In this paper, several {actors that could lead to the appearance of false peak were investigated by using on-line sample sweeping technique under different experimental conditions. The tested analytes were buflomedil ...In this paper, several {actors that could lead to the appearance of false peak were investigated by using on-line sample sweeping technique under different experimental conditions. The tested analytes were buflomedil hydrochloride, ephedrine hydrochloride, benzyl alcohol, vanillin, p-hydroxybenzaldehyde and m-methylphenol. Results showed mat among the six compounds, three of them, i.e., buflomedil hydrochloride, ephedrine hydrochloride and benzyl alcohol will cause false peaks to appear when sample injection time is long, sodium dodecyl sulfate (SDS) concentration is high and there is pH gradient between cathode and anode. In order to avoid the appearance of false peak, the pH gradient should be avoided.展开更多
A new method for the determination of atrazine, simazine and prometryn in water samples by on-line sweeping concentration technique in micellar electrokinetic chromatography （MEKC） was developed. Various parameters ...A new method for the determination of atrazine, simazine and prometryn in water samples by on-line sweeping concentration technique in micellar electrokinetic chromatography （MEKC） was developed. Various parameters affecting sample enrichment and separation efficiency were systematically studied. Compared with the conventional MEKC method, up to 60-200-fold improvement in concentration sensitivity was achieved in terms of peak height by using this sweeping injection technique. The compound strychnine was used as the internal standard for the improvement of the experimental reproducibility. The limits of detection （S/ N = 3：1） for atrazine, simazine and prometryn were 9, 10 and 0.5 ng mL-1, respectively. This method has been successfully applied to the analysis of atrazine, simazine and prometryn in lake, steam and ground water.展开更多
A sensitive and simple micellar electrokinetic chromatography （MEKC） method was developed for the determination of antiepileptic drug, carbamazepine （CBZ）, using sweeping on-line concentration method with photodio...A sensitive and simple micellar electrokinetic chromatography （MEKC） method was developed for the determination of antiepileptic drug, carbamazepine （CBZ）, using sweeping on-line concentration method with photodiode array detection. Under the optimal conditions, the calibration curve was linear over a range of 0.5-40μg·mL^-1 for CBZ with a correlation coefficient of 0.998. The detection limit （S/N = 3：1） of CBZ was 0.10 μg·mL^-1. The sweeping-MEKC method has been successfully applied to the analysis of CBZ in human serum.展开更多
An on-line monitoring system for partial discharge from high voltage transformer is presented with structure of hardware and principle of software discussed and a new effective method combining DFT with DWT is propose...An on-line monitoring system for partial discharge from high voltage transformer is presented with structure of hardware and principle of software discussed and a new effective method combining DFT with DWT is proposed to get rid of both sinusoidal continuous noise and other external discharges.展开更多
This study presented an insulation state monitoring method for large generator based on radio frequency (RF) technique. As an on-line condition monitor and the precondition of condition-based maintenance (CBM), the RF...This study presented an insulation state monitoring method for large generator based on radio frequency (RF) technique. As an on-line condition monitor and the precondition of condition-based maintenance (CBM), the RF monitor used the high frequency current mutual inductor to detect the partial discharge signal from neutral wire of stator windings. According to the magnitude of indicative value of RF monitor, a five phase model was also proposed to manage the generator’s running better. The practices show that the proposed method is effective.展开更多
With the development of distribution automation system, the centralized meter reading system has been adopted more and more extensively, which provides real-time electricity consumption data of end-users, and conseque...With the development of distribution automation system, the centralized meter reading system has been adopted more and more extensively, which provides real-time electricity consumption data of end-users, and consequently lays foundation for operating condition on-line analysis of distribution network. In this paper, a modified back/forward sweep method, which directly uses real-time electricity consumption data acquired from the centralized meter reading system, is proposedto realize voltage analysis based on 24-hour electricity consumption data of a typical transformer district. Furthermore, the calculated line losses are verified through data collected from the energy metering of the distribution transformer, illustrating that the proposed method can be applied in analyzing voltage level and discovering unknown energy losses, which will lay foundation for on-line analysis, calculation and monitoring of power distribution network.展开更多
On-line chemical characterization of atmospheric particulate matter(PM)with soft ionization technique and ultrahigh-resolution Mass Spectrometry(UHRMS)provides molecular information of organic constituents in real tim...On-line chemical characterization of atmospheric particulate matter(PM)with soft ionization technique and ultrahigh-resolution Mass Spectrometry(UHRMS)provides molecular information of organic constituents in real time.Here we describe the development and application of an automatic measurement system that incorporates PM_(2.5)sampling,thermal desorption,atmospheric pressure photoionization,and UHRMS analysis.Molecular formulas of detected organic compounds were deducted from the accurate(±10 ppm)molecular weights obtained at a mass resolution of 100,000,allowing the identification of small organic compounds in PM_(2.5).Detection efficiencies of 28 standard compounds were determined and we found a high sensitivity and selectivity towards organic amines with limits of detection below 10 pg.As a proof of principle,PM_(2.5)samples collected off-line in winter in the urban area of Beijing were analyzed using the Ionization Module and HRMS of the system.The automatic system was then applied to conduct on-line measurements during the summer time at a time resolution of 2 hr.The detected organic compounds comprised mainly CHON and CHN compounds below 350 m/z.Pronounced seasonal variations in elemental composition were observed with shorter carbon backbones and higher O/C ratios in summer than that in winter.This result is consistent with stronger photochemical reactions and thus a higher oxidation state of organics in summer.Diurnal variation in signal intensity of each formula provides crucial information to reveal its source and formation pathway.In summary,the automatic measurement system serves as an important tool for the on-line characterization and identification of organic species in PM_(2.5).展开更多
A micellar capillary electrophoresis（MCE） method based on on-line sweeping technique was（developed） for a determination of trace quinolones,ciprofloxacin ofloxacin and enrofloxacin in pork tissue.The pork tissue s...A micellar capillary electrophoresis（MCE） method based on on-line sweeping technique was（developed） for a determination of trace quinolones,ciprofloxacin ofloxacin and enrofloxacin in pork tissue.The pork tissue samples were deproteinized with trichloroacetic acid and in the running buffer of 20 mmol/L（Na2B4O7）+80 mmol/L sodium dodecyl sulfate（SDS）,pH=9.6,the ciprofloxacin,ofloxacin and enrofloxacin in the sample were successfully separated and detected within 200 s,in a non-coating fused-silica capillary column（48.5 cm×75 μm i.d.,effective length 40 cm） at separation voltage of 18 kV,and the injection pressure of 15×102 Pa,with UV detection at 278 nm.The detection limits of ciprofloxacin,ofloxacin and enrofloxacin were 0.007,0.016 and 0.020 mg/L,and RSD were 2.0%,2.4% and 2.6%,respectively.This method allows of up to 600-fold accumulation concentration of ciprofloxacin and can be used to separate and detect the residuals of trace medicines in animal food.展开更多
在2.4m跨声速风洞开展连续变迎角试验技术研究中,遇到了3个难题:跨声速流场被持续扰动,快速精确补偿困难;试验有用信号频率与干扰信号频率产生重叠,降噪处理困难;信号间不同步对试验数据的影响增大,信号精确同步困难。采用总静压滤波优...在2.4m跨声速风洞开展连续变迎角试验技术研究中,遇到了3个难题:跨声速流场被持续扰动,快速精确补偿困难;试验有用信号频率与干扰信号频率产生重叠,降噪处理困难;信号间不同步对试验数据的影响增大,信号精确同步困难。采用总静压滤波优化和PID(Proportional Integral Differential)调节优化等方法提高流场快速跟随性,硬件+软件+小波等复合滤波方式进行降噪处理,并利用互相关函数实现各信号的精确同步,建立了2.4m跨声速风洞连续变迎角试验技术。使用J7等标模对该项技术进行了验证,结果表明,上述问题均得到有效解决,连续变迎角试验流场Ma数稳定在±0.002范围内,数据的精准度达到阶梯测力试验水平。展开更多
基金theNaturalScienceFoundationofHebeiProvince (No .2 0 0 077)andtheNationalNaturalScienceFoundationofChina (No .2 0 0 75 0 0 5 )
文摘In this paper, several {actors that could lead to the appearance of false peak were investigated by using on-line sample sweeping technique under different experimental conditions. The tested analytes were buflomedil hydrochloride, ephedrine hydrochloride, benzyl alcohol, vanillin, p-hydroxybenzaldehyde and m-methylphenol. Results showed mat among the six compounds, three of them, i.e., buflomedil hydrochloride, ephedrine hydrochloride and benzyl alcohol will cause false peaks to appear when sample injection time is long, sodium dodecyl sulfate (SDS) concentration is high and there is pH gradient between cathode and anode. In order to avoid the appearance of false peak, the pH gradient should be avoided.
基金sponsored by the Natural Science Foundation of Hebei (Nos.B2006000413,B2008000210).
文摘A new method for the determination of atrazine, simazine and prometryn in water samples by on-line sweeping concentration technique in micellar electrokinetic chromatography （MEKC） was developed. Various parameters affecting sample enrichment and separation efficiency were systematically studied. Compared with the conventional MEKC method, up to 60-200-fold improvement in concentration sensitivity was achieved in terms of peak height by using this sweeping injection technique. The compound strychnine was used as the internal standard for the improvement of the experimental reproducibility. The limits of detection （S/ N = 3：1） for atrazine, simazine and prometryn were 9, 10 and 0.5 ng mL-1, respectively. This method has been successfully applied to the analysis of atrazine, simazine and prometryn in lake, steam and ground water.
文摘A sensitive and simple micellar electrokinetic chromatography （MEKC） method was developed for the determination of antiepileptic drug, carbamazepine （CBZ）, using sweeping on-line concentration method with photodiode array detection. Under the optimal conditions, the calibration curve was linear over a range of 0.5-40μg·mL^-1 for CBZ with a correlation coefficient of 0.998. The detection limit （S/N = 3：1） of CBZ was 0.10 μg·mL^-1. The sweeping-MEKC method has been successfully applied to the analysis of CBZ in human serum.
文摘An on-line monitoring system for partial discharge from high voltage transformer is presented with structure of hardware and principle of software discussed and a new effective method combining DFT with DWT is proposed to get rid of both sinusoidal continuous noise and other external discharges.
文摘This study presented an insulation state monitoring method for large generator based on radio frequency (RF) technique. As an on-line condition monitor and the precondition of condition-based maintenance (CBM), the RF monitor used the high frequency current mutual inductor to detect the partial discharge signal from neutral wire of stator windings. According to the magnitude of indicative value of RF monitor, a five phase model was also proposed to manage the generator’s running better. The practices show that the proposed method is effective.
文摘With the development of distribution automation system, the centralized meter reading system has been adopted more and more extensively, which provides real-time electricity consumption data of end-users, and consequently lays foundation for operating condition on-line analysis of distribution network. In this paper, a modified back/forward sweep method, which directly uses real-time electricity consumption data acquired from the centralized meter reading system, is proposedto realize voltage analysis based on 24-hour electricity consumption data of a typical transformer district. Furthermore, the calculated line losses are verified through data collected from the energy metering of the distribution transformer, illustrating that the proposed method can be applied in analyzing voltage level and discovering unknown energy losses, which will lay foundation for on-line analysis, calculation and monitoring of power distribution network.
基金supported by the National Natural Science Foundation of China(No.41805105)。
文摘On-line chemical characterization of atmospheric particulate matter(PM)with soft ionization technique and ultrahigh-resolution Mass Spectrometry(UHRMS)provides molecular information of organic constituents in real time.Here we describe the development and application of an automatic measurement system that incorporates PM_(2.5)sampling,thermal desorption,atmospheric pressure photoionization,and UHRMS analysis.Molecular formulas of detected organic compounds were deducted from the accurate(±10 ppm)molecular weights obtained at a mass resolution of 100,000,allowing the identification of small organic compounds in PM_(2.5).Detection efficiencies of 28 standard compounds were determined and we found a high sensitivity and selectivity towards organic amines with limits of detection below 10 pg.As a proof of principle,PM_(2.5)samples collected off-line in winter in the urban area of Beijing were analyzed using the Ionization Module and HRMS of the system.The automatic system was then applied to conduct on-line measurements during the summer time at a time resolution of 2 hr.The detected organic compounds comprised mainly CHON and CHN compounds below 350 m/z.Pronounced seasonal variations in elemental composition were observed with shorter carbon backbones and higher O/C ratios in summer than that in winter.This result is consistent with stronger photochemical reactions and thus a higher oxidation state of organics in summer.Diurnal variation in signal intensity of each formula provides crucial information to reveal its source and formation pathway.In summary,the automatic measurement system serves as an important tool for the on-line characterization and identification of organic species in PM_(2.5).
文摘A micellar capillary electrophoresis（MCE） method based on on-line sweeping technique was（developed） for a determination of trace quinolones,ciprofloxacin ofloxacin and enrofloxacin in pork tissue.The pork tissue samples were deproteinized with trichloroacetic acid and in the running buffer of 20 mmol/L（Na2B4O7）+80 mmol/L sodium dodecyl sulfate（SDS）,pH=9.6,the ciprofloxacin,ofloxacin and enrofloxacin in the sample were successfully separated and detected within 200 s,in a non-coating fused-silica capillary column（48.5 cm×75 μm i.d.,effective length 40 cm） at separation voltage of 18 kV,and the injection pressure of 15×102 Pa,with UV detection at 278 nm.The detection limits of ciprofloxacin,ofloxacin and enrofloxacin were 0.007,0.016 and 0.020 mg/L,and RSD were 2.0%,2.4% and 2.6%,respectively.This method allows of up to 600-fold accumulation concentration of ciprofloxacin and can be used to separate and detect the residuals of trace medicines in animal food.
文摘在2.4m跨声速风洞开展连续变迎角试验技术研究中,遇到了3个难题:跨声速流场被持续扰动,快速精确补偿困难;试验有用信号频率与干扰信号频率产生重叠,降噪处理困难;信号间不同步对试验数据的影响增大,信号精确同步困难。采用总静压滤波优化和PID(Proportional Integral Differential)调节优化等方法提高流场快速跟随性,硬件+软件+小波等复合滤波方式进行降噪处理,并利用互相关函数实现各信号的精确同步,建立了2.4m跨声速风洞连续变迎角试验技术。使用J7等标模对该项技术进行了验证,结果表明,上述问题均得到有效解决,连续变迎角试验流场Ma数稳定在±0.002范围内,数据的精准度达到阶梯测力试验水平。
