Optimized nitrogen(N)management can increase N-use efficiency in intercropping systems.Legume-nonlegume intercropping systems can reduce N input by exploiting biological N fixation by legumes.Measurement of N utilizat...Optimized nitrogen(N)management can increase N-use efficiency in intercropping systems.Legume-nonlegume intercropping systems can reduce N input by exploiting biological N fixation by legumes.Measurement of N utilization can help in dissecting the mechanisms underlying N uptake and utilization in legume-nonlegume intercropping systems.An experiment was performed with three planting patterns:monoculture maize(MM),monoculture soybean(SS),and maize-soybean relay intercropping(IMS),and three N application levels:zero N(NN),reduced N(RN),and conventional N(CN)to investigate crop N uptake and utilization characteristics.N recovery efficiency and 15N recovery rate of crops were higher under RN than under CN,and those under RN were higher under intercropping than under the corresponding monocultures.Compared with MM,IMS showed a lower soil N-dependent rate(SNDR)in 2012.However,the SNDR of MM rapidly declined from 86.8%in 2012 to 49.4%in 2014,whereas that of IMS declined slowly from 75.4%in 2012 to 69.4%in 2014.The interspecific N competition rate(NCRms)was higher under RN than under CN,and increased yearly.Soybean nodule dry weight and nitrogenase activities were respectively 34.2%and 12.5%higher under intercropping than in monoculture at the beginning seed stage.The amount(Ndfa)and ratio(%Ndfa)of soybean N2 fixation were significantly greater under IS than under SS.In conclusion,N fertilizer was more efficiently used under RN than under CN;in particular,the relay intercropping system promoted N fertilizer utilization in comparison with the corresponding monocultures.An intercropping system helps to maintain soil fertility because interspecific N competition promotes biological N fixation by soybean by reducing N input.Thus,a maize-soybean relay intercropping system with reduced N application is sustainable and environmentally friendly.展开更多
The excessive nitrogen (N) fertilizer input coupled with flood irrigation might result in higher N leaching and lower nitrogen recovery efficiency (NRE). Under an intensive rice system in the Ningxia irrigation re...The excessive nitrogen (N) fertilizer input coupled with flood irrigation might result in higher N leaching and lower nitrogen recovery efficiency (NRE). Under an intensive rice system in the Ningxia irrigation region, China, environmental friendly N management practices are hreavily needed to balance the amount of N input for optimum crop production while minimize the nitrogen loss. The objective of this study was to determine the influences of side-dressing (SD) technique in mechanical transplanting systems on the NRE, N leaching losses and rice yield in anthropogenic-alluvial soil during two rice growing seasons (2010-2011). Four fertilizer N treatments were established, including conventional urea rate (CU, 300 kg ha-1 yr-1); higher SD of controlled-release N fertilizer rate (SD1,176 kg ha-1 yr-1); lower SD of controlled-release N fertilizer rate (SD2, 125 kg ha-1 yr-1); and control (CK, no N fertilizer). Field lysimeters were used to quantify drainage from undisturbed soil during six rice growing stages. Meanwhile, the temporal variations of total nitrigen (TN), NO3--N, and NH4+-N concentrations in percolation water were examined. The results showed that SD1 substantially improved NRE and reduced N leaching losses while maintaining rice yields. Across two years, the averaged NRE under SD1 treatment increased by 25.5% as relative to CU, but yet the rice yield was similar between two treatments. On average, the nitrogen loss defined as TN, NH4+-N, and NO3--N under the SD1 treatment reduced by 27.4, 37.2 and 24.1%, respectively, when compared with CU during the study periods. Although the SD2 treatment could further reduce N leaching loss to some extent, this technique would sharply decline rice yield, with the magnitude of as high as 21.0% relative to CU treatment. Additionally, the average NRE under SD2 was 11.2% lower than that under SD1 treatment. Overall, the present study concluded that the SO technique is an effective strategy to reduce N leaching and increase NRE, thus potentially mitigate local environmental threat. We propose SD1 as a novel alternative fertilizer technique under an irrigated rice-based system in Ningxia irrigation region when higher yields are under consideration.展开更多
Field experiments were conducted in farmers’ rice fields in 2001 and 2002 to study the effects of nitrogen (N) man-agement strategies on N use efficiency in recovery (RE), agronomy (AE) and physiology (PE) and redist...Field experiments were conducted in farmers’ rice fields in 2001 and 2002 to study the effects of nitrogen (N) man-agement strategies on N use efficiency in recovery (RE), agronomy (AE) and physiology (PE) and redistribution of dry matter accumulation (DMA) and nitrogen accumulation (NA) in two typical rice cultivars in Jinhua, Zhejiang Province. This study aimed mainly at identifying the possible causes of poor fertilizer N use efficiency (NUE) of rice in Zhejiang by comparing farmers’ fertilizer practice (FFP) with advanced site-specific nutrient management (SSNM) and real-time N management (RTNM). The results showed that compared to FFP, SSNM and RTNM reduced DMA and NA before panicle initiation and increased DMA and NA at post-flowering. There is no significant difference between SSNM and FFP in post-flowering dry matter redistribution (post-DMR) and post-flowering nitrogen redistribution (post-NR). These results suggest that high input rate of fertilizer N and improper fertilizer N timing are the main factors causing low NUE of irrigated rice in the farmer’s routine practice of Zhejiang. With SSNM, about 15% of the current total N input in direct-seeding early rice and 45% in single rice could be reduced without yield loss in Zhejiang, China.展开更多
This work is focused on the theoretical investigation of internal leakage of a newly developed pi lotscale fluid switcherenergy recovery device (FSERD) for reverse osmosis (RO) system. For the purpose of in creasi...This work is focused on the theoretical investigation of internal leakage of a newly developed pi lotscale fluid switcherenergy recovery device (FSERD) for reverse osmosis (RO) system. For the purpose of in creasing FSERD efficiency and reducing the operating cost of RO, it is required to control the internal leakage in a low level. In this work, the internal leakage rates at different leakage gaps and retentate brine pressures are investigated by computational fluid dynamics (CFD) method and validating experiments. It is found that the internal leak age has a linear relationship with the retentate brine pressure and a polynomial relationship with the scale of leakage gap. The results of the present work imply that low internal leakage and high retentate brine pressure bring benefits to achieve high FSRD efficiency.展开更多
Field experiments were conducted to study the effects of the controlled release urea (CRU) application on growth yield and nitrogen recovery efficiency of cotton in the main cotton zone of the Yangtze River basin in 2...Field experiments were conducted to study the effects of the controlled release urea (CRU) application on growth yield and nitrogen recovery efficiency of cotton in the main cotton zone of the Yangtze River basin in 2010. Different nitrogen levels were set in order to determine the suitable dosage of CRU on cotton. The special purpose was to provide evidence for the CRU application in cotton fields. The results show that the application of CRU promotes the growth of cotton significantly and enhances the nitrogen supply in the whole period. Compared to the treatment with total N as base fertilizer (UB), the bod, flower, little bolls and total bolls are increased significantly. There are no significant differences in the yield between the CRU treatment and the treatment of controlled release urea and urea combined application (60%CRU + 40%U), but an increase by 12.38%-22.67% compared to the UB treatment, and an increase by 4.49%-7.23% compared to the treatments of total N split application (UD). The nitrogen uptake of CRU treatment was significantly increased by 13.01%-48.32% and 30.27%-13.01% than UB treatment and UD treatment, respectively. The nutrient recovery efficiency of CRU treatment is increased by 16.42-20.59, 5.92-11.29 and 4.22-12.59 percentage points compared to the UB treatment, UD treatment and 60%CRU + 40%U treatment, respectively. In this study, there was a good linearity relationship between the cotton yield and amount of CRU in Wuxue site. The yield of cotton response to amount of CRU could be described by the model of linear plus plateau in Jingzhou site.展开更多
The cow-calf (Bos taurus) industry in subtropical United States and other parts of the world that depends almost totally on grazed pastures is facing several production constraints like changing climatic conditions an...The cow-calf (Bos taurus) industry in subtropical United States and other parts of the world that depends almost totally on grazed pastures is facing several production constraints like changing climatic conditions and increasing cost of fertilizers, especially nitrogen (N). Particularly little is known about the response of forage species to the combined effect of water-logging and the addition of N. A two-year greenhouse study was conducted in 2008 and 2009 to determine i) the effect of flooding duration on N recovery and agronomic efficiency of bahiagrass (Paspalum notatum Fluegge) compared with two flooding tolerant forages, limpograss (Hemarthria altissima Poir), and maidencane (Panicum hematomon Schult) and ii) if N fertilization could mitigate the negative effect of flooding. Nitrogen recovery and agronomic efficiency varied significantly (P ≤ 0.001) among forage species. Averaged across levels of N, N recovery of bahiagrass and limpograss was reduced by about 41% and 56%, respectively after 84 d of continued flooding while N recovery of maidencane was slightly increase by about 5% between 0 and 84 d of flooding. Agronomic efficiencies of bahiagrass (41% to 26%) and limpograss (44% to 31%) were reduced by flooding while agronomic efficiency of maidencane was increased from 24% (no flooding) to 46% at 84 d of continued flooding. However, N recovery and agronomic efficiency of three forage species was positively affected by N fertilization. The overall N recovery of bahiagrass, limpograss, and maidencane ranged from 44% to 59%. Nitrogen fertilization could improve N recovery and agronomic efficiency of forage species under waterlogged condition.展开更多
The need to have naval units ever faster pushed the ship design to design hull shapes with increasingly higher performance thanks to the use of lightweight materials such as aluminum, and more powerful engines, etc., ...The need to have naval units ever faster pushed the ship design to design hull shapes with increasingly higher performance thanks to the use of lightweight materials such as aluminum, and more powerful engines, etc., but without substantially modifying the traditional forms of hull. The hull patented Monotricat high hydrodynamic efficiency and energy saving it represents an evolution of the traditional architectures of the hulls, as its shape is adapted to recover wave formation engendered from the bow and sprays associated with it so as to reduce the resistance to the benefit of the speed, and navigating in displacement at speeds of planing hulls with an efficiency of about 20%. The patented hull Monotricat represents the overcoming of distinction between displacement and planing hulls, because, unlike previous solutions, the hull conventionally called Monotricat is the first displacement hull that can navigate at both displacement and planning speeds, with a resistance curve almost straight, maintaining the characteristics of a displacement hull, since it combines the characteristics of displacement and planning hull. It presents an innovative architecture that could be defined as a hybrid between a monohull and catamaran, navigating on spray self-produced. The combination of these three types of naval hulls allows it to ensure: safety, comfort navigation, best seakeeping and maneuverability in restricted waters, stability, reduction of resistance to motion, cost management, regularity on the routes even in adverse weather-sea. These characteristics of the hull have been studied, tested and validated by leading research institutes and universities with more ameliorative results in each subsequent experimentation, reported in the present work, which demonstrated a greater hydrodynamic efficiency compared to conventional hulls of 20%.展开更多
The processes of flooding—water flooding, polymer flooding and ternary combination flooding—were simulated respectively on a 2-D positive rhythm profile geological model by using the ASP numerical modeling softw...The processes of flooding—water flooding, polymer flooding and ternary combination flooding—were simulated respectively on a 2-D positive rhythm profile geological model by using the ASP numerical modeling software developed by RIPED (Yuan, et al. 1995). The recovery coefficient, remaining oil saturation, sweep efficiency and displacement efficiency were calculated and correlated layer by layer. The results show that the sweep efficiency and displacement efficiency work different effects on different layers in the severely heterogeneous reservoir. The study shows that the displacement efficiency and sweep efficiency play different roles in different layers for severely heterogeneous reservoirs. The displacement efficiency contributes mainly to the high permeability zones, the sweep efficiency to the low permeability zones, both of which contribute to the middle permeable zones. To improve the sweep efficiency in the low permeability zones is of significance for enhancing the whole recovery of the reservoir. It is an important path for improving the effectiveness of chemical flooding in the severely heterogeneous reservoirs to inject ternary combination slug after profile control.展开更多
[Objective] The aim of the research was to study the effect of the ice bath time after heat shock and the incubation time on the transformation efficacy,and to establish a simple and quick transformation method.[Metho...[Objective] The aim of the research was to study the effect of the ice bath time after heat shock and the incubation time on the transformation efficacy,and to establish a simple and quick transformation method.[Method]Competent cells were prepared with two buffer solutions;with the ice bath time after heat shock and the recovery time as the variables,the relationship between these two factors and transformation efficacy was studied.[Result]The transformation efficacy was the best when the ice bath time was 2 min and the recovery time was 30 or 40 min;when the ice bath time and the recovery time was 0 min,a certain amount of transformants still could be obtained.[Conclusion]The ice bath time after heat shock and the recovery time had certain impact on transformation efficacy,but they were not the decisive factors.Therefore,in the general transformation experiment,these two steps could be omitted.展开更多
Agronomically optimizing the timing and rates of nitrogen(N) fertilizer application can increase crop yield and decrease N loss to the environment. Wheat(Triticum aestivum L.)–peanut(Arachis hypogaea L.) relay interc...Agronomically optimizing the timing and rates of nitrogen(N) fertilizer application can increase crop yield and decrease N loss to the environment. Wheat(Triticum aestivum L.)–peanut(Arachis hypogaea L.) relay intercropping systems are a mainstay of economic and food security in China. We performed a field experiment to investigate the effects of N fertilizer on N recovery efficiency, crop yield, and N loss rate in wheat–peanut relay intercropping systems in the Huang-Huai-Hai Plain, China during 2015–2017. The N was applied on the day before sowing, the jointing stage(G30) or the booting stage(G40) of winter wheat, and the anthesis stage(R1) of peanut in the following percentage splits: 50-50-0-0(N1), 35-35-0-30(N2), and 35-0-35-30(N3), using 300 kg N ha-1, with 0 kg N ha-1(N0) as control. ^(15)N-labeled(20.14 atom %) urea was used to trace the fate of N in microplots. The yields of wheat and peanut increased by 12.4% and 15.4% under the N2 and N3 treatments, relative to those under the N1 treatment. The ^(15)N recovery efficiencies( ^(15)NRE) were 64.9% and 58.1% for treatments N2 and N3, significantly greater than that for the N1 treatment(45.3%). The potential N loss rates for the treatments N2 and N3 were23.7% and 7.0%, significantly lower than that for treatment N1(30.1%). Withholding N supply until the booting stage(N3) did not reduce the wheat grain yield; however, it increased the N content derived from ^(15)N-labeled urea in peanuts, promoted the distribution of ^(15)N to pods, and ultimately increased pod yields in comparison with those obtained by topdressing N at jointing stage(N2). In comparison with N2, the N uptake and N recovery efficiency(NRE) of N3 was increased by 12.0% and 24.1%,respectively, while the apparent N loss decreased by 16.7%. In conclusion, applying N fertilizer with three splits and delaying topdressing fertilization until G40 of winter wheat increased total grain yields and NRE and reduced N loss. This practice could be an environment-friendly N management strategy for wheat–peanut relay intercropping systems in China.展开更多
One of the basic ways to reduce polluting emissions of ship power plants is application of innovative devices for on-board energy generation by means of secondary energy resources.The combined gas turbine and diesel e...One of the basic ways to reduce polluting emissions of ship power plants is application of innovative devices for on-board energy generation by means of secondary energy resources.The combined gas turbine and diesel engine plant with thermochemical recuperation of the heat of secondary energy resources has been considered.It is suggested to conduct the study with the help of mathematical modeling methods.The model takes into account basic physical correlations,material and thermal balances,phase equilibrium,and heat and mass transfer processes.The paper provides the results of mathematical modeling of the processes in a gas turbine and diesel engine power plant with thermochemical recuperation of the gas turbine exhaust gas heat by converting a hydrocarbon fuel.In such a plant,it is possible to reduce the specific fuel consumption of the diesel engine by 20%.The waste heat potential in a gas turbine can provide efficient hydrocarbon fuel conversion at the ratio of powers of the diesel and gas turbine engines being up to 6.When the diesel engine and gas turbine operate simultaneously with the use of the LNG vapor conversion products,the efficiency coefficient of the plant increases by 4%–5%.展开更多
We conducted two field experiments to investigate combined effects of organic and inorganic fertilizers on nitrogen use and recovery efficiencies of hybrid rice (Palethwe-1) during dry and wet seasons, 2015. Four leve...We conducted two field experiments to investigate combined effects of organic and inorganic fertilizers on nitrogen use and recovery efficiencies of hybrid rice (Palethwe-1) during dry and wet seasons, 2015. Four levels of inorganic fertilizer (0%, 50%, 75%, and 100% NPK), based on recommended rates of 150 kg N ha-1, 70 kg P2O5 ha-1, and 120 kg K2O ha-1, were used with cow manure, poultry manure, and vermicompost (5 t·ha-1each) in a split-plot design with three replicates. In both seasons, with 50% NPK, the N uptake level achieved with poultry manure was similar to that obtained with 75% and 100% NPK. The greatest N use, internal, agronomic N use, and recovery efficiencies were obtained with 50% NPK + poultry manure, but were similar to those obtained from cow manure and vermicompost subplots. As the amount of applied N from organic and inorganic fertilizer increased, the N use efficiency and related parameters decreased, due to similar yields among plots with different NPK application levels. Poultry manure resulted in the highest significant correlations between applied N and N accumulation, followed by cow manure and vermicompost, in both seasons. Neither chemical fertilizer nor organic manure alone led to optimum N use and N recovery efficiencies. The combination of 50% inorganic fertilizer (75 kg N ha-1) and poultry manure (5 t·ha-1) enhanced the N uptake, the N use and recovery efficiencies of hybrid rice. Cow manure (5 t·ha-1) in combination with 75% inorganic fertilizer (112.5 kg N ha-1) was an adequate substitute for reduced chemical fertilizer usage. Therefore, this study highlighted combined application of inorganic fertilizers and organic manures had the benefits not only in reducing the need for chemical fertilizers but also in improving N uptake by hybrid rice (Palethwe-1) leading to the better environment.展开更多
Rational nitrogen(N) application can greatly increase rice(Oryza sativa L.) yield. However, excessive N input can lead not only to low N use efficiency(NUE) but also to severe environmental pollution.Reducing N applic...Rational nitrogen(N) application can greatly increase rice(Oryza sativa L.) yield. However, excessive N input can lead not only to low N use efficiency(NUE) but also to severe environmental pollution.Reducing N application rate with a higher planting density(RNHD) is recommended to maintain rice yield and improve NUE. The effects of RNHD on fertilizer N fate and rice root growth traits remain unclear. We accordingly conducted a two-year field experiment to investigate the influence of RNHD on rice yield, fertilizer 15N fate, and root growth in a double-rice cropping system in China. In comparison with the conventional practice of high N application with sparse planting, RNHD resulted in similar yield and biomass production as well as plant N uptake. RNHD increased agronomic NUEs by 23.3%–31.9%(P < 0.05) and N recovery efficiency by 17.4%–24.1%(P < 0.05). RNHD increased fertilizer 15N recovery rate by 14.5%–34.7%(P < 0.05), but reduced15 N retention rate by 9.2%–12.0%(P < 0.05). Although a reduced N rate led to significantly reduced root length, surface area, volume, and biomass, these root traits were significantly increased by higher planting density. RNHD did not affect these root morphological traits and reduced activities of nitrate reductase(NR) and glutamine synthetase(GS) only at tillering stage. Plant N uptake was significantly positively correlated with these root traits, but not correlated with NR and GS activities. Together, these findings show that reducing N application with dense planting can lead to high plant N uptake by maintaining rice root growth and thus increase NUE.展开更多
The optimized nitrogen fertilization location differs in different rice-growing regions. We optimized nitrogen deep-point application in root-growing zone(NARZ) for transplanted rice in subtropical China. Field plot...The optimized nitrogen fertilization location differs in different rice-growing regions. We optimized nitrogen deep-point application in root-growing zone(NARZ) for transplanted rice in subtropical China. Field plot experiments were conducted over two years(2014–2015) in a double-rice cropping system to evaluate the effects of nitrogen(N) fertilizer location on grain yield and N use efficiency(NUE). Four different nitrogen deep-point application methods(DN) were compared with traditional broadcast application(BN) using granular urea. The results showed that grain yield, recovery efficiency of N(REN), agronomic efficiency of N(AEN), and partial factor productivity of N(PFP_N) significantly increased 10.3–63.4, 13.7–56.7, 24.7–201.9 and 10.2–63.4%, respectively, in DN treatment compared to BN, respectively. We also find that DN treatments increased grain yield as well as grain N content, and thus grain quality, in comparison with conventional BN treatment. Correlation analysis indicated that significant improvement in grain yield and NUE mainly resulted from increases in productive panicle number and grain N content. In our proposed NARZ method, granular urea should be placed 0 to 5 cm around the rice seeding at a 12-cm depth druing rice transplanting. In NARZ, balanced application of N, P and K further improved grain yield and NUE over treatments with a single N deep-point application. High N uptake by the rice plant did not cause significant soil fertility depletion, demonstrating that this method could guarantee sustainable rice production.展开更多
Experiments were conducted for the extraction of phenols from the phenol fraction obtained from the coal tar distillate. The phenol fraction for the present investigation has been procured from Visakhapatnam Steel Pla...Experiments were conducted for the extraction of phenols from the phenol fraction obtained from the coal tar distillate. The phenol fraction for the present investigation has been procured from Visakhapatnam Steel Plant, Visakhapatnam whose composition is known. The phenol fraction from coal tar distillate can be treated for extracting phenols using caustic soda. An attempt has been made to find out whether the existing practice of using only 8%-15% can be modified by increasing the strength of sodium hydroxide and also explore the possibilities of substituting the sodium hydroxide with KOH as an extractant. The different streams of liquids obtained during experimentation have been analyzed by gas chromatograph. Salient features of the study are that higher concentrations of the alkali significantly improved the separation efficiencies of phenols and also regenerate the phenolate with higher phenol content. Increase in the alkali strength has greatly improved the separation as well as the phenol content in the regenerated phenols. Disposal of effluents containing phenols may lead to environmental problem of ground water pollution and the study throws a light on the removal of phenols from the effluents to the extent possible by using higher strength alkali solutions.展开更多
<span style="font-family:Verdana;">This study investigates the economic benefits of energy efficiency to petroleum refineries regarding Tema Oil Refinery (TOR), Ghana. The study explores lessons relati...<span style="font-family:Verdana;">This study investigates the economic benefits of energy efficiency to petroleum refineries regarding Tema Oil Refinery (TOR), Ghana. The study explores lessons relating to the cost of production, energy recovery levels and economic fortunes of the refinery activities and designs a conceptual framework for improving the energy efficiency of Tema Oil Refinery (TOR). The study adopted a descriptive design using a quantitative approach to provide a statistical background to investigate the economic benefits of energy efficiency. A sample of 84 was adopted for study from a staff population of 520 working at Tema Oil refinery. In addition to primary data, secondary data on energy supply and consumption values from 2008 to 2019 was gathered. For the primary survey, 84 respondents were sampled from TOR and a structured questionnaire was used to retrieve information. A correlation analysis at P < 0.05 was conducted to test the relationship and significance of energy efficiency and economic benefits to the refinery. The study concludes that there is a linear trend between energy production (supply) and energy consumption. The energy generated in the entire economy of Ghana far exceeds the amount of energy consumed thus raising issues of waste or excesses that calls for better policies and management plan to improve EE. The study also identified that issues of lost energy are critical to the operations of the petroleum industry as the situation is compounded by the inability of the refineries to explore better ways to reduce and manage the waste. The study concludes that a significant and positive correlation between energy efficiency and the economic fortunes of Tema Oil Refinery is necessary for its economic fortunes. The supply of energy should have equivalence to the public consumption of energy.展开更多
Laboratory experiments,numerical simulations and fracturing technology were combined to address the problems in shale oil recovery by CO_(2)injection.The laboratory experiments were conducted to investigate the displa...Laboratory experiments,numerical simulations and fracturing technology were combined to address the problems in shale oil recovery by CO_(2)injection.The laboratory experiments were conducted to investigate the displacement mechanisms of shale oil extraction by CO_(2)injection,and the influences of CO_(2)pre-pad on shale mechanical properties.Numerical simulations were performed about influences of CO_(2)pre-pad fracturing and puff-n-huff for energy replenishment on the recovery efficiency.The findings obtained were applied to the field tests of CO_(2)pre-pad fracturing and single well puff-n-huff.The results show that the efficiency of CO_(2)puff-n-huff is affected by micro-and nano-scale effect,kerogen,adsorbed oil and so on,and a longer soaking time in a reasonable range leads to a higher exploitation degree of shale oil.In the"injection+soaking"stage,the exploitation degree of heavy hydrocarbons is enhanced by CO_(2)through its effects of solubility-diffusion and mass-transfer.In the"huff"stage,crude oil in large pores is displaced by CO_(2)to surrounding larger pores or bedding fractures and finally flows to the production well.The injection of CO_(2)pre-pad is conducive to keeping the rock brittle and reducing the fracture breakdown pressure,and the CO_(2)is liable to filter along the bedding surface,thereby creating a more complex fracture.Increasing the volume of CO_(2)pre-pad can improve the energizing effect,and enhance the replenishment of formation energy.Moreover,the oil recovery is more enhanced by CO_(2)huff-n-puff with the lower shale matrix permeability,the lower formation pressure,and the larger heavy hydrocarbon content.The field tests demonstrate a good performance with the pressure maintained well after CO_(2)pre-pad fracturing,the formation energy replenished effectively after CO_(2)huff-n-puff in a single well,and the well productivity improved.展开更多
Current high power load simulators are generally incapable of obtaining both high loading performance and high energy efficiency. Simulators with high energy efficiency are used to simulate static-state load, and thos...Current high power load simulators are generally incapable of obtaining both high loading performance and high energy efficiency. Simulators with high energy efficiency are used to simulate static-state load, and those with high dynamic performance typically have low energy efficiency. In this paper, the variants of secondary control(VSC) with power recovery are developed to solve this problem for loading hydraulic driving devices that operate under variable pressure, unlike classical secondary control(CSC) that operates in constant pressure network. Hydrostatic secondary control units are used as the loading components, by which the absorbed mechanical power from the tested device is converted into hydraulic power and then fed back into the tested system through 4 types of feedback passages(FPs). The loading subsystem can operate in constant pressure network, controlled variable pressure network, or the same variable pressure network as that of the tested device by using different FPs. The 4 types of systems are defined, and their key techniques are analyzed, including work principle, simulating the work state of original tested device, static operation points, loading performance, energy efficiency, and control strategy, etc. The important technical merits of the 4 schemes are compared, and 3 of the schemes are selected, designed, simulated using AMESim and evaluated. The researching results show that the investigated systems can simulate the given loads effectively, realize the work conditions of the tested device, and furthermore attain a high power recovery efficiency that ranges from 0.54 to 0.85, even though the 3 schemes have different loading performances and energy efficiencies. This paper proposes several loading schemes that can achieve both high dynamic performance and high power recovery efficiency.展开更多
Increasing production and disposal of coal fly ash (CFA) is a matter of serious environment concern. However, CFA contains various beneficial metals and mineral matters whose demand is increasing in the industrializ...Increasing production and disposal of coal fly ash (CFA) is a matter of serious environment concern. However, CFA contains various beneficial metals and mineral matters whose demand is increasing in the industrialized world, while natural supplies are diminishing. Therefore, recovery of these potential resources from CFA can be an alternative way to save mineral resources, as well as to reduce the environmental burden of CFA disposal. There are numerous methods developed for the recovery of beneficial products from CFA. Based on the US patents and journal literatures, the present review describes the recovery status and technologies of major elements such as Al, Si, Fe and Ti, and trace elements such as V, Ga, Ge, Se, Li, Mo, U, Au, Ag, Pt groups and rare earth elements (REEs) and other beneficial products such as magnetic materials, cenospheres, and unburned carbon from CFA. It also highlights the recovery efficiency and drawbacks for their extraction, and suggests future research to develop satisfactory results in terms of selective recovery and purification.展开更多
Conversion of CO2 into CO using plasma processing powered by renewable energy is a promising method to convert intermittent sustainable electricity into storable chemical energy.Despite extensive research efforts worl...Conversion of CO2 into CO using plasma processing powered by renewable energy is a promising method to convert intermittent sustainable electricity into storable chemical energy.Despite extensive research efforts worldwide,there is currently no process that achieves economically viable values for both CO2 conversion fraction and energy recovery efficiency simultaneously.Here we demonstrate that a process that utilizes the Boudouard reaction,CO^2++C→2 CO,driven by a thermal plasma allows both 95%CO2 conversion to CO and energy recovery efficiency of 70%,values far higher than seen so far.By comparing the conversion process with and without CO2 excitation by a plasma and by using optical emission spectroscopy we show that the improved performance is due to a novel mode of operation where CO2 is pyrolyzed into an active mixture of CO,O and O2 by an arc discharge which is then introduced into a fixed bed to interact with carbon material.In this way,the free oxygen in the mixture combusts with carbon to form CO,and residual plasma excited CO2 is reduced by carbon.In the overall process,the endothermic Boudouard reaction is partially replaced by an exothermic reaction,and the excess electric energy to produce CO2 plasma is reused in the carbon bed.展开更多
基金supported by the National Natural Science Foundation of China(31671625,31271669)the National Key Research and Development Program of China(2016YFD0300202)
文摘Optimized nitrogen(N)management can increase N-use efficiency in intercropping systems.Legume-nonlegume intercropping systems can reduce N input by exploiting biological N fixation by legumes.Measurement of N utilization can help in dissecting the mechanisms underlying N uptake and utilization in legume-nonlegume intercropping systems.An experiment was performed with three planting patterns:monoculture maize(MM),monoculture soybean(SS),and maize-soybean relay intercropping(IMS),and three N application levels:zero N(NN),reduced N(RN),and conventional N(CN)to investigate crop N uptake and utilization characteristics.N recovery efficiency and 15N recovery rate of crops were higher under RN than under CN,and those under RN were higher under intercropping than under the corresponding monocultures.Compared with MM,IMS showed a lower soil N-dependent rate(SNDR)in 2012.However,the SNDR of MM rapidly declined from 86.8%in 2012 to 49.4%in 2014,whereas that of IMS declined slowly from 75.4%in 2012 to 69.4%in 2014.The interspecific N competition rate(NCRms)was higher under RN than under CN,and increased yearly.Soybean nodule dry weight and nitrogenase activities were respectively 34.2%and 12.5%higher under intercropping than in monoculture at the beginning seed stage.The amount(Ndfa)and ratio(%Ndfa)of soybean N2 fixation were significantly greater under IS than under SS.In conclusion,N fertilizer was more efficiently used under RN than under CN;in particular,the relay intercropping system promoted N fertilizer utilization in comparison with the corresponding monocultures.An intercropping system helps to maintain soil fertility because interspecific N competition promotes biological N fixation by soybean by reducing N input.Thus,a maize-soybean relay intercropping system with reduced N application is sustainable and environmentally friendly.
基金supported by the National Science and Technology Major Project of China (2014ZX07201009)the Special Foundation for Basic Scientific Research of Central Public Welfare Institute of China (BSRF201306)the Sustainable Agricultural Technique Research and Development Project Phase II between China and Japan
文摘The excessive nitrogen (N) fertilizer input coupled with flood irrigation might result in higher N leaching and lower nitrogen recovery efficiency (NRE). Under an intensive rice system in the Ningxia irrigation region, China, environmental friendly N management practices are hreavily needed to balance the amount of N input for optimum crop production while minimize the nitrogen loss. The objective of this study was to determine the influences of side-dressing (SD) technique in mechanical transplanting systems on the NRE, N leaching losses and rice yield in anthropogenic-alluvial soil during two rice growing seasons (2010-2011). Four fertilizer N treatments were established, including conventional urea rate (CU, 300 kg ha-1 yr-1); higher SD of controlled-release N fertilizer rate (SD1,176 kg ha-1 yr-1); lower SD of controlled-release N fertilizer rate (SD2, 125 kg ha-1 yr-1); and control (CK, no N fertilizer). Field lysimeters were used to quantify drainage from undisturbed soil during six rice growing stages. Meanwhile, the temporal variations of total nitrigen (TN), NO3--N, and NH4+-N concentrations in percolation water were examined. The results showed that SD1 substantially improved NRE and reduced N leaching losses while maintaining rice yields. Across two years, the averaged NRE under SD1 treatment increased by 25.5% as relative to CU, but yet the rice yield was similar between two treatments. On average, the nitrogen loss defined as TN, NH4+-N, and NO3--N under the SD1 treatment reduced by 27.4, 37.2 and 24.1%, respectively, when compared with CU during the study periods. Although the SD2 treatment could further reduce N leaching loss to some extent, this technique would sharply decline rice yield, with the magnitude of as high as 21.0% relative to CU treatment. Additionally, the average NRE under SD2 was 11.2% lower than that under SD1 treatment. Overall, the present study concluded that the SO technique is an effective strategy to reduce N leaching and increase NRE, thus potentially mitigate local environmental threat. We propose SD1 as a novel alternative fertilizer technique under an irrigated rice-based system in Ningxia irrigation region when higher yields are under consideration.
基金Project supported by the International Rice Research Institute (IRRI)Swiss Agency for Development and Cooperation (SDC)+3 种基金the Potash & Phosphate Institute and the Potash & Phosphate Institute of Canada (PPI-PPIC)the International Fertilizer Industry Association (IFA)the International Potash Institute (IPI)948 Project of the Ministry of Agriculture of China (No. 2003-Z53)
文摘Field experiments were conducted in farmers’ rice fields in 2001 and 2002 to study the effects of nitrogen (N) man-agement strategies on N use efficiency in recovery (RE), agronomy (AE) and physiology (PE) and redistribution of dry matter accumulation (DMA) and nitrogen accumulation (NA) in two typical rice cultivars in Jinhua, Zhejiang Province. This study aimed mainly at identifying the possible causes of poor fertilizer N use efficiency (NUE) of rice in Zhejiang by comparing farmers’ fertilizer practice (FFP) with advanced site-specific nutrient management (SSNM) and real-time N management (RTNM). The results showed that compared to FFP, SSNM and RTNM reduced DMA and NA before panicle initiation and increased DMA and NA at post-flowering. There is no significant difference between SSNM and FFP in post-flowering dry matter redistribution (post-DMR) and post-flowering nitrogen redistribution (post-NR). These results suggest that high input rate of fertilizer N and improper fertilizer N timing are the main factors causing low NUE of irrigated rice in the farmer’s routine practice of Zhejiang. With SSNM, about 15% of the current total N input in direct-seeding early rice and 45% in single rice could be reduced without yield loss in Zhejiang, China.
基金Supported by the Research and Development Programs of Tianjin(10JCYBJC04700,10ZCKFSH02100)
文摘This work is focused on the theoretical investigation of internal leakage of a newly developed pi lotscale fluid switcherenergy recovery device (FSERD) for reverse osmosis (RO) system. For the purpose of in creasing FSERD efficiency and reducing the operating cost of RO, it is required to control the internal leakage in a low level. In this work, the internal leakage rates at different leakage gaps and retentate brine pressures are investigated by computational fluid dynamics (CFD) method and validating experiments. It is found that the internal leak age has a linear relationship with the retentate brine pressure and a polynomial relationship with the scale of leakage gap. The results of the present work imply that low internal leakage and high retentate brine pressure bring benefits to achieve high FSRD efficiency.
文摘Field experiments were conducted to study the effects of the controlled release urea (CRU) application on growth yield and nitrogen recovery efficiency of cotton in the main cotton zone of the Yangtze River basin in 2010. Different nitrogen levels were set in order to determine the suitable dosage of CRU on cotton. The special purpose was to provide evidence for the CRU application in cotton fields. The results show that the application of CRU promotes the growth of cotton significantly and enhances the nitrogen supply in the whole period. Compared to the treatment with total N as base fertilizer (UB), the bod, flower, little bolls and total bolls are increased significantly. There are no significant differences in the yield between the CRU treatment and the treatment of controlled release urea and urea combined application (60%CRU + 40%U), but an increase by 12.38%-22.67% compared to the UB treatment, and an increase by 4.49%-7.23% compared to the treatments of total N split application (UD). The nitrogen uptake of CRU treatment was significantly increased by 13.01%-48.32% and 30.27%-13.01% than UB treatment and UD treatment, respectively. The nutrient recovery efficiency of CRU treatment is increased by 16.42-20.59, 5.92-11.29 and 4.22-12.59 percentage points compared to the UB treatment, UD treatment and 60%CRU + 40%U treatment, respectively. In this study, there was a good linearity relationship between the cotton yield and amount of CRU in Wuxue site. The yield of cotton response to amount of CRU could be described by the model of linear plus plateau in Jingzhou site.
文摘The cow-calf (Bos taurus) industry in subtropical United States and other parts of the world that depends almost totally on grazed pastures is facing several production constraints like changing climatic conditions and increasing cost of fertilizers, especially nitrogen (N). Particularly little is known about the response of forage species to the combined effect of water-logging and the addition of N. A two-year greenhouse study was conducted in 2008 and 2009 to determine i) the effect of flooding duration on N recovery and agronomic efficiency of bahiagrass (Paspalum notatum Fluegge) compared with two flooding tolerant forages, limpograss (Hemarthria altissima Poir), and maidencane (Panicum hematomon Schult) and ii) if N fertilization could mitigate the negative effect of flooding. Nitrogen recovery and agronomic efficiency varied significantly (P ≤ 0.001) among forage species. Averaged across levels of N, N recovery of bahiagrass and limpograss was reduced by about 41% and 56%, respectively after 84 d of continued flooding while N recovery of maidencane was slightly increase by about 5% between 0 and 84 d of flooding. Agronomic efficiencies of bahiagrass (41% to 26%) and limpograss (44% to 31%) were reduced by flooding while agronomic efficiency of maidencane was increased from 24% (no flooding) to 46% at 84 d of continued flooding. However, N recovery and agronomic efficiency of three forage species was positively affected by N fertilization. The overall N recovery of bahiagrass, limpograss, and maidencane ranged from 44% to 59%. Nitrogen fertilization could improve N recovery and agronomic efficiency of forage species under waterlogged condition.
文摘The need to have naval units ever faster pushed the ship design to design hull shapes with increasingly higher performance thanks to the use of lightweight materials such as aluminum, and more powerful engines, etc., but without substantially modifying the traditional forms of hull. The hull patented Monotricat high hydrodynamic efficiency and energy saving it represents an evolution of the traditional architectures of the hulls, as its shape is adapted to recover wave formation engendered from the bow and sprays associated with it so as to reduce the resistance to the benefit of the speed, and navigating in displacement at speeds of planing hulls with an efficiency of about 20%. The patented hull Monotricat represents the overcoming of distinction between displacement and planing hulls, because, unlike previous solutions, the hull conventionally called Monotricat is the first displacement hull that can navigate at both displacement and planning speeds, with a resistance curve almost straight, maintaining the characteristics of a displacement hull, since it combines the characteristics of displacement and planning hull. It presents an innovative architecture that could be defined as a hybrid between a monohull and catamaran, navigating on spray self-produced. The combination of these three types of naval hulls allows it to ensure: safety, comfort navigation, best seakeeping and maneuverability in restricted waters, stability, reduction of resistance to motion, cost management, regularity on the routes even in adverse weather-sea. These characteristics of the hull have been studied, tested and validated by leading research institutes and universities with more ameliorative results in each subsequent experimentation, reported in the present work, which demonstrated a greater hydrodynamic efficiency compared to conventional hulls of 20%.
基金This project is supported by the China National Key Basis Research Project (No: G1999022512)
文摘The processes of flooding—water flooding, polymer flooding and ternary combination flooding—were simulated respectively on a 2-D positive rhythm profile geological model by using the ASP numerical modeling software developed by RIPED (Yuan, et al. 1995). The recovery coefficient, remaining oil saturation, sweep efficiency and displacement efficiency were calculated and correlated layer by layer. The results show that the sweep efficiency and displacement efficiency work different effects on different layers in the severely heterogeneous reservoir. The study shows that the displacement efficiency and sweep efficiency play different roles in different layers for severely heterogeneous reservoirs. The displacement efficiency contributes mainly to the high permeability zones, the sweep efficiency to the low permeability zones, both of which contribute to the middle permeable zones. To improve the sweep efficiency in the low permeability zones is of significance for enhancing the whole recovery of the reservoir. It is an important path for improving the effectiveness of chemical flooding in the severely heterogeneous reservoirs to inject ternary combination slug after profile control.
基金Supported by Foundation for Returned Scholars of Hebei Province(2010)Research Fund for the Doctoral Program of Hebei Normal University(L2009B13)~~
文摘[Objective] The aim of the research was to study the effect of the ice bath time after heat shock and the incubation time on the transformation efficacy,and to establish a simple and quick transformation method.[Method]Competent cells were prepared with two buffer solutions;with the ice bath time after heat shock and the recovery time as the variables,the relationship between these two factors and transformation efficacy was studied.[Result]The transformation efficacy was the best when the ice bath time was 2 min and the recovery time was 30 or 40 min;when the ice bath time and the recovery time was 0 min,a certain amount of transformants still could be obtained.[Conclusion]The ice bath time after heat shock and the recovery time had certain impact on transformation efficacy,but they were not the decisive factors.Therefore,in the general transformation experiment,these two steps could be omitted.
基金supported by the National Key Technology R&D Program of China (2014BAD11B04-2)the National Natural Science Foundation of China (30840056, 31171496)Shandong Modern Agricultural Technology and Industry System (SDAIT-04-01)
文摘Agronomically optimizing the timing and rates of nitrogen(N) fertilizer application can increase crop yield and decrease N loss to the environment. Wheat(Triticum aestivum L.)–peanut(Arachis hypogaea L.) relay intercropping systems are a mainstay of economic and food security in China. We performed a field experiment to investigate the effects of N fertilizer on N recovery efficiency, crop yield, and N loss rate in wheat–peanut relay intercropping systems in the Huang-Huai-Hai Plain, China during 2015–2017. The N was applied on the day before sowing, the jointing stage(G30) or the booting stage(G40) of winter wheat, and the anthesis stage(R1) of peanut in the following percentage splits: 50-50-0-0(N1), 35-35-0-30(N2), and 35-0-35-30(N3), using 300 kg N ha-1, with 0 kg N ha-1(N0) as control. ^(15)N-labeled(20.14 atom %) urea was used to trace the fate of N in microplots. The yields of wheat and peanut increased by 12.4% and 15.4% under the N2 and N3 treatments, relative to those under the N1 treatment. The ^(15)N recovery efficiencies( ^(15)NRE) were 64.9% and 58.1% for treatments N2 and N3, significantly greater than that for the N1 treatment(45.3%). The potential N loss rates for the treatments N2 and N3 were23.7% and 7.0%, significantly lower than that for treatment N1(30.1%). Withholding N supply until the booting stage(N3) did not reduce the wheat grain yield; however, it increased the N content derived from ^(15)N-labeled urea in peanuts, promoted the distribution of ^(15)N to pods, and ultimately increased pod yields in comparison with those obtained by topdressing N at jointing stage(N2). In comparison with N2, the N uptake and N recovery efficiency(NRE) of N3 was increased by 12.0% and 24.1%,respectively, while the apparent N loss decreased by 16.7%. In conclusion, applying N fertilizer with three splits and delaying topdressing fertilization until G40 of winter wheat increased total grain yields and NRE and reduced N loss. This practice could be an environment-friendly N management strategy for wheat–peanut relay intercropping systems in China.
文摘One of the basic ways to reduce polluting emissions of ship power plants is application of innovative devices for on-board energy generation by means of secondary energy resources.The combined gas turbine and diesel engine plant with thermochemical recuperation of the heat of secondary energy resources has been considered.It is suggested to conduct the study with the help of mathematical modeling methods.The model takes into account basic physical correlations,material and thermal balances,phase equilibrium,and heat and mass transfer processes.The paper provides the results of mathematical modeling of the processes in a gas turbine and diesel engine power plant with thermochemical recuperation of the gas turbine exhaust gas heat by converting a hydrocarbon fuel.In such a plant,it is possible to reduce the specific fuel consumption of the diesel engine by 20%.The waste heat potential in a gas turbine can provide efficient hydrocarbon fuel conversion at the ratio of powers of the diesel and gas turbine engines being up to 6.When the diesel engine and gas turbine operate simultaneously with the use of the LNG vapor conversion products,the efficiency coefficient of the plant increases by 4%–5%.
文摘We conducted two field experiments to investigate combined effects of organic and inorganic fertilizers on nitrogen use and recovery efficiencies of hybrid rice (Palethwe-1) during dry and wet seasons, 2015. Four levels of inorganic fertilizer (0%, 50%, 75%, and 100% NPK), based on recommended rates of 150 kg N ha-1, 70 kg P2O5 ha-1, and 120 kg K2O ha-1, were used with cow manure, poultry manure, and vermicompost (5 t·ha-1each) in a split-plot design with three replicates. In both seasons, with 50% NPK, the N uptake level achieved with poultry manure was similar to that obtained with 75% and 100% NPK. The greatest N use, internal, agronomic N use, and recovery efficiencies were obtained with 50% NPK + poultry manure, but were similar to those obtained from cow manure and vermicompost subplots. As the amount of applied N from organic and inorganic fertilizer increased, the N use efficiency and related parameters decreased, due to similar yields among plots with different NPK application levels. Poultry manure resulted in the highest significant correlations between applied N and N accumulation, followed by cow manure and vermicompost, in both seasons. Neither chemical fertilizer nor organic manure alone led to optimum N use and N recovery efficiencies. The combination of 50% inorganic fertilizer (75 kg N ha-1) and poultry manure (5 t·ha-1) enhanced the N uptake, the N use and recovery efficiencies of hybrid rice. Cow manure (5 t·ha-1) in combination with 75% inorganic fertilizer (112.5 kg N ha-1) was an adequate substitute for reduced chemical fertilizer usage. Therefore, this study highlighted combined application of inorganic fertilizers and organic manures had the benefits not only in reducing the need for chemical fertilizers but also in improving N uptake by hybrid rice (Palethwe-1) leading to the better environment.
基金supported by the National Natural Science Foundation of China(31601263)the National Key Research and Development Program of China(2018YFD0301103)+2 种基金the China Postdoctoral Science Foundation(2017M622100)the Jiangxi Province Postdoctoral Science Foundation(2017KY11)the Open Foundation of Guangxi Key Laboratory of Rice Genetics and Breeding(160-380-16-2)。
文摘Rational nitrogen(N) application can greatly increase rice(Oryza sativa L.) yield. However, excessive N input can lead not only to low N use efficiency(NUE) but also to severe environmental pollution.Reducing N application rate with a higher planting density(RNHD) is recommended to maintain rice yield and improve NUE. The effects of RNHD on fertilizer N fate and rice root growth traits remain unclear. We accordingly conducted a two-year field experiment to investigate the influence of RNHD on rice yield, fertilizer 15N fate, and root growth in a double-rice cropping system in China. In comparison with the conventional practice of high N application with sparse planting, RNHD resulted in similar yield and biomass production as well as plant N uptake. RNHD increased agronomic NUEs by 23.3%–31.9%(P < 0.05) and N recovery efficiency by 17.4%–24.1%(P < 0.05). RNHD increased fertilizer 15N recovery rate by 14.5%–34.7%(P < 0.05), but reduced15 N retention rate by 9.2%–12.0%(P < 0.05). Although a reduced N rate led to significantly reduced root length, surface area, volume, and biomass, these root traits were significantly increased by higher planting density. RNHD did not affect these root morphological traits and reduced activities of nitrate reductase(NR) and glutamine synthetase(GS) only at tillering stage. Plant N uptake was significantly positively correlated with these root traits, but not correlated with NR and GS activities. Together, these findings show that reducing N application with dense planting can lead to high plant N uptake by maintaining rice root growth and thus increase NUE.
基金financially supported by the National Basic Research Program of China(2013CB127401)the National Natural Science Foundation of China(41401258)+1 种基金the Natural Science Foundation of Jiangsu Province,China(BK20131044)the Natural Science Foundation of Jiangxi Province,China(20142BAB214005)
文摘The optimized nitrogen fertilization location differs in different rice-growing regions. We optimized nitrogen deep-point application in root-growing zone(NARZ) for transplanted rice in subtropical China. Field plot experiments were conducted over two years(2014–2015) in a double-rice cropping system to evaluate the effects of nitrogen(N) fertilizer location on grain yield and N use efficiency(NUE). Four different nitrogen deep-point application methods(DN) were compared with traditional broadcast application(BN) using granular urea. The results showed that grain yield, recovery efficiency of N(REN), agronomic efficiency of N(AEN), and partial factor productivity of N(PFP_N) significantly increased 10.3–63.4, 13.7–56.7, 24.7–201.9 and 10.2–63.4%, respectively, in DN treatment compared to BN, respectively. We also find that DN treatments increased grain yield as well as grain N content, and thus grain quality, in comparison with conventional BN treatment. Correlation analysis indicated that significant improvement in grain yield and NUE mainly resulted from increases in productive panicle number and grain N content. In our proposed NARZ method, granular urea should be placed 0 to 5 cm around the rice seeding at a 12-cm depth druing rice transplanting. In NARZ, balanced application of N, P and K further improved grain yield and NUE over treatments with a single N deep-point application. High N uptake by the rice plant did not cause significant soil fertility depletion, demonstrating that this method could guarantee sustainable rice production.
文摘Experiments were conducted for the extraction of phenols from the phenol fraction obtained from the coal tar distillate. The phenol fraction for the present investigation has been procured from Visakhapatnam Steel Plant, Visakhapatnam whose composition is known. The phenol fraction from coal tar distillate can be treated for extracting phenols using caustic soda. An attempt has been made to find out whether the existing practice of using only 8%-15% can be modified by increasing the strength of sodium hydroxide and also explore the possibilities of substituting the sodium hydroxide with KOH as an extractant. The different streams of liquids obtained during experimentation have been analyzed by gas chromatograph. Salient features of the study are that higher concentrations of the alkali significantly improved the separation efficiencies of phenols and also regenerate the phenolate with higher phenol content. Increase in the alkali strength has greatly improved the separation as well as the phenol content in the regenerated phenols. Disposal of effluents containing phenols may lead to environmental problem of ground water pollution and the study throws a light on the removal of phenols from the effluents to the extent possible by using higher strength alkali solutions.
文摘<span style="font-family:Verdana;">This study investigates the economic benefits of energy efficiency to petroleum refineries regarding Tema Oil Refinery (TOR), Ghana. The study explores lessons relating to the cost of production, energy recovery levels and economic fortunes of the refinery activities and designs a conceptual framework for improving the energy efficiency of Tema Oil Refinery (TOR). The study adopted a descriptive design using a quantitative approach to provide a statistical background to investigate the economic benefits of energy efficiency. A sample of 84 was adopted for study from a staff population of 520 working at Tema Oil refinery. In addition to primary data, secondary data on energy supply and consumption values from 2008 to 2019 was gathered. For the primary survey, 84 respondents were sampled from TOR and a structured questionnaire was used to retrieve information. A correlation analysis at P < 0.05 was conducted to test the relationship and significance of energy efficiency and economic benefits to the refinery. The study concludes that there is a linear trend between energy production (supply) and energy consumption. The energy generated in the entire economy of Ghana far exceeds the amount of energy consumed thus raising issues of waste or excesses that calls for better policies and management plan to improve EE. The study also identified that issues of lost energy are critical to the operations of the petroleum industry as the situation is compounded by the inability of the refineries to explore better ways to reduce and manage the waste. The study concludes that a significant and positive correlation between energy efficiency and the economic fortunes of Tema Oil Refinery is necessary for its economic fortunes. The supply of energy should have equivalence to the public consumption of energy.
基金Supported by Basic and Forward-Looking Project of the Science and Technology Department of SINOPEC(P22213-4)。
文摘Laboratory experiments,numerical simulations and fracturing technology were combined to address the problems in shale oil recovery by CO_(2)injection.The laboratory experiments were conducted to investigate the displacement mechanisms of shale oil extraction by CO_(2)injection,and the influences of CO_(2)pre-pad on shale mechanical properties.Numerical simulations were performed about influences of CO_(2)pre-pad fracturing and puff-n-huff for energy replenishment on the recovery efficiency.The findings obtained were applied to the field tests of CO_(2)pre-pad fracturing and single well puff-n-huff.The results show that the efficiency of CO_(2)puff-n-huff is affected by micro-and nano-scale effect,kerogen,adsorbed oil and so on,and a longer soaking time in a reasonable range leads to a higher exploitation degree of shale oil.In the"injection+soaking"stage,the exploitation degree of heavy hydrocarbons is enhanced by CO_(2)through its effects of solubility-diffusion and mass-transfer.In the"huff"stage,crude oil in large pores is displaced by CO_(2)to surrounding larger pores or bedding fractures and finally flows to the production well.The injection of CO_(2)pre-pad is conducive to keeping the rock brittle and reducing the fracture breakdown pressure,and the CO_(2)is liable to filter along the bedding surface,thereby creating a more complex fracture.Increasing the volume of CO_(2)pre-pad can improve the energizing effect,and enhance the replenishment of formation energy.Moreover,the oil recovery is more enhanced by CO_(2)huff-n-puff with the lower shale matrix permeability,the lower formation pressure,and the larger heavy hydrocarbon content.The field tests demonstrate a good performance with the pressure maintained well after CO_(2)pre-pad fracturing,the formation energy replenished effectively after CO_(2)huff-n-puff in a single well,and the well productivity improved.
文摘Current high power load simulators are generally incapable of obtaining both high loading performance and high energy efficiency. Simulators with high energy efficiency are used to simulate static-state load, and those with high dynamic performance typically have low energy efficiency. In this paper, the variants of secondary control(VSC) with power recovery are developed to solve this problem for loading hydraulic driving devices that operate under variable pressure, unlike classical secondary control(CSC) that operates in constant pressure network. Hydrostatic secondary control units are used as the loading components, by which the absorbed mechanical power from the tested device is converted into hydraulic power and then fed back into the tested system through 4 types of feedback passages(FPs). The loading subsystem can operate in constant pressure network, controlled variable pressure network, or the same variable pressure network as that of the tested device by using different FPs. The 4 types of systems are defined, and their key techniques are analyzed, including work principle, simulating the work state of original tested device, static operation points, loading performance, energy efficiency, and control strategy, etc. The important technical merits of the 4 schemes are compared, and 3 of the schemes are selected, designed, simulated using AMESim and evaluated. The researching results show that the investigated systems can simulate the given loads effectively, realize the work conditions of the tested device, and furthermore attain a high power recovery efficiency that ranges from 0.54 to 0.85, even though the 3 schemes have different loading performances and energy efficiencies. This paper proposes several loading schemes that can achieve both high dynamic performance and high power recovery efficiency.
文摘Increasing production and disposal of coal fly ash (CFA) is a matter of serious environment concern. However, CFA contains various beneficial metals and mineral matters whose demand is increasing in the industrialized world, while natural supplies are diminishing. Therefore, recovery of these potential resources from CFA can be an alternative way to save mineral resources, as well as to reduce the environmental burden of CFA disposal. There are numerous methods developed for the recovery of beneficial products from CFA. Based on the US patents and journal literatures, the present review describes the recovery status and technologies of major elements such as Al, Si, Fe and Ti, and trace elements such as V, Ga, Ge, Se, Li, Mo, U, Au, Ag, Pt groups and rare earth elements (REEs) and other beneficial products such as magnetic materials, cenospheres, and unburned carbon from CFA. It also highlights the recovery efficiency and drawbacks for their extraction, and suggests future research to develop satisfactory results in terms of selective recovery and purification.
基金supported by the National Natural Science Foundation of China(Grants nos.11775155,51561135013,21603202)。
文摘Conversion of CO2 into CO using plasma processing powered by renewable energy is a promising method to convert intermittent sustainable electricity into storable chemical energy.Despite extensive research efforts worldwide,there is currently no process that achieves economically viable values for both CO2 conversion fraction and energy recovery efficiency simultaneously.Here we demonstrate that a process that utilizes the Boudouard reaction,CO^2++C→2 CO,driven by a thermal plasma allows both 95%CO2 conversion to CO and energy recovery efficiency of 70%,values far higher than seen so far.By comparing the conversion process with and without CO2 excitation by a plasma and by using optical emission spectroscopy we show that the improved performance is due to a novel mode of operation where CO2 is pyrolyzed into an active mixture of CO,O and O2 by an arc discharge which is then introduced into a fixed bed to interact with carbon material.In this way,the free oxygen in the mixture combusts with carbon to form CO,and residual plasma excited CO2 is reduced by carbon.In the overall process,the endothermic Boudouard reaction is partially replaced by an exothermic reaction,and the excess electric energy to produce CO2 plasma is reused in the carbon bed.