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INTERFACE BEHAVIOR AND DECAY RATES OF COMPRESSIBLE NAVIER-STOKES SYSTEM WITH DENSITY-DEPENDENT VISCOSITY AND A VACUUM 被引量:1
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作者 郭真华 张学耀 《Acta Mathematica Scientia》 SCIE CSCD 2024年第1期247-274,共28页
In this paper,we study the one-dimensional motion of viscous gas near a vacuum,with the gas connecting to a vacuum state with a jump in density.The interface behavior,the pointwise decay rates of the density function ... In this paper,we study the one-dimensional motion of viscous gas near a vacuum,with the gas connecting to a vacuum state with a jump in density.The interface behavior,the pointwise decay rates of the density function and the expanding rates of the interface are obtained with the viscosity coefficientμ(ρ)=ρ^(α)for any 0<α<1;this includes the timeweighted boundedness from below and above.The smoothness of the solution is discussed.Moreover,we construct a class of self-similar classical solutions which exhibit some interesting properties,such as optimal estimates.The present paper extends the results in[Luo T,Xin Z P,Yang T.SIAM J Math Anal,2000,31(6):1175-1191]to the jump boundary conditions case with density-dependent viscosity. 展开更多
关键词 decay rates INTERFACE Navier-Stokes equations VACUUM
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Generalized Quantum Measurement in Spin-Correlated Hyperon-Antihyperon Decays
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作者 Sihao Wu Chen Qian +1 位作者 Yang-Guang Yang Qun Wang 《Chinese Physics Letters》 SCIE EI CAS CSCD 2024年第11期1-11,共11页
The rapid developments of quantum information science(QIS)have opened up new avenues for exploring fundamental physics.Quantum nonlocality,a key aspect for distinguishing quantum information from classical one,has und... The rapid developments of quantum information science(QIS)have opened up new avenues for exploring fundamental physics.Quantum nonlocality,a key aspect for distinguishing quantum information from classical one,has undergone extensive examinations in particles’decays through the violation of Bell-type inequalities.Despite these advancements,a comprehensive framework based on quantum information theory for particle interaction is still lacking.Trying to close this gap,we introduce a generalized quantum measurement description for decay processes of spin-1/2 hyperons.We validate this approach by aligning it with established theoretical calculations and apply it to the joint decay of ΛΛ pairs.We employ quantum simulation to observe the violation of Clauser–Horne–Shimony–Holt inequalities in η_(c)/χ_(c0)→ΛΛˉprocesses.Our generalized measurement description is adaptable and can be extended to a variety of high energy processes,including decays of vector mesons,J/ψ,ψ(2S)→ΛΛ,in the Beijing Spectrometer Ⅲ(BESⅢ)experiment at the Beijing Electron Positron Collider(BEPC).The methodology developed in this study can be applied to quantum correlation and information processing in fundamental interactions. 展开更多
关键词 quantum BESⅢ decay
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MINIMIZERS OF L^(2)-SUBCRITICAL VARIATIONAL PROBLEMS WITH SPATIALLY DECAYING NONLINEARITIES IN BOUNDED DOMAINS
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作者 陈彬 高永帅 +1 位作者 郭玉劲 吴越 《Acta Mathematica Scientia》 SCIE CSCD 2024年第3期984-996,共13页
This paper is concerned with the minimizers of L^(2)-subcritical constraint variar tional problems with spatially decaying nonlinearities in a bounded domain Ω of R~N(N≥1).We prove that the problem admits minimizers... This paper is concerned with the minimizers of L^(2)-subcritical constraint variar tional problems with spatially decaying nonlinearities in a bounded domain Ω of R~N(N≥1).We prove that the problem admits minimizers for any M> 0.Moreover,the limiting behavior of minimizers as M→∞ is also analyzed rigorously. 展开更多
关键词 decaying nonlinearity L~2-subcritical MINIMIZERS bounded domains mass concentration
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Decoding the fruit microbiome:A climate smart strategy to manage postharvest decays
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作者 Manori Kuruppu Kong Lih Ling +3 位作者 Phebe Ding Khairulmazmi Ahmad Asgar Ali Yasmeen Siddiqui 《Horticultural Plant Journal》 SCIE CAS CSCD 2024年第5期1061-1072,共12页
There is an urgent necessity to shift our diets toward those rich in fruits and vegetables and at reduce postharvest losses of perishables.Approximately 20%-50%of fruits and vegetables are lost due to poor postharvest... There is an urgent necessity to shift our diets toward those rich in fruits and vegetables and at reduce postharvest losses of perishables.Approximately 20%-50%of fruits and vegetables are lost due to poor postharvest handling and pathogen infections in developing countries while it was estimated as 5%-35%in developed countries. Fresh fruits have evolved with a plethora of microorganisms having important roles in maintaining fruit health. However, little information is available on the dynamics, structure, and functional capacities of underpinning fruit microbiomes. The present review discussed environmental conditions favoring fruit-harbored antagonists and their different modes of action for suppressing postharvest pathogens in fruits. It also provides information on omics technologies such as next-generation sequencing (NGS),metaproteomics, metatranscriptomic, and metabolomics studies to characterize fruit microbiomes. With the advent of NGS and meta-omics technologies, microbiome research could bring remarkable development and understanding in succeeding biological treatments. In addition, they may provide us with a fundamental understanding of microclimate requirements for fruit microbiome establishment and microbiome shifts during post-harvest storage, which would be advantageous in developing composite biocontrol treatments for post-harvest decay management. 展开更多
关键词 Biological control Food loss Fruit microbiome Meta-omics MICROCLIMATE Postharvest decay
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αDecay in extreme laser fields within a deformed Gamow-like model
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作者 Qiong Xiao Jun-Hao Cheng +3 位作者 Yang-Yang Xu You-Tian Zou Jun-Gang Deng Tong-Pu Yu 《Nuclear Science and Techniques》 SCIE EI CAS CSCD 2024年第2期131-144,共14页
In this study, the effect of extreme laser fields on the α decay process of ground-state even–even nuclei was investigated.Using the deformed Gamow-like model, we found that state-of-the-art lasers can cause a sligh... In this study, the effect of extreme laser fields on the α decay process of ground-state even–even nuclei was investigated.Using the deformed Gamow-like model, we found that state-of-the-art lasers can cause a slight change in the α decay penetration probability of most nuclei. In addition, we studied the correlation between the rate of change of the α decay penetration probability and angle between the directions of the laser electric field and α particle emission for different nuclei. Based on this correlation, the average effect of extreme laser fields on the half-life of many nuclei with arbitrary α particle emission angles was calculated. The calculations show that the laser suppression and promotion effects on the α decay penetration probability of the nuclei population with completely random α particle-emission directions are not completely canceled.The remainder led to a change in the average penetration probability of the nuclei. Furthermore, the possibility of achieving a higher average rate of change by altering the spatial shape of the laser is explored. We conclude that circularly polarized lasers may be helpful in future experiments to achieve a more significant average rate of change of the α decay half-life of the nuclei population. 展开更多
关键词 αdecay Deformed Gamow-like model HALF-LIVES Extreme laser field Penetration probability
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Structure and 2p decay mechanism of^(18)Mg
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作者 Long Zhou De-Qing Fang +1 位作者 Si-Min Wang Hui Hua 《Nuclear Science and Techniques》 SCIE EI CAS CSCD 2024年第6期145-154,共10页
The recently discovered,extremely proton-rich nuclide 18 Mg exhibits ground-state decay via two sequential two-proton(2p)emissions through the intermediate nucleus,16Ne.This study investigates the structure and the in... The recently discovered,extremely proton-rich nuclide 18 Mg exhibits ground-state decay via two sequential two-proton(2p)emissions through the intermediate nucleus,16Ne.This study investigates the structure and the initial 2p decay mechanism of^(18)Mgby examining the density and correlations of the valence protons using a three-body Gamow coupled-channel method.The results show that the ground state of^(18)Mgis significantly influenced by the continuum,resulting in a significant s-wave component.However,based on the current framework,this does not lead to a significant deviation in mirror symmetry in either the structure or spectroscopy of the 18Mg-18C pair.Additionally,the time evolution analysis of the^(18)Mgground state suggests a simultaneous 2p emission during the first step of decay.The observed nucleon-nucleon correlations align with those of the light-mass 2p emitters,indicating a consistent decay behavior within this nuclear region. 展开更多
关键词 Structure of^(18)Mg Two-proton decay Proton-proton correlation
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Study on the Influence of Setting Parameters of Tunnel Centralized Smoke Extraction System on Fire Smoke Flow and Temperature Decay
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作者 Zhisheng Xu SohailMahmood Zihan Yu 《Frontiers in Heat and Mass Transfer》 EI 2024年第3期791-816,共26页
The centralized smoke exhaust system of shield tunnel is an important determinant for tunnel fire safety,and the use of different design parameters of the tunnel smoke exhaust system will affect the smoke exhaust effe... The centralized smoke exhaust system of shield tunnel is an important determinant for tunnel fire safety,and the use of different design parameters of the tunnel smoke exhaust system will affect the smoke exhaust effect in the tunnel,and the influence of different design parameters on the smoke exhaust effect and temperature attenuation of the tunnel can help engineers in designing a more effective centralized smoke exhaust system for the tunnel.In this paper,the Fire Dynamic Simulator(FDS)is utilized to examine smoke exhaust vent settings for a centralized exhaust system in shield tunnel with both flat and sloped conditions,including slopes of+4.5%and−4.5%,under a 30MWfire power with a 150m^(3)/s smoke exhaust rate.The results suggest that maintaining a vent spacing of 60m and a vent size of 4.0 m×1.5 m is a reasonable configuration for centralized smoke exhaust systems in both flat and slope shield tunnels.This choice helpsminimize construction costs and prevent excessive smoke accumulation.It also promotes favorable conditions for maintaining temperature distribution at 2-m height,visibility,smoke spread distance,and temperature below the ceiling,all below the threshold values,while ensuring high smoke extraction efficiency.However,in the slope section,the chimney effect can disrupt exhaust efficiency,visibility,ceiling temperature,and temperature distribution at a height of 2 m.Employing different opening methods,such as having 2 vents up and 4 vents down in a+4.5%slope and 4 vents up and 2 vents down in a−4.5%slope,can help mitigate these effects.Furthermore,the temperature decay formula for shield tunnels follows a bi-exponential decay pattern,and different design parameters of centralized smoke exhaust systems have minimal effects on temperature decay in shield tunnels. 展开更多
关键词 Smoke exhaust setting smoke spread efficiency temperature decay
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Inhibiting Voltage Decay in Li-Rich Layered Oxide Cathode:From O3-Type to O2-Type Structural Design
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作者 Guohua Zhang Xiaohui Wen +2 位作者 Yuheng Gao Renyuan Zhang Yunhui Huang 《Nano-Micro Letters》 SCIE EI CAS CSCD 2024年第12期81-102,共22页
Li-rich layered oxide(LRLO)cathodes have been regarded as promising candidates for next-generation Li-ion batteries due to their exceptionally high energy density,which combines cationic and anionic redox activities.H... Li-rich layered oxide(LRLO)cathodes have been regarded as promising candidates for next-generation Li-ion batteries due to their exceptionally high energy density,which combines cationic and anionic redox activities.However,continuous voltage decay during cycling remains the primary obstacle for practical applications,which has yet to be fundamentally addressed.It is widely acknowledged that voltage decay originates from the irreversible migration of transition metal ions,which usually further exacerbates structural evolution and aggravates the irreversible oxygen redox reactions.Recently,constructing O2-type structure has been considered one of the most promising approaches for inhibiting voltage decay.In this review,the relationship between voltage decay and structural evolution is systematically elucidated.Strategies to suppress voltage decay are systematically summarized.Additionally,the design of O2-type structure and the corresponding mechanism of suppressing voltage decay are comprehensively discussed.Unfortunately,the reported O2-type LRLO cathodes still exhibit partially disordered structure with extended cycles.Herein,the factors that may cause the irreversible transition metal migrations in O2-type LRLO materials are also explored,while the perspectives and challenges for designing high-performance O2-type LRLO cathodes without voltage decay are proposed. 展开更多
关键词 Lithium-ion batteries Li-rich layered oxide Voltage decay Migration of transition metal ions O2-type structural design
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Microbial Growth and Decay: A Commented Review of the Model
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作者 Alberto Schiraldi 《Advances in Microbiology》 CAS 2024年第1期1-10,共10页
The paper reviews previous publications and reports some comments about a semi empirical model of the growth and decay process of a planktonic microbial culture. After summarizing and reshaping some fundamental mathem... The paper reviews previous publications and reports some comments about a semi empirical model of the growth and decay process of a planktonic microbial culture. After summarizing and reshaping some fundamental mathematical expressions, the paper highlights the reasons for the choice of a suitable time origin that makes the parameters of the model self-consistent. Besides the potential applications to predictive microbiology studies and to effects of bactericidal drugs, the model allows a suitable proxy of the fitness of the microbial culture, which can be of interest for the studies on the evolution across some thousand generations of a Long Term Evolution Experiment. 展开更多
关键词 Microbial Cultures MODEL Time Scale Growth and decay EVOLUTION
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Estimation of Landfill Gas and Its Renewable Energy Potential from the Polesgo Controlled Landfill Using First-Order Decay (FOD) Models
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作者 Haro Kayaba Ouarma Issoufou +4 位作者 Dabilgou Téré Compaore Abdoulaye Sanogo Oumar Bere Antoine Koulidiati Jean 《Journal of Environmental Protection》 2024年第10期975-993,共19页
Methane generation in landfills and its inadequate management represent the major avoidable source of anthropogenic methane today. This paper models methane production and the potential resources expected (electrical ... Methane generation in landfills and its inadequate management represent the major avoidable source of anthropogenic methane today. This paper models methane production and the potential resources expected (electrical energy production and potential carbon credits from avoided CH4 emissions) from its proper management in a municipal solid waste landfill located in Ouagadougou, Burkina Faso. The modeling was carried out using two first-order decay (FOD) models (LandGEM V3.02 and SWANA) using parameters evaluated on the basis of the characteristics of the waste admitted to the landfill and weather data for the site. At the same time, production data have been collected since 2016 in order to compare them with the model results. The results obtained from these models were compared to experimental one. For the simulation of methane production, the SWANA model showed better consistency with experimental data, with a coefficient of determination (R²) of 0.59 compared with the LandGEM model, which obtained a coefficient of 0.006. Thus, despite the low correlation values linked to the poor consistency of experimental data, the SWANA model models methane production much better than the LandGEM model. Thus, despite the low correlation values linked to the poor consistency of the experimental data, the SWANA model models methane production much better than the LandGEM V3.02 model. It was noted that the poor consistency of the experimental data justifies these low coefficients, and that they can be improved in the future thanks to ongoing in situ measurements. According to the SWANA model prediction, in 27 years of operation a biogas plant with 33% electrical efficiency using biogas from the Polesgo landfill would avoid 1,340 GgCO2e. Also, the evaluation of revenues due to electricity and carbon credit gave a total revenue derived from methane production of US$27.38 million at a cost of US$10.5/tonne CO2e. 展开更多
关键词 First-Order decay METHANE Modeling LANDFILL Renewable Energy
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Calculation of Particle Decay Times in the Standard Model
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作者 Jan Helm 《Journal of Modern Physics》 2024年第3期271-321,共51页
We present here a two-step method of classification and calculation for decay rates in the Standard Model. The first step is a phenomenological classification method, which is an extended and improved schematic experi... We present here a two-step method of classification and calculation for decay rates in the Standard Model. The first step is a phenomenological classification method, which is an extended and improved schematic experimental formula for decay width originally introduced by Chang. This schematic formula separates decays into seven classes. Furthermore, from it is derived a process-specific interaction energy m<sub>X</sub>. The second step is a numerical calculation method, which calculates this interaction energy m<sub>X</sub> numerically by minimization of action from the Lagrangian of the process, from which follows the decay width via the phenomenological formula. The Lagrangian is based on an extension of the Standard Model, the extended SU(4)-preon-model. A comparison of numerically calculated and observed decay widths for a large selection of decays shows a good agreement. 展开更多
关键词 Particle decay decay Width Interaction Energy Minimization of Action Ex-tension of Standard Model
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Global Existence and Decay of Solutions for a Class of a Pseudo-Parabolic Equation with Singular Potential and Logarithmic Nonlocal Source
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作者 Xiaoxin Yang 《Journal of Applied Mathematics and Physics》 2024年第1期181-193,共13页
This article investigates the well posedness and asymptotic behavior of Neumann initial boundary value problems for a class of pseudo-parabolic equations with singular potential and logarithmic nonlinearity. By utiliz... This article investigates the well posedness and asymptotic behavior of Neumann initial boundary value problems for a class of pseudo-parabolic equations with singular potential and logarithmic nonlinearity. By utilizing cut-off techniques and combining with the Faedo Galerkin approximation method, local solvability was established. Based on the potential well method and Hardy Sobolev inequality, derive the global existence of the solution. In addition, we also obtained the results of decay. 展开更多
关键词 Nonlocal Parabolic Equation Singular Potential Logarithmic Nonlocal Source Global Existence decay
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Effect of MnO_4^- and silver content on electrochemical behaviour of Pb-Ag alloy anodes during potential decay periods 被引量:4
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作者 张伟 涂常青 +2 位作者 陈艺锋 Houlachi GEORGEOS 肖利 《Transactions of Nonferrous Metals Society of China》 SCIE EI CAS CSCD 2013年第7期2174-2180,共7页
The effect of MnO4- and silver content on electrochemical behaviour of five commercial Pb-Ag alloy anodes was studied in acid zinc sulphate electrolyte with and without MnO4- ions at 38 °C during potential decay ... The effect of MnO4- and silver content on electrochemical behaviour of five commercial Pb-Ag alloy anodes was studied in acid zinc sulphate electrolyte with and without MnO4- ions at 38 °C during potential decay periods. When the anodes were immersed into acid zinc sulphate electrolyte without MnO4- ions, the Pb-0.72%Ag anode entered complete passivation state in the shortest time among the five anodes, followed by anodes Pb-0.67%Ag, Pb-0.60%Ag, Pb-0.58%Ag and Pb-0.29%Ag-0.1%Ca by measurement of open circuit potential. During immersion of the anodes, MnO4 ions accelerated the passivation and increased the corrosion current density of the anodes. After immersion in zinc electrolyte with MnO4-, the anode Pb-0.72%Ag had the best corrosion resistance, followed by anodes Pb-0.67%Ag, Pb-0.60%Ag, then the close anodes Pb-0.58%Ag and Pb-0.29%Ag-0.1%Ca by the electrochemical impedance spectroscopy (EIS) analysis. 展开更多
关键词 electrochemical behaviour Pb-Ag anode permanganate ion potential decay periods zinc sulphate electrolyte
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Decay rates and time lags of heat conduction in building construction under field conditions
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作者 彭昌海 吴智深 +1 位作者 陈振乾 李敏 《Journal of Southeast University(English Edition)》 EI CAS 2010年第2期249-253,共5页
The field measurements of decay rates and time lags of heat conduction in a building construction taken in Nanjing during the summer of 2001 are presented.The decay rates and time lags are calculated according to the ... The field measurements of decay rates and time lags of heat conduction in a building construction taken in Nanjing during the summer of 2001 are presented.The decay rates and time lags are calculated according to the frequency responses of the heat absorbed by the room's internal surfaces,inside surface temperature,indoor air temperature and outdoor synthetic temperature.The measured results match very well with the theoretical results of the zeroth and the first order values of the decay rates and time lags of heat conduction in the building construction,but the difference between the measured values and the theoretical values for the second order is too great to be accepted.It is therefore difficult to accurately test the second order value.However,it is still advisable to complete the analysis using the zeroth-and the first-orders values of the decay rates and time lags of heat conduction in building construction under field conditions,because in these cases the decay rates of heat conduction reach twenty which meets the requirements of engineering plans. 展开更多
关键词 decay rates time lags heat conduction building construction FIELD
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GLOBAL EXISTENCE, UNIFORM DECAY AND EXPONENTIAL GROWTH FOR A CLASS OF SEMI-LINEAR WAVE EQUATION WITH STRONG DAMPING 被引量:7
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作者 陈化 刘功伟 《Acta Mathematica Scientia》 SCIE CSCD 2013年第1期41-58,共18页
In this paper, we consider the nonlinearly damped semi-linear wave equation associated with initial and Dirichlet boundary conditions. We prove the existence of a local weak solution and introduce a family of potentia... In this paper, we consider the nonlinearly damped semi-linear wave equation associated with initial and Dirichlet boundary conditions. We prove the existence of a local weak solution and introduce a family of potential wells and discuss the invariants and vacuum isolating behavior of solutions. Furthermore, we prove the global existence of solutions in both cases which are polynomial and exponential decay in the energy space respectively, and the asymptotic behavior of solutions for the cases of potential well family with 0 〈 E(0) 〈 d. At last we show that the energy will grow up as an exponential function as time goes to infinity, provided the initial data is large enough or E(0) 〈 0. 展开更多
关键词 strong damping nonlinear damping global existence polynomial decay exponential decay exponential growth
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GENERAL DECAY OF SOLUTIONS FOR A VISCOELASTIC EQUATION WITH NONLINEAR DAMPING AND SOURCE TERMS 被引量:13
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作者 Wu Shuntang 《Acta Mathematica Scientia》 SCIE CSCD 2011年第4期1436-1448,共13页
The initial boundary value problem for a viscoelastic equation | u t | ρ u tt △u-△u tt + t 0 g(ts)△u(s)ds + | u t | m u t = | u | p u in a bounded domain is considered, where ρ, m, p 〉 0 and g is a n... The initial boundary value problem for a viscoelastic equation | u t | ρ u tt △u-△u tt + t 0 g(ts)△u(s)ds + | u t | m u t = | u | p u in a bounded domain is considered, where ρ, m, p 〉 0 and g is a nonnegative and decaying function. The general uniform decay of solution energy is discussed under some conditions on the relaxation function g and the initial data by adopting the method of [14, 15, 19]. This work generalizes and improves earlier results in the literature. 展开更多
关键词 global existence asymptotic behavior general decay
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L^2 DECAY OF THE INCOMPRESSIBLE NAVIER-STOKES EQUATIONS WITH DAMPING 被引量:6
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作者 蔡晓静 雷利华 《Acta Mathematica Scientia》 SCIE CSCD 2010年第4期1235-1248,共14页
In this article, we show large time behavior of weak solutions to the Cauchy problem of the Navier-Stokes equations with damping α|u|^β-1u (α0).
关键词 Navier-Stokes equations DAMPING weak solutions decay
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Optical Free-Induction Decay Effect in a Λ-Type Quantum-Beat Three-Level System 被引量:4
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作者 CAO Zhuo-liang 《Chinese Physics Letters》 SCIE CAS CSCD 1997年第5期352-355,共4页
With Bloch form,a coherent transient effect-optical free-induction decay is studied semiclassi-cally in theΛ-type three-level system driven by a coherent microwave field.The decay behavior has three contributions:a h... With Bloch form,a coherent transient effect-optical free-induction decay is studied semiclassi-cally in theΛ-type three-level system driven by a coherent microwave field.The decay behavior has three contributions:a homogeneous part with transverse relaxation time and two inhomo-geneous parts with different time constants that reflect the velocity bandwidth excited and the action of the driving microwave field. 展开更多
关键词 field. decay COHERENT
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Effect of 1-MCP on Senescence and Decay of Vegetable Soybean Pods During Storage 被引量:5
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作者 ZHENG Yong-hua, SU Xin-guo, ZHANG Lan, FENG Lei, WANG Feng and JIANG Yue-ming(College of Food Science and Technology, Nanjing Agricultural University, Nanjing 210095 , P.R.China South China Institute of Botany , Chinese Academy of Sciences , Guangzhou 510650 , P. R. China) 《Agricultural Sciences in China》 CAS CSCD 2002年第12期1393-1399,共7页
The effects of 1-MCP on decay and senescence in vegetable soybean pods during storage were investigated. Treatments with 0. 5,1, or 2μl L-1 1-MCP significantly inhibited the senescence process of harvested vegetable ... The effects of 1-MCP on decay and senescence in vegetable soybean pods during storage were investigated. Treatments with 0. 5,1, or 2μl L-1 1-MCP significantly inhibited the senescence process of harvested vegetable soybean pods, as manifested in lower levels of ethylene production, respiratory rate, MDA and superoxide contents and higher levels of SOD, ASA-POD activities, Vc and chlorophyll contents. Moreover, 1-MCP promoted PAL activity and lignin synthesis, inhibited decay incidence. 2μl L-1-MCP treatment, however, inhibited PAL activity during the later period of storage, thereby increasing decay incidence. 展开更多
关键词 Vegetable soybean 1-MCP STORAGE ETHYLENE decay SENESCENCE
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Decay Dynamics of N, N-Dimethylthioacetamide in S3(ππ*) State
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作者 陈笑 薛佳丹 郑旭明 《Chinese Journal of Chemical Physics》 SCIE CAS CSCD 2015年第1期27-34,I0001,共9页
The decay dynamics of N, N-dimethylthioacetamide after excitation to the S3(ππ*) state was studied by using the resonance Raman spectroscopy and complete active space self- consistent field method calculations. T... The decay dynamics of N, N-dimethylthioacetamide after excitation to the S3(ππ*) state was studied by using the resonance Raman spectroscopy and complete active space self- consistent field method calculations. The UV-absorption and vibrational spectra were as- signed. The A-band resonance Raman spectra were obtained in acetonitrile, methanol and water with the laser excitation wavelengths in resonance with the first intense absorption band to probe the Franck-Condon region structural dynamics. The CASSCF calculations were carried out to determine the excitation energies and optimized structures of the lower- lying singlet states and conical intersection point. The A-band structural dynamics and the corresponding decay mechanism were obtained by the analysis of the resonance Raman in- tensity pattern and the CASSCF calculated structural parameters. The major decay channel of S3,FC (ππ*)→S3(ππ*)/S1 (nπ*)→S1(nπ*) is proposed. 展开更多
关键词 N N-Dimethylthioacetamide Structural dynamics decay dynamics Reso-nance Raman spectrum CASSCF calculation Conical intersection
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