Ten series of aromatic hydrocarbon compounds (biphenyl, naphthalene, phenanthrene, anthracene, retene, chrysene, benzoanthracene, dibenzofuran, fluorene, dibenzothiophene) isolated from seven Triassic and Jurassic lac...Ten series of aromatic hydrocarbon compounds (biphenyl, naphthalene, phenanthrene, anthracene, retene, chrysene, benzoanthracene, dibenzofuran, fluorene, dibenzothiophene) isolated from seven Triassic and Jurassic lacustrine mudstone samples and three swamp coal samples, as well as five crude oil samples collected in the Kuche depression of the Tarim Basin, NW China, have been analysed by GC-MS techniques. It is found that the relative abundances of dibenzofuran series are higher in the three swamp coal samples than those in the lacustrine mudstone samples. Based on the similar relative abundances of dibenzofuran series, especially dibenzofuran compound, in the TICs of aromatic hydrocarbons, crude oils from wells SA3 (K), YTK5 (E, K) and QL1 (E) are thought to have been derived predominantly from the coals of the Lower Jurassic Yangxia Formation or Middle Jurassic Kezilenuer Formation, whereas those from wells YM7 (O) and YH1 (E) were derived mainly from Triassic and Jurassic lacustrine mudstones in the Kuche depression. This is the first report about how to distinguish coal-generated oils from lacustrine mudstone-generated oils in the Kuche depression in terms of the dibenzofuran series. The present paper has enlightening and directive significance for further oil-source rock correlations and oil and/or gas exploration in the Kuche depression of the Tarim Basin.展开更多
The origin of the marine oils in the Tarim Basin has long been a disputed topic. A total of 58 DST (drill stem test) crude oil and 8 rock samples were investigated using a comprehensive geochemical method to charact...The origin of the marine oils in the Tarim Basin has long been a disputed topic. A total of 58 DST (drill stem test) crude oil and 8 rock samples were investigated using a comprehensive geochemical method to characterize and identify the origin of the Ordovician oils in the Tazhong Uplift, Tarim Basin, northwest China. Detailed oil–oil and oil–source rock correlations show that the majority of the oils have typical biomarker characteristics of the Middle-Upper Ordovician (O2+3) source rock and the related crude oil. These characteristics include a distinct "V-shaped" relative abundance of C27, C28 and C29 regular steranes, low abundance of dinosterane, 24-norcholestanes, triaromatic dinosteroids and gammacerane. Only a few oils display typical biomarker characteristics indicating the Cambrian–Lower Ordovician (∈-O1) genetic affinity, such as linear or anti "L" shape distribution of C27, C28 and C29 regular sterane, with relatively high concentrations of dinosterane, 24-norcholestanes, triaromatic dinosteroids and gammacerane. It appears that most of the Ordovician oils in the Tazhong Uplift were derived from the O2+3 intervals, as suggested by previous studies. However, the compound specific n-alkane stable carbon isotope data indicate that the Ordovician oils are mixtures from both the ∈-O1 and O2+3 source rocks rather than from the O2+3 strata alone. It was calculated that the proportion of the∈-O1 genetic affinity oils mixed is about 10.8%-74.1%, with an increasing trend with increasing burial depth. This new oil-mixing model is critical for understanding hydrocarbon generation and accumulation mechanisms in the region, and may have important implications for further hydrocarbon exploration in the Tarim Basin.展开更多
The oleanane parameter, i.e., OP (oleananes/(oleananes+C30hopanes)) in the two sedimentary columns of the Beibuwan Basin, South China Sea, can be used to delimit the top of oil generation window, with Ro (/%) o...The oleanane parameter, i.e., OP (oleananes/(oleananes+C30hopanes)) in the two sedimentary columns of the Beibuwan Basin, South China Sea, can be used to delimit the top of oil generation window, with Ro (/%) of 0.53 in Well M1 and 0.55 in Wells H1/Hd1/Hd2, respectively. Comparing with vitrinite reflectance (Ro/%), the OP features a dynamic range and can indicate the oil generation window more precisely. By using OP and other geochemical indices, the oil-source correlation is also conducted. It suggests that the oils in wells M1 and M2 are derived from the source rocks in situ. The mudstone in Huachang uplift is not the main source rocks for oils in this area, The OP is also a useful oil-source correlation parameter in some Tertiary lacustrine basins.展开更多
Series of 2-alkyl-1,3,4-trimethylbenzenes(ATMBs)were detected in most of crude oils and source rocks collected from various strata and locations of the Tarim Basin.They appeared to have heavy carbon isotopic signatur...Series of 2-alkyl-1,3,4-trimethylbenzenes(ATMBs)were detected in most of crude oils and source rocks collected from various strata and locations of the Tarim Basin.They appeared to have heavy carbon isotopic signatures(δ13C,up to~-16‰)compared to those hydrocarbons from oxygenic phototrophic organisms,indicating that the unequivocal source of green sulfur bacteria(GSB)and photic zone euxinia(PZE)existed in the original environment.Considering the high paleoproductivity,the PZE may have enhanced the preservation of organic matter,which triggered the formation of extremely organic-rich source rocks with TOC up to 29.8%for the Lower Cambrian Yuertus Formation(€1y).The coexistence of ATMBs and the diagnostic products from secondary alterations(e.g.,abundant 25-norhopanes,thiadiamondoids,and diamondoids)indicated a stronger ability of anti-second-alterations.Combined with the results of quantitatively de-convoluting mixed oil,the oil-source correlation based on ATMBs from a large number of Lower Paleozoic samples of the Tarim Basin suggested that the abundant deep crude oil resources co ntained a dominant contribution(>50%)from the€1y source rocks.Therefore,the ATMBs,as diagnostic biomarkers indicating unequivocal precursors under special habitat conditions,might provide important insights for the exploration of deep Lower Paleozoic crude oils in the Tarim Basin.展开更多
In the future time the exploration of marine oil and gas will be one of the significant domains in China. In this paper the biomarker assemblage characteristics of oilshow in the Nanlinghu Formation of the Majiashan p...In the future time the exploration of marine oil and gas will be one of the significant domains in China. In this paper the biomarker assemblage characteristics of oilshow in the Nanlinghu Formation of the Majiashan pro- file, which is located in Chaoxian County, south of Anhui Province, are described in the light of gas chromatogra- phy/mass spectrometric (GCMS) analysis on the qualitative and quantitative basis. Based on the investigation of the biomarker assemblage characteristics of possible source rocks developed in the area studied, a conclusion is drawn that the oilshow was generated from the Nanlinghu Formation source rocks (abbreviated as T1n), instead of the Qixia Formation source rocks (abbreviated as P1q). It is pointed out that the T1n is of strong potential for future oil explora- tion, and therefore much attention should be paid to it.展开更多
The anisotropy induced by rock bedding structures is usually manifested in the mechanical behaviors and failure modes of rocks.Brazilian tests are conducted for seven groups of shale specimens featuring different bedd...The anisotropy induced by rock bedding structures is usually manifested in the mechanical behaviors and failure modes of rocks.Brazilian tests are conducted for seven groups of shale specimens featuring different bedding angles. Acoustic emission (AE) and digital image correlation (DIC) technologies are used to monitor the in-situ failure of the specimens. Furthermore, the crack morphology of damaged samples is observed through scanning electron microscopy (SEM). Results reveal the structural dependence on the tensile mechanical behavior of shales. The shale disk exhibits compression in the early stage of the experiment with varying locations and durations. The location of the compression area moves downward and gradually disappears when the bedding angle increases. The macroscopic failure is well characterized by AE event location results, and the dominant frequency distribution is related to the bedding angle. The b-value is found to be stress-dependent.The crack turning angle between layers and the number of cracks crossing the bedding both increase with the bedding angle, indicating competition between crack propagations. SEM results revealed that the failure modes of the samples can be classified into three types:tensile failure along beddings with shear failure of the matrix, ladder shear failure along beddings with tensile failure of the matrix, and shear failure along multiple beddings with tensile failure of the matrix.展开更多
The origin and source of the petroleum in the Jurassic reservoirs within the eastern Fukang sub-depression were geochemically investigated.They show thermal maturities matching the peak generation stage,while the cond...The origin and source of the petroleum in the Jurassic reservoirs within the eastern Fukang sub-depression were geochemically investigated.They show thermal maturities matching the peak generation stage,while the condensates are at the early stage of intense cracking.Oils and condensates may have experienced mild evaporative fractionation,while mixing of severely biodegraded with non-biodegraded oils has occurred.Using biomarkers and isotopes,petroleums were classified into GroupⅠ,ⅡandⅢgenetic groups,with GroupⅢfurther divided intoⅢa andⅢb subgroups.GroupⅠpetroleum displays heavy carbon isotopes,a strong predominance of pristine over phytane,high C_(19)and C_(20)tricyclic and C_(24)tetracyclic terpanes,low gammacerane,and dominant C_(29)steranes,while GroupⅡshows light carbon isotopes,a predominance of phytane over pristine,high C_(21)and C_(23)tricyclic with low C_(24)tetracyclic terpanes,high gammacerane and dominant C_(27)steranes.GroupⅢa petroleum shows mixing compositions of GroupⅠandⅡ,while GroupⅢb displays similar compositions to Group I,but with significantly higher Ts,C_(29)Ts and C_(30)diahopane proportions.Oil-source rock correlation suggests GroupⅠandⅡpetroleums originate from Jurassic and Permian source rocks,respectively,while GroupⅢa are mixtures sourced from these rocks andⅢb are mixtures from Jurassic and Triassic source rocks.展开更多
Three-dimensional(3D)printing technology is increasingly used in experimental research of geotechnical engineering.Compared to other materials,3D layer-by-layer printing specimens are extremely similar to the inherent...Three-dimensional(3D)printing technology is increasingly used in experimental research of geotechnical engineering.Compared to other materials,3D layer-by-layer printing specimens are extremely similar to the inherent properties of natural layered rock masses.In this paper,soft-hard interbedded rock masses with different dip angles were prepared based on 3D printing(3DP)sand core technology.Uniaxial compression creep tests were conducted to investigate its anisotropic creep behavior based on digital imaging correlation(DIC)technology.The results show that the anisotropic creep behavior of the 3DP soft-hard interbedded rock mass is mainly affected by the dip angles of the weak interlayer when the stress is at low levels.As the stress level increases,the effect of creep stress on its creep anisotropy increases significantly,and the dip angle is no longer the main factor.The minimum value of the long-term strength and creep failure strength always appears in the weak interlayer within 30°–60°,which explains why the failure of the layered rock mass is controlled by the weak interlayer and generally emerges at 45°.The tests results are verified by comparing with theoretical and other published studies.The feasibility of the 3DP soft-hard interbedded rock mass provides broad prospects and application values for 3DP technology in future experimental research.展开更多
Shearing dislocation is a common failure type for rock–backfill interfaces because of backfill sedimentation and rock strata movement in backfill mining goaf.This paper designed a test method for rock–backfill shear...Shearing dislocation is a common failure type for rock–backfill interfaces because of backfill sedimentation and rock strata movement in backfill mining goaf.This paper designed a test method for rock–backfill shearing dislocation.Using digital image techno-logy and three-dimensional(3D)laser morphology scanning techniques,a set of 3D models with rough joint surfaces was established.Further,the mechanical behavior of rock–backfill shearing dislocation was investigated using a direct shear test.The effects of interface roughness on the shear–displacement curve and failure characteristics of rock–backfill specimens were considered.The 3D fractal dimen-sion,profile line joint roughness coefficient(JRC),profile line two-dimensional fractal dimension,and the surface curvature of the frac-tures were obtained.The correlation characterization of surface roughness was then analyzed,and the shear strength could be measured and calculated using JRC.The results showed the following:there were three failure threshold value points in rock–backfill shearing dis-location:30%–50%displacement before the peak,70%–90%displacement before the peak,and 100%displacement before the peak to post-peak,which could be a sign for rock–backfill shearing dislocation failure.The surface JRC could be used to judge the rock–backfill shearing dislocation failure,including post-peak sliding,uniform variations,and gradient change,corresponding to rock–backfill disloca-tion failure on the field site.The research reveals the damage mechanism for rock–backfill complexes based on the free joint surface,fills the gap of existing shearing theoretical systems for isomerism complexes,and provides a theoretical basis for the prevention and control of possible disasters in backfill mining.展开更多
Oil and gas exploration near faults in shallow strata is investigated in this study based on an analysis of oil-source faults in reservoire-cap rock combinations without a source rock.The oil-source faults were mapped...Oil and gas exploration near faults in shallow strata is investigated in this study based on an analysis of oil-source faults in reservoire-cap rock combinations without a source rock.The oil-source faults were mapped by superimposition of the distribution area of oil-source faults and the leakage area of cap rocks.This method is applied to the mapping of oil-source faults for two sets of reservoire-cap rock combinations without a source rock in the Banqiao area of the Qikou Sag in the Bohai Bay Basin,eastern China.Combination B is formed by a mudstone cap rock of the middle sub-member of the 1st member of the Shahejie Formation(E3s1 M)with its underlying reservoir,while Combination C is formed by a mudstone cap rock of the 2nd member of the Dongying Formation(E_(3)d_(2))with its underlying reservoir.The results show that the oil-source faults of Combination B are relatively better developed and mainly occur in the northeast and southeast,while those of Combination C are not as well developed and are only distributed at the southeastern edge of the study area with a small proportion in the north.These results are consistent with the fact that oil and gas are mainly distributed near oil-source faults,proving the method proposed is workable in determining the oil-source faults in reservoire-cap rock combinations without a source rock.展开更多
Cohesion(c) and friction angle(φ) of rock are important parameters required for reliability analysis of rock slope stability. There is correlation between c and φ which affects results of reliability analysis of roc...Cohesion(c) and friction angle(φ) of rock are important parameters required for reliability analysis of rock slope stability. There is correlation between c and φ which affects results of reliability analysis of rock slope stability. However, the characterization of joint probability distribution of c and φ through which their correlation can be estimated requires a large amount of rock property data, which are often not available for most rock engineering projects. As a result, the correlation between c and φ is often ignored or simply assumed during reliability studies, which may lead to bias estimation of failure probability. In probabilistic rock slope stability analysis, the influence of ignoring or simply assuming the correlation of the rock strength parameters(i.e., c and φ) on the reliability of rock slopes has not been fully investigated. In this study, a Bayesian approach is developed to characterize the correlation between c and φ, and an expanded reliability-based design(RBD) approach is developed to assess the influence of correlation between c and φ on reliability of a rock slope. The Bayesian approach characterizes the sitespecific joint probability distribution of c and φ, and quantifies the correlation between c and φ using available limited data pairs of c and φ from a rock project. The expanded RBD approach uses the joint probability distribution of c and φ obtained through the Bayesian approach as inputs, to determine the reliability of a rock slope. The approach gives insight into the propagation of the correlation between c and φ through their joint probability into the reliability analysis, and their influence on the calculated reliability of the rock slope. The approaches may be applied in practice with little additional effort from a conventional analysis. The proposed approaches are illustrated using real c and φ data pairs obtained from laboratory tests of fractured rock at Forsmark, Sweden.展开更多
In this paper, uniaxial compression tests were carried out on a series of composite rock specimens with different dip angles, which were made from two types of rock-like material with different strength. The acoustic ...In this paper, uniaxial compression tests were carried out on a series of composite rock specimens with different dip angles, which were made from two types of rock-like material with different strength. The acoustic emission technique was used to monitor the acoustic signal characteristics of composite rock specimens during the entire loading process. At the same time, an optical non-contact 3 D digital image correlation technique was used to study the evolution of axial strain field and the maximal strain field before and after the peak strength at different stress levels during the loading process. The effect of bedding plane inclination on the deformation and strength during uniaxial loading was analyzed. The methods of solving the elastic constants of hard and weak rock were described. The damage evolution process, deformation and failure mechanism, and failure mode during uniaxial loading were fully determined. The experimental results show that the θ = 0?–45?specimens had obvious plastic deformation during loading, and the brittleness of the θ = 60?–90?specimens gradually increased during the loading process. When the anisotropic angle θincreased from 0?to 90?, the peak strength, peak strain,and apparent elastic modulus all decreased initially and then increased. The failure mode of the composite rock specimen during uniaxial loading can be divided into three categories:tensile fracture across the discontinuities(θ = 0?–30?), slid-ing failure along the discontinuities(θ = 45?–75?), and tensile-split along the discontinuities(θ = 90?). The axial strain of the weak and hard rock layers in the composite rock specimen during the loading process was significantly different from that of the θ = 0?–45?specimens and was almost the same as that of the θ = 60?–90?specimens. As for the strain localization highlighted in the maximum principal strain field, the θ = 0?–30?specimens appeared in the rock matrix approximately parallel to the loading direction,while in the θ = 45?–90?specimens it appeared at the hard and weak rock layer interface.展开更多
This study considers the Upper Cretaceous Qingshankou Formation,Yaojia Formation,and the first member of the Nenjiang Formation in the Western Slope of the northern Songliao Basin.Dark mudstone with high abundances of...This study considers the Upper Cretaceous Qingshankou Formation,Yaojia Formation,and the first member of the Nenjiang Formation in the Western Slope of the northern Songliao Basin.Dark mudstone with high abundances of organic matter of Gulong and Qijia sags are considered to be significant source rocks in the study area.To evaluate their development characteristics,differences and effectiveness,geochemical parameters are analyzed.One-dimensional basin modeling and hydrocarbon evolution are also applied to discuss the effectiveness of source rocks.Through the biomarker characteristics,the source–source,oil–oil,and oil–source correlations are assessed and the sources of crude oils in different rock units are determined.Based on the results,Gulong and Qijia source rocks have different organic matter primarily detrived from mixed sources and plankton,respectively.Gulong source rock has higher thermal evolution degree than Qijia source rock.The biomarker parameters of the source rocks are compared with 31 crude oil samples.The studied crude oils can be divided into two groups.The oil–source correlations show that group I oils from Qing II–III,Yao I,and Yao II–III members were probably derived from Gulong source rock and that only group II oils from Nen I member were derived from Qijia source rock.展开更多
Aiming at the large deformation and support problems of high-stress and broken-expansion surrounding rock, and taking 1 000 m level roadway of Mine II in Jinchuan as the research object, an investigation on the deform...Aiming at the large deformation and support problems of high-stress and broken-expansion surrounding rock, and taking 1 000 m level roadway of Mine II in Jinchuan as the research object, an investigation on the deformation and damage of roadway surrounding rock and an analysis of its mechanism were carried out. The gray correlation theory was used in support scheme optimization design. First, causes and mechanism of deformation of the 1 000 m horizontal transport channel were analyzed through field investigation, laboratory test and data processing methods. We arguued that poor engineering geological conditions and deep pressure increases were the main factors, and the deformation mechanism was mainly the ground deformation pressure. Second, the gray correlation theory was used to construct supporting optimization decision method in the deep roadway. This method more comprehensively considers various factors, including construction, costs, and supporting material functions. The combined support with pre-stressed anchor cables, shotcrete layer, bolt and metal net was put forward according to the actual roadway engineering characteristics. Finally, 4 support schemes were put forward for new roadways. The gray relational theory was applied to optimizing the supporting method, undertaking technical and economic comparison to obtain the correlation degree, and accordingly the schemes were evaluated. It was concluded as follows: the best was the flexible retaining scheme using the steel strand anchor; the second best was the one using plate anchors on the top and rigid common screw steel bolt on the two sides; the third was; the rigid common screw steel bolt in full section of roadway; and the worst is the planished steel rigid support. The optimized scheme was applied to the 1000 m level of new excavation roadway. The results show that the roadway surrounding rock can reach a stable state after 5 to 6 months monitoring, with a convergence rate less than 1 mm/d.展开更多
Studied forecasting and controlling the blasting fragmentation by using artifi- cial neural network for multi-ingredients. At the same time, according to the characteris- tic of multi-parameters input to network model...Studied forecasting and controlling the blasting fragmentation by using artifi- cial neural network for multi-ingredients. At the same time, according to the characteris- tic of multi-parameters input to network model, the gray correlation theory was employed to find out key factors, which can not only save time of computation and parameters in- put, but improve the stability of the model.展开更多
文摘Ten series of aromatic hydrocarbon compounds (biphenyl, naphthalene, phenanthrene, anthracene, retene, chrysene, benzoanthracene, dibenzofuran, fluorene, dibenzothiophene) isolated from seven Triassic and Jurassic lacustrine mudstone samples and three swamp coal samples, as well as five crude oil samples collected in the Kuche depression of the Tarim Basin, NW China, have been analysed by GC-MS techniques. It is found that the relative abundances of dibenzofuran series are higher in the three swamp coal samples than those in the lacustrine mudstone samples. Based on the similar relative abundances of dibenzofuran series, especially dibenzofuran compound, in the TICs of aromatic hydrocarbons, crude oils from wells SA3 (K), YTK5 (E, K) and QL1 (E) are thought to have been derived predominantly from the coals of the Lower Jurassic Yangxia Formation or Middle Jurassic Kezilenuer Formation, whereas those from wells YM7 (O) and YH1 (E) were derived mainly from Triassic and Jurassic lacustrine mudstones in the Kuche depression. This is the first report about how to distinguish coal-generated oils from lacustrine mudstone-generated oils in the Kuche depression in terms of the dibenzofuran series. The present paper has enlightening and directive significance for further oil-source rock correlations and oil and/or gas exploration in the Kuche depression of the Tarim Basin.
基金This study is funded by the Natural Science Research Council of China (973 State Key Research and Development Program 2006CB202308)National Natural Science Foundation of China (Grant No.40973031)
文摘The origin of the marine oils in the Tarim Basin has long been a disputed topic. A total of 58 DST (drill stem test) crude oil and 8 rock samples were investigated using a comprehensive geochemical method to characterize and identify the origin of the Ordovician oils in the Tazhong Uplift, Tarim Basin, northwest China. Detailed oil–oil and oil–source rock correlations show that the majority of the oils have typical biomarker characteristics of the Middle-Upper Ordovician (O2+3) source rock and the related crude oil. These characteristics include a distinct "V-shaped" relative abundance of C27, C28 and C29 regular steranes, low abundance of dinosterane, 24-norcholestanes, triaromatic dinosteroids and gammacerane. Only a few oils display typical biomarker characteristics indicating the Cambrian–Lower Ordovician (∈-O1) genetic affinity, such as linear or anti "L" shape distribution of C27, C28 and C29 regular sterane, with relatively high concentrations of dinosterane, 24-norcholestanes, triaromatic dinosteroids and gammacerane. It appears that most of the Ordovician oils in the Tazhong Uplift were derived from the O2+3 intervals, as suggested by previous studies. However, the compound specific n-alkane stable carbon isotope data indicate that the Ordovician oils are mixtures from both the ∈-O1 and O2+3 source rocks rather than from the O2+3 strata alone. It was calculated that the proportion of the∈-O1 genetic affinity oils mixed is about 10.8%-74.1%, with an increasing trend with increasing burial depth. This new oil-mixing model is critical for understanding hydrocarbon generation and accumulation mechanisms in the region, and may have important implications for further hydrocarbon exploration in the Tarim Basin.
基金supported by the Natural Science Foundation of China(Grant No.40672093)CNPC Innovation Fund(07El001)the ESS-China Hydrocarbon Geosciences Collaboration Project under Natural Resources Canada's International Opportunities Program.
文摘The oleanane parameter, i.e., OP (oleananes/(oleananes+C30hopanes)) in the two sedimentary columns of the Beibuwan Basin, South China Sea, can be used to delimit the top of oil generation window, with Ro (/%) of 0.53 in Well M1 and 0.55 in Wells H1/Hd1/Hd2, respectively. Comparing with vitrinite reflectance (Ro/%), the OP features a dynamic range and can indicate the oil generation window more precisely. By using OP and other geochemical indices, the oil-source correlation is also conducted. It suggests that the oils in wells M1 and M2 are derived from the source rocks in situ. The mudstone in Huachang uplift is not the main source rocks for oils in this area, The OP is also a useful oil-source correlation parameter in some Tertiary lacustrine basins.
基金financial support provided by the National Science and Technology Major Project of the Ministry of Science and Technology of China (2016ZX04004-004)National Natural Science Foundation of China (41672125)
文摘Series of 2-alkyl-1,3,4-trimethylbenzenes(ATMBs)were detected in most of crude oils and source rocks collected from various strata and locations of the Tarim Basin.They appeared to have heavy carbon isotopic signatures(δ13C,up to~-16‰)compared to those hydrocarbons from oxygenic phototrophic organisms,indicating that the unequivocal source of green sulfur bacteria(GSB)and photic zone euxinia(PZE)existed in the original environment.Considering the high paleoproductivity,the PZE may have enhanced the preservation of organic matter,which triggered the formation of extremely organic-rich source rocks with TOC up to 29.8%for the Lower Cambrian Yuertus Formation(€1y).The coexistence of ATMBs and the diagnostic products from secondary alterations(e.g.,abundant 25-norhopanes,thiadiamondoids,and diamondoids)indicated a stronger ability of anti-second-alterations.Combined with the results of quantitatively de-convoluting mixed oil,the oil-source correlation based on ATMBs from a large number of Lower Paleozoic samples of the Tarim Basin suggested that the abundant deep crude oil resources co ntained a dominant contribution(>50%)from the€1y source rocks.Therefore,the ATMBs,as diagnostic biomarkers indicating unequivocal precursors under special habitat conditions,might provide important insights for the exploration of deep Lower Paleozoic crude oils in the Tarim Basin.
文摘In the future time the exploration of marine oil and gas will be one of the significant domains in China. In this paper the biomarker assemblage characteristics of oilshow in the Nanlinghu Formation of the Majiashan pro- file, which is located in Chaoxian County, south of Anhui Province, are described in the light of gas chromatogra- phy/mass spectrometric (GCMS) analysis on the qualitative and quantitative basis. Based on the investigation of the biomarker assemblage characteristics of possible source rocks developed in the area studied, a conclusion is drawn that the oilshow was generated from the Nanlinghu Formation source rocks (abbreviated as T1n), instead of the Qixia Formation source rocks (abbreviated as P1q). It is pointed out that the T1n is of strong potential for future oil explora- tion, and therefore much attention should be paid to it.
基金financially supported by the National Natural Science Foundation of China (No.51934003)the Major Science and Technology Special Project of Yunnan Province,China(Nos.202102AF080001 and 202102AG050024)。
文摘The anisotropy induced by rock bedding structures is usually manifested in the mechanical behaviors and failure modes of rocks.Brazilian tests are conducted for seven groups of shale specimens featuring different bedding angles. Acoustic emission (AE) and digital image correlation (DIC) technologies are used to monitor the in-situ failure of the specimens. Furthermore, the crack morphology of damaged samples is observed through scanning electron microscopy (SEM). Results reveal the structural dependence on the tensile mechanical behavior of shales. The shale disk exhibits compression in the early stage of the experiment with varying locations and durations. The location of the compression area moves downward and gradually disappears when the bedding angle increases. The macroscopic failure is well characterized by AE event location results, and the dominant frequency distribution is related to the bedding angle. The b-value is found to be stress-dependent.The crack turning angle between layers and the number of cracks crossing the bedding both increase with the bedding angle, indicating competition between crack propagations. SEM results revealed that the failure modes of the samples can be classified into three types:tensile failure along beddings with shear failure of the matrix, ladder shear failure along beddings with tensile failure of the matrix, and shear failure along multiple beddings with tensile failure of the matrix.
基金supported by the Fundamental Research Funds for the Central Universities(Grant No.20CX02108A)the Development Fund of the Key Laboratory of Deep Oil&Gas,China University of Petroleum(East China)。
文摘The origin and source of the petroleum in the Jurassic reservoirs within the eastern Fukang sub-depression were geochemically investigated.They show thermal maturities matching the peak generation stage,while the condensates are at the early stage of intense cracking.Oils and condensates may have experienced mild evaporative fractionation,while mixing of severely biodegraded with non-biodegraded oils has occurred.Using biomarkers and isotopes,petroleums were classified into GroupⅠ,ⅡandⅢgenetic groups,with GroupⅢfurther divided intoⅢa andⅢb subgroups.GroupⅠpetroleum displays heavy carbon isotopes,a strong predominance of pristine over phytane,high C_(19)and C_(20)tricyclic and C_(24)tetracyclic terpanes,low gammacerane,and dominant C_(29)steranes,while GroupⅡshows light carbon isotopes,a predominance of phytane over pristine,high C_(21)and C_(23)tricyclic with low C_(24)tetracyclic terpanes,high gammacerane and dominant C_(27)steranes.GroupⅢa petroleum shows mixing compositions of GroupⅠandⅡ,while GroupⅢb displays similar compositions to Group I,but with significantly higher Ts,C_(29)Ts and C_(30)diahopane proportions.Oil-source rock correlation suggests GroupⅠandⅡpetroleums originate from Jurassic and Permian source rocks,respectively,while GroupⅢa are mixtures sourced from these rocks andⅢb are mixtures from Jurassic and Triassic source rocks.
基金the support of the National Natural Science Foundation of China(Grant Nos.42207199,52179113,42272333)Zhejiang Postdoctoral Scientific Research Project(Grant Nos.ZJ2022155,ZJ2022156)。
文摘Three-dimensional(3D)printing technology is increasingly used in experimental research of geotechnical engineering.Compared to other materials,3D layer-by-layer printing specimens are extremely similar to the inherent properties of natural layered rock masses.In this paper,soft-hard interbedded rock masses with different dip angles were prepared based on 3D printing(3DP)sand core technology.Uniaxial compression creep tests were conducted to investigate its anisotropic creep behavior based on digital imaging correlation(DIC)technology.The results show that the anisotropic creep behavior of the 3DP soft-hard interbedded rock mass is mainly affected by the dip angles of the weak interlayer when the stress is at low levels.As the stress level increases,the effect of creep stress on its creep anisotropy increases significantly,and the dip angle is no longer the main factor.The minimum value of the long-term strength and creep failure strength always appears in the weak interlayer within 30°–60°,which explains why the failure of the layered rock mass is controlled by the weak interlayer and generally emerges at 45°.The tests results are verified by comparing with theoretical and other published studies.The feasibility of the 3DP soft-hard interbedded rock mass provides broad prospects and application values for 3DP technology in future experimental research.
基金supported by the National Key Research and Development Program of China(No.2021YFC3001302)the National Natural Science Foundation of China(No.52274072).
文摘Shearing dislocation is a common failure type for rock–backfill interfaces because of backfill sedimentation and rock strata movement in backfill mining goaf.This paper designed a test method for rock–backfill shearing dislocation.Using digital image techno-logy and three-dimensional(3D)laser morphology scanning techniques,a set of 3D models with rough joint surfaces was established.Further,the mechanical behavior of rock–backfill shearing dislocation was investigated using a direct shear test.The effects of interface roughness on the shear–displacement curve and failure characteristics of rock–backfill specimens were considered.The 3D fractal dimen-sion,profile line joint roughness coefficient(JRC),profile line two-dimensional fractal dimension,and the surface curvature of the frac-tures were obtained.The correlation characterization of surface roughness was then analyzed,and the shear strength could be measured and calculated using JRC.The results showed the following:there were three failure threshold value points in rock–backfill shearing dis-location:30%–50%displacement before the peak,70%–90%displacement before the peak,and 100%displacement before the peak to post-peak,which could be a sign for rock–backfill shearing dislocation failure.The surface JRC could be used to judge the rock–backfill shearing dislocation failure,including post-peak sliding,uniform variations,and gradient change,corresponding to rock–backfill disloca-tion failure on the field site.The research reveals the damage mechanism for rock–backfill complexes based on the free joint surface,fills the gap of existing shearing theoretical systems for isomerism complexes,and provides a theoretical basis for the prevention and control of possible disasters in backfill mining.
基金The National Natural Science Foundation of China(grant IDs 41872157,42072157).
文摘Oil and gas exploration near faults in shallow strata is investigated in this study based on an analysis of oil-source faults in reservoire-cap rock combinations without a source rock.The oil-source faults were mapped by superimposition of the distribution area of oil-source faults and the leakage area of cap rocks.This method is applied to the mapping of oil-source faults for two sets of reservoire-cap rock combinations without a source rock in the Banqiao area of the Qikou Sag in the Bohai Bay Basin,eastern China.Combination B is formed by a mudstone cap rock of the middle sub-member of the 1st member of the Shahejie Formation(E3s1 M)with its underlying reservoir,while Combination C is formed by a mudstone cap rock of the 2nd member of the Dongying Formation(E_(3)d_(2))with its underlying reservoir.The results show that the oil-source faults of Combination B are relatively better developed and mainly occur in the northeast and southeast,while those of Combination C are not as well developed and are only distributed at the southeastern edge of the study area with a small proportion in the north.These results are consistent with the fact that oil and gas are mainly distributed near oil-source faults,proving the method proposed is workable in determining the oil-source faults in reservoire-cap rock combinations without a source rock.
基金supported by grants from the Research Grants Council of the Hong Kong,Special Administrative Region,China [Project No.9042172 (CityU11200115)and Project No.8779012(T22-603/15N)]
文摘Cohesion(c) and friction angle(φ) of rock are important parameters required for reliability analysis of rock slope stability. There is correlation between c and φ which affects results of reliability analysis of rock slope stability. However, the characterization of joint probability distribution of c and φ through which their correlation can be estimated requires a large amount of rock property data, which are often not available for most rock engineering projects. As a result, the correlation between c and φ is often ignored or simply assumed during reliability studies, which may lead to bias estimation of failure probability. In probabilistic rock slope stability analysis, the influence of ignoring or simply assuming the correlation of the rock strength parameters(i.e., c and φ) on the reliability of rock slopes has not been fully investigated. In this study, a Bayesian approach is developed to characterize the correlation between c and φ, and an expanded reliability-based design(RBD) approach is developed to assess the influence of correlation between c and φ on reliability of a rock slope. The Bayesian approach characterizes the sitespecific joint probability distribution of c and φ, and quantifies the correlation between c and φ using available limited data pairs of c and φ from a rock project. The expanded RBD approach uses the joint probability distribution of c and φ obtained through the Bayesian approach as inputs, to determine the reliability of a rock slope. The approach gives insight into the propagation of the correlation between c and φ through their joint probability into the reliability analysis, and their influence on the calculated reliability of the rock slope. The approaches may be applied in practice with little additional effort from a conventional analysis. The proposed approaches are illustrated using real c and φ data pairs obtained from laboratory tests of fractured rock at Forsmark, Sweden.
基金supported by the National Basic Research 973 Program of China (Grant 2014CB046905)the Natural Science Foundation of Jiangsu Province for Distinguished Young Scholars (Grant BK20150005)+1 种基金the Fundamental Research Funds for the Central Universities (China University of Mining and Technology) (Grant 2014XT03)the innovation research project for academic graduate of Jiangsu Province (Grant KYLX16_0536)
文摘In this paper, uniaxial compression tests were carried out on a series of composite rock specimens with different dip angles, which were made from two types of rock-like material with different strength. The acoustic emission technique was used to monitor the acoustic signal characteristics of composite rock specimens during the entire loading process. At the same time, an optical non-contact 3 D digital image correlation technique was used to study the evolution of axial strain field and the maximal strain field before and after the peak strength at different stress levels during the loading process. The effect of bedding plane inclination on the deformation and strength during uniaxial loading was analyzed. The methods of solving the elastic constants of hard and weak rock were described. The damage evolution process, deformation and failure mechanism, and failure mode during uniaxial loading were fully determined. The experimental results show that the θ = 0?–45?specimens had obvious plastic deformation during loading, and the brittleness of the θ = 60?–90?specimens gradually increased during the loading process. When the anisotropic angle θincreased from 0?to 90?, the peak strength, peak strain,and apparent elastic modulus all decreased initially and then increased. The failure mode of the composite rock specimen during uniaxial loading can be divided into three categories:tensile fracture across the discontinuities(θ = 0?–30?), slid-ing failure along the discontinuities(θ = 45?–75?), and tensile-split along the discontinuities(θ = 90?). The axial strain of the weak and hard rock layers in the composite rock specimen during the loading process was significantly different from that of the θ = 0?–45?specimens and was almost the same as that of the θ = 60?–90?specimens. As for the strain localization highlighted in the maximum principal strain field, the θ = 0?–30?specimens appeared in the rock matrix approximately parallel to the loading direction,while in the θ = 45?–90?specimens it appeared at the hard and weak rock layer interface.
文摘This study considers the Upper Cretaceous Qingshankou Formation,Yaojia Formation,and the first member of the Nenjiang Formation in the Western Slope of the northern Songliao Basin.Dark mudstone with high abundances of organic matter of Gulong and Qijia sags are considered to be significant source rocks in the study area.To evaluate their development characteristics,differences and effectiveness,geochemical parameters are analyzed.One-dimensional basin modeling and hydrocarbon evolution are also applied to discuss the effectiveness of source rocks.Through the biomarker characteristics,the source–source,oil–oil,and oil–source correlations are assessed and the sources of crude oils in different rock units are determined.Based on the results,Gulong and Qijia source rocks have different organic matter primarily detrived from mixed sources and plankton,respectively.Gulong source rock has higher thermal evolution degree than Qijia source rock.The biomarker parameters of the source rocks are compared with 31 crude oil samples.The studied crude oils can be divided into two groups.The oil–source correlations show that group I oils from Qing II–III,Yao I,and Yao II–III members were probably derived from Gulong source rock and that only group II oils from Nen I member were derived from Qijia source rock.
基金Funded by Plan Projects of Hunan Provincial Science&Technology Department(2014FJ3046)Scientific Research Fund of Hunan Provincial Education Department(No.14A045)+1 种基金National Natural Science Foundation of China(Grant Nos.51434006,51374105 and 51374106)China Postdoctoral Science Foundation 2014M562135)
文摘Aiming at the large deformation and support problems of high-stress and broken-expansion surrounding rock, and taking 1 000 m level roadway of Mine II in Jinchuan as the research object, an investigation on the deformation and damage of roadway surrounding rock and an analysis of its mechanism were carried out. The gray correlation theory was used in support scheme optimization design. First, causes and mechanism of deformation of the 1 000 m horizontal transport channel were analyzed through field investigation, laboratory test and data processing methods. We arguued that poor engineering geological conditions and deep pressure increases were the main factors, and the deformation mechanism was mainly the ground deformation pressure. Second, the gray correlation theory was used to construct supporting optimization decision method in the deep roadway. This method more comprehensively considers various factors, including construction, costs, and supporting material functions. The combined support with pre-stressed anchor cables, shotcrete layer, bolt and metal net was put forward according to the actual roadway engineering characteristics. Finally, 4 support schemes were put forward for new roadways. The gray relational theory was applied to optimizing the supporting method, undertaking technical and economic comparison to obtain the correlation degree, and accordingly the schemes were evaluated. It was concluded as follows: the best was the flexible retaining scheme using the steel strand anchor; the second best was the one using plate anchors on the top and rigid common screw steel bolt on the two sides; the third was; the rigid common screw steel bolt in full section of roadway; and the worst is the planished steel rigid support. The optimized scheme was applied to the 1000 m level of new excavation roadway. The results show that the roadway surrounding rock can reach a stable state after 5 to 6 months monitoring, with a convergence rate less than 1 mm/d.
文摘Studied forecasting and controlling the blasting fragmentation by using artifi- cial neural network for multi-ingredients. At the same time, according to the characteris- tic of multi-parameters input to network model, the gray correlation theory was employed to find out key factors, which can not only save time of computation and parameters in- put, but improve the stability of the model.