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The combined effects of farm yard manure and boron application on growth,and oil quality of Canola grown under newly reclaimed soils
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作者 Farid Hellal Saied El Sayed +1 位作者 Amany Abdel Mohsen Ramadan Doaa M.Abobasha 《Oil Crop Science》 CSCD 2024年第1期53-59,共7页
Two field experiments were conducted during the main seasons of 2021/2022 at the Research and Production Station of National Research Centre in Egypt to investigate the effects of farmyard manure(FYM)and boron on Cano... Two field experiments were conducted during the main seasons of 2021/2022 at the Research and Production Station of National Research Centre in Egypt to investigate the effects of farmyard manure(FYM)and boron on Canola growth,yield,oil yield,and quality.The results unequivocally demonstrated that the combined application of FYM at a rate of 14.4 ton ha^(-1)with a foliar spray of boron at 100 ppm positively influenced plant characteristics,leading to enhanced growth rates and higher yields compared to the control group.Moreover,this integrated approach significantly improved nutrient content by enhancing levels of oil content,carbohydrates,proteins,phenolics,flavonoids,and total soluble sugars.These findings provide compelling evidence that utilizing farm manure along with boron can effectively enhance Canola properties in newly reclaimed soils while promoting sustainable agricultural practices. 展开更多
关键词 Oil quality Farmyard manure Phytochemical content CANOLA Yield production
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Genome-wide association study exposed the pleiotropic genes for yield-related and oil quality traits in Brassica napus L.
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作者 Yang Xiang M.M.U.Helal +8 位作者 Longbing Liang Minqin Zhang Hongshi Han Xianglai Dai Jixian Zhao Dalun Chen Xianping Wang Min Li Chuanji Zhao 《Oil Crop Science》 CSCD 2023年第3期156-164,共9页
Oilseed rape(Brassica napus L.) is an allotetraploid(AACC,2n=38) crop,valued for its edible oil and protein content.seed yield and nutritional composition of rapeseed are influenced by its yield and oil quality traits... Oilseed rape(Brassica napus L.) is an allotetraploid(AACC,2n=38) crop,valued for its edible oil and protein content.seed yield and nutritional composition of rapeseed are influenced by its yield and oil quality traits.However,the genetic basis of yield-related and oil-quality traits remain ambiguous.A panel of 266 diversified oilseed rape accessions was genotyped using 223 simple sequence repeat(SSR) markers covering all 19 chromosomes to identify significant markers associated with yield and quality traits.Twelve yield-related and six quality traits were investigated in two consecutive years(2014 and 2015),with three replications in two environments(Changshun,CS;and Qinghe,QH).Using the model GLM with population structure and kinship(Q+K),a total of 25 significant SSR markers(P <0.001) were detected to be associated with these twelve yield-related and six quality traits,explaining 4.56%-19.17% of the phenotypic variation for each trait.Based on these markers,BnaA03g23490D, BnaC09g46370D,BnaA07g37150D,BnaA01g32590D, and BnaC09g37280D were identified as pleiotropic genes controlling multiple traits.These candidate genes illustrated the potential for the genetic understanding of yield and oil quality traits.Most importantly,these significant markers can be used for marker-assisted breeding of oilseed rape in different environments. 展开更多
关键词 Brassica napus GWAS Yield-related and oil quality traits SSR markers
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Effect of Main Cultivation Factors on Oil Quality and Stability of Brassica napus Hybrids 被引量:1
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作者 赵继献 杜才富 +2 位作者 任廷波 程国平 王仙萍 《Agricultural Science & Technology》 CAS 2014年第5期795-800,共6页
[Objective] This study aimed to analyze the influence of five cultivation factors: sowing date, plant density, nitrogen fertilizer amount, phosphate fertilizer amount and potash fertilizer amount on oil quality and ... [Objective] This study aimed to analyze the influence of five cultivation factors: sowing date, plant density, nitrogen fertilizer amount, phosphate fertilizer amount and potash fertilizer amount on oil quality and stability of Brassica napus hybrids. [Method] Statistical analysis was carried out based on the data from previous studies and our work. [Result] Sowing date had no significant influence on oil quality and stability of B. napus hybrids. The plant density shared a positive correlation with 18-C fatty acid (FA) content, unsaturated fatty acid (UFA) content, total content of linoleic acid and linolenic acid, index of unsaturated fatty acid (IUFA), so a large plant density can improve the oil quality (by increasing18-C FA content, UFA content, total content of linoleic acid and linolenic acid), but reduce the oil stability (by increasing IUFA). The amount of nitrogen fertilizer had no significant influence on the contents of 18-C FA and UFA, but significant positive correlations with the total content of linoleic acid and linolenic acid and IUFA. So, the total content of linoleic acid and linolenic acid can be reduced by increasing nitrogen amount, meanwhile the oil stability was also decreased. Phosphate fertilizer amount did not affect 18-C FA significantly, but was negatively correlated with the UFA content, total content of linoleic acid and linolenic acid, and IUFA. So, increasing the amount of applied phosphate fertilizer can reduce UFA content, total content of linoleic acid and linolenic acid, thereby improving oil stability. Potash fertilizer had no significant influence on the IUFA, a significant positive correlation with 18-C FA content, an insignificant positive correlation with the the UFA content, and a negative correlation with the total content of linoleic acid and linolenic acid. The oil content of rapeseed shared an extremely significant positive correlation with 18-C FA content and UFA content, an negative correlation with the total content of linoleic acid and linolenic acid, and no significant correlation with IUFA. [Conclusion] This study identified the effects of five main cultivation factors on oil quality and stability of B. napus hybrids, and the correlations of oil content with 18-C FA content, UFA content, total content of linoleic acid and linolenic acid, and IUFA. 展开更多
关键词 Brassica napus hybrids Cultivation factors Oil quality Oil stability INFLUENCE
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Application of Hydrocracking Process for Upgrading Tail Oil Quality in 1.0 Mt/a Hydrocracker Unit at SINOPEC Yangzi Petrochemical Company
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作者 Zhang Haichun Dong Jianwei 《China Petroleum Processing & Petrochemical Technology》 SCIE CAS 2009年第1期13-17,共5页
This article focuses on the hydrocracking technology for upgrading the quality of tail oil and the first commercial application of the RN-32V/RHC- 1 catalysts in the 1.0 Mt/a hydrocracker at the Yangzi Petrochemical C... This article focuses on the hydrocracking technology for upgrading the quality of tail oil and the first commercial application of the RN-32V/RHC- 1 catalysts in the 1.0 Mt/a hydrocracker at the Yangzi Petrochemical Company, which was started up successfully in September 2008. One month after start-up of the hydrocracking unit, an evaluation opera- tion has been conducted fbr assessing the catalysts performance. The technical calibration results showed that the RN- 32V/RHC-1 catalysts had high activity, and the product yield distribution was reasonable. The hydrocracker can provide abundant feedstocks for the downstream aromatic production unit and ethylene production unit. 展开更多
关键词 HYDROCRACKING upgrading tail oil quality catalysts APPLICATION
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Individual and interactive influences of elevated air temperature and soil drought at the flowering and boll-forming stage on cottonseed yield and nutritional quality
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作者 Bingjie Xu Min Gao +3 位作者 Wei Hu Wenqing Zhao Shanshan Wang Zhiguo Zhou 《The Crop Journal》 SCIE CSCD 2022年第1期128-139,共12页
As the main byproduct of cotton production,cottonseed yields edible vegetable oil,ruminant feed,and industrial products.We evaluated the individual and interactive effects of elevated air temperature and soil drought ... As the main byproduct of cotton production,cottonseed yields edible vegetable oil,ruminant feed,and industrial products.We evaluated the individual and interactive effects of elevated air temperature and soil drought on cottonseed yield and nutritional quality using two cotton cultivars,Sumian 15(heat-susceptible)and PHY370 WR(heat-tolerant).The experiment was conducted under three levels of soil relative water content(SRWC):(75±5)%,(60±5)%and(45±5)%and two temperature regimes:ambient temperature(AT,31.0/26.4℃,mean daytime/night temperature)and elevated temperature(ET,33.4/28.9℃).Cottonseed yield,boll number,seed number,and single-seed weight were lower under combined ET and SRWC(45±5)%than either individual stress or combined stresses in comparison with the control treatment(SRWC(75±5)%under AT).Drought tended to increase oil content and reduce protein content,whereas ET showed almost the opposite effects.Under the combination of ET and soil drought,oil content was still higher than under control,although ET weakened the beneficial effects of drought.For protein,ET offset the negative impacts of mild drought on protein content,but protein content was not increased under SRWC(45±5)%.Each stress or combined stress reduced oil and protein yields under all treatments,owing to declines in cottonseed yields.The combined stress reduced unsaturated fatty acid(UFA)/saturated fatty acid(SFA)and essential amino acid(EAA)/non-essential amino acid(NAA).Compared with PHY370 WR,the sensitivity of Sumian 15 to the combined factors was evidenced in the following ways:(1)seed yield,yield components,oil and protein yields were decreased more for Sumian 15 than PHY370 WR compared with the control treatment;(2)the combined stresses caused lower oil content,UFA,and UFA/SFA in Sumian 15 than PHY370 WR;(3)interaction effects of the combined factors on protein content and EAA/NAA were detected only in Sumian 15. 展开更多
关键词 COTTONSEED Elevated temperature Drought Oil yield and quality Protein yield and quality
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Evaluation of seed quality and oil parameters in native Iranian almond(Prunus L.spp.) species
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作者 Soghra Kiani Shakiba Rajabpoor +1 位作者 Karim Sorkheh Sezai Ercisli 《Journal of Forestry Research》 SCIE CAS CSCD 2015年第1期115-122,共8页
We assessed chemical composition and variation in oil content and seed weight of 40 wild-growing almonds(Prunus L. spp.) accessions collected from different parts of Iran. There were significant differences in kerne... We assessed chemical composition and variation in oil content and seed weight of 40 wild-growing almonds(Prunus L. spp.) accessions collected from different parts of Iran. There were significant differences in kernel weight and oil parameters. Accessions ranged from0.20 to 1.5 g in kernel weight, 0.2–3.0 mm in shell thickness, and 16–55 % in oil content. The predominant vegetable oil components of kernels were 4.6–9.5 % palmitic acid, 0.4–0.8 % palmitoleic acid, 1.0–3.4 % stearic acid,48.8–88.4 % oleic acid and 11.3–33.2 % linoleic acid.Linolenic acid was detected in 15 accessions. High heritability was recorded for all studied traits and was maximum for shell thickness(98.5 %) and minimum for oil content(97.1 %). Maximum and minimum ‘Euclidean'pair wise dissimilarities were 17.9 and 0.5, respectively.All 40 accessions were grouped into two major clusters. 展开更多
关键词 Genetic diversity Kernel quality Oil parameters Wild almond(Prunus L.spp.)
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Influence of two-stage harvesting on the properties of cold-pressed rapeseed(Brassica napus L.)oils 被引量:4
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作者 NING Ning HU Bing +8 位作者 BAI Chen-yang LI Xiao-hua KUAI Jie HE Han-zi REN Yi-lin WANG Bo JIA Cai-hua ZHOU Guang-sheng ZHAO Si-ming 《Journal of Integrative Agriculture》 SCIE CAS CSCD 2023年第1期265-278,共14页
Rapeseed(Brassica napus L.)harvesting method is critical since it significantly determines the seed yield,oil quality,and industrial efficiency.This study investigated the influences of harvesting methods on the quali... Rapeseed(Brassica napus L.)harvesting method is critical since it significantly determines the seed yield,oil quality,and industrial efficiency.This study investigated the influences of harvesting methods on the quality of cold-pressed rapeseed oil of two varieties.Oil color,peroxide value(POV),tocopherol content,fatty acid composition,and polarity of total polyphenols(PTP)contents of two rapeseed varieties in Huanggang and Xiangyang were compared through artificially simulated combined harvesting and two-stage harvesting.Results showed significant differences in the quality of rapeseed oil between the two harvesting methods.The red value(R-value),POV,total tocopherol contents,linoleic and linolenic acid content,and PTP content of the pressed rapeseed oil prepared by the combined harvesting method were about 27.6,5.7,15.8,2.0,0.5,and 28.6%lower than those of the oil produced from the two-stage harvesting method,respectively.Xiangyang and Huayouza62 performed better in the two regions and two varieties,respectively.To sum up,the rapeseed oil obtained 41–44 days after final flowering of combined harvesting,35 days after final flowering,and six days of post-ripening of the two-stage harvesting had the best quality. 展开更多
关键词 RAPESEED two-stage harvesting combined harvesting oil quality
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Seed Priming Influence on Early Crop Growth, Phenological Development and Yield Performance of Linola (Linum usitatissimum L.) 被引量:4
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作者 Hafeez ur Rehman Muhammad Qaiser Nawaz +3 位作者 Shahzad Maqsood Ahmed Basra Irfan Afzal Azra Yasmeen Fayyaz ul-Hassan 《Journal of Integrative Agriculture》 SCIE CAS CSCD 2014年第5期990-996,共7页
Reduced early crop growth and limited branching are amongst yield limiting factors of linola. Field response of seed priming treatments viz. 50 mmol L^-1 salicylic acid (SA), 2.2% CaCl2 and 3.3% moringa leaf extract... Reduced early crop growth and limited branching are amongst yield limiting factors of linola. Field response of seed priming treatments viz. 50 mmol L^-1 salicylic acid (SA), 2.2% CaCl2 and 3.3% moringa leaf extract (MLE) including untreated dry and hydropriming controls was evaluated on early crop growth and yield performance of linola. Osmopriming with CaCl2 reduced emergence time and produced the highest seedling fresh and dry weights including Chl. a contents. Osmopriming with CaCl2 reduced crop branching and flowering and maturity times and had the maximum plant height, number of branches, tillers, pods and seeds per pod followed by MLE. Increase in seed weight, biological and seed yields was 9.30, 34.16 and 39.49%, harvest index (4.12%) and oil contents (13.39%) for CaCl2 osmopriming. Positive relationship between emergence and seedling vigor traits, 100-seed weight, seed yield with maturity time, 100-seed weight and seed yield were found. The study concludes that seed osmopriming with CaC12 or MLE can play significant role to improve early crop growth and seed yields of linola. 展开更多
关键词 LINSEED oil quality stand establishment CACL2
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Genome-wide scan for oil quality reveals a coregulation mechanism of tocopherols and fatty acids in soybean seeds 被引量:2
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作者 Danni Chu Zhifang Zhang +6 位作者 Yang Hu Chao Fang Xindan Xu Jia Yuan Jinsong Zhang Zhixi Tian Guodong Wang 《Plant Communications》 SCIE CSCD 2023年第5期234-245,共12页
Tocopherols(vitamin E)play essential roles in human health because of their antioxidant activity,and plantderived oils are the richest sources of tocopherols in the human diet.Although soybean(Glycinemax)is one of the... Tocopherols(vitamin E)play essential roles in human health because of their antioxidant activity,and plantderived oils are the richest sources of tocopherols in the human diet.Although soybean(Glycinemax)is one of themain sources of plant-derived oil and tocopherol in the world,the relationship between tocopherol and oil in soybean seeds remains unclear.Here,we focus on dissecting tocopherol metabolism with the longterm goal of increasing a-tocopherol content and soybean oil quality.We first collected tocopherol and fatty acid profiles in a soybean population(>800 soybean accessions)and found that tocopherol content increased during soybean domestication.A strong positive correlation between tocopherol and oil content was also detected.Five tocopherol pathway–related lociwere identified using a metabolite genome-wide association study strategy.Genetic variations in three tocopherol pathway genes were responsible for total tocopherol content and composition in the soybean population through effects on enzyme activity,mainly caused by non-conserved amino acid substitution or changes in gene transcription level.Moreover,the fatty acid regulatory transcription factor GmZF351 directly activated tocopherol pathway gene expression,increasing both fatty acid and tocopherol contents in soybean seeds.Our study reveals the functional differentiation of tocopherol pathway genes in soybean populations and provides a framework for development of new soybean varieties with high a-tocopherol content and oil quality in seeds. 展开更多
关键词 SOYBEAN fatty acid TOCOPHEROL vitamin E mGWAS oil quality
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Biochemical Characteristics of Saint Mary’s Thistle Varieties (<i>Silybum marianum</i>L. <i>Gaertn.</i>) under Soil-Climate Conditions of the Khorezm Region
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作者 Umorbek K. Abdurakhimov Rustam M. Usmanov +3 位作者 Nurbek U. Khamraev Fatima R. Nurmetova Yulduzxon A. Matyakubova Anarjan A. Matkarimova 《American Journal of Plant Sciences》 2020年第7期987-993,共7页
This article deals with the biochemical characteristics of varieties of Saint Mary’s Thistle such as Panacea, Debut and Samaryanka. Based on the studies, it was found that the highest oil content was found in the spe... This article deals with the biochemical characteristics of varieties of Saint Mary’s Thistle such as Panacea, Debut and Samaryanka. Based on the studies, it was found that the highest oil content was found in the species Debut (26%). <span style="font-family:Verdana;">The lowest oil content was observed in the variety </span><span style="font-family:Verdana;">Samaryanka</span><span style="font-family:Verdana;"> (19%). The highest protein content and the sum of total amino acids in the seeds of St. Mary’s Thistle varieties were found in the variety Debut (131.1), and the lowest indication was observed in the species Samaryanka (79.2). By the number of replaceable amino acids existing in the seeds of the species of St. Mary’s Thistle, it was found in the Varieties Debut (126.3), and the lowest indication was observed in the variety Samaryanka (112). Based on the results of studies and the noted biochemical characteristics and varietal differences of the St. Mary’s Thistle, the possibility and expediency of expanding the crops of this species in the soil and climatic conditions of the Khorezm region are suggested. The research was conducted 2017-2019 y.</span> 展开更多
关键词 St. Mary’s Thistle Variety Biochemical Properties Chemical Composition Oil Content of Seeds Oil quality Essential and Replaceable Amino Acids Vitamins Soil and Climatic Conditions Khorezm Region
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Effect of dietary incorporation of n-3 polyunsaturated fatty acids rich oil sources on fatty acid profile, keeping quality and sensory attributes of broiler chicken meat 被引量:5
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作者 Sridhar Kalakuntla Nalini K.Nagireddy +3 位作者 Arun K.Panda Narasimha Jatoth Raghunandan Thirunahari Ravinder R.Vangoor 《Animal Nutrition》 SCIE 2017年第4期386-391,共6页
The present study was undertaken to investigate the effect of dietary replacement of commonly used vegetable oil(sunflower oil, SFO) with n-3 polyunsaturated fatty acids(PUFA) rich oil sources on broiler chicken perfo... The present study was undertaken to investigate the effect of dietary replacement of commonly used vegetable oil(sunflower oil, SFO) with n-3 polyunsaturated fatty acids(PUFA) rich oil sources on broiler chicken performance, carcass yield, meat fatty acid composition, keeping quality and sensory attributes of meat. In the current experiment, 300 day-old Krishibro broiler chicks were randomly distributed to 5 dietary groups(50 replicates with 6 chicks in each) prepared by replacing SFO(2% and 3% of diet during starter and finisher periods, respectively) with n-3 PUFA rich soybean oil(SO), mustard oil(MO), linseed oil(LO) or fish oil(FO) on weight basis. Variation in oil sources had no influence(P > 0.05) on performance and carcass yield. Supplementation of MO, LO or FO significantly(P < 0.01) increased the n-3 PUFA, lowered the n-6 PUFA deposition and n-6:n-3 ratio in breast and thigh without affecting the organoleptic characters(appearance, flavour, juiciness, tenderness and overall acceptability) of meat.However, thiobarbituric acid reacting substances concentration in meat was increased(P < 0.01) with LO and FO supplementation compared with SFO. It is concluded that, dietary incorporation of MO, LO or FO at 2% and 3% levels during starter and finisher phase can enrich broiler chicken meat with n-3 PUFA without affecting the bird's performance and sensory characters of meat. 展开更多
关键词 Broiler chickens Fatty acid composition Keeping quality n-3 PUFA rich oils Performance Sensory characters of meat
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Rapid quantitative detection of mineral oil contamination in vegetable oil by near-infrared spectroscopy 被引量:5
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作者 Mantong Zhao Dawei Zhang +2 位作者 Lulu Zheng Otto Condliffe Yi Kang 《Chinese Optics Letters》 SCIE EI CAS CSCD 2020年第4期97-101,共5页
This study provides a rapid method for quantification of mineral oil in rapeseed oil using near-infrared spectroscopy.The data were processed by direct orthogonal signal correction(DOSC),successive projections algorit... This study provides a rapid method for quantification of mineral oil in rapeseed oil using near-infrared spectroscopy.The data were processed by direct orthogonal signal correction(DOSC),successive projections algorithm(SPA),partial least squares,and principal component regression(PCR).Good correlation coefficients(R)of 0.998 and root-mean-squared error(RMSE)of 0.005 were obtained,and the DOSC-SPA-PCR model was identified as the optimal method.A satisfactory accuracy with R and RMSE of prediction by DOSC-SPA-PCR of 0.990 and 0.006,was obtained.The results demonstrate that the proposed methodology is a promising method for the rapid quantitative detection of mineral oil in vegetable oil. 展开更多
关键词 near-infrared spectroscopy mineral oil oil quality control DOSC-SPA-PCR
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Capacitive sensor probe to assess frying oil degradation 被引量:1
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作者 Alfadhl Yahya Khaled Samsuzana Abd Aziz Fakhrul Zaman Rokhani 《Information Processing in Agriculture》 EI 2015年第2期142-148,共7页
The repeated usage of frying oil has been proven hazardous due to the degradation process by chemical reactions that lead to changes in the quality of the oil.Currently,the degree of frying oil degradation is indicate... The repeated usage of frying oil has been proven hazardous due to the degradation process by chemical reactions that lead to changes in the quality of the oil.Currently,the degree of frying oil degradation is indicated by the percentage of its total polar compounds(TPC).In this study,a capacitive sensor was designed to assess frying oil degradation at several heating time intervals by measuring changes on its electrical capacitance.The sensor was designed using interdigitated electrode structure.A total of 30 samples of 130 ml palm oil were heated at 180℃ up to 30 h.For each one hour interval,one sample was moved out from the laboratory oven.The electrical capacitance,total polar compound(TPC)and viscosity of the samples were measured for analysis.Preliminary results demonstrated significant correlation between oil electrical capacitance with TPC and viscosity with R^2 ranged from 0.83 to 0.90.The designed sensor has good potential for simple and inexpensive way of determining frying oil quality. 展开更多
关键词 Capacitance sensor Frying oil quality HEATING
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Co-pyrolysis of oil sludge with hydrogen-rich plastics in a vertical stirring reactor:Kinetic analysis,emissions,and products
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作者 Lujun Zhao Jiaming Shao +3 位作者 Li Xiang Yiping Feng Zhihua Wang Fawei Lin 《Frontiers of Environmental Science & Engineering》 SCIE EI CSCD 2022年第10期131-143,共13页
Pyrolysis is an effective method to treat oily sludge(OS)due to its balance between oil recovery and nonhazardous disposal.However,tank bottom OS contains a high content of heavy fractions,which creates obstacles for ... Pyrolysis is an effective method to treat oily sludge(OS)due to its balance between oil recovery and nonhazardous disposal.However,tank bottom OS contains a high content of heavy fractions,which creates obstacles for pyrolysis due to the high activation energy.The incomplete cracking of macromolecules and secondary polymerization decreases the oil quality and causes coking during the operation process.This study introduced polyethylene(PE)into OS to deploy the H/Ceff ratio of feedstocks for pyrolysis A strong interaction between OS and PE during copyrolysis could be observed from the TG/DTG curves.PE tightly participated in OS degradation,while OS also promoted PE degradation at high temperature.Apparent pits were generated in solid residues from copyrolysis,which was attributed to the uniform and violent gas release.In addition to HCN,other nitrogenous and sulphurous pollutants were inhibited.Accordingly,more gas products were attained after PE addition with more value-added compositions of alkanes and alkenes.Although the oil yield decreased after PE addition,the oil products from copyrolysis possessed higher heating values and higher contents of light fractions with short chains as well as paraffins.Consequently,copyrolysis of OS and PE significantly improved the pyrolysis process and resulted in high oil quality. 展开更多
关键词 Oily sludge PYROLYSIS POLYETHYLENE H/Ceff ratio Oil quality
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Rapid quantification of acid value in frying oil using iron tetraphenylporphyrin fluorescent sensor coupled with density functional theory and multivariate analysis
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作者 Haiyang Gu Yining Dong +2 位作者 Riqin Lv Xingyi Huang Quansheng Chen 《Food Quality and Safety》 SCIE CSCD 2022年第4期534-544,共11页
A metalloporphyrin-based fluorescent sensor was developed to determine the acid value in frying oil.The electronic and structural performances of iron tetraphenylporphyrin(FeTPP)were theoretically investigated using t... A metalloporphyrin-based fluorescent sensor was developed to determine the acid value in frying oil.The electronic and structural performances of iron tetraphenylporphyrin(FeTPP)were theoretically investigated using time-dependent density functional theory and density functional theory at the B3LYP/LANL2DZ level.The quantified FeTPP-based fluorescent sensor results revealed its excellent performance in discriminating different analytes.In the present work,the acid value of palm olein was determined after every single frying cycle.A total of 10 frying cycles were conducted each day for 10 consecutive days.The FeTPP-based fluorescent sensor was used to quantify the acid value,and the results were compared with the chemical data obtained by conventional titration method.The synchronous fluorescence spectrum for each sample was recorded.Parallel factor analysis was used to decompose the three-dimensional spectrum data.Then,the support vector regression(SVR),partial least squares,and back-propagation artificial neural network methods were applied to build the regression models.After the comparison of the constructed models,the SVR models exhibited the highest correlation coefficients among all models,with 0.9748 and 0.9276 for the training and test sets,respectively.The findings suggested the potential of FeTPP-based fluorescent sensor in rapid monitoring of frying oil quality and perhaps also in other foods with higher oil contents. 展开更多
关键词 Synchronous fluorescence spectrum fluorescent sensor oil quality density functional theory parallel factor analysis
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