This paper addresses increasing concern about the pollution threat of used oil being illegally dumped and the impact of oil on air pollution and freshwater ecosystems in Asian countries. Used oil is a very serious was...This paper addresses increasing concern about the pollution threat of used oil being illegally dumped and the impact of oil on air pollution and freshwater ecosystems in Asian countries. Used oil is a very serious waste management problem. These results call for management action such as maximising the collection and recovery of used oil. The Thai government recognizes the need to recycle used oil and has been active in encouraging programs to accomplish this goal. Thus unless new approaches and incentives are developed, used oil generation may become an increasing serious problem to our environment. The purpose of this study is to examine the technical and economic feasibility, of recycling used oils. In addition, this paper briefly discusses the problems to be overcome and outlines potential mechanisms for providing the necessary disposal controls in order to maximize the protection to public health and environmental quality from potential hazards posed by used lube oil disposal.展开更多
An outdoor experiment was set up to investigate the effects of used lubricating oil (5 L/m^2) on Aegiceras corniculatum Blanco. and Avicennia marina (Forsk) Vierh., two salt-excreting mangroves. A. marina was more...An outdoor experiment was set up to investigate the effects of used lubricating oil (5 L/m^2) on Aegiceras corniculatum Blanco. and Avicennia marina (Forsk) Vierh., two salt-excreting mangroves. A. marina was more sensitive to used lubricating oil than A. corniculatum and canopy-oiling resulted in more direct physical damage and stronger lethal effects than base-oiling. When treated with canopy-oiling, half of A. corniculatum plants survived for the whole treatment time (90 d); but, for A. marina, high mortality (83%) resulted from canopy-oiling within 3 weeks and no plants survived for 80 d. Base-oiling had no lethal effects on A. corniculatum plants even at the termination of this experiment, but 83% of A. marina plants died 80 d after treatment. Forty days after canopyoiling, 93% ofA. corniculatum leaves fell and no live leaves remained on A. marina plants. By the end of the experiment, base-oiling treatment resulted in about 45% ofA. corniculatum leaves falling, while all A. mar/na leaves and buds were burned to die. Lubricating oil resulted in physiological damage to A. corniculatum leaves, including decreases in chlorophyll and carotenoid contents, nitrate reductase, peroxidase and superoxide dismutase activities, and increases in malonaldehyde contents. For both species, oil pollution significantly reduced leaf, root, and total biomass, but did not significantly affect stem biomass. Oil pollution resulted in damage to the xylem vessels of fine roots but not to those of mediate roots.展开更多
In the present paper, we have investigated the tribological properties and microstructure of the used gear oil theoretically and experimentally. The deterioration process of the in-service gear lubricant oils was also...In the present paper, we have investigated the tribological properties and microstructure of the used gear oil theoretically and experimentally. The deterioration process of the in-service gear lubricant oils was also discussed. The viscosity and microstructure of oils running different mileages were analyzed by viscometer and Fourier Transform Infrared Spectroscopy (FTIR), respectively. In addition, the friction and wear behaviors of the friction pair of the GCr15 steel ball and disc were investigated using a ball on disc tribometer under different mileages’ gear oils lubrication conditions. These techniques give reproducible and reliable data with which to evaluate the severity of deterioration process of oils. The objective of this work is to understand the deterioration process of gear oil and analyze the influence of deterioration on the performance and microstructure of lubricant oils used in gear box. Possible explanations of deterioration process as well as its influence on friction and wear behaviors are also discussed. The results reveals the tribological properties of used oils depended on strongly the microstructure and its deterioration process of oil.展开更多
This study analyzed the pyrolysis mechanism,developed a pyrolysis kinetic model,and determined the corresponding thermodynamic parameters for the removal of calcium from used lubricating oil using sulfurized calcium a...This study analyzed the pyrolysis mechanism,developed a pyrolysis kinetic model,and determined the corresponding thermodynamic parameters for the removal of calcium from used lubricating oil using sulfurized calcium alkyl phenolate(T-115B)as a model compound.The pyrolysis process and products were evaluated by Fourier transform infrared spectroscopy and X-ray photoelectron spectroscopy.Visual inspection indicated that the removal of calcium from T-115B depended primarily on the destruction of micelles caused by the pyrolysis of compounds at high temperatures.The pyrolysis characteristics of T-115B at different heating rates were investigated by thermogravimetry and differential thermal analysis,which revealed two distinct pyrolysis phases.Thus,the pyrolysis mechanism can be described by a twostep model.The activation energy and thermodynamic parameters(ΔH,ΔG,andΔS)were determined by applying the Kissinger-Akahira-Sunose,Flynn-Wall-Ozawa,Friedman,and Starink methods;the average activation energies for T-115B pyrolysis obtained using these methods were 115.80,119.84,124.96,and 116.14 kJ/mol,respectively.Further,both stages of the pyrolysis reaction followed Fn mechanisms with n=1.39 in the first stage and n=0.86 in the second stage.This study provides reliable and effective pyrolysis models along with kinetic and thermodynamic parameters to facilitate the largescale industrial application of used lubricating oil.展开更多
Crude and used engine oil degrading ability of two white rot fungi Pleurotus ostreatus and P. pulmonarius were investigated for six months. One hundred grams of sterilized soil moistened with 75% distilled water (w/v)...Crude and used engine oil degrading ability of two white rot fungi Pleurotus ostreatus and P. pulmonarius were investigated for six months. One hundred grams of sterilized soil moistened with 75% distilled water (w/v) were weighed into 9 × 9 × 4 cm (350 cm3) jam bottles and mixed thoroughly with bonny light crude oil and used engine oil at different concentrations (0%, 5%, 10%, 15%, 25% and 30%), separately. Each bottle was then inoculated with two agar plugs of a vigorously grown mycelium of P. ostreatus and P. pulmonarius using a sterile cork borer. The bottles were incubated at room temperature for 6 months. The mycelia-ramified waste was separated from soils and analysed for physicochemical parameters such as organic matter, carbon, nitrogen, phosphorus, potassium, pH and total hydrocarbon content, (THC) after drying. The organic carbon, nitrogen and phosphorus contents in contaminated and inoculated soils were increased after six months. However, decrease in potassium, pH and THC occurred in these soils after the period of investigation. P. ostreatus reduced the initial THC to 8% and 9% in soils contaminated with 20% of crude and engine oils, respectively, which was lower than that of P. pulmonarius. The two white rot fungi could be exploited in bioremediation of soils contaminated with bonny light crude and used engine oils.展开更多
The authors performed economic assessment of producing biodiesel at pilot scale using used cooking oil as feed-oil in a Bio-Pro 380 EX biodiesel reactor. The overall results suggest that the biodiesel production using...The authors performed economic assessment of producing biodiesel at pilot scale using used cooking oil as feed-oil in a Bio-Pro 380 EX biodiesel reactor. The overall results suggest that the biodiesel production using used cooking oil is a viable project even at large or medium scale. The payback period for producing biodiesel at a pilot scale of 31,320 liters per year was 1.5 years, which was 1 month longer than the payback period for a large plant capacity of 66,000 liters per year. The study demonstrated that the unit selling price and unit production cost are sensitive to the economic feasibility of biodiesel production, since price variations of BWP 1 result in at least a 13% increase and 12% decrease in profit, respectively. The study further revealed that feed-oil (used cooking oil) was the most expensive among all the inputs accounting for 61%, followed by methanol and direct labour with 19% and 13% respectively. The overall energy recorded to produce approximately 360 liters of biodiesel contributed to 2% only, suggesting that Bio-Pro 380 EX biodiesel reactor is relatively a low energy intensity processor. The situation is suitable for the promotion of biodiesel particularly in countries where initiatives to stimulate the development of biofuels are at its infant stage Botswana included.展开更多
Dear Editor The mosquitoes Aedes aegypli(I,) and Aedes albopictus (Skuse)(Diptera:Culicidae) are important vectors of dengue fever in tropical and subtropical parts of the world. Chemical control has been considered a...Dear Editor The mosquitoes Aedes aegypli(I,) and Aedes albopictus (Skuse)(Diptera:Culicidae) are important vectors of dengue fever in tropical and subtropical parts of the world. Chemical control has been considered as an effective tool for their management in different areas of the world.However, injudicious use of the chemicals result in environmental pollution,ill effects to humans and other animals,and the development of insecticide resistance,which ultimately limits the efficacy of many insecticides!’].Essential oils can be used for mosquito control with no harmful effects to the ecosystem and non-target organisms.Essentials oils from different plants have been found very展开更多
Ridge-furrow rainwater harvesting (RFRH) planting pattern can lessen the effect of water deficits throughout all crop growth stages, but water shortage would remain unavoidable during some stages of crop growth in a...Ridge-furrow rainwater harvesting (RFRH) planting pattern can lessen the effect of water deficits throughout all crop growth stages, but water shortage would remain unavoidable during some stages of crop growth in arid and semiarid areas. Supplemental irrigation would still be needed to achieve a higher production. Field experiments were conducted for two growing seasons (2012-2013 and 2013-2014)to determine an appropriate amount of supplemental irrigation to be applied to winter oilseed rape at the stem-elongation stage with RFRH planting pattern. Four treatments, including supplemental irrigation amount of 0 (I1), 60 mm (I2) and 120 mm (I3) with RFRH planting pattern and a control (CK) irrigated with 120 mm with flat planting pattern, were set up to evaluate the effects of supplemental irrigation on aboveground dry matter (ADM), nitrogen nutrition index (NNI), radiation use efficiency (RUE), water use efficiency (WUE), and seed yield and oil content of the oilseed rape. Results showed that supplemental irrigation improved NNI, RUE, seed yield and oil content, and WUE. However, the NNI, RUE, seed yield and oil content, and WUE did not increase significantly or even showed a downward trend with excessive irrigation. Seed yield was the highest in 13 for both growing seasons. Seed yield and WUE in 13 averaged 3235 kg ha^-1 and 8.85 kg ha^-1 mm-1, respectively. The highest WUE was occurred in 12 for both growing seasons. Seed yield and WUE in 12 averaged 3089 kg ha^-1 and 9.63 kg ha^-1 mm^-1, respectively. Compared to 13, 12 used 60 mm less irrigation amount, had an 8.9% higher WUE, but only 4.5 and 0.4% lower seed yield and oil content, respectively. 12 saved water without substantially sacrificing yield or oil content, so it is recommended as an appropriate cultivation and irrigation schedule for winter oilseed rape at the stem-elongation stage.展开更多
Two field experiments were carried out during growing seasons 2010 and 2011, it executed in research farm of national research center in Nubaryia region, Egypt to study the effect of pulse drip irrigation and mulching...Two field experiments were carried out during growing seasons 2010 and 2011, it executed in research farm of national research center in Nubaryia region, Egypt to study the effect of pulse drip irrigation and mulching systems for saving water, increasing and improving yield of soybean. The study factors were, pulse drip irrigation technology (adding of daily water requirements on 4 times, 8 times, 12 times compared with adding of daily water requirements on 1 time) and mulching systems (covering the soil with black plastic mulch “BPM”, rice straw mulch “RSM” and the control treatment was soil surface without mulch “WM”). The following parameters were studied to evaluate the effect of pulse drip irrigation and mulching systems: 1) Soil moisture distribution in root zone, 2) Growth characters of soybean plant, 3) Yield of soybean, 4) Irrigation water use efficiency of soybean “IWUE soybean”, and 5) Oil content and oil yield, 6) Protein content and protein yield, 7) Economical parameter. According to the economical view and the results of statistical analysis for effect of pulse drip irrigation and mulching systems on yield, quality traits and IWUE soybean indicated that, applying the irrigation requirements on 8 pulses/day with using BPM is the best conditions because under these conditions was occurred the highest value of yield, quality traits and IWUE soybean and there was significant deference between this case and other treatments. Where, pulse irrigation technique increase from water movement in horizontal direction than vertical direction hence improve from soil moisture distribution and wetted soil volume in root zone and using BPM decrease from evaporation process rate from soil surface hence decreasing of salts accumulation in addition to decreasing of weed growth in the root zone. All traits at AIR on 12 pulses/ day are decreased by increasing of pulses, this may be due to irrigation water was very small with every pulse at AIR on 12 pulses/day in addition increasing the total time of time-off, this mean, un-sufficient application for irrigation water to remove water stress in the root zone.展开更多
This paper takes the analysis of economical land use in the design of oil field stations as the research object.Firstly,it elaborates the significance of saving land.Then combined with the"Fire Prevention Code of...This paper takes the analysis of economical land use in the design of oil field stations as the research object.Firstly,it elaborates the significance of saving land.Then combined with the"Fire Prevention Code of Petrol Chemical Enterprise Design",the paper analyzes and studies the safety and economical use of the general drawing design of the oil field stations for reference.展开更多
In recent decades, the demand for cold-rolled steel sheets has remarkably increased. To prevent the sheets from rusting before the manufacturing process, a layer of rust-preventive oil has to be coated on the sheets. ...In recent decades, the demand for cold-rolled steel sheets has remarkably increased. To prevent the sheets from rusting before the manufacturing process, a layer of rust-preventive oil has to be coated on the sheets. In this study, the shipment and storage environments were simulated through a salt spray test and a damp-heat experiment, respectively, and the packaging status of the sheets was imitated by a laminated sheet test. The protection effect of oil on the steel sheet was investigated under the different environmental conditions and oil weights by using electrochemical approaches, scanning electron microscopy ( SEM), and X-ray diffraction (XRD) techniques. It was found that chloride ions had more severe effects on the corrosion resistance of the oils than hydrothermal conditions did. This was shown in the sheets with oil weights of 0.4,0.9 ,and 1.2 g · m^-2 ,which were too severely corroded after a four-hour salt spraying test to meet the demands of subsequent processing. However, the sheets showed satisfactory corrosion resistance after a three-week damp-heat experiment with a temperature of 49 ℃ and 95 % RH. In addition, it was disclosed that the penetration of the chloride ions determined the protection mechanism of the oil, i. e.,the corrosion resistance was initially enhanced by the increase in the oil content. As long as the chloride ion reached the interface between the oil film and the sheet, the oil distribution became the predominant factor in the protection of the sheet. The corrosion mechanism of the steel sheet was dependent on the stacking style of the sample. When exposed to air, the corrosion product of the sample was rust red with a composition of Fe2O3, whereas the black product that is mainly composed of Fe3O4 was found on the edge of the laminated sheets, which resulted from the oxygen concentration cell.展开更多
The reforms in oil and gas sector have been accelerated in 2015. The reform of mineral rights has begun and 6 oil and gas exploration zones in Xinjiang Autonomous Region have served as the tender pilots, breaking thro...The reforms in oil and gas sector have been accelerated in 2015. The reform of mineral rights has begun and 6 oil and gas exploration zones in Xinjiang Autonomous Region have served as the tender pilots, breaking through the requirements on the resources varieties, exploration phase and enterprise qual!fication. The right of importing and using of the crude oil has been gradually relaxed and 13 local refineries have obtained the right to use imported crude oil of 55.1888 million tons per year. The natural gas price for non-residential use was unified and a universal price was set ~r the incremental supply and existing supply. Tire Shanghai Petroleum and Gas Exchange (SHPGX) was established and laid foundation for the market mechanism to detervnine the price. The government governance has undergone continuous adjustments such as regulating the tax instead of charging the fees, streamlining administration and delegating power to tire lower levels.The Guidelines on Deepening tire Reform of State-owned Enterprises was released, symbolizing the accomplishment of the overall planning ~ the SOE reform.展开更多
To examine the REDD+ (Reducing Emissions from Deforestation and Forest Degradation) program as an alternative to an oil palm plantation in West Kutai district of East Kalimantan, we determined the profitability of lan...To examine the REDD+ (Reducing Emissions from Deforestation and Forest Degradation) program as an alternative to an oil palm plantation in West Kutai district of East Kalimantan, we determined the profitability of land use and REDD+, and the land use preferences and practices of the local people, as well as their participation in and preferences for forestry programs. Our findings indicate the following: 1) the profitability of an oil palm plantation was higher than that from other land uses and the REDD+ program;2) the local preferences for land uses were mostly consistent with the profitability of the land uses, except for oil palm plantation due to non-financial concerns;3) the local people combined each land use in accordance with their various needs;and 4) the local people were interested in a Forest and Land Rehabilitation (RHL) program in nonforestry zones. Considering these evidences, an improved RHL program based on an intensive agroforestry system and a conservation-based REDD+ program based on existing customary conservation forest management by the local people are proposed. Given the high opportunity cost and the low preference for an oil palm plantation, designing the REDD+ program by paying attention to the non-financial benefits for a community is a way forward. To enhance the non-financial benefits, it is important to take into consideration local preferences and livelihood activities in designing the REDD+ program. This study also implies the need for a reconsideration of the position of participation of local people in the safeguards of REDD+.展开更多
The manufacturing industry today due to worldwide competition is focused on shorter development cycle. In this situation, computer aided education (CAE) technology as a tool for simultaneous achievement of quality, ...The manufacturing industry today due to worldwide competition is focused on shorter development cycle. In this situation, computer aided education (CAE) technology as a tool for simultaneous achievement of quality, cost and delivery (QCD) plays an important role. The hardware-software environment surrounding CAE has evolved. Though technological problems have been understood and general solutions have been derived and reflected in the CAE analysis software, research findings that boost the credibility of CAE have still not been incorporated fully enough into the development of design process. The real technical mechanism issue is not precisely capture. Therefore, it is important to clarify the real cause in CAE results through CAE simulation in order to assure product reliability and assurance. It is the aim of this study to realize the prediction of design analysis process through understanding of unclear technical mechanism in abnormal occurrences with the utilization of CAE simulation. In other words, it is the aim of this study to focus on issue in automotive transaxle oil seal leakage to understand, grasp, and visualize the main cause through usage of CAE analysis process. It is understood that the point of contact and pump volume was related and this could contribute towards seals quality design. Plus, the utilization of CAE analysis in prediction phase to realized design development is also possible展开更多
Aim: A simulation experiment was carried out in which oyster mushrooms (Pleurotus?pulmonarius) was grown on used engine oil. This study was designed to evaluate the remnant hydrocarbon in the sporophore (fruiting body...Aim: A simulation experiment was carried out in which oyster mushrooms (Pleurotus?pulmonarius) was grown on used engine oil. This study was designed to evaluate the remnant hydrocarbon in the sporophore (fruiting body) of?Pleurotuspulmonarius?and to assess its suitability for human consumption. Method: The mycelia of the mushroom were used to inoculate Spent Engine Oil (SEO, 10% (v/w)) polluted soil. After four weeks of incubation, fruiting bodies growing on the polluted soil were analyzed for remnant hydrocarbon profile. Results: Results showed that total Polycyclic Aromatic Hydrocarbon (PAH) was 10 mg/kg and Aliphatic Hydrocarbon (AH) was 23 mg/kg. The hydrocarbon profile indicated some AH and PAH were within the non-cancer reference dose while a few others were above the non-cancer daily reference dose range. Conclusion: The detection of some hydrocarbon profile above the non-cancer daily reference dose makes the test-mushroom used for bioremediation not safe for human consumption. This underscores the need for caution in consuming mushrooms found in oil polluted environment.展开更多
Ⅰ The Indexes of Detecting Oil and Gas Resources The deeply buried reservoir which in a dynamic equilibrium state has a great pressure inside, and between it and earth surface there is a great difference of pressure....Ⅰ The Indexes of Detecting Oil and Gas Resources The deeply buried reservoir which in a dynamic equilibrium state has a great pressure inside, and between it and earth surface there is a great difference of pressure. Therefore the hydrocarbon must spread and move vertically to the surface along the pressure gradient orientation. Hydrocarbons in the reservoir along some small rifts, cracks, joints and cleavages penetrate the overlying strata and seepage onto the surface. Thus the hydrocarbons become unvisble oil and gas signs. This process is called the phenomena of hydrocarbon microseepage of reservoir. Hydrocarbons microseepage in the process展开更多
This paper discusses the use of GIS in oilfield power system,combined with the basic concept and advantages of GIS,combined with the characteristics of the oilfield power system,put forward the overall design system o...This paper discusses the use of GIS in oilfield power system,combined with the basic concept and advantages of GIS,combined with the characteristics of the oilfield power system,put forward the overall design system of the oilfield power system,ensure the stability of the power system operation,give full play to the role of GIS.展开更多
The aim of this study was to investigate the effects of Baccharis coridifolia essential oil on the Activity of Antibiotics. Assays were performed with ampicillin (10 μg), cephalothin (30 μg), chloramphenicol (30 μg...The aim of this study was to investigate the effects of Baccharis coridifolia essential oil on the Activity of Antibiotics. Assays were performed with ampicillin (10 μg), cephalothin (30 μg), chloramphenicol (30 μg), gentamicin (10 μg) and tetracycline (30 μg) alone and in combination with the essential oil (4% v/v) through the disk diffusion susceptibility test. The results showed the effects of essential oil on the activity of the antibiotics tested. Zones of inhibition of bacterial growth with different diameters were observed surrounding the antibiotic disks, whether or not they were impregnated with the essential oil. The occurrence of the synergistic or antagonistic effect was observed in both bacterial strains assessed—Staphylococcus aureus (ATCC-25923) and Escherichia coli (ATCC-25922). These results show that the use of products derived from plants can, in some cases, interfere with the effectiveness of antibiotics during clinical therapy.展开更多
文摘This paper addresses increasing concern about the pollution threat of used oil being illegally dumped and the impact of oil on air pollution and freshwater ecosystems in Asian countries. Used oil is a very serious waste management problem. These results call for management action such as maximising the collection and recovery of used oil. The Thai government recognizes the need to recycle used oil and has been active in encouraging programs to accomplish this goal. Thus unless new approaches and incentives are developed, used oil generation may become an increasing serious problem to our environment. The purpose of this study is to examine the technical and economic feasibility, of recycling used oils. In addition, this paper briefly discusses the problems to be overcome and outlines potential mechanisms for providing the necessary disposal controls in order to maximize the protection to public health and environmental quality from potential hazards posed by used lube oil disposal.
基金Project supported by the Program for New Century Excellent Talents in University(NCET)Environment and Conservation Fund of the HKSAR(No.9210007)
文摘An outdoor experiment was set up to investigate the effects of used lubricating oil (5 L/m^2) on Aegiceras corniculatum Blanco. and Avicennia marina (Forsk) Vierh., two salt-excreting mangroves. A. marina was more sensitive to used lubricating oil than A. corniculatum and canopy-oiling resulted in more direct physical damage and stronger lethal effects than base-oiling. When treated with canopy-oiling, half of A. corniculatum plants survived for the whole treatment time (90 d); but, for A. marina, high mortality (83%) resulted from canopy-oiling within 3 weeks and no plants survived for 80 d. Base-oiling had no lethal effects on A. corniculatum plants even at the termination of this experiment, but 83% of A. marina plants died 80 d after treatment. Forty days after canopyoiling, 93% ofA. corniculatum leaves fell and no live leaves remained on A. marina plants. By the end of the experiment, base-oiling treatment resulted in about 45% ofA. corniculatum leaves falling, while all A. mar/na leaves and buds were burned to die. Lubricating oil resulted in physiological damage to A. corniculatum leaves, including decreases in chlorophyll and carotenoid contents, nitrate reductase, peroxidase and superoxide dismutase activities, and increases in malonaldehyde contents. For both species, oil pollution significantly reduced leaf, root, and total biomass, but did not significantly affect stem biomass. Oil pollution resulted in damage to the xylem vessels of fine roots but not to those of mediate roots.
文摘In the present paper, we have investigated the tribological properties and microstructure of the used gear oil theoretically and experimentally. The deterioration process of the in-service gear lubricant oils was also discussed. The viscosity and microstructure of oils running different mileages were analyzed by viscometer and Fourier Transform Infrared Spectroscopy (FTIR), respectively. In addition, the friction and wear behaviors of the friction pair of the GCr15 steel ball and disc were investigated using a ball on disc tribometer under different mileages’ gear oils lubrication conditions. These techniques give reproducible and reliable data with which to evaluate the severity of deterioration process of oils. The objective of this work is to understand the deterioration process of gear oil and analyze the influence of deterioration on the performance and microstructure of lubricant oils used in gear box. Possible explanations of deterioration process as well as its influence on friction and wear behaviors are also discussed. The results reveals the tribological properties of used oils depended on strongly the microstructure and its deterioration process of oil.
基金We are grateful for the support of the Science and Technology Innovation 2025 Major project of Ningbo[2018B10038]the Chair Professorship Program of Shandong University of Technology[117002]the Natural Science Foundation of Shandong Province[ZR2020MB130].
文摘This study analyzed the pyrolysis mechanism,developed a pyrolysis kinetic model,and determined the corresponding thermodynamic parameters for the removal of calcium from used lubricating oil using sulfurized calcium alkyl phenolate(T-115B)as a model compound.The pyrolysis process and products were evaluated by Fourier transform infrared spectroscopy and X-ray photoelectron spectroscopy.Visual inspection indicated that the removal of calcium from T-115B depended primarily on the destruction of micelles caused by the pyrolysis of compounds at high temperatures.The pyrolysis characteristics of T-115B at different heating rates were investigated by thermogravimetry and differential thermal analysis,which revealed two distinct pyrolysis phases.Thus,the pyrolysis mechanism can be described by a twostep model.The activation energy and thermodynamic parameters(ΔH,ΔG,andΔS)were determined by applying the Kissinger-Akahira-Sunose,Flynn-Wall-Ozawa,Friedman,and Starink methods;the average activation energies for T-115B pyrolysis obtained using these methods were 115.80,119.84,124.96,and 116.14 kJ/mol,respectively.Further,both stages of the pyrolysis reaction followed Fn mechanisms with n=1.39 in the first stage and n=0.86 in the second stage.This study provides reliable and effective pyrolysis models along with kinetic and thermodynamic parameters to facilitate the largescale industrial application of used lubricating oil.
文摘Crude and used engine oil degrading ability of two white rot fungi Pleurotus ostreatus and P. pulmonarius were investigated for six months. One hundred grams of sterilized soil moistened with 75% distilled water (w/v) were weighed into 9 × 9 × 4 cm (350 cm3) jam bottles and mixed thoroughly with bonny light crude oil and used engine oil at different concentrations (0%, 5%, 10%, 15%, 25% and 30%), separately. Each bottle was then inoculated with two agar plugs of a vigorously grown mycelium of P. ostreatus and P. pulmonarius using a sterile cork borer. The bottles were incubated at room temperature for 6 months. The mycelia-ramified waste was separated from soils and analysed for physicochemical parameters such as organic matter, carbon, nitrogen, phosphorus, potassium, pH and total hydrocarbon content, (THC) after drying. The organic carbon, nitrogen and phosphorus contents in contaminated and inoculated soils were increased after six months. However, decrease in potassium, pH and THC occurred in these soils after the period of investigation. P. ostreatus reduced the initial THC to 8% and 9% in soils contaminated with 20% of crude and engine oils, respectively, which was lower than that of P. pulmonarius. The two white rot fungi could be exploited in bioremediation of soils contaminated with bonny light crude and used engine oils.
文摘The authors performed economic assessment of producing biodiesel at pilot scale using used cooking oil as feed-oil in a Bio-Pro 380 EX biodiesel reactor. The overall results suggest that the biodiesel production using used cooking oil is a viable project even at large or medium scale. The payback period for producing biodiesel at a pilot scale of 31,320 liters per year was 1.5 years, which was 1 month longer than the payback period for a large plant capacity of 66,000 liters per year. The study demonstrated that the unit selling price and unit production cost are sensitive to the economic feasibility of biodiesel production, since price variations of BWP 1 result in at least a 13% increase and 12% decrease in profit, respectively. The study further revealed that feed-oil (used cooking oil) was the most expensive among all the inputs accounting for 61%, followed by methanol and direct labour with 19% and 13% respectively. The overall energy recorded to produce approximately 360 liters of biodiesel contributed to 2% only, suggesting that Bio-Pro 380 EX biodiesel reactor is relatively a low energy intensity processor. The situation is suitable for the promotion of biodiesel particularly in countries where initiatives to stimulate the development of biofuels are at its infant stage Botswana included.
文摘Dear Editor The mosquitoes Aedes aegypli(I,) and Aedes albopictus (Skuse)(Diptera:Culicidae) are important vectors of dengue fever in tropical and subtropical parts of the world. Chemical control has been considered as an effective tool for their management in different areas of the world.However, injudicious use of the chemicals result in environmental pollution,ill effects to humans and other animals,and the development of insecticide resistance,which ultimately limits the efficacy of many insecticides!’].Essential oils can be used for mosquito control with no harmful effects to the ecosystem and non-target organisms.Essentials oils from different plants have been found very
基金supported by the Special Fund for Agro-scientific Research in the Public Interest,China(201503105 and 201503125)the National High-Tech R&D Program of China(863 Program,2011AA100504)
文摘Ridge-furrow rainwater harvesting (RFRH) planting pattern can lessen the effect of water deficits throughout all crop growth stages, but water shortage would remain unavoidable during some stages of crop growth in arid and semiarid areas. Supplemental irrigation would still be needed to achieve a higher production. Field experiments were conducted for two growing seasons (2012-2013 and 2013-2014)to determine an appropriate amount of supplemental irrigation to be applied to winter oilseed rape at the stem-elongation stage with RFRH planting pattern. Four treatments, including supplemental irrigation amount of 0 (I1), 60 mm (I2) and 120 mm (I3) with RFRH planting pattern and a control (CK) irrigated with 120 mm with flat planting pattern, were set up to evaluate the effects of supplemental irrigation on aboveground dry matter (ADM), nitrogen nutrition index (NNI), radiation use efficiency (RUE), water use efficiency (WUE), and seed yield and oil content of the oilseed rape. Results showed that supplemental irrigation improved NNI, RUE, seed yield and oil content, and WUE. However, the NNI, RUE, seed yield and oil content, and WUE did not increase significantly or even showed a downward trend with excessive irrigation. Seed yield was the highest in 13 for both growing seasons. Seed yield and WUE in 13 averaged 3235 kg ha^-1 and 8.85 kg ha^-1 mm-1, respectively. The highest WUE was occurred in 12 for both growing seasons. Seed yield and WUE in 12 averaged 3089 kg ha^-1 and 9.63 kg ha^-1 mm^-1, respectively. Compared to 13, 12 used 60 mm less irrigation amount, had an 8.9% higher WUE, but only 4.5 and 0.4% lower seed yield and oil content, respectively. 12 saved water without substantially sacrificing yield or oil content, so it is recommended as an appropriate cultivation and irrigation schedule for winter oilseed rape at the stem-elongation stage.
文摘Two field experiments were carried out during growing seasons 2010 and 2011, it executed in research farm of national research center in Nubaryia region, Egypt to study the effect of pulse drip irrigation and mulching systems for saving water, increasing and improving yield of soybean. The study factors were, pulse drip irrigation technology (adding of daily water requirements on 4 times, 8 times, 12 times compared with adding of daily water requirements on 1 time) and mulching systems (covering the soil with black plastic mulch “BPM”, rice straw mulch “RSM” and the control treatment was soil surface without mulch “WM”). The following parameters were studied to evaluate the effect of pulse drip irrigation and mulching systems: 1) Soil moisture distribution in root zone, 2) Growth characters of soybean plant, 3) Yield of soybean, 4) Irrigation water use efficiency of soybean “IWUE soybean”, and 5) Oil content and oil yield, 6) Protein content and protein yield, 7) Economical parameter. According to the economical view and the results of statistical analysis for effect of pulse drip irrigation and mulching systems on yield, quality traits and IWUE soybean indicated that, applying the irrigation requirements on 8 pulses/day with using BPM is the best conditions because under these conditions was occurred the highest value of yield, quality traits and IWUE soybean and there was significant deference between this case and other treatments. Where, pulse irrigation technique increase from water movement in horizontal direction than vertical direction hence improve from soil moisture distribution and wetted soil volume in root zone and using BPM decrease from evaporation process rate from soil surface hence decreasing of salts accumulation in addition to decreasing of weed growth in the root zone. All traits at AIR on 12 pulses/ day are decreased by increasing of pulses, this may be due to irrigation water was very small with every pulse at AIR on 12 pulses/day in addition increasing the total time of time-off, this mean, un-sufficient application for irrigation water to remove water stress in the root zone.
文摘This paper takes the analysis of economical land use in the design of oil field stations as the research object.Firstly,it elaborates the significance of saving land.Then combined with the"Fire Prevention Code of Petrol Chemical Enterprise Design",the paper analyzes and studies the safety and economical use of the general drawing design of the oil field stations for reference.
文摘In recent decades, the demand for cold-rolled steel sheets has remarkably increased. To prevent the sheets from rusting before the manufacturing process, a layer of rust-preventive oil has to be coated on the sheets. In this study, the shipment and storage environments were simulated through a salt spray test and a damp-heat experiment, respectively, and the packaging status of the sheets was imitated by a laminated sheet test. The protection effect of oil on the steel sheet was investigated under the different environmental conditions and oil weights by using electrochemical approaches, scanning electron microscopy ( SEM), and X-ray diffraction (XRD) techniques. It was found that chloride ions had more severe effects on the corrosion resistance of the oils than hydrothermal conditions did. This was shown in the sheets with oil weights of 0.4,0.9 ,and 1.2 g · m^-2 ,which were too severely corroded after a four-hour salt spraying test to meet the demands of subsequent processing. However, the sheets showed satisfactory corrosion resistance after a three-week damp-heat experiment with a temperature of 49 ℃ and 95 % RH. In addition, it was disclosed that the penetration of the chloride ions determined the protection mechanism of the oil, i. e.,the corrosion resistance was initially enhanced by the increase in the oil content. As long as the chloride ion reached the interface between the oil film and the sheet, the oil distribution became the predominant factor in the protection of the sheet. The corrosion mechanism of the steel sheet was dependent on the stacking style of the sample. When exposed to air, the corrosion product of the sample was rust red with a composition of Fe2O3, whereas the black product that is mainly composed of Fe3O4 was found on the edge of the laminated sheets, which resulted from the oxygen concentration cell.
文摘The reforms in oil and gas sector have been accelerated in 2015. The reform of mineral rights has begun and 6 oil and gas exploration zones in Xinjiang Autonomous Region have served as the tender pilots, breaking through the requirements on the resources varieties, exploration phase and enterprise qual!fication. The right of importing and using of the crude oil has been gradually relaxed and 13 local refineries have obtained the right to use imported crude oil of 55.1888 million tons per year. The natural gas price for non-residential use was unified and a universal price was set ~r the incremental supply and existing supply. Tire Shanghai Petroleum and Gas Exchange (SHPGX) was established and laid foundation for the market mechanism to detervnine the price. The government governance has undergone continuous adjustments such as regulating the tax instead of charging the fees, streamlining administration and delegating power to tire lower levels.The Guidelines on Deepening tire Reform of State-owned Enterprises was released, symbolizing the accomplishment of the overall planning ~ the SOE reform.
文摘To examine the REDD+ (Reducing Emissions from Deforestation and Forest Degradation) program as an alternative to an oil palm plantation in West Kutai district of East Kalimantan, we determined the profitability of land use and REDD+, and the land use preferences and practices of the local people, as well as their participation in and preferences for forestry programs. Our findings indicate the following: 1) the profitability of an oil palm plantation was higher than that from other land uses and the REDD+ program;2) the local preferences for land uses were mostly consistent with the profitability of the land uses, except for oil palm plantation due to non-financial concerns;3) the local people combined each land use in accordance with their various needs;and 4) the local people were interested in a Forest and Land Rehabilitation (RHL) program in nonforestry zones. Considering these evidences, an improved RHL program based on an intensive agroforestry system and a conservation-based REDD+ program based on existing customary conservation forest management by the local people are proposed. Given the high opportunity cost and the low preference for an oil palm plantation, designing the REDD+ program by paying attention to the non-financial benefits for a community is a way forward. To enhance the non-financial benefits, it is important to take into consideration local preferences and livelihood activities in designing the REDD+ program. This study also implies the need for a reconsideration of the position of participation of local people in the safeguards of REDD+.
文摘The manufacturing industry today due to worldwide competition is focused on shorter development cycle. In this situation, computer aided education (CAE) technology as a tool for simultaneous achievement of quality, cost and delivery (QCD) plays an important role. The hardware-software environment surrounding CAE has evolved. Though technological problems have been understood and general solutions have been derived and reflected in the CAE analysis software, research findings that boost the credibility of CAE have still not been incorporated fully enough into the development of design process. The real technical mechanism issue is not precisely capture. Therefore, it is important to clarify the real cause in CAE results through CAE simulation in order to assure product reliability and assurance. It is the aim of this study to realize the prediction of design analysis process through understanding of unclear technical mechanism in abnormal occurrences with the utilization of CAE simulation. In other words, it is the aim of this study to focus on issue in automotive transaxle oil seal leakage to understand, grasp, and visualize the main cause through usage of CAE analysis process. It is understood that the point of contact and pump volume was related and this could contribute towards seals quality design. Plus, the utilization of CAE analysis in prediction phase to realized design development is also possible
文摘Aim: A simulation experiment was carried out in which oyster mushrooms (Pleurotus?pulmonarius) was grown on used engine oil. This study was designed to evaluate the remnant hydrocarbon in the sporophore (fruiting body) of?Pleurotuspulmonarius?and to assess its suitability for human consumption. Method: The mycelia of the mushroom were used to inoculate Spent Engine Oil (SEO, 10% (v/w)) polluted soil. After four weeks of incubation, fruiting bodies growing on the polluted soil were analyzed for remnant hydrocarbon profile. Results: Results showed that total Polycyclic Aromatic Hydrocarbon (PAH) was 10 mg/kg and Aliphatic Hydrocarbon (AH) was 23 mg/kg. The hydrocarbon profile indicated some AH and PAH were within the non-cancer reference dose while a few others were above the non-cancer daily reference dose range. Conclusion: The detection of some hydrocarbon profile above the non-cancer daily reference dose makes the test-mushroom used for bioremediation not safe for human consumption. This underscores the need for caution in consuming mushrooms found in oil polluted environment.
文摘Ⅰ The Indexes of Detecting Oil and Gas Resources The deeply buried reservoir which in a dynamic equilibrium state has a great pressure inside, and between it and earth surface there is a great difference of pressure. Therefore the hydrocarbon must spread and move vertically to the surface along the pressure gradient orientation. Hydrocarbons in the reservoir along some small rifts, cracks, joints and cleavages penetrate the overlying strata and seepage onto the surface. Thus the hydrocarbons become unvisble oil and gas signs. This process is called the phenomena of hydrocarbon microseepage of reservoir. Hydrocarbons microseepage in the process
文摘This paper discusses the use of GIS in oilfield power system,combined with the basic concept and advantages of GIS,combined with the characteristics of the oilfield power system,put forward the overall design system of the oilfield power system,ensure the stability of the power system operation,give full play to the role of GIS.
基金thank IBAMA-Brazilian Institute for the Environment,for the license for collection of bio-logical material and the União de Ensino do Sudoeste do Paraná,for financing this project.
文摘The aim of this study was to investigate the effects of Baccharis coridifolia essential oil on the Activity of Antibiotics. Assays were performed with ampicillin (10 μg), cephalothin (30 μg), chloramphenicol (30 μg), gentamicin (10 μg) and tetracycline (30 μg) alone and in combination with the essential oil (4% v/v) through the disk diffusion susceptibility test. The results showed the effects of essential oil on the activity of the antibiotics tested. Zones of inhibition of bacterial growth with different diameters were observed surrounding the antibiotic disks, whether or not they were impregnated with the essential oil. The occurrence of the synergistic or antagonistic effect was observed in both bacterial strains assessed—Staphylococcus aureus (ATCC-25923) and Escherichia coli (ATCC-25922). These results show that the use of products derived from plants can, in some cases, interfere with the effectiveness of antibiotics during clinical therapy.