Volatile organic compounds(VOCs)are the important precursors of the tropospheric ozone(O3)and secondary organic aerosols(SOA),both of which are known to harm human health and disrupt the earth’s climate system.In thi...Volatile organic compounds(VOCs)are the important precursors of the tropospheric ozone(O3)and secondary organic aerosols(SOA),both of which are known to harm human health and disrupt the earth’s climate system.In this study,VOC emission factors,O3 and SOA formation potentials were estimated for two types of industrial boilers:coal-fired boilers(n=3)and oil-fired boilers(n=3).Results showed that EVOCs concentrations were more than nine times higher for oil-fire d boilers compared to those for coal-fired boilers.Emission factors ofΣVOCs were found to be higher for oil-fired boilers(9.26-32.83 mg-VOC/kg)than for coal-fired boilers(1.57-4.13 mg-VOC/kg).Alkanes and aromatics were obtained as the most abundant groups in coal-fired boilers,while oxygenated organics and aromatics were the most contributing groups in oil-fired boilers.Benzene,n-hexane and o-ethyl toluene were the abundant VOC species in coal-fired boiler emissions,whereas toluene was the most abundant VOC species emitted from oil-fired boilers.O3 and SOA formation potentials were found 12 and 18 times,respectively,higher for oil-fired than for coal-fired boilers.Total OFP ranged from 3.99 to 11.39 mg-O3/kg for coal-fired boilers.For oil-fired boilers,total OFP ranged from 36.16 to 131.93 mg-O3/kg.Moreover,total secondary organic aerosol potential(SOAP)ranged from 65.4 to 122.5 mg-SOA/kg and 779.9 to 2252.5 mg-SOA/kg for the coal-fired and oil-fired boilers,respectively.展开更多
To reduce CO_(2) emissions from coal-fired power plants,the development of low-carbon or carbon-free fuel combustion technologies has become urgent.As a new zero-carbon fuel,ammonia(NH_(3))can be used to address the s...To reduce CO_(2) emissions from coal-fired power plants,the development of low-carbon or carbon-free fuel combustion technologies has become urgent.As a new zero-carbon fuel,ammonia(NH_(3))can be used to address the storage and transportation issues of hydrogen energy.Since it is not feasible to completely replace coal with ammonia in the short term,the development of ammonia-coal co-combustion technology at the current stage is a fast and feasible approach to reduce CO_(2) emissions from coal-fired power plants.This study focuses on modifying the boiler and installing two layers of eight pure-ammonia burners in a 300-MW coal-fired power plant to achieve ammonia-coal co-combustion at proportions ranging from 20%to 10%(by heat ratio)at loads of 180-to 300-MW,respectively.The results show that,during ammonia-coal co-combustion in a 300-MW coal-fired power plant,there was a more significant change in NO_(x) emissions at the furnace outlet compared with that under pure-coal combustion as the boiler oxygen levels varied.Moreover,ammonia burners located in the middle part of the main combustion zone exhibited a better high-temperature reduction performance than those located in the upper part of the main combustion zone.Under all ammonia co-combustion conditions,the NH_(3) concentration at the furnace outlet remained below 1 parts per million(ppm).Compared with that under pure-coal conditions,the thermal efficiency of the boiler slightly decreased(by 0.12%-0.38%)under different loads when ammonia co-combustion reached 15 t·h^(-1).Ammonia co-combustion in coal-fired power plants is a potentially feasible technology route for carbon reduction.展开更多
Dry deposition samples were collected in a weekly basis during 2010 in a site located at the Mexican Pacific Coast: Manzanillo, Colima. Samples were collected with an automatic wet/dry deposition sampler using nylon f...Dry deposition samples were collected in a weekly basis during 2010 in a site located at the Mexican Pacific Coast: Manzanillo, Colima. Samples were collected with an automatic wet/dry deposition sampler using nylon filters as surrogate surfaces. Samples were extracted with deionized water and analyzed for pH, conductivity, Na+, K+, Ca2+, Mg2+, NH4-, NO3-, SO42- and Cl-. Nitrate and sulfate were the most abundant ions, contributing with 53% to the total ionic mass;and their levels exceeded the hemispheric background concentrations proposed for marine remote sites. The influence of the power plants burning combustoleo located upwind the sampling site was completely evident. From meteorological analysis, it could be observed that the sampling site was all time under the influence of power plants as a result of the effect of breezes. However, in spite of the high levels of NO3- and SO42- found in the samples collected, pH value average was almost neutral, with 28% of samples slightly acid. Potassium was the most abundant cation and from the quantification of the neutralization effect of the main alkaline components, the prevalence role of K+ was completely evident, suggesting the influence of the mining complex Pe?a Colorada located upwind the sampling site, where amyl xanthate potassium is used as collector in tailing dams. Dry deposition fluxes were estimated for all ions measured. Nitrogen dry deposition at Manzanillo is already in the upper extreme of the threshold value reported for sensible ecosystems. On the other hand, sulfur deposition exceeded slightly the critical load value reported for some ecosystems in Europe. Even at this moment, nitrogen and sulfur deposition is not a problem, it is necessary to take steps to avoid that total deposition of these elements exceeds critical loads, considering that results reported in this study not include the wet deposition fluxes.展开更多
A liquid-solid circulating fluidized bed boiler is designed and built for visualization research by applying the fluidized bed heat transfer and fouling prevention technology to the water side of the boiler. Four type...A liquid-solid circulating fluidized bed boiler is designed and built for visualization research by applying the fluidized bed heat transfer and fouling prevention technology to the water side of the boiler. Four types of engineering plastic particles with different physical properties are selected as the solid working media. The effect of particle types on the fluidization and distribution of particles in the boiler is investigated under different feedwater flow rates and amount of added particles by using the charge couple device image measurement and acquisition system. The results show that all kinds of particles can't be normally fluidized and accumulate in the drum at low amount of added particles and feedwater flow rate. The particles with great density and low sphericity are more likely to accumulate. The average solid holdup in the riser tubes increases with the increase in feedwater flow rate and the amount of added particles. The non-uniform degree of particle distribution in the riser tubes generally decreases with the increase in feedwater flow rate and the amount of added particles. The particles with small density and settling velocity have high average solid holdup in the riser tubes under close sphericity. In generally,the smaller the density and settling velocity, the more uniform the particle distribution in the riser tubes.Three-dimensional diagrams of the non-uniform degree of particle distribution in the riser tubes of the boiler are established.展开更多
The purpose of this article is to receive environmental assessments of combustion of different types of coal fuel depending on the preparation(unscreened,size-graded,briquetted and heat-treated)in automated boilers an...The purpose of this article is to receive environmental assessments of combustion of different types of coal fuel depending on the preparation(unscreened,size-graded,briquetted and heat-treated)in automated boilers and boilers with manual load-ing.The assessments were made on the basis of data obtained from experimental methods of coal preparation and calculated methods of determining the amount of pollutant and greenhouse gas emissions,as well as the mass of ash and slag waste.The main pollutants from coal combustion are calculated:particulate matter,benz(a)pyrene,nitrogen oxides,sulfur dioxide,carbon monoxide.Of the greenhouse gases carbon dioxide is calculated.As a result of conducted research it is shown that the simplest preliminary preparation(size-graded)of coal significantly improves combustion efficiency and environmental performance:emissions are reduced by 13%for hard coal and up to 20%for brown coal.The introduction of automated boil-ers with heat-treated coal in small boiler facilities allows to reduce emissions and ash and slag waste by 2-3 times.The best environmental indicators correspond to heat-treated lignite,which is characterized by the absence of sulfur dioxide emissions.展开更多
A 600 MW coal-fired boiler with a four-corner tangential combustion mode is considered here to study the combustion features and pollutant emissions at different loads for large-percentages of blending dried sludges.T...A 600 MW coal-fired boiler with a four-corner tangential combustion mode is considered here to study the combustion features and pollutant emissions at different loads for large-percentages of blending dried sludges.The influence of the over-fired air(OFA)coefficient is examined and the impact of the blending ratio on the boiler operation is explored.The results show that for low blending ratios,a slight increase in the blending ratio can improve the combustion of bituminite,whereas a further increase leads to the deterioration of the combustion of blended fuels and thus reduces the boiler efficiency.Enhancing the supporting capability of the secondary air effectively reduces the slagging degree in the bottom ash hopper and improves the burnout rate of coals.For a large-percentage blending case at full load,it is found that the OFA coefficient must be reduced appropriately,otherwise,a secondary high-temperature combustion zone can be generated in the vicinity of the furnace arches,causing high temperature slagging and superheater tube bursting.Considering the influences of combustion and pollutant emissions,the recommended OFA coefficient is 0.2.Blending dried sludge under low loads increases the flue gas temperature at the furnace exit.While reducing the flue gas temperature in the main combustion region,which is beneficial to the safe operation of the denitrification system.Increasing the blending ratio and reducing load lead to an increase in NOx concentration at the furnace exit Sludges with low nitrogen content are suggested for the practical operation of boilers.展开更多
文摘Volatile organic compounds(VOCs)are the important precursors of the tropospheric ozone(O3)and secondary organic aerosols(SOA),both of which are known to harm human health and disrupt the earth’s climate system.In this study,VOC emission factors,O3 and SOA formation potentials were estimated for two types of industrial boilers:coal-fired boilers(n=3)and oil-fired boilers(n=3).Results showed that EVOCs concentrations were more than nine times higher for oil-fire d boilers compared to those for coal-fired boilers.Emission factors ofΣVOCs were found to be higher for oil-fired boilers(9.26-32.83 mg-VOC/kg)than for coal-fired boilers(1.57-4.13 mg-VOC/kg).Alkanes and aromatics were obtained as the most abundant groups in coal-fired boilers,while oxygenated organics and aromatics were the most contributing groups in oil-fired boilers.Benzene,n-hexane and o-ethyl toluene were the abundant VOC species in coal-fired boiler emissions,whereas toluene was the most abundant VOC species emitted from oil-fired boilers.O3 and SOA formation potentials were found 12 and 18 times,respectively,higher for oil-fired than for coal-fired boilers.Total OFP ranged from 3.99 to 11.39 mg-O3/kg for coal-fired boilers.For oil-fired boilers,total OFP ranged from 36.16 to 131.93 mg-O3/kg.Moreover,total secondary organic aerosol potential(SOAP)ranged from 65.4 to 122.5 mg-SOA/kg and 779.9 to 2252.5 mg-SOA/kg for the coal-fired and oil-fired boilers,respectively.
基金supported by the National Key Research and Development Program of China(2023YFB4005700,2023YFB4005705,and 2023YFB4005702-03)the Academy-Local Cooperation Project of the Chinese Academy of Engineering(2023-DFZD-01)+4 种基金the National Natural Science Foundation of China(52207151)the Natural Science Foundation of Anhui Province(2208085QA29)the University Synergy Innovation Program of Anhui Province(GXXT-2022025)the independent project of the Energy Research Institute of Hefei Comprehensive National Science Center(Anhui Energy Laboratory22KZZ525,23KZS402,22KZS301,and 22KZS304).
文摘To reduce CO_(2) emissions from coal-fired power plants,the development of low-carbon or carbon-free fuel combustion technologies has become urgent.As a new zero-carbon fuel,ammonia(NH_(3))can be used to address the storage and transportation issues of hydrogen energy.Since it is not feasible to completely replace coal with ammonia in the short term,the development of ammonia-coal co-combustion technology at the current stage is a fast and feasible approach to reduce CO_(2) emissions from coal-fired power plants.This study focuses on modifying the boiler and installing two layers of eight pure-ammonia burners in a 300-MW coal-fired power plant to achieve ammonia-coal co-combustion at proportions ranging from 20%to 10%(by heat ratio)at loads of 180-to 300-MW,respectively.The results show that,during ammonia-coal co-combustion in a 300-MW coal-fired power plant,there was a more significant change in NO_(x) emissions at the furnace outlet compared with that under pure-coal combustion as the boiler oxygen levels varied.Moreover,ammonia burners located in the middle part of the main combustion zone exhibited a better high-temperature reduction performance than those located in the upper part of the main combustion zone.Under all ammonia co-combustion conditions,the NH_(3) concentration at the furnace outlet remained below 1 parts per million(ppm).Compared with that under pure-coal conditions,the thermal efficiency of the boiler slightly decreased(by 0.12%-0.38%)under different loads when ammonia co-combustion reached 15 t·h^(-1).Ammonia co-combustion in coal-fired power plants is a potentially feasible technology route for carbon reduction.
文摘Dry deposition samples were collected in a weekly basis during 2010 in a site located at the Mexican Pacific Coast: Manzanillo, Colima. Samples were collected with an automatic wet/dry deposition sampler using nylon filters as surrogate surfaces. Samples were extracted with deionized water and analyzed for pH, conductivity, Na+, K+, Ca2+, Mg2+, NH4-, NO3-, SO42- and Cl-. Nitrate and sulfate were the most abundant ions, contributing with 53% to the total ionic mass;and their levels exceeded the hemispheric background concentrations proposed for marine remote sites. The influence of the power plants burning combustoleo located upwind the sampling site was completely evident. From meteorological analysis, it could be observed that the sampling site was all time under the influence of power plants as a result of the effect of breezes. However, in spite of the high levels of NO3- and SO42- found in the samples collected, pH value average was almost neutral, with 28% of samples slightly acid. Potassium was the most abundant cation and from the quantification of the neutralization effect of the main alkaline components, the prevalence role of K+ was completely evident, suggesting the influence of the mining complex Pe?a Colorada located upwind the sampling site, where amyl xanthate potassium is used as collector in tailing dams. Dry deposition fluxes were estimated for all ions measured. Nitrogen dry deposition at Manzanillo is already in the upper extreme of the threshold value reported for sensible ecosystems. On the other hand, sulfur deposition exceeded slightly the critical load value reported for some ecosystems in Europe. Even at this moment, nitrogen and sulfur deposition is not a problem, it is necessary to take steps to avoid that total deposition of these elements exceeds critical loads, considering that results reported in this study not include the wet deposition fluxes.
基金supported by the open foundation of State Key Laboratory of Chemical Engineering (SKL–ChE–18B03)the Municipal Science and Technology Commission of Tianjin, China (2009ZCKFGX01900)。
文摘A liquid-solid circulating fluidized bed boiler is designed and built for visualization research by applying the fluidized bed heat transfer and fouling prevention technology to the water side of the boiler. Four types of engineering plastic particles with different physical properties are selected as the solid working media. The effect of particle types on the fluidization and distribution of particles in the boiler is investigated under different feedwater flow rates and amount of added particles by using the charge couple device image measurement and acquisition system. The results show that all kinds of particles can't be normally fluidized and accumulate in the drum at low amount of added particles and feedwater flow rate. The particles with great density and low sphericity are more likely to accumulate. The average solid holdup in the riser tubes increases with the increase in feedwater flow rate and the amount of added particles. The non-uniform degree of particle distribution in the riser tubes generally decreases with the increase in feedwater flow rate and the amount of added particles. The particles with small density and settling velocity have high average solid holdup in the riser tubes under close sphericity. In generally,the smaller the density and settling velocity, the more uniform the particle distribution in the riser tubes.Three-dimensional diagrams of the non-uniform degree of particle distribution in the riser tubes of the boiler are established.
基金The research was carried out under State Assignment Projects(FWEU-2021-0004,FWEU-2021-0005)of the Fundamental Research Program of Russian Federation 2021-2030.
文摘The purpose of this article is to receive environmental assessments of combustion of different types of coal fuel depending on the preparation(unscreened,size-graded,briquetted and heat-treated)in automated boilers and boilers with manual load-ing.The assessments were made on the basis of data obtained from experimental methods of coal preparation and calculated methods of determining the amount of pollutant and greenhouse gas emissions,as well as the mass of ash and slag waste.The main pollutants from coal combustion are calculated:particulate matter,benz(a)pyrene,nitrogen oxides,sulfur dioxide,carbon monoxide.Of the greenhouse gases carbon dioxide is calculated.As a result of conducted research it is shown that the simplest preliminary preparation(size-graded)of coal significantly improves combustion efficiency and environmental performance:emissions are reduced by 13%for hard coal and up to 20%for brown coal.The introduction of automated boil-ers with heat-treated coal in small boiler facilities allows to reduce emissions and ash and slag waste by 2-3 times.The best environmental indicators correspond to heat-treated lignite,which is characterized by the absence of sulfur dioxide emissions.
文摘A 600 MW coal-fired boiler with a four-corner tangential combustion mode is considered here to study the combustion features and pollutant emissions at different loads for large-percentages of blending dried sludges.The influence of the over-fired air(OFA)coefficient is examined and the impact of the blending ratio on the boiler operation is explored.The results show that for low blending ratios,a slight increase in the blending ratio can improve the combustion of bituminite,whereas a further increase leads to the deterioration of the combustion of blended fuels and thus reduces the boiler efficiency.Enhancing the supporting capability of the secondary air effectively reduces the slagging degree in the bottom ash hopper and improves the burnout rate of coals.For a large-percentage blending case at full load,it is found that the OFA coefficient must be reduced appropriately,otherwise,a secondary high-temperature combustion zone can be generated in the vicinity of the furnace arches,causing high temperature slagging and superheater tube bursting.Considering the influences of combustion and pollutant emissions,the recommended OFA coefficient is 0.2.Blending dried sludge under low loads increases the flue gas temperature at the furnace exit.While reducing the flue gas temperature in the main combustion region,which is beneficial to the safe operation of the denitrification system.Increasing the blending ratio and reducing load lead to an increase in NOx concentration at the furnace exit Sludges with low nitrogen content are suggested for the practical operation of boilers.
