Water-related diseases,including diarrhea,are a leading cause of death in children of developing countries.However,they can be prevented and controlled by improving access to safe drinking water and sanitation,
A transition-metal-and oxidant-free amination/cyclization reaction to access 1,2,4-triazolo[1,5-a]pyridines was realized in water by using amino diphenylphosphinate as amino source.A broad array of readily accessible ...A transition-metal-and oxidant-free amination/cyclization reaction to access 1,2,4-triazolo[1,5-a]pyridines was realized in water by using amino diphenylphosphinate as amino source.A broad array of readily accessible N-(pyridyl)amides could be converted into the products featuring a diverse set of functional groups.The sustainable methodology was successfully applied to the late-stage functionalization of natural products and drugs.展开更多
Some oxindoles derivatives are synthesized from the condensation of indoles with isatins in the presence of green and recycable catalyst [(CH2)4SO3HMIM] [HSO4] in water at room temperature.
Organic reactions in water have attracted great attention due to their advantages such as unique reaction performance and environmental friendliness.Organic reactions as well as polymerizations in aqueous media have b...Organic reactions in water have attracted great attention due to their advantages such as unique reaction performance and environmental friendliness.Organic reactions as well as polymerizations in aqueous media have been extensively investigated,and so far,there has been a massive amount of reporting about polymerizations in water.However,reports about click polymerization in water have been rare.Herein,click polymerization of activated alkyne and aromatic amine in aqueous media is developed.The“on water”effect facilitates polymerization in aqueous media better than in organic solvents,and its mechanism is deciphered through experimental data and theoretical calculations.Water participates in the reaction and reduces the energy barrier to some extent.Besides,polymerization makes it possible for aromatic amine with low reactivity to be linked.By using this strategy,polymers with high molecular weights can be obtained in high yields(up to 95.4%).They show good thermal stability and high refractivity.They can be photodegraded.The polymers with tetraphenylethylene moieties show aggregation-induced emission and can be used as materials for generating photopatterns and visualizing agents for specific staining of lysosome in living cells.展开更多
The 595th session of the Xiangshan Science Conferences was recently held in Fragrant Hill Hotel,Beijing,on May 22-23,2017.The theme of this highly successful session was on"Health Risk ad Control of Disinfection By-p...The 595th session of the Xiangshan Science Conferences was recently held in Fragrant Hill Hotel,Beijing,on May 22-23,2017.The theme of this highly successful session was on"Health Risk ad Control of Disinfection By-products(DBPs)in China".More than fifty prominent scientists from Australia,Canada,China,and the United States actively participated in the two-day meeting and engaged in lively discussions.展开更多
The Thirty-Second Workshop on Water Waves and Floating Bodies was held in Dalian from April23-26,2017,and hosted by State Key Laboratory of Coastal and Offshore Engineering,Dalian University of Technology(DUT).IWWWF...The Thirty-Second Workshop on Water Waves and Floating Bodies was held in Dalian from April23-26,2017,and hosted by State Key Laboratory of Coastal and Offshore Engineering,Dalian University of Technology(DUT).IWWWFB2017 attracts over90 participants from 17 countries,in which 65participants from abroad.展开更多
Mosquitoes may be annoying,disease-carrying, blood-sucking pests,but they have a pair of talents that no other animal has:They can both walk up walls and walk on water,and a new study reveals exactly how they manage t...Mosquitoes may be annoying,disease-carrying, blood-sucking pests,but they have a pair of talents that no other animal has:They can both walk up walls and walk on water,and a new study reveals exactly how they manage these circus feats.展开更多
Heteropoly acids efficiently catalyzed the cyclocondensation reaction of anthranilamide with aldehydes in water at ambient temperature and afforded the corresponding 2,3-dihydro-4(1H)-quinazolinones compounds in goo...Heteropoly acids efficiently catalyzed the cyclocondensation reaction of anthranilamide with aldehydes in water at ambient temperature and afforded the corresponding 2,3-dihydro-4(1H)-quinazolinones compounds in good to excellent yields.This method provides mild reaction conditions and clean reaction profiles,using a small quantity of catalyst and a simple workup procedure.展开更多
This paper mainly investigated the value of the rainwater by introducing a “Logic of Encounter” that is a new logic beyond the logos and lemma through the metaphors which compare the real rainwater to one’s life. A...This paper mainly investigated the value of the rainwater by introducing a “Logic of Encounter” that is a new logic beyond the logos and lemma through the metaphors which compare the real rainwater to one’s life. A consideration regarding sustainable rainwater resource utilization has been described and the main results are summarized in the paper.展开更多
In order to clarify how groundwater leakage and river runoff occur in a catchment under tectonic movement, the water balance was estimated in the forested (88.3% in area) Oikamanai River catchment (area, 62.6 km2), Ho...In order to clarify how groundwater leakage and river runoff occur in a catchment under tectonic movement, the water balance was estimated in the forested (88.3% in area) Oikamanai River catchment (area, 62.6 km2), Hokkaido, Japan. The catchment’s geology is early Miocene to Pliocene sedimentary bedrock of partly high permeability, accompanied by currently active faults. Daily evapotranspiration, E, in water balance was calculated by applying the one-layer model to meteorological data in the rainfall season of 2011 and 2012, with the topographic influence on heat balance of the catchment considered. The coupling with the short-term water balance method for river runoff events allows us to estimate groundwater leaking to the other catchments through the faults and bedrock. As a result, the leakage corresponded to 50% - 80% of effective rainfall (=P - E: P, rainfall) in 2011, whereas it was lower or negative in 2012. The estimate of leakage then included variability of ca. 80%. In 2012, shallow groundwater storage seems to retain high baseflow during non-rainfall.展开更多
Although many sensitivity analyses using the soil and water assessment tool(SWAT) in a complex watershed have been conducted, little attention has been paid to the application potential of the model in unique plots. I...Although many sensitivity analyses using the soil and water assessment tool(SWAT) in a complex watershed have been conducted, little attention has been paid to the application potential of the model in unique plots. In addition, sensitivity analysis of percolation and evapotranspiration with SWAT has seldom been undertaken. In this study, SWAT99.2 was calibrated to simulate water balance components for unique plots in Southern China from 2000 to 2001, which included surface runoff, percolation, and evapotranspiration. Twenty-one parameters classified into four categories, including meteorological conditions, topographical characteristics, soil properties, and vegetation attributes, were used for sensitivity analysis through one-at-a-time(OAT) sampling to identify the factor that contributed most to the variance in water balance components. The results were shown to be different for different plots, with parameter sensitivity indices and ranks varying for different water balance components. Water balance components in the broad-leaved forest and natural grass plots were most sensitive to meteorological conditions, less sensitive to vegetation attributes and soil properties, and least sensitive to topographical characteristics. Compared to those in the natural grass plot, water balance components in the broad-leaved forest plot demonstrated higher sensitivity to the maximum stomatal conductance(GSI) and maximum leaf area index(BLAI).展开更多
A unified perturbation theory is developed here for calculating solitary waves of all heights by series expansion of base flow variables in powers of a small base parameter to eighteenth order for the one-parameter fa...A unified perturbation theory is developed here for calculating solitary waves of all heights by series expansion of base flow variables in powers of a small base parameter to eighteenth order for the one-parameter family of solutions in exact form, with all the coefficients determined in rational numbers. Comparative studies are pursued to investigate the effects due to changes of base parameters on (i) the accuracy of the theoretically predicted wave properties and (ii) the rate of convergence of perturbation expansion. Two important results are found by comparisons between the theoretical predictions based on a set of parameters separately adopted for expansion in turn. First, the accuracy and the convergence of the perturbation expansions, appraised versus the exact solution provided by an earlier paper [1] as the standard reference, are found to depend, quite sensitively, on changes in base parameter. The resulting variations in the solution are physically displayed in various wave properties with differences found dependent on which property (e.g. the wave amplitude, speed, its profile, excess mass, momentum, and energy), on what range in value of the base, and on the rank of the order n in the expansion being addressed. Secondly, regarding convergence, the present perturbation series is found definitely asymptotic in nature, with the relative error δ (n) (the relative mean-square difference between successive orders n of wave elevations) reaching a minimum, δm at a specific order, n = n both depending on the base adopted, e.g. nm,α= 11-12 based on parameter α (wave amplitude), nm,δ = 15 on δ (amplitude-speed square ratio), and nm.ε= 17 on ε ( wave number squared). The asymptotic range is brought to completion by the highest order of n = 18 reached in this work.展开更多
A new theory is developed here for evaluating solitary waves on water, with results of high accuracy uniformly valid for waves of all heights, from the highest wave with a corner crest of 120<SUP></SUP> do...A new theory is developed here for evaluating solitary waves on water, with results of high accuracy uniformly valid for waves of all heights, from the highest wave with a corner crest of 120<SUP></SUP> down to very low ones of diminishing height. Solutions are sought for the Euler model by employing a unified expansion of the logarithmic hodograph in terms of a set of intrinsic component functions analytically determined to represent all the intrinsic properties of the wave entity from the wave crest to its outskirts. The unknown coefficients in the expansion are determined by minimization of the mean-square error of the solution, with the minimization optimized so as to take as few terms as needed to attain results as high in accuracy as attainable. In this regard, Stokess formula, F<SUP>2</SUP>= tan , relating the wave speed (the Froude number F) and the logarithmic decrement of its wave field in the outskirt, is generalized to establish a new criterion requiring (for minimizing solution error) the functional expansion to contain a finite power series in M terms of Stokess basic term (singular in ), such that 2M is just somewhat beyond unity, i.e. 2M1. This fundamental criterion is fully validated by solutions for waves of various amplitude-to-water depth ratio =a/h, especially about 0.01, at which M=10 by the criterion. In this pursuit, the class of dwarf solitary waves, defined for waves with 0.01, is discovered as a group of problems more challenging than even the highest wave. For the highest wave, a new solution is determined here to give the maximum height <SUB>hst</SUB>=0.8331990, and speed F<SUB>hst</SUB>=1.290890, accurate to the last significant figure, which seems to be a new record.展开更多
The maneuverability and stealth of aerial-aquatic vehicles(AAVs)is of significant importance for future integrated air-sea combat missions.To improve the maneuverability and stealth of AAVs near the water surface,this...The maneuverability and stealth of aerial-aquatic vehicles(AAVs)is of significant importance for future integrated air-sea combat missions.To improve the maneuverability and stealth of AAVs near the water surface,this paper proposed a high-maneuverability skipping motion strategy for the tandem twin-rotor AAV,inspired by the motion behavior of the flying fish to avoid aquatic and aerial predators near the water surface.The novel tandem twin-rotor AAV was employed as the research subject and a strategybased ADRC control method for validation,comparing it with a strategy-based PID control method.The results indicate that both control methods enable the designed AAV to achieve high stealth and maneuverability near the water surface with robust control stability.The strategy-based ADRC control method exhibits a certain advantage in controlling height,pitch angle,and reducing impact force.This motion strategy will offer an inspiring approach for the practical application of AAVs to some extent.展开更多
Introduced is the regional feature and development plan of Osaka in Japan with statistic at figures. The paper makes an analysis of the meaning of regional architecture with balanced consideration of modern technology...Introduced is the regional feature and development plan of Osaka in Japan with statistic at figures. The paper makes an analysis of the meaning of regional architecture with balanced consideration of modern technology and social development based on its homeland.展开更多
A coupled unsaturated-saturated water flow numerical model was developed. The water flow in the unsaturated zone is considered the one-dimensional vertical flow, which changes in the horizontal direction according to ...A coupled unsaturated-saturated water flow numerical model was developed. The water flow in the unsaturated zone is considered the one-dimensional vertical flow, which changes in the horizontal direction according to the groundwater table and the atmospheric boundary conditions. The groundwater flow is treated as the three-dimensional water flow. The recharge flux to groundwater from soil water is considered the bottom flux for the numerical simulation in the unsaturated zone, and the upper flux for the groundwater simulation. It connects and unites the two separated water flow systems. The soil water equation is solved based on the assumed groundwater table.and the subsequent predicted recharge flux. Then, the groundwater equation is solved with the predicted recharge flux as the upper boundary condition. Iteration continues until the discrepancy between the assumed and calculated groundwater nodal heads have a certain accuracy. Illustrative examples with different water flow scenarios regar.ding the Dirichlet boundary condition, the Neumann boundary condition, the a.tmospheric boundary condition, and the source or sink term were calculated by the coupled model. The results are compared with those of other models, including Hydrus-lD, SWMS-2D, and FEFLOW, which demonstrate that the coupled model is effective and accurate and can significantly reduce the computational time for the large number of nodes in saturated-unsaturated water flow simulation.展开更多
文摘Water-related diseases,including diarrhea,are a leading cause of death in children of developing countries.However,they can be prevented and controlled by improving access to safe drinking water and sanitation,
基金financial support from the National Natural Science Foundation of China(No.82003585)the Program for Science&Technology Innovation Talents in Universities of Henan Province(No.24HASTIT069)+5 种基金the Technical Innovation Team of Henan Normal University(No.2022TD03)the Special Project for Fundamental Research in University of Henan Province(No.23ZX009)the Henan Science and Technology Program(No.232102310364)the Key Project of Henan Educational Committee(No.22A150041)Excellent Youth Foundation of Henan Scientific Committee(No.222300420012)the Young Core Instructor Training Program of Xinyang Agriculture and Forestry University(2023)。
文摘A transition-metal-and oxidant-free amination/cyclization reaction to access 1,2,4-triazolo[1,5-a]pyridines was realized in water by using amino diphenylphosphinate as amino source.A broad array of readily accessible N-(pyridyl)amides could be converted into the products featuring a diverse set of functional groups.The sustainable methodology was successfully applied to the late-stage functionalization of natural products and drugs.
文摘Some oxindoles derivatives are synthesized from the condensation of indoles with isatins in the presence of green and recycable catalyst [(CH2)4SO3HMIM] [HSO4] in water at room temperature.
基金supported by the National Natural Science Foundation of China(grant nos.21788102 and 22101028)the Research Grants Council of Hong Kong(grant nos.16304819,16305320,and C6014-20W)+3 种基金the Innovation and Technology Commission(grant no.ITC-CNERC14SC01)the Natural Science Foundation of Guangdong Province(grant no.2019B121205002)the China Postdoctoral Science Foundation(grant no.2021M691414)the Scientific and Technological Innovation Team of Shaanxi Province(grant no.2022TD-36).
文摘Organic reactions in water have attracted great attention due to their advantages such as unique reaction performance and environmental friendliness.Organic reactions as well as polymerizations in aqueous media have been extensively investigated,and so far,there has been a massive amount of reporting about polymerizations in water.However,reports about click polymerization in water have been rare.Herein,click polymerization of activated alkyne and aromatic amine in aqueous media is developed.The“on water”effect facilitates polymerization in aqueous media better than in organic solvents,and its mechanism is deciphered through experimental data and theoretical calculations.Water participates in the reaction and reduces the energy barrier to some extent.Besides,polymerization makes it possible for aromatic amine with low reactivity to be linked.By using this strategy,polymers with high molecular weights can be obtained in high yields(up to 95.4%).They show good thermal stability and high refractivity.They can be photodegraded.The polymers with tetraphenylethylene moieties show aggregation-induced emission and can be used as materials for generating photopatterns and visualizing agents for specific staining of lysosome in living cells.
文摘The 595th session of the Xiangshan Science Conferences was recently held in Fragrant Hill Hotel,Beijing,on May 22-23,2017.The theme of this highly successful session was on"Health Risk ad Control of Disinfection By-products(DBPs)in China".More than fifty prominent scientists from Australia,Canada,China,and the United States actively participated in the two-day meeting and engaged in lively discussions.
文摘The Thirty-Second Workshop on Water Waves and Floating Bodies was held in Dalian from April23-26,2017,and hosted by State Key Laboratory of Coastal and Offshore Engineering,Dalian University of Technology(DUT).IWWWFB2017 attracts over90 participants from 17 countries,in which 65participants from abroad.
文摘Mosquitoes may be annoying,disease-carrying, blood-sucking pests,but they have a pair of talents that no other animal has:They can both walk up walls and walk on water,and a new study reveals exactly how they manage these circus feats.
基金the financial support of Key Laboratory of Resources and Environment Chemistry of West China(No.XZ0704).
文摘Heteropoly acids efficiently catalyzed the cyclocondensation reaction of anthranilamide with aldehydes in water at ambient temperature and afforded the corresponding 2,3-dihydro-4(1H)-quinazolinones compounds in good to excellent yields.This method provides mild reaction conditions and clean reaction profiles,using a small quantity of catalyst and a simple workup procedure.
文摘This paper mainly investigated the value of the rainwater by introducing a “Logic of Encounter” that is a new logic beyond the logos and lemma through the metaphors which compare the real rainwater to one’s life. A consideration regarding sustainable rainwater resource utilization has been described and the main results are summarized in the paper.
文摘In order to clarify how groundwater leakage and river runoff occur in a catchment under tectonic movement, the water balance was estimated in the forested (88.3% in area) Oikamanai River catchment (area, 62.6 km2), Hokkaido, Japan. The catchment’s geology is early Miocene to Pliocene sedimentary bedrock of partly high permeability, accompanied by currently active faults. Daily evapotranspiration, E, in water balance was calculated by applying the one-layer model to meteorological data in the rainfall season of 2011 and 2012, with the topographic influence on heat balance of the catchment considered. The coupling with the short-term water balance method for river runoff events allows us to estimate groundwater leaking to the other catchments through the faults and bedrock. As a result, the leakage corresponded to 50% - 80% of effective rainfall (=P - E: P, rainfall) in 2011, whereas it was lower or negative in 2012. The estimate of leakage then included variability of ca. 80%. In 2012, shallow groundwater storage seems to retain high baseflow during non-rainfall.
基金supported by the National Natural Science Foundation of China(Grants No.51569007 and 41301289)the Natural Science Foundation of Guangxi Province,China(Grant No.2015GXNSFCA139004)+1 种基金the Fund of the IRCK by UNESCO(Grant No.KDL201601)the Project of High Level Innovation Team and Outstanding Scholar in Guangxi Colleges and Universities(Grant No.002401013001)
文摘Although many sensitivity analyses using the soil and water assessment tool(SWAT) in a complex watershed have been conducted, little attention has been paid to the application potential of the model in unique plots. In addition, sensitivity analysis of percolation and evapotranspiration with SWAT has seldom been undertaken. In this study, SWAT99.2 was calibrated to simulate water balance components for unique plots in Southern China from 2000 to 2001, which included surface runoff, percolation, and evapotranspiration. Twenty-one parameters classified into four categories, including meteorological conditions, topographical characteristics, soil properties, and vegetation attributes, were used for sensitivity analysis through one-at-a-time(OAT) sampling to identify the factor that contributed most to the variance in water balance components. The results were shown to be different for different plots, with parameter sensitivity indices and ranks varying for different water balance components. Water balance components in the broad-leaved forest and natural grass plots were most sensitive to meteorological conditions, less sensitive to vegetation attributes and soil properties, and least sensitive to topographical characteristics. Compared to those in the natural grass plot, water balance components in the broad-leaved forest plot demonstrated higher sensitivity to the maximum stomatal conductance(GSI) and maximum leaf area index(BLAI).
基金The project partly supported by the National Natural Science Foundation of China(19925414,10474045)
文摘A unified perturbation theory is developed here for calculating solitary waves of all heights by series expansion of base flow variables in powers of a small base parameter to eighteenth order for the one-parameter family of solutions in exact form, with all the coefficients determined in rational numbers. Comparative studies are pursued to investigate the effects due to changes of base parameters on (i) the accuracy of the theoretically predicted wave properties and (ii) the rate of convergence of perturbation expansion. Two important results are found by comparisons between the theoretical predictions based on a set of parameters separately adopted for expansion in turn. First, the accuracy and the convergence of the perturbation expansions, appraised versus the exact solution provided by an earlier paper [1] as the standard reference, are found to depend, quite sensitively, on changes in base parameter. The resulting variations in the solution are physically displayed in various wave properties with differences found dependent on which property (e.g. the wave amplitude, speed, its profile, excess mass, momentum, and energy), on what range in value of the base, and on the rank of the order n in the expansion being addressed. Secondly, regarding convergence, the present perturbation series is found definitely asymptotic in nature, with the relative error δ (n) (the relative mean-square difference between successive orders n of wave elevations) reaching a minimum, δm at a specific order, n = n both depending on the base adopted, e.g. nm,α= 11-12 based on parameter α (wave amplitude), nm,δ = 15 on δ (amplitude-speed square ratio), and nm.ε= 17 on ε ( wave number squared). The asymptotic range is brought to completion by the highest order of n = 18 reached in this work.
文摘A new theory is developed here for evaluating solitary waves on water, with results of high accuracy uniformly valid for waves of all heights, from the highest wave with a corner crest of 120<SUP></SUP> down to very low ones of diminishing height. Solutions are sought for the Euler model by employing a unified expansion of the logarithmic hodograph in terms of a set of intrinsic component functions analytically determined to represent all the intrinsic properties of the wave entity from the wave crest to its outskirts. The unknown coefficients in the expansion are determined by minimization of the mean-square error of the solution, with the minimization optimized so as to take as few terms as needed to attain results as high in accuracy as attainable. In this regard, Stokess formula, F<SUP>2</SUP>= tan , relating the wave speed (the Froude number F) and the logarithmic decrement of its wave field in the outskirt, is generalized to establish a new criterion requiring (for minimizing solution error) the functional expansion to contain a finite power series in M terms of Stokess basic term (singular in ), such that 2M is just somewhat beyond unity, i.e. 2M1. This fundamental criterion is fully validated by solutions for waves of various amplitude-to-water depth ratio =a/h, especially about 0.01, at which M=10 by the criterion. In this pursuit, the class of dwarf solitary waves, defined for waves with 0.01, is discovered as a group of problems more challenging than even the highest wave. For the highest wave, a new solution is determined here to give the maximum height <SUB>hst</SUB>=0.8331990, and speed F<SUB>hst</SUB>=1.290890, accurate to the last significant figure, which seems to be a new record.
基金supported by Southern Marine Science and Guangdong Laboratory(Zhuhai)(Grant No.SML2023SP229)。
文摘The maneuverability and stealth of aerial-aquatic vehicles(AAVs)is of significant importance for future integrated air-sea combat missions.To improve the maneuverability and stealth of AAVs near the water surface,this paper proposed a high-maneuverability skipping motion strategy for the tandem twin-rotor AAV,inspired by the motion behavior of the flying fish to avoid aquatic and aerial predators near the water surface.The novel tandem twin-rotor AAV was employed as the research subject and a strategybased ADRC control method for validation,comparing it with a strategy-based PID control method.The results indicate that both control methods enable the designed AAV to achieve high stealth and maneuverability near the water surface with robust control stability.The strategy-based ADRC control method exhibits a certain advantage in controlling height,pitch angle,and reducing impact force.This motion strategy will offer an inspiring approach for the practical application of AAVs to some extent.
文摘Introduced is the regional feature and development plan of Osaka in Japan with statistic at figures. The paper makes an analysis of the meaning of regional architecture with balanced consideration of modern technology and social development based on its homeland.
基金supported by the National Basic Research Program of China (Grant No. 2010CB428802)Scholarship Award for Excellent Doctoral Students granted by Ministry of Education+1 种基金the Fundamental Research Funds for the Central Universitiesthe Ph. D. Candidates' Self-research Program of Wuhan University in 2008
文摘A coupled unsaturated-saturated water flow numerical model was developed. The water flow in the unsaturated zone is considered the one-dimensional vertical flow, which changes in the horizontal direction according to the groundwater table and the atmospheric boundary conditions. The groundwater flow is treated as the three-dimensional water flow. The recharge flux to groundwater from soil water is considered the bottom flux for the numerical simulation in the unsaturated zone, and the upper flux for the groundwater simulation. It connects and unites the two separated water flow systems. The soil water equation is solved based on the assumed groundwater table.and the subsequent predicted recharge flux. Then, the groundwater equation is solved with the predicted recharge flux as the upper boundary condition. Iteration continues until the discrepancy between the assumed and calculated groundwater nodal heads have a certain accuracy. Illustrative examples with different water flow scenarios regar.ding the Dirichlet boundary condition, the Neumann boundary condition, the a.tmospheric boundary condition, and the source or sink term were calculated by the coupled model. The results are compared with those of other models, including Hydrus-lD, SWMS-2D, and FEFLOW, which demonstrate that the coupled model is effective and accurate and can significantly reduce the computational time for the large number of nodes in saturated-unsaturated water flow simulation.