggar Basin are investigated.Four sets of potential source rocks are developed in the Mahu Sag.Specifically,the source rocks of the Permian Fengcheng Formation have the highest hydrocarbon generation potential and contain mainly TypesⅡandⅠorganic matters,with a high oil generation capacity.In contrast,the source rocks in other formations exhibit lower hydrocarbon generation potential and contain mainly TypeⅢorganic matter,with dominant gas generation.Oils in the Mahu Sag can be classified as three types:A,B and C,which display ascending,mountainous and descending C_(20)-C_(21)-C_(23)tricyclic terpenes abundance patterns in sequence,and gradually increasing relative content of tricyclic terpenes and sterane isomerization parameters,indicating an increasing oil maturity.Different types of oils are distributed spatially in an obviously orderly manner:Type A oil is close to the edge of the sag,Type C oil is concentrated in the center of the sag,and Type B oil lies in the slope area between Type A and Type C.The results of oil-source correlation and thermal simulation experiments show that the three types of oils come from the source rocks of the Fengcheng Formation at different thermal evolution stages.This new understanding of the differential genesis of oils in the Mahu Sag reasonably explains the source,distribution,and genetic mechanism of the three types of oils.The study results are of important guidance for the comprehensive and three-dimensional oil exploration,the identification of oil distribution in the total petroleum system,and the prediction of favorable exploration areas in the Mahu Sag.展开更多
This paper reports some results of geo-scientific evaluation of the petroleum systems in the northeastern area of the Song Hong Basin offshore Vietnam. Geological-geophysical data, including regional studies, 2D and 3...This paper reports some results of geo-scientific evaluation of the petroleum systems in the northeastern area of the Song Hong Basin offshore Vietnam. Geological-geophysical data, including regional studies, 2D and 3D seismic ＆ logging interpretation results as well as core/cutting samples analysis were integrated to reveals that the north-eastern area were controlled by pull apart activities along Song Hong river fault system, rifting phase during Eocene-Oligocene and subsidence during Miocene-Quaternary. Inversion activities at the end of Oligocene and late Miocene also play very important roles. These activities convert Pre-tertiary carbonate basement rocks to be potential reservoirs. The main source rock, overlying and adjacent to basement highs, was deposited in the lacustrine environment during rifting phase of Eocene and Oligocene and is still at the depth of oil generation window. The mentioned source rock layer is also considered as a good top seal for the basement. Petroleum system has been proven by the drilling and testing results and the studied area become more attractive and have higher chance of success.展开更多
On September 15,2014,China National Offshore Oil Co.,Ltd announced that a high production of oil and gas flow of 1.6106 m3/d was obtained in Well LS17-2-1 in deepwater area in northern South China Sea,which is the fi...On September 15,2014,China National Offshore Oil Co.,Ltd announced that a high production of oil and gas flow of 1.6106 m3/d was obtained in Well LS17-2-1 in deepwater area in northern South China Sea,which is the first great oil and gas discovery for self-run deepwater exploration in China sea areas,and a strategic breakthrough was made in natural gas exploration in deepwater area of Lingshui sag in Qiongdongnan Basin.Under the combined action of climax of international deepwater exploration,high oil prices,national demands of China,practical needs of exploration,breakthroughs in seismic exploration and testing technologies,innovations in geological cognition and breakthroughs in deepwater operation equipment,Lingshui 17-2 gas field is discovered.Among these factors,the innovation in reservoir forming geological cognition directly promotes the discovery.The quality of seismic data in the early time is poor,so key reservoir forming conditions such as effective source rocks,high quality reservoirs and oil-gas migration pathways are unable to be ascertained;with support of new seismic acquisition and processing technology,some researches show that Lingshui sag is a successive large and deep sag with an area of 5000 km2 and the maximum thickness of Cenozoic stratum of 13 km.In the Early Oligocene,the Lingshui sag was a semi-closed delta-estuarine environment,where the coalmeasure and marine mudstones in Lower Oligocene Yacheng Formation were developed.The Lingshui sag is a sag with high temperature,and the bottom temperature of source rocks in Yacheng Formation can exceed 250C,but the simulation experiment of hydrocarbon generation at high temperature indicates that the main part of this set of source rock is still in the gas-generation window,with resources of nearly 1 trillion cubic meters,so the Lingshui sag is a hydrocarbon-rich generation sag.In the Neogene,the axial canyon channel from the Thu Bon River in Vietnam passed through the Lingshui sag,and five stages of secondary channels were developed in the axial canyon channel,where four types of reservoirs with excellent physical properties including the axial sand,lateral accretion sand,natural levee sand as well as erosion residual sand were developed,and lithologic traps or structural-lithologic traps were formed.The diapiric zone in the southern Lingshui sag connects deep source rocks in Yacheng Formation and shallow sandstones in the channels,and the migration pattern of natural gas is a T-type migration pattern,in other words,the natural gas generated from Yacheng Formation migrates vertically to the interior of the channel sandbody,and then migrates laterally in the channel reservoirs and forms the reservoirs.Innovations of geophysical exploration technologies for complicated geological conditions of deepwater areas are made,such as the detuning comprehensive quantitative amplitude hydrocarbon detection technology,which greatly improves the success rate of deepwater exploration;key technologies of deepwater safety exploratory well testing represented by the platform-dragged riser displacement technology are developed,which greatly reduces the drilling test cost.The above key exploration technologies provide a strong guarantee for the efficient exploration and development of Lingshui gas field.展开更多
基金supported by the Certificate of National Science and Technology Major Project of the Ministry of Science and Technology of China(No.2016ZX05006007-004)the National Natural Science Foundation of China(Nos.42172145,42072130)。
文摘Coal is a solid combustible mineral,and coal-bearing strata have important hydrocarbon generation potential and contribute to more than 12%of the global hydrocarbon resources.However,the deposition and hydrocarbon evolution process of ancient coal-bearing strata is characterized by multiple geological times,leading to obvious distinctions in their hydrocarbon generation potential,geological processes,and production,which affect the evaluation and exploration of hydrocarbon resources derived from coaly source rocks worldwide.This study aimed to identify the differences on oil-generated parent macerals and the production of oil generated from different coaly source rocks and through different oil generation processes.Integrating with the analysis of previous tectonic burial history and hydrocarbon generation history,high-temperature and high-pressure thermal simulation experiments,organic geochemistry,and organic petrology were performed on the Carboniferous-Permian(C-P)coaly source rocks in the Huanghua Depression,Bohai Bay Basin.The oil-generated parent macerals of coal's secondary oil generation process(SOGP)were mainly hydrogen-rich collotelinite,collodetrinite,sporinite,and cutinite,while the oil-generated parent macerals of tertiary oil generation process(TOGP)were the remaining small amount of hydrogen-rich collotelinite,sporinite,and cutinite,as well as dispersed soluble organic matter and unexhausted residual hydrocarbons.Compared with coal,the oil-generated parent macerals of coaly shale SOGP were mostly sporinite and cutinite.And part of hydrogen-poor vitrinite,lacking hydrocarbon-rich macerals,and macerals of the TOGP,in addition to some remaining cutinite and a small amount of crude oil and bitumen from SOGP contributed to the oil yield.The results indicated that the changes in oil yield had a good junction between SOGP and TOGP,both coal and coaly shale had higher SOGP aborted oil yield than TOGP starting yield,and coaly shale TOGP peak oil yield was lower than SOGP peak oil yield.There were significant differences in saturated hydrocarbon and aromatic parameters in coal and coaly shale.Coal SOGP was characterized by a lower Ts/Tm and C31-homohopane22S/(22S+22R)and a higher Pr/n C17compared to coal TOGP,while the aromatic parameter methyl dibenzothiophene ratio(MDR)exhibited coaly shale TOGP was higher than coaly shale SOGP than coaly TOGP than coaly SOGP,and coal trimethylnaphthalene ratio(TNR)was lower than coaly shale TNR.Thus,we established oil generation processes and discriminative plates.In this way,we distinguished the differences between oil generation parent maceral,oil generation time,and oil production of coaly source rocks,and therefore,we provided important support for the evaluation,prediction,and exploration of oil resources from global ancient coaly source rocks.
基金funded by the 973 Prophase Special Program of China(NO.2011CB211701)National Natural Science Foundation of China(41172134)CNPC Innovation Foundation (2011D-5006-0101)
文摘The theory of ＂source rock control＂ has evolved from source-rock-control hydrocarbon accumulation, to effective source-rock-control hydrocarbon accumulation, and to high-quality source- rock-control hydrocarbon accumulation. However, there are problems, such as whether high-quality source rocks exist or not？ What high-quality source rocks are, and how to identify them, are yet to be agreed upon. Aimed at this issue of concern to explorationists, and taking the Beier Sag in the Hailaer Basin as an example, this paper defines the high-quality source rocks and the lower limit for evaluation of high-quality source rocks, by using the inflection point on the relationship curve of hydrocarbon （oil） expulsion, which is calculated by the material balance principle, versus total organic carbon （TOC）. The results show that when TOC is low, all source rocks have limited hydrocarbon expulsion and slow growth rate, thus they cannot be high-quality source rocks. However, when TOC rises to some threshold, hydrocarbon expulsion increases significantly with TOC. This inflection point should be the lower limit of high-quality source rocks： those with TOC greater than the inflection-point value are high-quality source rocks. In addition, the lower limit of high-quality source rocks is also related to the type and maturity of organic matters in the source rocks, as well as the mineral components of the source rocks affecting the residual hydrocarbons. Theoretically, the lower limit of high-quality source rocks depends on geological conditions rather than being a constant value. However, for the sake of simplicity and practicability, in this paper TOC=2.0% is regarded as the lower limit of high-quality source rocks. The examination of such standard in the work area indicates that the high-quality source rocks in members K^n2 and K^n~ of the Nantun formation contribute 76% and 82% to oil generation, and 96% and 91% to oil expulsion, respectively. The distribution of high-quality source rocks is also closely related to the distribution of hydrocarbon reservoirs in the region, demonstrating that high-quality source rocks control hydrocarbon accumulation.
基金Supported by the National Key Basic Research and Development Program(973 Program),China(2014CB239000)China National Science and Technology Major Project(2016ZX05046)
文摘Based on the transitional background of the global energy structure, exploration and development of unconventional oil and gas, and investigation of key basins, the unconventional oil and gas resources are divided into three types: source rock oil and gas, tight oil and gas, and retention and accumulated oil and gas. Source rock oil and gas resources are the global strategic supplies of oil and gas, the key resource components in the second 150-year life cycle of the future petroleum industry, and the primary targets for "exploring petroleum inside source kitchen". The geological connotation of source rock oil and gas was proposed, and the models of source rock oil and gas generation, expulsion and accumulation were built, and five source rock oil and gas generation sections were identified, which may determine the actual resource potential under available technical conditions. The formation mechanism of the "sweet sections" was investigated, that is, shale oil is mainly accumulated in the shale section that is close to the oil generation section and has higher porosity and permeability, while the "sweet sections" of coal-bed methane(CBM) and shale gas have self-contained source and reservoir and they are absorbed in coal seams or retained in the organic-rich black shale section, so evaluation and selection of good "sweet areas(sections)" is the key to "exploring petroleum inside source kitchen". Source rock oil and gas resources have a great potential and will experience a substantial growth for over ten world-class large "coexistence basins" of conventional-unconventional oil and gas in the future following North America, and also will be the primary contributor to oil stable development and the growth point of natural gas production in China, with expected contribution of 15% and 30% to oil and gas, respectively, in 2030. Challenges in source rock oil and gas development should be paid more attention to, theoretical innovation is strongly recommended, and a development pilot zone can be established to strengthen technology and promote national support. The source rock oil and gas geology is the latest progress of the "source control theory" at the stage of unconventional oil and gas. It will provide a new theoretical basis for the new journey of the upstream business in the post-industry age.
文摘Based on the geological and geochemical analysis of potential source rocks in different formations and the classification of crude oil types,combined with the hydrocarbon generation thermal simulation experiments,the source,genesis,and distribution of different types of oils in the Mahu large oil province of the Junggar Basin are investigated.Four sets of potential source rocks are developed in the Mahu Sag.Specifically,the source rocks of the Permian Fengcheng Formation have the highest hydrocarbon generation potential and contain mainly TypesⅡandⅠorganic matters,with a high oil generation capacity.In contrast,the source rocks in other formations exhibit lower hydrocarbon generation potential and contain mainly TypeⅢorganic matter,with dominant gas generation.Oils in the Mahu Sag can be classified as three types:A,B and C,which display ascending,mountainous and descending C_(20)-C_(21)-C_(23)tricyclic terpenes abundance patterns in sequence,and gradually increasing relative content of tricyclic terpenes and sterane isomerization parameters,indicating an increasing oil maturity.Different types of oils are distributed spatially in an obviously orderly manner:Type A oil is close to the edge of the sag,Type C oil is concentrated in the center of the sag,and Type B oil lies in the slope area between Type A and Type C.The results of oil-source correlation and thermal simulation experiments show that the three types of oils come from the source rocks of the Fengcheng Formation at different thermal evolution stages.This new understanding of the differential genesis of oils in the Mahu Sag reasonably explains the source,distribution,and genetic mechanism of the three types of oils.The study results are of important guidance for the comprehensive and three-dimensional oil exploration,the identification of oil distribution in the total petroleum system,and the prediction of favorable exploration areas in the Mahu Sag.
文摘This paper reports some results of geo-scientific evaluation of the petroleum systems in the northeastern area of the Song Hong Basin offshore Vietnam. Geological-geophysical data, including regional studies, 2D and 3D seismic ＆ logging interpretation results as well as core/cutting samples analysis were integrated to reveals that the north-eastern area were controlled by pull apart activities along Song Hong river fault system, rifting phase during Eocene-Oligocene and subsidence during Miocene-Quaternary. Inversion activities at the end of Oligocene and late Miocene also play very important roles. These activities convert Pre-tertiary carbonate basement rocks to be potential reservoirs. The main source rock, overlying and adjacent to basement highs, was deposited in the lacustrine environment during rifting phase of Eocene and Oligocene and is still at the depth of oil generation window. The mentioned source rock layer is also considered as a good top seal for the basement. Petroleum system has been proven by the drilling and testing results and the studied area become more attractive and have higher chance of success.
基金The work was supported by China National Significant Science and Technology Project(No.2008ZX05025,No.2011ZX05025,No.2016ZX05026)China National Key Basic Research and Development Program(973 Program)(2009CB219400)Project of Ministry of Land and Resources of the People's Republic of China(XQ2004-05,XQ2007-05).
文摘On September 15,2014,China National Offshore Oil Co.,Ltd announced that a high production of oil and gas flow of 1.6106 m3/d was obtained in Well LS17-2-1 in deepwater area in northern South China Sea,which is the first great oil and gas discovery for self-run deepwater exploration in China sea areas,and a strategic breakthrough was made in natural gas exploration in deepwater area of Lingshui sag in Qiongdongnan Basin.Under the combined action of climax of international deepwater exploration,high oil prices,national demands of China,practical needs of exploration,breakthroughs in seismic exploration and testing technologies,innovations in geological cognition and breakthroughs in deepwater operation equipment,Lingshui 17-2 gas field is discovered.Among these factors,the innovation in reservoir forming geological cognition directly promotes the discovery.The quality of seismic data in the early time is poor,so key reservoir forming conditions such as effective source rocks,high quality reservoirs and oil-gas migration pathways are unable to be ascertained;with support of new seismic acquisition and processing technology,some researches show that Lingshui sag is a successive large and deep sag with an area of 5000 km2 and the maximum thickness of Cenozoic stratum of 13 km.In the Early Oligocene,the Lingshui sag was a semi-closed delta-estuarine environment,where the coalmeasure and marine mudstones in Lower Oligocene Yacheng Formation were developed.The Lingshui sag is a sag with high temperature,and the bottom temperature of source rocks in Yacheng Formation can exceed 250C,but the simulation experiment of hydrocarbon generation at high temperature indicates that the main part of this set of source rock is still in the gas-generation window,with resources of nearly 1 trillion cubic meters,so the Lingshui sag is a hydrocarbon-rich generation sag.In the Neogene,the axial canyon channel from the Thu Bon River in Vietnam passed through the Lingshui sag,and five stages of secondary channels were developed in the axial canyon channel,where four types of reservoirs with excellent physical properties including the axial sand,lateral accretion sand,natural levee sand as well as erosion residual sand were developed,and lithologic traps or structural-lithologic traps were formed.The diapiric zone in the southern Lingshui sag connects deep source rocks in Yacheng Formation and shallow sandstones in the channels,and the migration pattern of natural gas is a T-type migration pattern,in other words,the natural gas generated from Yacheng Formation migrates vertically to the interior of the channel sandbody,and then migrates laterally in the channel reservoirs and forms the reservoirs.Innovations of geophysical exploration technologies for complicated geological conditions of deepwater areas are made,such as the detuning comprehensive quantitative amplitude hydrocarbon detection technology,which greatly improves the success rate of deepwater exploration;key technologies of deepwater safety exploratory well testing represented by the platform-dragged riser displacement technology are developed,which greatly reduces the drilling test cost.The above key exploration technologies provide a strong guarantee for the efficient exploration and development of Lingshui gas field.
