Gas-hydrate formation,agglomeration and inhibition in oil-based drilling fluids for deep-water drilling

One of the main challenges in deep-water drilling is gas-hydrate plugs,which make the drilling unsafe.Some oil-based drilling fluids（OBDF） that would be used for deep-water drilling in the South China Sea were tested to investigate the characteristics of gas-hydrate formation,agglomeration and inhibition by an experimental system under the temperature of 4 ？C and pressure of 20 MPa,which would be similar to the case of 2000 m water depth.The results validate the hydrate shell formation model and show that the water cut can greatly influence hydrate formation and agglomeration behaviors in the OBDF.The oleophobic effect enhanced by hydrate shell formation which weakens or destroys the interfacial films effect and the hydrophilic effect are the dominant agglomeration mechanism of hydrate particles.The formation of gas hydrates in OBDF is easier and quicker than in water-based drilling fluids in deep-water conditions of low temperature and high pressure because the former is a W/O dispersive emulsion which means much more gas-water interfaces and nucleation sites than the later.Higher ethylene glycol concentrations can inhibit the formation of gas hydrates and to some extent also act as an anti-agglomerant to inhibit hydrates agglomeration in the OBDF.

Biological Stability of Water-Based Cutting Fluids:Progress and Application

The application of cutting fluid in the field of engineering manufacturing has a history of hundreds of years,and it plays a vital role in the processing efficiency and surface quality of parts.Among them,water-based cutting fluid accounts for more than 90%of the consumption of cutting fluid.However,long-term recycling of water-based cutting fluid could easily cause deterioration,and the breeding of bacteria could cause the cutting fluid to fail,increase manufacturing costs,and even endanger the health of workers.Traditional bactericides could improve the biological stability of cutting fluids,but they are toxic to the environment and do not conform to the development trend of low-carbon manufacturing.Low-carbon manufacturing is inevitable and the direction of sustainable manufacturing.The use of nanomaterials,transition metal complexes,and physical sterilization methods on the bacterial cell membrane and genetic material could effectively solve this problem.In this article,the mechanism of action of additives and microbial metabolites was first analyzed.Then,the denaturation mechanism of traditional bactericides on the target protein and the effect of sterilization efficiency were summarized.Further,the mechanism of nanomaterials disrupting cell membrane potential was discussed.The effects of lipophilicity and the atomic number of transition metal complexes on cell membrane penetration were also summarized,and the effects of ultraviolet rays and ozone on the destruction of bacterial genetic material were reviewed.In other words,the bactericidal performance,hazard,degradability,and economics of various sterilization methods were comprehensively evaluated,and the potential development direction of improving the biological stability of cutting fluid was proposed.

Rheological properties of oil-based drilling fluids at high temperature and high pressure

The rheological properties of two kinds of oil-based drilling fluids with typically composition were studied at pressures up to 138 MPa and temperatures up to 204 ℃ using the RheoChan 7400 Rheometer.The experimental results show that the apparent viscosity,plastic viscosity and yield point decrease with the increase of temperature,and increase with the increase of pressure.The effect of pressure on the apparent viscosity,plastic viscosity and yield point is considerable at ambient temperature.However,this effect gradually reduces with the increase of temperature.The major factor influencing the rheological properties of oil-based drilling fluids is temperature instead of pressure in the deep sections of oil wells.On the basis of numerous experiments,the model for predict the apparent viscosity,plastic viscosity and yield point of oil-based drilling fluids at high temperature and pressure was established using the method of regressive analysis.It is confirmed that the calculated data are in good agreement with the measured data,and the correlation coefficients are more than 0.98.The model is convenient for use and suitable for the application in drilling operations.

A novel predictive model of drag coefficient and settling velocity of drill cuttings in non-Newtonian drilling fluids

In oil and gas well drilling operations,it is of great significance to accurately predict the drag coefficient and settling velocity of drill cuttings in non-Newtonian drilling fluids.In this paper,the free-falling of 172 groups of spheres and 522 groups of irregular-shaped sand particles in Newtonian/non-Newtonian fluids were investigated experimentally.It was found that the drag coefficient calculated based on Newtonian correlations can result in a significant error when the particle settles in the non-Newtonian fluid.Therefore,predictive models of drag coefficient were established respectively for different types of fluids.The validity of the proposed drag coefficient model of spheres was verified by comparing it with the previous works.On this basis,the drag coefficient model of irregular-shaped sand particles was established by introducing a shape factor.The models do not use the shape factor that requires detailed threedimensional shape and size information.Instead,two-dimensional geometric information(circularity)is obtained via image analysis techniques.The present new models predict the settling velocity of sand particles in the power-law fluid and Herschel-Bulkley fluid accurately with a mean relative error of5.03%and 6.74%,respectively,which verifies the accuracy of the model.

Determining the Effect of Cutting Fluids on Surface Roughness in Turning AISI 1330 Alloy Steel Using Taguchi Method

Taguchi method has been employed to investigate the effects of cutting fluids on surface roughness in turning AISI 1330 alloy steel, using manually operated lathe machine. Experiments have been conducted using L27 (34) orthogonal array and each experiment was repeated three times and each test used a new cutting tool, High Speed Steel (HSS), to ensure accurate readings of the surface roughness. The statistical methods of Signal-to-Noise (S/N) ratio and the Analysis of Variance (ANOVA) were applied to investigate effects of cutting speed, feed rate and depth of cut on surface roughness under different cutting fluids. Minitab 14 software was used to analyze the effect of variables on the surface roughness. Results obtained indicated that optimal variables for the minimum surface roughness were cutting speed of 35 m/min (level 2), feed of 0.124 mm/rev (level 1), depth of cut of 0.3 mm (level 1) and a cutting fluid with a viscosity of 2.898 mm2/s (level 3). Hence, the optimal parameters to obtain better surface roughness of the workpiece material were obtained when groundnut oil based cutting fluid was used. Analysis of variance shows that feed rate has the most significant effect on surface roughness.

Comparison and application of different empirical correlations for estimating the hydrate safety margin of oil-based drilling fluids containing ethylene glycol

As the oil and gas industries continue to increase their activity in deep water, gas hydrate hazards will become more serious and challenging, both at present and in the future. Accurate predictions of the hydrate-free zone and the suitable addition of salts and/or alcohols in preparing drilling fluids are particularly important both in preventing hydrate problems and decreasing the cost of drilling operations. In this paper, we compared several empirical correlations commonly used to estimate the hydrate inhibition effect of aqueous organic and electrolyte solutions using experiments with ethylene glycol （EG） as a hydrate inhibitor. The results show that the Najibi et al. correlation （for single and mixed thermodynamic inhibitors） and the Ostergaard et al. empirical correlation （for single thermodynamic inhibitors） are suitable for estimating the hydrate safety margin of oil-based drilling fluids （OBDFs） in the presence of thermodynamic hydrate inhibitors. According to the two correlations, the OBDF, composed of 1.6 L vaporizing oil, 2% emulsifying agent, 1% organobentonite, 0.5% SP-1, 1% LP-1, 10% water and 40% EG, can be safely used at a water depth of up to 1900 m. However, for more accurate predictions for drilling fluids, the effects of the solid phase, especially bentonite, on hydrate inhibition need to be considered and included in the application of these two empirical correlations.

Simulation Research on Coal-Water Slurry Gasification of Oil-Based Drill Cuttings Based on Fluent

In this paper,based on Fluent software,a five-nozzle gasifier reactor was established to simulate the gasification process of oil-based drill cuttings coal-water slurry.The influence of concentration and oxygen/carbon atomic ratio on the gasification process of oil-based drill cuttings coal-water slurry was investigated.The results show that when the oxygen flow is constant,the outlet temperature of gasifier decreases,the content of effective gas increases,and the carbon conversion rate decreases with the increase of concentration;When the ratio of oxygen to carbon atoms is constant,the effective gas content rises and the temperature rises with the increase of the concentration,and the carbon conversion rate reaches the maximum value when the concentration of oil-based drill cuttings coal-water slurry is 65%;When the concentration is constant,the effective gas content decreases and the outlet temperature rises with the increase of the oxygen/carbon atom ratio,and the carbon conversion rate reaches 99.80%when the oxygen/carbon atom ratio is 1.03.It shows that this method can effectively decompose the organic matter in oilbased drill cuttings and realize the efficient and cooperative treatment of oil-based drill cuttings.

Vegetable and Mineral Used Oils as Cutting Fluids: Effect on Surface Roughness of Aluminum Alloy

The use of cutting fluids in mechanical machining operation is important to make cutting easy, produce low surface roughness, increase the rate of productivity, and alleviate the negative effect on work environment and operators. In this project the effect of using different cutting fluids on the surface roughness of aluminum alloy (T6-6061) was studied. The experiment involved the use of constant cutting parameters (cutting speed of 860 rpm, depth of cut at 1.5 mm, and feed rate of 0.12 mm/rev). Three local cutting fluids: mineral used oil, kerosene, and natural used oil (refined sunflower oil) mixed with water at different ratios (5%, 10%, 15%, 20%, and 25%) were used to study their effect on the surface roughness compared to a common lubricate oil used in the cooling process. Results revealed that mineral used oil gave the lowest (best) roughness coefficient at 5% water ratio followed by lubricate oil. Kerosene and natural oil had the highest roughness coefficients. Mineral oil could be recommended for use with local cutting machines reducing the huge amounts of waste oil produced in the country.

Investigation of Nanofluids as Potential Cutting Fluids in Gear Hobbing Processes of AISI 4118 Steel

The present work focuses on the performance of nanofluids called CN46-NanoAl2O3.80 formulated by using dispersions of nano aluminum oxide （Al2O3） in the ISO VG46 industrial oil on machining performance during gear hobbing of AISI 4118 steel. In machining gears, hobbing is one of the most important processes, especially to produce various gear shapes for adapting to diverse applications. However, the demand for high quality brings attention to product quality, particularly the roughness of the machined gear surface because of its effect on product appearance, function, and reliability. For additional improvement, applying nanofluids may produce superior product quality, as the rolling action of billions of nanoparticle units in the tool chip interface can significantly decrease the friction led to reduce the cutting forces. In addition, the characteristics of heat transfer of nanoparticles can contribute to reduce tool wear. In this experimental study, the performance of nanolubricant compared with the case of using ordinary cutting-fluid systems in the existing production line is investigated. The experimental results reveal that the tool life of the hob is significantly enhanced of 55.2%, gear surface roughness is smaller （27.3%）, and gear accuracy is significantly increased by using the nanofluid. This result, therefore, shows a promising solution to achieve the engineering-economy effectiveness in gear machining.

A Decision-Making Framework Model of Cutting Fluid Selection for Green Manufacturing and the Case Study

Pursuing the green manufacturing (GM) of products i s very beneficial in the alleviation of environment burdens. In order to reap such benefits, green manufacturing is involved in every aspect of manufacturing proc esses. During the machining process, cutting fluid is one of the main roots of e nvironmental pollution. And how to make an optimal selection for cutting fluid f or GM is an important path to reduce the environmental pollution. The objective factors of decision-making problems in the traditional selection of cutting flu id are usually two: quality and cost. But from the viewpoint of GM, environmenta l impact (E) should be considered together. In this paper, a multi-object d ecision-making model of cutting fluid selection for GM is put forward, in which the objects of Quality (Q), Cost(C) and Environmental impact (E) are considered together. In this model, E means to minimize the environmental impact, Q means to maximize the quality and C means to minimize the cost. Each objective is anal yzed in detail too. A case study on a decision-making problem of cutting fluid selection in a gear hobbing process is analyzed, and the result shows the model is practical.

Squeeze-Strengthening Effect of Silicone Oil-based Magnetorheological Fluid

In order to study the squeeze-strengthening effect of silicone oil-based magnetorheological fluid （MRF）, theoretical basis of disc squeezing brake was presented and a squeezing braking characteristics test-bed for MRF was designed. Moreover, relevant experiments were carded out and the relationship between squeezing pressure and braking torque was proposed. Experiments results showed that the yield stress of MRF improved linearly with the increasing of external squeezing pressure and the braking torque increased three times when external squeezing pressure achieved 2 MPa.

Optimization of Surface Milling of Hardened AISI4340 Steel with Minimal Fluid Application Using a High Velocity Narrow Pulsing Jet of Cutting Fluid

Surface milling of hardened steel is carried out with copious supply of cutting fluid and is obviously associated with problems related to procurement and storage of cutting fluid. The disposal of cutting fluid has to comply with environmental legislation such as OSHA regulations. The present investigation proposes an environment friendly minimal pulsed jet cutting fluid application scheme for surface milling of AISI4340 steel with a hardness of 45 HRC using commercially available carbide tools. This scheme can be implemented as such on the shop floor with out the need for any major alternations on the existing facilities and it was observed that the new scheme is not only environment friendly but also provided better cutting performance when compared to conventional wet milling which requires copious supply of cutting fluid.

Development of a High Temperature and High Pressure Oil-Based Drilling Fluid Emulsion Stability Tester

When drilling deep wells and ultra-deep wells, the downhole high temperature and high pressure environment will affect the emulsion stability of oil-based drilling fluids. Moreover, neither the demulsification voltage method nor the centrifugal method currently used to evaluate the stability of oil-based drilling fluids can reflect the emulsification stability of drilling fluids under high temperature and high pressure on site. Therefore, a high-temperature and high-pressure oil-based drilling fluid emulsion stability evaluation instrument is studied, which is mainly composed of a high-temperature autoclave body, a test electrode, a temperature control system, a pressure control system, and a test system. The stability test results of the instrument show that the instrument can achieve stable testing and the test data has high reliability. This instrument is used to analyze the factors affecting the emulsion stability of oil-based drilling fluids. The experimental results show that under the same conditions, the higher the stirring speed, the better the emulsion stability of the drilling fluid;the longer the stirring time, the better the emulsion stability of the drilling fluid;the greater the oil-water ratio, the better the emulsion stability of the drilling fluid. And the test results of the emulsification stability of oil-based drilling fluids at high temperature and high pressure show that under the same pressure, as the temperature rises, the emulsion stability of oil-based drilling fluids is significantly reduced;at the same temperature, the With the increase in pressure, the emulsion stability of oil-based drilling fluids is in a downward trend, but the decline is not large. Relatively speaking, the influence of temperature on the emulsion stability of oil-based drilling fluids is greater than that of pressure.

Vegetable Oil-Based Nanolubricants in Machining:From Physicochemical Properties to Application

Cutting fluid is crucial in ensuring surface quality and machining accuracy during machining.However,traditional mineral oil-based cutting fluids no longer meet modern machining’s health and environmental protection require-ments.As a renewable,pollution-free alternative with excellent processing characteristics,vegetable oil has become an inevitable replacement.However,vegetable oil lacks oxidation stability,extreme pressure,and antiwear proper-ties,which are essential for machining requirements.The physicochemical characteristics of vegetable oils and the improved methods’application mechanism are not fully understood.This study aims to investigate the effects of viscosity,surface tension,and molecular structure of vegetable oil on cooling and lubricating properties.The mechanisms of autoxidation and high-temperature oxidation based on the molecular structure of vegetable oil are also discussed.The study further investigates the application mechanism and performance of chemical modification and antioxidant additives.The study shows that the propionic ester of methyl hydroxy-oleate obtained by epoxidation has an initial oxidation temperature of 175℃.The application mechanism and extreme pressure performance of conventional extreme pressure additives and nanoparticle additives were also investigated to solve the problem of insufficient oxidation resistance and extreme pressure performance of nanobiological lubricants.Finally,the study discusses the future prospects of vegetable oil for chemical modification and nanoparticle addition.The study provides theoretical guidance and technical support for the industrial application and scientific research of vegetable oil in the field of lubrication and cooling.It is expected to promote sustainable development in the manufacturing industry.

Experimental Study Optimizing Hole Cleaning-Cuttings Transport in Oil Drilling Engineering

With a clear understanding of the drilling fluid techniques and the cutting taking mechanism, a new advanced model is set up for analyzing field data and quantitative forecast of cutting taking mechanism. Therefore, a number of values affecting the drilling rate and the hole cleaning are studied over a wide range of parameters. Drilling data obtained under high borehole pressure conditions are analyzed to determine the causes of the reduction in rate of penetration (ROP) as the borehole pressure increases, which in some cases is caused by the buildup of rock debris under the bit. The theoretical achievement and testing conclusions can be very instructional for horizontal well drilling. Much higher annular velocities are required for effective hole cleaning in directional wells than in vertical wells. High viscosity muds are observed to provide better transport than low viscosity muds.

Scratching and Turning Experiments on Machinability of Optical Glass SF6 in Diamond Cutting Process

To improve the machinability of optical glass and achieve optical parts with satisfied surface quality and dimensional accuracy, scratching experiments with increasing cutting depth were conducted on glass SF6 to evaluate the influence of cutting fluid properties on the machinability of glass. The sodium carbonate solution of 10.5% concentration was chosen as cutting fluid. Then the critical depths in scratching experiments with and without cutting fluid were examined. Based on this, turning experiments were carried out, and the surface quality of SF6 was assessed. Compared with the process of dry cutting, the main indexes of surface roughness decrease by over 70% totally. Experimental results indicated that the machinability of glass SF6 can be improved by using the sodium carbonate solution as cutting fluid.

Development of key additives for organoclay-free oil-based drilling mud and system performance evaluation

Traditional oil-based drilling muds(OBMs) have a relatively high solid content, which is detrimental to penetration rate increase and reservoir protection. Aimed at solving this problem, an organoclay-free OBM system was studied, the synthesis methods and functioning mechanism of key additives were introduced, and performance evaluation of the system was performed. The rheology modifier was prepared by reacting a dimer fatty acid with diethanolamine, the primary emulsifier was made by oxidation and addition reaction of fatty acids, the secondary emulsifier was made by amidation of a fatty acid, and finally the fluid loss additive of water-soluble acrylic resin was synthesized by introducing acrylic acid into styrene/butyl acrylate polymerization. The rheology modifier could enhance the attraction between droplets, particles in the emulsion via intermolecular hydrogen bonding and improve the shear stress by forming a three-dimensional network structure in the emulsion. Lab experimental results show that the organoclay-free OBM could tolerate temperatures up to 220 ?C and HTHP filtration is less than 5 m L. Compared with the traditional OBMs, the organoclay-free OBM has low plastic viscosity, high shear stress, high ratio of dynamic shear force to plastic viscosity and high permeability recovery, which are beneficial to penetration rate increase, hole cleaning and reservoir protection.

Reversible adsorption of metalworking fluids (MWFs) on Cu-BTC metal organic framework

Metalworking fluids(MWFs) are classified as hazardous substances. Due to the characteristics of the stable oil–water emulsions, it requires more costly and complicate treatment techniques to remove oil from spent MWFs. Metal organic frameworks(MOFs) are a porous network material used to remove contaminants from environment. One of the most prominent of MOFs is HKUST-1 or Cu-BTC. In this study, the Cu-BTCs were prepared by solvothermal method in various conditions and used as absorbent for removing oil micelles in MWF emulsion. The particle size of all synthesized Cu-BTCs ranged from ≈80 to 400 nm. The ability of all synthesized Cu-BTCs to remove oil micelle was greater than 95% in 60 min, while the capacity of GAC was obtained the result for only 6.8%. The maximum adsorption capacity(q _(max)) of oil micelles on Cu-BTCs was 1666.7 mg·g^(-1). The highest removal capacity of oil micelles in MWF emulsion is greater than 99% in 24 h by using Cu-BTCs washed with either butanol or ethanol.

A High-Mathematical Model Optimizing Cuttings Transport in Oil Drilling Engineering

With special drilling operation equipment and specific conditions of geology, how does drilling fluid carry cuttings effectively? So far, it is still an urgent problem for drilling researchers to study. This work just aims at the actual engineering background to develop studying model. In this paper, according to non Newtonian fluid mechanics, the law of the solid liquid, two phase fluid flow and actual drilling engineering, the major factors affecting cuttings transport are drilling fluid velocity, hole inclination and fluid rheological properties. Getting a clear understanding of the law of drilling fluid and its cutting taking mechanism, this paper puts forward a model for analysis of field data and quantitative forecast of cutting taking capability of drilling fluid. The full scale annular test section was 6.1 m with 76 and 114 mm drillpipe in a 203 mm ID (wellbore diameter). Hole angle varied from 0° to 90°.

ADVANCES IN THEORETICAL RESEARCH ON ANNULAR HYDRAULICS AND CUTTINGS TRANSPORT

ＡＤＶＡＮＣＥＳＩＮＴＨＥＯＲＫＥＴＩＣＡＬＲＥＳＥＡＲＣＨＯＮＡＮＮＵＬＡＲＨＹＤＲＡＵＬＩＣＳＡＮＤＣＵＴＴＩＮＧＳＴＲＡＮＳＰＯＲＴＬｉｕＸｉｓｈｅｎｇ，ＷａｎｇＨａｉｇｅＵｎｉｖｅｒｓｉｔｙｏｆＰｅｔｒｏｌｅｕｍ，Ｂｅｉｊｉｎｇ１０００８３，...