Based on the vibrational potential curves coupled with the minimum energy reaction path, the partial potential energy surface of the reaction I＋HI→IH＋I was constructed at the QCISD（T）//MP4SDQ level with pseudo po...Based on the vibrational potential curves coupled with the minimum energy reaction path, the partial potential energy surface of the reaction I＋HI→IH＋I was constructed at the QCISD（T）//MP4SDQ level with pseudo potential method. And the formation mechanism of the scattering resonance states of this reaction was well interpreted with the partial potential energy surface. The scattering resonance states of this reaction should belong to Feshbach resonance because of the coupling of the vibrational mode and the translational mode. With the one-dimensional square potential well model, the resonance width and lifetime of the I＋HI（v=0）→IH（v＇=0）＋I state-to-state reaction were calculated, which preferably explained the high-resolved threshold photodetachment spectroscopy of the IHI- anion performed by Neumark et al..展开更多
Differences of the time periods in two independent quantum systems are examined on a semiclassical level. The systems are the electron in the hydrogen atom and a free-electron particle moving in a one-dimensional pote...Differences of the time periods in two independent quantum systems are examined on a semiclassical level. The systems are the electron in the hydrogen atom and a free-electron particle moving in a one-dimensional potential box, respectively. It is demonstrated that in both systems the relativistic correction to the time interval can be expressed as a multiple of the same quantum of time. The size of the quantum is proportional to the ratio of the Planck’s constant and the rest energy of the electron particle.展开更多
基金Ⅴ. ACKN0WLEDGMENTS This work was supported by the National Natural Science Foundation of China （No.20573064） and Ph.D. Special Research Foundation of Chinese Education Department.
文摘Based on the vibrational potential curves coupled with the minimum energy reaction path, the partial potential energy surface of the reaction I＋HI→IH＋I was constructed at the QCISD（T）//MP4SDQ level with pseudo potential method. And the formation mechanism of the scattering resonance states of this reaction was well interpreted with the partial potential energy surface. The scattering resonance states of this reaction should belong to Feshbach resonance because of the coupling of the vibrational mode and the translational mode. With the one-dimensional square potential well model, the resonance width and lifetime of the I＋HI（v=0）→IH（v＇=0）＋I state-to-state reaction were calculated, which preferably explained the high-resolved threshold photodetachment spectroscopy of the IHI- anion performed by Neumark et al..
文摘Differences of the time periods in two independent quantum systems are examined on a semiclassical level. The systems are the electron in the hydrogen atom and a free-electron particle moving in a one-dimensional potential box, respectively. It is demonstrated that in both systems the relativistic correction to the time interval can be expressed as a multiple of the same quantum of time. The size of the quantum is proportional to the ratio of the Planck’s constant and the rest energy of the electron particle.
