Theory analysis and experimental research on on-line contamination detecting technology in hydraulic oil

A system of on-line contamination detecting in hydraulic oil based on silting principle is accomplished, where, metal filter membrane as detector, solenoid as active force to propel piston to blotter and gain differential pressure, step motor drives the membrane to filtrate and counter-flush, LabVIEW as detecting software platform, oil's contamination detecting indirectly by gauging differential pressure. Based on theory analysis, accomplished is relation between contamination level and differential pressure, realizing polynomial curve fitting, and calibration experiment. Field experiment is simulated in the condition of experimental laboratory, has credible precision and real-time performance, which can popularize to the field of production.

On-line Chatter Detection Using an Improved Support Vector Machine

On-line chatter detection can avoid unstable cutting through monitoring the machining process.In order to identify chatter in a timely manner,an improved Support Vector Machine(SVM)is developed in this paper,based on extracted features.In the SVM model,the penalty factor(e)and the core parameter(g)have important influence on the classification,more than from Kernel Functions(KFs).Hence,first the classification results are conducted using different KFs.Then two methods are presented for exploring the best parameters.The chatter identification results show that the Genetic Algorithm(GA)approach is more suitable for deciding the parameters than the Grid Explore(GE)approach.

On-Line Detection of EDM Spark Locations Using Potential Difference Method

The valuation relation of potential difference with discharging time in Electrical Discharge Machining (EDM) is analyzed theoretically and tested and verified by experiments designed in this paper and the relation between potential difference and spark location is induced and analyzed, and proceed by experiments under the condition of onedimension.

PRECONCENTRATION OF TRACE ZINC IN SEAWATER ON CPPI RESIN BY FIA AND ON-LINE DETECTION BY ICP-AFS

A quite new type of chelating resin Carboxymethylated Polyethylenimine-Polymethylenepolyphenylene Isocyanate(CPPI)is used for the preconcentration of Zn from high salt water such as seawater. The preconcentration is controlled through the technique of Flow Injection Analysis(FIA).The concentrated sample solution is then directly transferred to an Inductively Coupled Plasma-Atomic Fluorescence Spectrometer(ICP-AFS)for determination.The detection limit of Zn by the technique is about 0.06 ppb.

Microfluidic Analytical System with On-Line Luminol Chemiluminescence Detection Based on Annular Flow of Phase Separation Multiphase Flow

Microfluidic analytical system was developed based on annular flow of phase separation multiphase flow with a ternary water-hydrophilic/hydrophobic organic solvent solution. The analytical system was combined with on-line luminol chemiluminescence detection for catechin analysis. The water (10 mM phosphate buffer, pH 7.3)-acetonitrile-ethyl acetate mixed solution (3:8:4, volume ratio) containing 60 μM luminol and 2 mM hydrogen peroxide as a carrier was fed into the capillary tube (open-tubular fused-silica, 75 μm inner diameter, 110 cm effective length) at a flow rate of 1.0 μL·min-1. The carrier solution showed stable chemiluminescence as a baseline on the flow chart. Eight catechins were detected as negative peaks for their antioxidant potential with different detection times. The system was applied to analyze the amounts of catechin in commercially available green tea beverages.

Study of pressure effects on ocean in-situ detection using laser-induced breakdown spectroscopy

Laser-induced breakdown spectroscopy(LIBS) has attracted extensive attention as a new technique for in-situ marine application. In this work, the influence of deep-sea high pressure environment on LIBS signals was investigated by using a compact LIBS-sea system developed by Ocean University of China for the in-situ chemical analysis of seawater. The results from the field measurements show that the liquid pressure has a significant effect on the LIBS signals. Higher peak intensity and larger line broadening were obtained as the pressure increases. By comparing the variations of the temperature and salinity with the LIBS signals, a weak correlation between them can be observed. Under high pressure conditions, the optimal laser energy was higher than that in air environment. When the laser energy exceeded 17 mJ, the effect of laser energy on the signal intensity weakened. The signal intensity decreases gradually at larger delays. The obtained results verified the feasibility of the LIBS technique for the deep-sea in-situ detection, and we hope this technology can contribute to surveying more deep-sea environments such as the hydrothermal vent regions.

Flow-Injection Microcolumn on-Line Preconcentration for theDetermination of Chromium(Ⅵ)

A rapid and sensitive on-line preconcentration method for spectrophotometric determination of chromium (VI) in nature water is described. Preconcentration and determination are based on (i) the quantitative and fast adsorption of chromium (VI) on the high surface area nanometer-size TiO2 (anatase) powders, which prepared by a sol-gel method from hydrolysis of TiCI4 and (ii) the quantitative and reproducible elution of Cr (VI) by 2. 0 mol. L-1 HCI. A mini-column system for preconcentration is developed, Cr(VI)on the mini-column is eluted and merged with a stream water and DPCB (1, 5-diphenylcarbazide ) as the chromogenic reagent. The Proposed system permits throughputs of 6 sample h--l (0. 001 μg mL-1 Cr(VI) ) or 20 sample h-1 (0. 1 μg mL-1Cr (VI) . The preconcentration factor is 55. The detection limit is 0. 8 ng·mL-1 Cr(VI). The reproducibility is satisfactory with a relative standard deviation of less than 3. 35% (0. Of μg'mL-1Cr (VI), n = 5).

PMOXA/PAA Brushes toward on-Line Preconcentration for BSA in Capillary Electrophoresis

In this work, a binary-mixed-brushes-coated (BBC) capillary with switchable protein adsorption/desorption properties was developed and applied for on-line preconcentration of proteins. Firstly, amine-terminated poly(2-methyl-2-oxazoline)(PMOXA-NH2) and thiolterminated poly(acrylic acid)(PAA-SH) were synthesized by using cationic ring-opening polymerization (CROP) and reversible addition fragmentation chain transfer (RAFT) polymerization, respectively. Then, the BBC capillary based on poly(2-methyl-2-oxazoline)(PMOXA) and poly(acrylic acid)(PAA) was prepared by sequentially grafting of PMOXA-NH2 and PAA-SH onto fused-silica capillary inner surface through poly(dopamine)(PDA) as an anchor. The obtained PMOXA/PAA coating formed on the capillary or capillary's raw material was characterized in terms of the thickness, surface chemical composition by using scanning electron microscope (SEM) and X-ray photoelectron spectrum (XPS). The switchable protein adsorption/desorption performance of the BBC capillary was investigated by using fluorescence microscope under di erent solutions with certain pH and ionic strength(I). The results showed that bovine serum albumin (BSA) could be adsorbed on BBC capillary at pH=5.0 (I=10^-5 mol/L), and then the adsorbed BSA could be released at pH=9.0 (I=0.1 mol/L). This switchable protein adsorption/desorption property of coated capillary was then used to preconcentrate proteins on-line for increasing the detection sensitivity of BSA in capillary electrophoresis (CE). With this method, a sensitivity enhancement factor (SEF) more than 5000 for BSA detection was obtained.

On-line coupling of derivatization with pre-concentration to determine trace levels of methotrexate

A new simple, sensitive and precise green analytical procedure using an automated packed-reactor derivatization technique coupled with on-line solid-phase enrichment （SPEn） has been developed and evaluated to determine trace levels of methotrexate （MTX）. The method was based on injection of MTX into a flowing stream of phosphate buffer （0.04 M, ptt 3.4）, carried through the packed oxidant reactor of Cerium （IV） trihydroxyhydroperoxide for oxidative cleavage of the drug into highly fluorescent product, 2,4-diaminopteridine- 6-carboxylic acid, followed by SPEn on a head of short ODS column （10mm x 4.6 mm i.d., 5 I＋tm particle size）. The flow rate was 0.25 mL/min and packed reactor temperaturc was 40 ~C. The trapped product was back-flush eluted from the ODS column to the detector by column-switching with an environmentally friendly mobile phase consisting of ethanol and phosphate buffer （0.04 M, pH 3.4） in the ratio of 5：95 （v/v）. The eluent was monitored at emission and excitation wavelengths of 460 and was linear over the concentration range of 1.25-50 360 nm, respectively. The calibration curve ng/mL with a detection limit of 0.08 ug/ml..The method was successfully applied to determine MTX in pharmaceutical formulations with mean percentage recovery ranging from 99.48 to 99.60.

In-situ determination of onset lithium plating for safe Li-ion batteries

Lithium plating in working batteries has attracted wide attention in the exploration of safe energy storage. Establishing an effective and rapid early-warning method is strongly considered but quite challenging since lithium plating behavior is determined by diverse factors. In this contribution, we present a non-destructive electrochemical detection method based on transient state analysis and threeelectrode cell configuration. Through dividing the iR drop value by the current density, the as-obtained impedance quantity(R_(i)) can serve as a descriptor to describe the change of electrochemical reaction impedance on the graphite anode. The onset of lithium plating can be identified from the sharp drop of R_(i). Once the dendritic plated lithium occurs, the extra electrochemical reactions at the lithium interfaces leads to growing active area and reduced surface resistance of the anode. We proposed a protocol to operate the batteries under the limited capacity, which renders the cell with 98.2% capacity retention after 1000 cycles without lithium plating. The early-warning method has also been validated in in-situ optical microscopy batteries and practical pouch cells, providing a general but effective method for online lithium plating detection towards safe batteries.

Automatic System for Failure Detection in Hydro-Power Generators

This paper presents an automatic system for failure detection in hydro-power generators. The main idea of this system is to detect failure using current and voltage signals acquired without any type of internal interference in the generator operation. The detected failures could be mechanical or electrical origins, such as: problems in bearings, unwanted vibrations, partial discharges, misalignment, unbalancing, among others. It is possible because the generator acts as a transducer for mechanical problems, and they appear in current and voltage signals. This automatic system based on electric signature analysis has been installed in Itapebi Power Plant generators since 2012. Some results are presented in this paper.

Overview of Industrial Materials Detection Based on Prompt Gamma Neutron Activation Analysis Technology

Prompt gamma neutron activation analysis (PGNAA) is a non-destructive online measurement nuclear analysis method. With its unique advantages, it has been widely used in online analysis of industrial materials such as coal, cement, and minerals in recent years. However, there are many kinds of literature on PGNAA in the field of industrial materials detection, and there are still a few concluding articles. To this end, based on the principle of PGNAA online analysis, the status quo and development of the real-time online detection of industrial material components in the field are reviewed and discussed by consulting a large number of domestic and foreign PGNAA related literature and data, to facilitate the reference of relevant scientific researchers.

On-Line Defect Detection of Aluminum Coating Using Fiber Optic Sensor

Aluminum metallization using the sprayed coating for exhaust mild steel （MS） pipes of tractors is a standard practice for avoiding rusting. Patches of thin metal coats are prone to rusting and are thus considered as defects in the surface coating. This paper reports a novel configuration of the fiber optic sensor for on-line checking the aluminum metaUization uniformity and hence for defect detection. An optimally chosen high bright 440 nm BLUE LED （light-emitting diode） launches light into a transmitting fiber inclined at the angle of 60° to the surface under inspection placed adequately. The reflected light is transported by a receiving fiber to a blue enhanced photo detector. The metallization thickness on the coated surface results in visually observable variation in the gray shades. The coated pipe is spirally inspected by a combination of linear and rotary motions. The sensor output is the signal conditioned and monitored with RISHUBH DAS. Experimental results show the good repeatability in the defect detection and coating non-uniformity measurement.

Change of extracellular ascorbic acid in the brain cortex following ice water vestibular stimulation： an on-line electrochemical detection coupled with in vivo microdialysis sampling for guinea pigs

Background Ascorbic acid （AA） represents one of the most important enzyme co-factors, antioxidants and neuromodulators and plays an important role in the cerebral system. Increasing evidence has suggested that AA could treat certain kinds of vertigo diseases such as Meniere＇s disease. To elucidate the neurochemical functions associated with AA in vertigo, the change of extracellular AA in the brain cortex following caloric vestibular stimulation （CVS） was evaluated.Methods An on-line electrochemical detection was coupled with in vivo microdialysis to continuously monitor the change of extracellular AA in the primary somatosensory （SI） area of guinea pigs following a caloric vestibular stimulation. Sixteen guinea pigs were divided into three groups, i.e., experimental group with irrigation of the ear canal with ice water （0℃） （n=-8）, and two control groups, one with irrigation of the ear canal with warm water （38℃） （n=-4） and the other with irrigation of the auricle with ice water （n=-4）.Results In the experimental group, the ice water irrigation of the left external ear canal induced a horizontal nystagmus towards the right side lasting about 45 seconds. No nystagmus was induced by warm water irrigation of the external ear canal or by ice water irrigation of the auricle. The extracellular AA concentration significantly increased following the ice water vestibular stimulation, reaching a maximum of （130±20）% （n=8） of the basal dialysate level （2.61±0.92） μmol/L （n=8）, lasting at least for an hour. AA level did not change distinctly after the irrigation of the left external ear canal with warm water or the irriclation of the auricle with ice water.Conclusions The concentration of extracellular AA in the brain cortex of the SI area increased following the ice water vestibular stimulation. This demonstration may be useful for the investigation of the neurochemical processes associated with AA in the process of vertigo.

Atmospheric Disturbance Characteristics in the Lower-middle Stratosphere Inferred from Observations by the Round-Trip Intelligent Sounding System(RTISS)in China

Through multi-order structure function analysis and singularity measurement,the Hurst index and intermittent parameter are obtained to quantitatively describe the characteristics of atmospheric disturbance based on the round-trip intelligent sounding system(RTISS)in the lower-middle stratosphere.According to the third-order structure function,small-scale gravity waves are classified into three states:stable,unstable,and accompanied by turbulence.The evolution of gravity waves is reflected by the variation of the third-order structure function over time,and the generation of turbulence is also observed.The atmospheric disturbance intensity parameter RT is defined in this paper and contains both wave disturbance(H_(1))and random intermittency(C_(1)).RT is considered to reflect the characteristics of atmospheric disturbance more reasonably than either of the above two alone.In addition,by obtaining the horizontal wavenumber spectrum from the flat-floating stage and the vertical wavenumber spectrum from the ascending and descending stages at the height range of18-24 km,we found that when the gravity wave activity is significantly enhanced in the horizontal direction,the amplitude of the vertical wavenumber spectrum below is significantly larger,which shows a significant impact of gravity wave activity on the atmospheric environment below.

Insight into the effect of thick graphite electrodes towards high-performance cylindrical Ni-rich NCA90 Li-ion batteries

This study explored the complex effect of graphite tortuosity on the electrochemical performance of Ni-rich NCA90 Li-ion batteries(LIBs).Different levels of graphite anode tortuosity were analyzed,revealing that low-tortuosity electrodes had better graphite utilization.The in-plane tortuosities of the graphite anode electrodes examined were 1.70,1.94,2.05,and 2.18,while their corresponding through-plane tortuosities were 4.74,6.94,8.19,and 9.80.In-operando X-ray diffraction and differential electrochemical mass spectrometry were employed to investigate the charge storage mechanism and gas evolution.The study revealed that while graphite electrode tortuosity impacted the amount of Li present in the lithiated graphite phase due to diffusion constraints,it did not affect gas generation.The Li-ion utilization in low-tortuosity electrodes was higher than that in high-tortuosity electrodes because of solid-diffusion limitations.Additionally,the galvanostatic intermittent titration technique(GITT) was employed to investigate a lithium-ion diffusion coefficient.Our results indicate that the lithium-ion diffusion coefficient exhibits a significant difference only during LiC_(6) phase transition.We also observed that the use of a lower tortuosity electrode leads to improved lithium-ion insertion.Consequently,graphite utilization is influenced by the porous electrode design.Safety tests adhering to UN38.3 guidelines verified battery safety.The study demonstrated the practical application of optimized NCA90 LIB cells with diverse graphite electrode tortuosities in a high-performance Lamborghini GoKart,paving the way for further advancements in Ni-rich LIB technology.

Design and Analysis of Fault Diagnosis and Fault-tolerant Control for a Class of MIMO Nonlinear State Systems

This paper presents a fault diagnosis and fault-tolerant control algorithm,which can be used for a class of multi-input multi-output(MIMO)nonlinear state systems.First,a state estimator is proposed,which is able to detect fault occurrence,by using a residual signal.Second,when the state is at an abnormal condition,the fault-tolerant control will be triggered to minimize the impact of the fault occurrence.This fault-tolerant control is designed by using a robust controller(original controller),and an on-line approximator to capture a nonlinear function that indicates the fault occurrence.The detailed analysis is given for the proposed fault accommodation control.

Research of EDM Spark Locations in Die-sinking

Detection of 2-dimention spark locations by electromagnetic detection method in electrical discharge machining (EDM) is studied. The method, which is applied and investigated, is based on the fact that the release of energy from a spark is transformed into electromagnetic wave around the workpiece. A new sensor system composed of high precision linear Hall components and cubic ferrite is used to detect the intensity of magnetic field. Relation equation between the output of the sensor system and 2-dimention spark locations experiment under a spiculate electrode is introduced, and its diagram of curve is drawn. As a result, the information that can be achieved by detecting spark’s location gives new possibilities for an extended analysis of the EDM-process.

Active Error Compensating Welding Fixture System for Auto Body

The welding fixtures are the most important devices for an auto body welding assembly line. The current special fixtures used by many automotive manufactures are only fit for one or several specific welding processes, and the dimensional problem in the circle due to several variation sources accumulation has no adjustment. The active error compensating welding fixture system for auto body is designed and manufactured. The detecting model, coordinate transformation model, and adjusting model based on auto body coordinate system are presented. The dowel pin modular design is adopted in the structure of the fixture to suit different workpieces with some similar characteristics. The online detection and adaptive control system using eddy current sensors and adaptive adjusting devices is analyzed. Three kinds of the left rear wheel covers SGM60 are selected to test workpieces of the developed system, and the active error compensating experiments are performed in the lab for many times. Test results show the validity of mechanism reconfigurations, on-line detections and error compensations of the developed welding fixture.

Energy Saving Technology for Lowering Air Leakage of Sintering Pallets and Dust Collectors in Sinter Plant

The hot-wire type anemometers were used for measuring the velocity of effective air flowing through sinter bed in this study.Meanwhile,microphones were installed beside the pathway and close to the outer sidewall of travelling pallets for monitoring sound pressure generated by an abnormal air leakage.For identifying the passing pallet,a thermal-resistant type RFID technology was adopted.Based on the measured data via anemometers,the air leakage rate of sintering machine was calculated with the mass balance method,and pallets with the abnormal leakage can be detected and ranked in the severity of leakage from the measured sound pressure with the relevant criteria.In addition,for examining the leakage situation,this study set up a capillary type of differential pressure gauge to double cone valve(DCV)below the electrostatic precipitator(EP)in sintering plant for collecting the larger dust.The criteria of determining leaked DCV and the patterns for replacing the DCV were proposed to develop a detecting and predicting system on the air leakage into dust collectors of sinter machine.It offered field staff a basis of maintaining or renewing DCV via a warning reminding and reducing air leakage to increase EP efficiency for avoiding the dust emission from the stack.These technologies had been implemented in the sintering plants of China Steel Corporation,and they can effectively reduce the air leakage rate by5%at least and further decrease the electricity consumption of the suction fan and coke rate,increase the production for the sintering machine.