Nd2O3 doped BaTiO3ceramics（the additive content was respectively 0.001, 0.002, 0.003, 0.005, 0.01 molar ratio）were prepared by Sol-Gel method to study their dielectric characteristics and electric conductivities thr...Nd2O3 doped BaTiO3ceramics（the additive content was respectively 0.001, 0.002, 0.003, 0.005, 0.01 molar ratio）were prepared by Sol-Gel method to study their dielectric characteristics and electric conductivities through X-ray photoelectron spectrum （XPS）. The results showed that the dielectric characteristics of Nd2O3 doped BaTiO3 ceramics were improved by doping. When Nd2O3 content was 0.003 mol, the results were even better, the dielectric constant was increased, the dielectric loss was decreased, the Curie-temperature （Tc） was 110 ℃, and the frequency characteristic was also good. The resistivity of Nd2O3 doped BaTiO3 ceramics was lower than that of pure BaTiO3 ceramics, when Nd2O3 content was 0.001 mol,the resistivity was （2.364×）108 Ω·m, the smallest. The grain resistance of Nd2O3 doped BaTiO3 ceramics exhibited NTC effect, but the grain boundary resistance showed PTC effect, and the grain boundary resistance was larger than that of the grain resistance, so the PTC effect originated from the grain boundary. The analysis of the element binding energy through X-ray photoelectron spectrum were indicated that the quantivalence of Ba2+and Ti4+in Nd2O3 doped BaTiO3 ceramics was variable, and resulted in the improvement of the conductibility of BaTiO3 ceramics.展开更多
The magnetotelluric （MT） survey along the Zhada （札达）-Quanshui （泉水） Lake profile on the western margin of the Qinghai （青海）-Tibet plateau shows that the study area is divided into three tectonic provinces ...The magnetotelluric （MT） survey along the Zhada （札达）-Quanshui （泉水） Lake profile on the western margin of the Qinghai （青海）-Tibet plateau shows that the study area is divided into three tectonic provinces by the Yalung Tsangpo and Bangong （班公）-Nujiang （怒江） sutures. From south to north these are the Himalayan terrane, Gangdise terrane, and Qiangtang （羌塘） terrane. For the study area, there are widespread high-conductivity layers in the mid and lower crust, the top layers of which fluctuate intensively. The high-conductivity layer within the Gangdise terrane is deeper than those within the Qiangtang terrane and the Himalaya terrane, and the deepest high-conductivity layer is to the south of the Bangong-Nujiang suture. The top surface of the high-conductivity layer in the south of the Bangong-Nujiang suture is about 20 km lower than that in the north of it. The high-conductivity layer within the Gangdise terrane dips toward north and there are two high-conductivity layers within the crust of the southern Qiangtang terrane. In the upper crust along the profile, there are groups of lateral electrical gradient zones or distortion zones of different scales and occurrence indicating the distribution of faults and sutures along the profile. According to the electrical structure, the structural characteristics and space distribution of the Yalung Tsangpo suture, Bangong.Nujiang suture, and the major faults of Longmucuo （龙木错） and Geerzangbu are inferred.展开更多
文摘Nd2O3 doped BaTiO3ceramics（the additive content was respectively 0.001, 0.002, 0.003, 0.005, 0.01 molar ratio）were prepared by Sol-Gel method to study their dielectric characteristics and electric conductivities through X-ray photoelectron spectrum （XPS）. The results showed that the dielectric characteristics of Nd2O3 doped BaTiO3 ceramics were improved by doping. When Nd2O3 content was 0.003 mol, the results were even better, the dielectric constant was increased, the dielectric loss was decreased, the Curie-temperature （Tc） was 110 ℃, and the frequency characteristic was also good. The resistivity of Nd2O3 doped BaTiO3 ceramics was lower than that of pure BaTiO3 ceramics, when Nd2O3 content was 0.001 mol,the resistivity was （2.364×）108 Ω·m, the smallest. The grain resistance of Nd2O3 doped BaTiO3 ceramics exhibited NTC effect, but the grain boundary resistance showed PTC effect, and the grain boundary resistance was larger than that of the grain resistance, so the PTC effect originated from the grain boundary. The analysis of the element binding energy through X-ray photoelectron spectrum were indicated that the quantivalence of Ba2+and Ti4+in Nd2O3 doped BaTiO3 ceramics was variable, and resulted in the improvement of the conductibility of BaTiO3 ceramics.
基金This paper is supported by the National Natural Science Foundation of China (No. 40404006)the Focused Subject Program of Beijing (No. XK104910598).
文摘The magnetotelluric （MT） survey along the Zhada （札达）-Quanshui （泉水） Lake profile on the western margin of the Qinghai （青海）-Tibet plateau shows that the study area is divided into three tectonic provinces by the Yalung Tsangpo and Bangong （班公）-Nujiang （怒江） sutures. From south to north these are the Himalayan terrane, Gangdise terrane, and Qiangtang （羌塘） terrane. For the study area, there are widespread high-conductivity layers in the mid and lower crust, the top layers of which fluctuate intensively. The high-conductivity layer within the Gangdise terrane is deeper than those within the Qiangtang terrane and the Himalaya terrane, and the deepest high-conductivity layer is to the south of the Bangong-Nujiang suture. The top surface of the high-conductivity layer in the south of the Bangong-Nujiang suture is about 20 km lower than that in the north of it. The high-conductivity layer within the Gangdise terrane dips toward north and there are two high-conductivity layers within the crust of the southern Qiangtang terrane. In the upper crust along the profile, there are groups of lateral electrical gradient zones or distortion zones of different scales and occurrence indicating the distribution of faults and sutures along the profile. According to the electrical structure, the structural characteristics and space distribution of the Yalung Tsangpo suture, Bangong.Nujiang suture, and the major faults of Longmucuo （龙木错） and Geerzangbu are inferred.
