Corrosion behavior of low-alloy steel was investigated in simulated cargo oil tank （COT） bottom plate service environment （10% NaCl solution, pH = 0.85）. The corrosion behavior of inclusion was studied by in-situ ...Corrosion behavior of low-alloy steel was investigated in simulated cargo oil tank （COT） bottom plate service environment （10% NaCl solution, pH = 0.85）. The corrosion behavior of inclusion was studied by in-situ scanning electron microscopy （SEM） and energy dispersive spectroscopy （EDS）. It was found that pitting corrosion was inclined to occur around the place where inclusions exist. After initial corrosion, an area of 10-20μm in diameter was formed as a cireinate cathode around the edge of inclusion. MnS inclusion dissolved in the simulated COT corrosion solution before low-alloy steel matrix, and pitting was formed at the place where MnS dissolved. TiO2 inclusion dissolved in the simulated COT corrosion solution after low alloy steel matrix, and pitting was formed at the place where steel matrix dissolved. The corrosion tended to occur at the area where the curvature radius of inclusion is smaller. The size of round TiO2 inclusions had little influence on corrosion behavior in this certain environment.展开更多
As international maritime organization （IMO） draft 289 was adopted to develop a low-alloy anti-corrosion steel for the deck of cargo oil tank and to understand corrosion mechanism, corrosion behavior of a low-alloy ...As international maritime organization （IMO） draft 289 was adopted to develop a low-alloy anti-corrosion steel for the deck of cargo oil tank and to understand corrosion mechanism, corrosion behavior of a low-alloy steel with chromium contents was studied in O2-CO2-SO2-H2 S wet gas environment. Corrosion rate was measured, and the microstructure and morphology of corrosion product film were characterized by scanning electron microscopy （SEM）. The phase and chemical composition of the corrosion product film were investigated by X-ray diffraction （XRD） and energy dispersive spectroscopy （EDS）, respectively. The effect of misorientation distribution on corro- sion resistance of steel was evaluated by electron backscattered diffraction （EBSD）. The results showed that corro- sion rate decreased with increasing chromium content in the low-alloy steel, and the corrosion type was general corrosion. The phenomenon of chromium enrichment was found in corrosion product film consisting of a-FeOOH, γ- FeOOH, sulphur, FeS2 and Fel-xS. The increase of chromium content decreases the amount of high-angle grain boundaries, thus resulting in the improvement of corrosion resistance.展开更多
A simulated corrosion test apparatus was used to investigate the corrosion behavior of a low alloy steel under simulated upper deck conditions in a cargo oil tank. The estimated corrosion loss of conventional E36 clas...A simulated corrosion test apparatus was used to investigate the corrosion behavior of a low alloy steel under simulated upper deck conditions in a cargo oil tank. The estimated corrosion loss of conventional E36 class ship plate steel is 4.27 mm, which is clearly inadequate compared with the standard adopted by International Maritime Organization. Outer rust layer of specimens starts to peel off after 77 days and becomes fragmented after 98 days. X-ray diffraction, scanning electron micros- copy, and Raman spectroscopy revealed that the resulting rust is composed of σ-FeOOH （the main protective phase）, Fe2O3, FeS, elemental S, and FeSO4. FeSO4 in the interface of the base and rust layer leads to localized corrosion. Elemental sulfur forms on the surface of σ-FeOOH, and the quantity and size thereof increase with increasing corrosion time. Furthermore, layered elemental sulfur promotes fracture and peels off the rust layer.展开更多
基金Item Sponsored by National Science and Technology Major Project of the Ministry of Science and Technology of China(2011ZX05016-004)National Key Technology Research and Development Program of the Ministry of Science and Technology of China(2011BAE25B00)
文摘Corrosion behavior of low-alloy steel was investigated in simulated cargo oil tank （COT） bottom plate service environment （10% NaCl solution, pH = 0.85）. The corrosion behavior of inclusion was studied by in-situ scanning electron microscopy （SEM） and energy dispersive spectroscopy （EDS）. It was found that pitting corrosion was inclined to occur around the place where inclusions exist. After initial corrosion, an area of 10-20μm in diameter was formed as a cireinate cathode around the edge of inclusion. MnS inclusion dissolved in the simulated COT corrosion solution before low-alloy steel matrix, and pitting was formed at the place where MnS dissolved. TiO2 inclusion dissolved in the simulated COT corrosion solution after low alloy steel matrix, and pitting was formed at the place where steel matrix dissolved. The corrosion tended to occur at the area where the curvature radius of inclusion is smaller. The size of round TiO2 inclusions had little influence on corrosion behavior in this certain environment.
基金Item Sponsored by National Science and Technology Major Project of the Ministry of Science and Technology of China(2011ZX05016-004)National Key Technology Research and Development Program of the Ministry of Science and Technology of China(2011BAE25B00)
文摘As international maritime organization （IMO） draft 289 was adopted to develop a low-alloy anti-corrosion steel for the deck of cargo oil tank and to understand corrosion mechanism, corrosion behavior of a low-alloy steel with chromium contents was studied in O2-CO2-SO2-H2 S wet gas environment. Corrosion rate was measured, and the microstructure and morphology of corrosion product film were characterized by scanning electron microscopy （SEM）. The phase and chemical composition of the corrosion product film were investigated by X-ray diffraction （XRD） and energy dispersive spectroscopy （EDS）, respectively. The effect of misorientation distribution on corro- sion resistance of steel was evaluated by electron backscattered diffraction （EBSD）. The results showed that corro- sion rate decreased with increasing chromium content in the low-alloy steel, and the corrosion type was general corrosion. The phenomenon of chromium enrichment was found in corrosion product film consisting of a-FeOOH, γ- FeOOH, sulphur, FeS2 and Fel-xS. The increase of chromium content decreases the amount of high-angle grain boundaries, thus resulting in the improvement of corrosion resistance.
文摘A simulated corrosion test apparatus was used to investigate the corrosion behavior of a low alloy steel under simulated upper deck conditions in a cargo oil tank. The estimated corrosion loss of conventional E36 class ship plate steel is 4.27 mm, which is clearly inadequate compared with the standard adopted by International Maritime Organization. Outer rust layer of specimens starts to peel off after 77 days and becomes fragmented after 98 days. X-ray diffraction, scanning electron micros- copy, and Raman spectroscopy revealed that the resulting rust is composed of σ-FeOOH （the main protective phase）, Fe2O3, FeS, elemental S, and FeSO4. FeSO4 in the interface of the base and rust layer leads to localized corrosion. Elemental sulfur forms on the surface of σ-FeOOH, and the quantity and size thereof increase with increasing corrosion time. Furthermore, layered elemental sulfur promotes fracture and peels off the rust layer.
