It is worthy of studying the effect of water content in crude oil on tribological behavior of stator rubber,because the different water content would affect the swelling and wear of rubber.Compatibility of dewatered c...It is worthy of studying the effect of water content in crude oil on tribological behavior of stator rubber,because the different water content would affect the swelling and wear of rubber.Compatibility of dewatered crude oil and water was observed after mixture of dewatered crude oil and water(called oil-water mixture)was mechanical stirred and statically placed.Static etching experiment of samples in oil-water mixture was performed using hanging patch test.Wetting contact angle of oilwater mixture on rubber surface was measured by contact angle meter.Tribological behavior of samples in mixture was measured using a ring-on-block tester.The result shows that when the water content is less than 15%,water can blend with dewatered crude oil,and oil-water separation happens when water content was more than 15%.With the increasing of water content in crude oil,Wettability of mixture and swelling increment of samples decrease.The wear loss of sample increases after treated by swelling experiment,and FKM owns better wear resistance than NBR.展开更多
探讨油脂在亚临界水中水解反应的影响因素和反应动力学。以橡胶籽油为原料,在间歇式高温高压反应釜中进行水解反应,试验结果表明,在水与橡胶籽油体积比为3∶1(摩尔比为162∶1),反应温度280℃,压力15 MPa,反应时间40 m in时,橡胶籽油水...探讨油脂在亚临界水中水解反应的影响因素和反应动力学。以橡胶籽油为原料,在间歇式高温高压反应釜中进行水解反应,试验结果表明,在水与橡胶籽油体积比为3∶1(摩尔比为162∶1),反应温度280℃,压力15 MPa,反应时间40 m in时,橡胶籽油水解为脂肪酸的转化率可达96.2%;动力学计算表明,橡胶籽油在亚临界水中水解反应级数为1.4,反应活化能为43.5 kJ/mol。该研究为超临界二步法制备生物柴油的水解反应的动力学提供了理论基础。展开更多
基金supported by the National Natural Science Foundation of China (50878178)Liaoning Provincial Natural Science Foundation of China (2013020039)
文摘It is worthy of studying the effect of water content in crude oil on tribological behavior of stator rubber,because the different water content would affect the swelling and wear of rubber.Compatibility of dewatered crude oil and water was observed after mixture of dewatered crude oil and water(called oil-water mixture)was mechanical stirred and statically placed.Static etching experiment of samples in oil-water mixture was performed using hanging patch test.Wetting contact angle of oilwater mixture on rubber surface was measured by contact angle meter.Tribological behavior of samples in mixture was measured using a ring-on-block tester.The result shows that when the water content is less than 15%,water can blend with dewatered crude oil,and oil-water separation happens when water content was more than 15%.With the increasing of water content in crude oil,Wettability of mixture and swelling increment of samples decrease.The wear loss of sample increases after treated by swelling experiment,and FKM owns better wear resistance than NBR.
文摘探讨油脂在亚临界水中水解反应的影响因素和反应动力学。以橡胶籽油为原料,在间歇式高温高压反应釜中进行水解反应,试验结果表明,在水与橡胶籽油体积比为3∶1(摩尔比为162∶1),反应温度280℃,压力15 MPa,反应时间40 m in时,橡胶籽油水解为脂肪酸的转化率可达96.2%;动力学计算表明,橡胶籽油在亚临界水中水解反应级数为1.4,反应活化能为43.5 kJ/mol。该研究为超临界二步法制备生物柴油的水解反应的动力学提供了理论基础。
