Transient pressure analysis of polymer flooding fractured wells with oil-water two-phase flow

The oil-water two-phase flow pressure-transient analysis model for polymer flooding fractured well is established by considering the comprehensive effects of polymer shear thinning,shear thickening,convection,diffusion,adsorption retention,inaccessible pore volume and effective permeability reduction.The finite volume difference and Newton iteration methods are applied to solve the model,and the effects of fracture conductivity coefficient,injected polymer mass concentration,initial polymer mass concentration and water saturation on the well-test type curves of polymer flooding fractured wells are discussed.The results show that with the increase of fracture conductivity coefficient,the pressure conduction becomes faster and the pressure drop becomes smaller,so the pressure curve of transitional flow goes downward,the duration of bilinear flow becomes shorter,and the linear flow appears earlier and lasts longer.As the injected polymer mass concentration increases,the effective water phase viscosity increases,and the pressure loss increases,so the pressure and pressure derivative curves go upward,and the bilinear flow segment becomes shorter.As the initial polymer mass concentration increases,the effective water phase viscosity increases,so the pressure curve after the wellbore storage segment moves upward as a whole.As the water saturation increases,the relative permeability of water increases,the relative permeability of oil decreases,the total oil-water two-phase mobility becomes larger,and the pressure loss is reduced,so the pressure curve after the wellbore storage segment moves downward as a whole.The reliability and practicability of this new model are verified by the comparison of the results from simplified model and commercial well test software,and the actual well test data.

Pressure transient characteristics of non-uniform conductivity fractured wells in viscoelasticity polymer flooding based on oil-water two-phase flow

Polymer flooding in fractured wells has been extensively applied in oilfields to enhance oil recovery.In contrast to water,polymer solution exhibits non-Newtonian and nonlinear behavior such as effects of shear thinning and shear thickening,polymer convection,diffusion,adsorption retention,inaccessible pore volume and reduced effective permeability.Meanwhile,the flux density and fracture conductivity along the hydraulic fracture are generally non-uniform due to the effects of pressure distribution,formation damage,and proppant breakage.In this paper,we present an oil-water two-phase flow model that captures these complex non-Newtonian and nonlinear behavior,and non-uniform fracture characteristics in fractured polymer flooding.The hydraulic fracture is firstly divided into two parts:high-conductivity fracture near the wellbore and low-conductivity fracture in the far-wellbore section.A hybrid grid system,including perpendicular bisection(PEBI)and Cartesian grid,is applied to discrete the partial differential flow equations,and the local grid refinement method is applied in the near-wellbore region to accurately calculate the pressure distribution and shear rate of polymer solution.The combination of polymer behavior characterizations and numerical flow simulations are applied,resulting in the calculation for the distribution of water saturation,polymer concentration and reservoir pressure.Compared with the polymer flooding well with uniform fracture conductivity,this non-uniform fracture conductivity model exhibits the larger pressure difference,and the shorter bilinear flow period due to the decrease of fracture flow ability in the far-wellbore section.The field case of the fall-off test demonstrates that the proposed method characterizes fracture characteristics more accurately,and yields fracture half-lengths that better match engineering reality,enabling a quantitative segmented characterization of the near-wellbore section with high fracture conductivity and the far-wellbore section with low fracture conductivity.The novelty of this paper is the analysis of pressure performances caused by the fracture dynamics and polymer rheology,as well as an analysis method that derives formation and fracture parameters based on the pressure and its derivative curves.

Stylistic Analysis on English On-line Chat

Based on the fact that on-line chat has become the most developing language form in the information age, this article point out the stylistic features of on-line English chat. Though in written language form, such language is spoken language in nature, thus it is worthwhile to analyze this special phaenomenon in lexical and grammatical level.

A New Dinuclear Zinc Polymer Based on 3-Methoxy-2-hydroxybenzaldehyde:Synthesis,Structure,Spectral Characterization and Hirshfeld Surface Analysis

A highly efficient fluorescence material dinuclear zinc polymer [Zn2（mhbd）2（dca）2]n （1, Hmhbd is 3-methoxy-2-hydroxybenzaldehyde, dca is N（CN）2？） has been synthesized under room temperature and structurally characterized by elemental analysis, IR, and single-crystal X-ray diffraction. The structure belongs to the triclinic system, space group P with a = 8.475（1）, b = 9.595（1）, c = 15.001（1） A, α = 86.84（1）, β = 81.10（1）, γ = 68.78（1）°, Mr = 565.15, V = 1123.5（1） ？3, Dc = 1.671 g？cm–3, F（000） = 568, μ = 2.185 mm–1, R = 0.0451, and wR = 0.1297. 1 is a dinuclear zinc complex which further constructs a 1D chain through double μ1,5-dca bridge. Luminescent property and Hirshfeld surface analysis of 1 have been studied. The result indicates that the fluorescence intensity of complex 1 is forty-one times the fluorescence intensity of Hmhbd ligand.

An Investigation of the Dimensional Changes of Polymer Mixture Tablets Containing a Soluble Drug, Using an Image Analysis Method. Influence of These Characteristics on Drug Release and Its Mechanism

The properties and characteristics of the polymer used for the preparation of matrix drug delivery systems considerably influence their performance and the extent of drug release and its mechanism. The objective of this research was to examine the dimensional changes, and gel evolution of polymer matrices consisting of three different polymers Polyox, sodium alginate (hydrophilic) and Ethocel (hydrophobic), using an image analysis method. Furthermore to explore how these changes influence the release rate of a soluble drug namely, venlafaxine. All tablets displayed marked dimensional expansion and gel growth particularly those consisting of two hydrophilic polymers Polyox/sodium alginate (POL/SA/V) compared to those consisting of the hydrophilic/hydrophobic Polyox/Ethocel (POL/ET/V). Similarly the thickness of the gel layer in POL/SA/V matrices increased considerably with time up to 8 hours. In general our findings show that the POL/SA/V matrices, due to their thicker gel layer produced a more effective barrier which results in a more pronounced sustained release delivery. This accounts for the slower and smaller overall drug release observed with the POL/SA/V matrices compared to those containing POL/ET/V and indicates that the formation of a thick and durable gel barrier is a characteristic necessary for the preparation of sustained drug release systems. Moreover the solubility of venlafaxine in combination with the polymer’s properties appears to play an important role on the extent of drug release and the release mechanism. Overall the polymer mixtures examined comprise a useful and promising combination of materials for the development and manufacture of sustained release preparations based on these polymers.

On-line Batch Process Monitoring and Diagnosing Based on Fisher Discriminant Analysis

A new on-line batch process monitoring and diagnosing approach based on Fisher discriminant analysis （FDA） was proposed. This method does not need to predict the future observations of variables, so it is more sensitive to fault detection and stronger implement for monitoring. In order to improve the monitoring performance, the variables trajectories of batch process are separated into several blocks. The key to the proposed approach for on-line monitoring is to calculate the distance of block data that project to low-dimension Fisher space between new batch and reference batch. Comparing the distance with the predefine threshold, it can be considered whether the batch process is normal or abnormal. Fault diagnosis is performed based on the weights in fault direction calculated by FDA. The proposed method was applied to the simulation model of fed-batch penicillin fermentation and the resuits were compared with those obtained using MPCA. The simulation results clearly show that the on-line monitoring method based on FDA is more efficient than the MPCA.

THE DEGREE OF CRYSTALLINITY OF MULTICOMPONENT POLYMERS BY X-RAY DIFFRACTION ANALYSIS

Based on the X-ray scattering intensity theory,the correction factors of the degree of crystallinity formulae of the multicomponent polymers have been clearly defined.The formula of degree of erystallinity of the multicomponent polymers was derived in terms of the WAXD theory ahd improved graphic multipeak resolution methods.The results calculated are compatible with the density measurement.

Mechanics Analysis of Overhead Transmission Lines Based On-line Monitoring

At present, the on-line monitoring is widely applied to the power line monitoring. In this paper, a new mechanical calculation model is established according to the on-line monitoring. And this model is based on the parameters that tension sensors and angle sensors on suspended points detect, and combines with the parameters of the wire itself, and also considers the deflection angel of wires due to wind. In this model, mechanics parameters of wires are turned into the new coordinate plane after deflection angel of wires due to wind, or windage yaw plane. A statics tension balance equation is built in the vertical direction of the new windage yaw plane. According to the theoretical analysis and algorithm, we verify the accuracy of this newly developed mechanical calculation model.

Characterization by Thermogravimetric Analysis of Polymeric Concrete with High Density Polyethylene Mechanically Recycled

This paper presents the results of the characterization by thermogravimetric analysis of a new composite material called polymeric concrete. The polymeric concrete contains micro-particles obtained from High Density Poly-Ethylene (HDPE) mechanically recycled (post-consumer bottles);the official Mexican standard NMX-E-232-SCFI-1999 considers the HDPE as the recyclable plastic material. Thermo-grams based on weight lost were obtained from the raw material (HDPE) and the polymer concrete in order to obtain the glass transition temperature (Tg) and melting temperature (Tf). The analysis conditions were defined from 20°C to 180°C and the heat rate of 1°C/minute. The results show that the glass transition temperature of polymeric concrete is 46°C and the HDPE is 38°C. These results mean that the polymeric concrete is more resistant to decomposition. With respect to the melting temperature, the results show that the 2°C difference between polymeric concrete and HDPE is not significant. The polymeric concrete with HDPE recycled can be considered as composite material thermoplastic. The new material melts when it is heated to 146°C and has the ability to be softened, processed and reprocessed with temperature and pressure changes, which make it possible to obtain molded pieces in the desired shape.

Research on the Teaching Reform of Polymer Materials Foundation Course-Based on the Case Analysis Method

In today's education and teaching reform,the traditional teaching method in the teaching of polymer materials has been gradually replaced with various new teaching methods.Among them,the case analysis method is a very efective teaching method,which has been applied to the teaching of polymer materials.Through example-based teaching,students 125 participation can be effectively improved,and their theoretical knowledge can be fully utilized.This would have a positive role in promoting the improvement of students'knowledge system and their learning ability.In regard to this,this article analyzes the application of case analysis in the teaching of polymer materials so as to improve its efficiency and quality.

Durability Testing of Composite Aerospace Materials Based on a New Polymer Carbon Fiber-Reinforced Epoxy Resin

In this study,the durability of a new polymer carbonfiber-reinforced epoxy resin used to produce composite material in the aerospacefield is investigated through analysis of the corrosion phenomena occurring at the microscopic scale,and the related infrared spectra and thermal properties.It is found that light and heat can con-tribute to the aging process.In particular,the longitudinal tensile strength displays a non-monotonic trend,i.e.,itfirst increases and then decreases over time.By contrast,the longitudinal compressive and inter-laminar shear strengths do not show significant changes.It is also shown that the inter-laminar shear strength of carbonfiber/epoxy resin composites with inter-laminar hybrid structure is better than that of pure carbonfiber materials.The related resistance to corrosion can be improved by more than 41%.

Multi-objective optimization of the cathode catalyst layer micro-composition of polymer electrolyte membrane fuel cells using a multi-scale,two-phase fuel cell model and data-driven surrogates

Polymer electrolyte membrane fuel cells(PEMFCs)are considered a promising alternative to internal combustion engines in the automotive sector.Their commercialization is mainly hindered due to the cost and effectiveness of using platinum(Pt)in them.The cathode catalyst layer(CL)is considered a core component in PEMFCs,and its composition often considerably affects the cell performance(V_(cell))also PEMFC fabrication and production(C_(stack))costs.In this study,a data-driven multi-objective optimization analysis is conducted to effectively evaluate the effects of various cathode CL compositions on Vcelland Cstack.Four essential cathode CL parameters,i.e.,platinum loading(L_(Pt)),weight ratio of ionomer to carbon(wt_(I/C)),weight ratio of Pt to carbon(wt_(Pt/c)),and porosity of cathode CL(ε_(cCL)),are considered as the design variables.The simulation results of a three-dimensional,multi-scale,two-phase comprehensive PEMFC model are used to train and test two famous surrogates:multi-layer perceptron(MLP)and response surface analysis(RSA).Their accuracies are verified using root mean square error and adjusted R^(2).MLP which outperforms RSA in terms of prediction capability is then linked to a multi-objective non-dominated sorting genetic algorithmⅡ.Compared to a typical PEMFC stack,the results of the optimal study show that the single-cell voltage,Vcellis improved by 28 m V for the same stack price and the stack cost evaluated through the U.S department of energy cost model is reduced by$5.86/k W for the same stack performance.

Flow Injection Analysis Technique for Online Preconcentration of Lead Ions in Airborne Particulate Matter Using Imprinted Polymer as the Sorbent

This work reported a simple and sensitive flow injection analysis(FIA)technique coupled with a Flame Atomic Absorption Spectrophotometer(FAAS)for online preconcentration of lead(Ⅱ)ions in the airborne particulate matter samples(PM_(2.5))using ion-imprinted polymers as adsorbent packed in minicolumn.A bulk polymerization method was chosen to synthesize the polymer based on a ternary complex of lead ions with 4-2-pyridilazo resorcinol and 4-vinyl pyridine with methacrylic acid as a functional monomer.The optimum pH for sorption was 6,and other variables for the FIA system were optimized,including breakthrough volume,eluent concentration,and eluent volume.The optimum conditions were reached with a breakthrough volume of 4.45 mL,calculated as a dynamic retention capacity of 5.20 mg/g of Pb(II)40 mg/L,with a 1.5 mL/min flow rate.The eluent used for the FIA system was 0.5 mL HNO_(3)of 3 mol/L.Linearity,precision,and limits of detection of the FIA system were determined before being applied to preconcentration and analysis of lead ions in PM_(2.5)samples.The precision of the method was determined to be 3.09%by calculating the coefficients of the variant.Linearity of the method in the concentration range of 50-1000μg/L gave a coefficient correlation of 0.9925,showing a good response,and the limit of detection of the system was 5.11μg/L,better than that of the FAAS method.Performances of the FIA system were evaluated and showed good results with an enrichment factor of more than 20 times higher and a concentration efficiency of 11.65 min^(-1)with a consumptive index of 4.5 mL.Preconcentration and analysis of the PM_(2.5)samples in Bandung City showed the concentrations of Pb(II)were 26.67μg/L and 33.3μg/L with the accuracy of the method for each sample of104.75%and 107.86%.

Improvement on On-line Ferrograph Image Identification

A newly developed on-line visual ferrograph（OLVF） gives a new way for engine wear state monitoring. However, the reliability of on-line wear debris image processing is challenged in both monitoring ship engines and the Caterpillar bench test, which weren＇t reported in previous studies. Two problems were encountered in monitoring engines and processing images. First, small wear debris becomes hard to be identified from the image background after monitoring for a period of time. Second, the identification accuracy for wear debris is greatly reduced by background noise because of oil getting dark after nmning a period of time. Therefore, the methods adopted in image processing are examined. Two main reasons for the problems in wear debris identification are generalized as follows. Generally, the binary threshold was determined by global image pixels, and was easily affected by the non-objective zone in the image. The boundary of the objective zone in the binary image was misrecognized because of oil color becoming lighter during monitoring. Accordingly, improvements were made as follows. The objective zone in a global binary image was identified by scanning a column of pixels, and then a secondary binary process confined in the objective zone was carried out to identify small wear debris. Linear filtering with a specific template was used to depress noise in a binary image, and then a low-pass filtering was performed to eliminate the residual noise. Furthermore, the morphology parameters of single wear debris were extracted by separating each wear debris by a gray stack, and two indexes, WRWR （relative wear rate） and WRWS （relative wear severity）, were proposed for wear description. New indexes were provided for on-line monitoring of engines.

Synthesis, Crystal Structure and Electrochemical Properties of a One-dimensional Chain Coordination Polymer [Cu(phen)(2,4,6-TMBA)_2(H_2O)]_n

A one-dimensional chain coordination polymer [Cu（phen）（2,4,6-TMBA）2（H2O）]n has been synthesized by reacting 2,4,6-trimethyl-benzoic acid, 1,10-phenanthroline and Cu（Ⅱ） perchlorate and its structure was characterized. Crystal data for this complex： tetragonal, space group I41, a = 2.0293（3）, b = 2.0293（3）, c = 1.3758（2） nm, α =β= γ = 90°, V= 5.6657（13） nm3, Dc= 1.379 g/cm3, Z = 8, μ（MoKa） = 0.815 mm-1, Mr = 588.14, F（000） = 2456, S = 1.047, R = 0.0459 and wR = 0.1053. The crystal structure shows that two neighboring Cu（Ⅱ） ions are linked together by one bridging-chelating 2,4,6-trimethyl-benzoic group, forming a one-dimensional chain structure. Each Cu（Ⅱ） ion is coordinated with two nitrogen atoms from one 1,10-phenanthroline molecule, three oxygen atoms from three 2,4,6-trimethyl-benzoic acid molecules and one oxygen atom from one water molecule, giving a six-coordinate distorted octahedral coordination geometry. The cyclic voltammetry behavior of the complex was also investigated.

Micro Model of Carbon Fiber/Cyanate Ester Composites and Analysis of Machining Damage Mechanism

Machining damage occurs on the surface of carbon fiber reinforced polymer (CFRP) composites during processing. In the current simulation model of CFRP, the initial defects on the carbon fiber and the periodic random distribution of the reinforcement phase in the matrix are not considered in detail, which makes the characteristics of the cutting model significantly different from the actual processing conditions. In this paper, a novel three-phase model of carbon fiber/cyanate ester composites is proposed to simulate the machining damage of the composites. The periodic random distribution of the carbon fiber reinforced phase in the matrix was realized using a double perturbation algorithm. To achieve the stochastic distribution of the strength of a single carbon fiber, a novel method that combines the Weibull intensity distribution theory with the Monte Carlo method is presented. The mechanical properties of the cyanate matrix were characterized by fitting the stress-strain curves, and the cohesive zone model was employed to simulate the interface. Based on the model, the machining damage mechanism of the composites was revealed using finite element simulations and by conducting a theoretical analysis. Furthermore, the milling surfaces of the composites were observed using a scanning electron microscope, to verify the accuracy of the simulation results. In this study, the simulations and theoretical analysis of the carbon fiber/cyanate ester composite processing were carried out based on a novel three-phase model, which revealed the material failure and machining damage mechanism more accurately.

Automatic analytical approach for the determination of 12 illicit drugs and nicotine metabolites in wastewater using on-line SPE-UHPLC-MS/MS

In this study,we developed a novel on-line solid phase extraction(SPE)-ultra-high-performance liquid chromatography tandem mass spectrometry(UHPLC-MS/MS)-based analytical method for simultaneously quantifying 12 illicit drugs and metabolites(methamphetamine,amphetamine,morphine,codeine,6-monoacetylmorphine,benzoylecgonine,3,4-methylenedioxymethamphetamine,3,4-methylenedioxyamphetamine,cocaine,ketamine,norketamine,and methcathinone)and cotinine(COT)in wastewater samples.The analysis was performed by loading 2 m L of the sample onto an Oasis hydrophilic-lipophilic balance cartridge and using a cleanup step(5%methanol)to eliminate interference with a total run time of 13 min.The isotope-labeled internal standard method was used to quantify the target substances and correct for unavoidable losses and matrix effects during the on-line SPE process.Typical analytical characteristics used for method validation were sensitivity,linearity,precision,repeatability,recovery,and matrix effects.The limit of detection(LOD)and limit of quantification(LOQ)of each target were set at 0.20 ng/L and 0.50 ng/L,respectively.The linearity was between 0.5 ng/L and250 ng/L,except for that of COT.The intra-and inter-day precisions were<10.45%and 25.64%,respectively,and the relative recovery ranged from 83.74%to 162.26%.The method was used to analyze various wastewater samples from 33 cities in China,and the results were compared with the experimental results of identical samples analyzed using off-line SPE.The difference rate was between 19.91%and-20.44%,and the error range could be considered acceptable.These findings showed that on-line SPE is a suitable alternative to off-line SPE for the analysis of illicit drugs in samples.

A Novel Three-dimensional(4,4)-Connected Coordination Polymer Based on Benzotriazole and Thiophene-2,5-dicarboxylic Acid： Synthesis, Crystal Structure,and Luminescence Properties

A novel coordination polymer [Zn2（BTA）2（TDC）]n（HBTA = benzotriazole, H2TDC = thiophene-2,5-dicarboxylic acid） has been synthesized by the reaction of zinc（Ⅱ）, H2TDC and HBTA. This compound is fully structurally characterized by elemental analysis, IR, and single-crystal X-ray crystallography. The bulk new materials were further identified by X-ray powder diffraction. Compound 1 crystallizes in the orthorhombic system, space group Pbcn, with a = 9.8825（8）, b = 9.4047（8）, c = 20.5567（17） , V = 1910.6（3） -3, C（18）H（10）N6O4SZn2, Mr = 537.12, Dc = 1.867 g/cm-3, μ（MoK α） = 2.662 mm-（-1）, F（000） = 1072, Z = 4, S = 1.058, the final R = 0.0201 and w R = 0.0530 for 1700 observed reflections（I 2σ（I））. Its compositional stability and photoluminescence properties were further investigated to establish the structure-property relationships. Structural analysis reveals that this compound is a 3D（4, 4）-connected framework with the（6-6）（6-4·8-2） topology.

Synthesis,Crystal Structure and Thermal Stability Properties of a Binuclear Copper(Ⅱ) Coordination Polymer {[Cu_2(4,4'-bipy)_2(o-ABA)_4(H_2O)_2][(H_2O)_2]}_n

One-dimensional chain copper（Ⅱ） coordination polymer has been synthesized and characterized in the solvent mixture of water and alcohol with o-acetamidobenzoic acid,4,4＇-bipyridine and copper perchlorate.It is of tetragonal,space group P41212 with a=1.57756（10）,b= 1.57756（10）,c=2.1438（3）nm,V=5.3352（8） nm^3,Dc=1.524 g/cm^3,Z=4,F（000）=2536,R= 0.0479 and wR=0.0979.The crystal structure shows two coordination modes.The copper（1） is coordinated with two nitrogen atoms of one 4,4＇-bipyridine molecule and two oxygen atoms from two o-acetamidobenzoic acid molecules,forming a distorted tetrahedral coordination geometry; the copper（2） is coordinated with two nitrogen atoms of one 4,4＇-bipyridine molecule,four oxygen atoms from two o-acetamidobenzoic acid molecules and two water molecules,generating a distorted octahedral coordination geometry.The result of TG analysis shows that the title complex is stable below 180.0 ℃.

Physicochemical and Thermal Characterization of Dura Palm Kernel Powder as a Load for Polymers: Case of Polyvinyl Chloride

This work presents the physical and thermal characterization of the dura palm kernel powder of Cameroon for their use as fillers for polymers composites. The powders of palm kernel were obtained using a percussion grinder mill with an industrial microniser which allowed obtaining a powder less than 50 μm with an apparent density between 0,505 ≤ ρ ≤ 0,680 g/cm3 at 1.56 of relative humidity. The infrared of the powder of palm kernel shows the presence of phenols groups with a large band around 3341 cm-1, -C-H at 2917.02 cm-1 and -C-O at 1040 cm-1 as the main peaks. The polyvinyl chloride of infrared obtained shows the presence of -C-Cl, -CH2 and CH as the mains peaks. The infrared of 12.5% of palm kernel powder with polyvinyl chloride shows an increase of the CH2 and CH bonds and a decrease of the -OH bonds. Thermogravimetric analysis and differential scanning calorimetric analysis of powders, polyvinyl chloride and mixture showed that the mixing powders are intermediate between the polyvinyl chloride and palm kernel powder. The powder decreased the phase temperatures of the mixture from 98.58℃ to 95℃ for the glass transition temperature and from 515℃ to 459℃ for the crystallization temperature. The thermogravimetric curves of palm kernel powder and polyvinyl chloride have showed that these materials lose their different masses in three different phases, and the one of composite (mixture of polyvinyl chloride with 12.5% of palm kernel powder) in two different phases.