The effect of fluidity on open cell AZ31 metal foam samples fabricated using a solid state space holder method was investigated.Granule was fabricated by plaster powder and perlite powder.Granules were sieved which co...The effect of fluidity on open cell AZ31 metal foam samples fabricated using a solid state space holder method was investigated.Granule was fabricated by plaster powder and perlite powder.Granules were sieved which compacted layer by layer in casting mold.Preforms which made by granules were then heated to 200℃,300℃,400℃,500℃ under a rough(mechanical)vacuum before pressure infiltration with AZ31 Mg alloy.Samples were infiltrated using vacuum pressure values range of 8-14 KPa.The conditions of pressure and temperature were performed in order to get different fluidity on manufacturer of open cell AZ31 metal foam specimen quantity.It is found that the fluidity plays significant role to determine the open cell AZ31 alloy foam.The fluidity is affected by preheat temperature and infiltration vacuum pressure.The macrostructure,the distribution of the pores,microstructure,infiltration length,and porosity were investigated.展开更多
The aluminum open cell foams have been prepared by the conventional precision casting method to investigate the thermal and acoustic properties.A water heating system and silencers were organized as a first step for i...The aluminum open cell foams have been prepared by the conventional precision casting method to investigate the thermal and acoustic properties.A water heating system and silencers were organized as a first step for its applications.The temperature increase between the top and bottom of the foam became larger as the cell size increased in the heat transfer measurement.Sound absorption ratio of the close cell foams was 60%-100%, whereas the open cell aluminum foam showed only 10%-20% of sound absorption at low frequency.When the prototype electric water heater manufactured by combining aluminum open cell foam with a heater was heated to 100-400℃,the highest temperature of water was in the range of 16-46~C.This suggests that there could be potential for this type of heater to be used as a commercial electric water heater.Sound silencer made with the aluminum open cell foam was applied to exit of exhaustion side at air pressure line.Sound silencing effect of open-celled aluminum foam showed that the noise level went down by introducing smaller cell size foam.展开更多
This manuscript deals with the electro-deposition of Cu on aluminum foams. Metallic foams are highly porous materials which present complex structure of three-dimensional open cells. This aspect causes strong limitati...This manuscript deals with the electro-deposition of Cu on aluminum foams. Metallic foams are highly porous materials which present complex structure of three-dimensional open cells. This aspect causes strong limitations in mass transport due to electro-deposition technology. Experimental tests were performed to study the influence of the operational parameters on the overall performance of the coated aluminum foams. The experimental findings revealed that the manufactured metal foams were characterized by a high thermal conductivity and low process costs, making these materials very promising in many technological fields. On the basis of the experimental results, analytical models are proposed to predict the quantity and the quality characteristics of the coating.展开更多
The monocrystalline silicon is a promising material that could be used in solar cells that convert light into electricity. Although the cost of ordinary silicon (Si) solar cells has decreased significantly over the pa...The monocrystalline silicon is a promising material that could be used in solar cells that convert light into electricity. Although the cost of ordinary silicon (Si) solar cells has decreased significantly over the past two decades, the conversion efficiency of these cells has remained relatively high. While solar cells have a great potential as a device of renewable energy, the high cost they incur per Watt continues to be a significant barrier to their widespread implementation. As a consequence, it is vital to conduct research into alternate materials that may be used in the construction of solar cells. The heterojunction solar cell (HJSC), which is based on n-type zinc oxide (n-ZnO) and p-type silicon (p-Si), is one of the numerous alternatives of the typical Si single homojunction solar cell. There are many deficiencies that can be found in the published research on n-ZnO/p-Si heterojunction solar cell. Inconsistencies in the stated value of open circuit voltage (V<sub>oc</sub>) of the solar cell are one example of deficiency. The absence of a full theoretical study to evaluate the potential of the solar cell structure is another deficiency that can be found in these researches. A lower value of experimentally obtained V<sub>OC</sub> in comparison to the theoretical prediction based on the band-gap between n-ZnO and p-Si. There needs to be more consensus among scientists regarding the optimal conditions for the growth of zinc oxide. Many software’s are available for simulating and optimizing the solar cells based on these parameters. For this purpose, in this dissertation, I provide computational results relevant to n-ZnO/p-Si HJSC to overcome deficiencies that have been identified. While modeling and simulating the potential of the solar cell structure with AFORS-HET, it is essential to consider the constraints that exist in the real world. AFORS-HET was explicitly designed to mimic the multilayer solar cell arrangement. In AFORS-HET, we can add up to seven layers for solar cell layout. By using this software, we can figure out the open circuit voltage (V<sub>OC</sub>), the short circuit current (J<sub>SC</sub>), the quantum efficiency (QE, %), the heterojunction energy band structure, and the power conversion efficiency (PCE).展开更多
The random models of open-cell foams that can reflect the actual cell geometrical properties are constructed with the Voronoi technique. The compression process of elastic open-cell foams is simulated with the nonline...The random models of open-cell foams that can reflect the actual cell geometrical properties are constructed with the Voronoi technique. The compression process of elastic open-cell foams is simulated with the nonlinear calculation module of finite element analysis program. In order to get the general results applicable to this kind of materials, the dimensionless compressive stress is used and the stress-strain curves of foam models with different geometrical properties are obtained. Then, the influences of open-cell geometrical properties, including the shape of strut cross section, relative density and cell shape irregularity, on the compressive nonlinear mechani- cal performance are analyzed. In addition, the numerical results are compared with the predicted results of cubic staggering model. Nu- merical results indicate that the simulated results reflect the compressive process of foams quite well and the geometrical properties of cell have significant influences on the nonlinear mechanical behavior of foams.展开更多
Contrastive research was carried out to study the thermal properties of open-celled aluminum foams prepared by counter-gravity infiltration casting system and the traditional process respectively.The experimental resu...Contrastive research was carried out to study the thermal properties of open-celled aluminum foams prepared by counter-gravity infiltration casting system and the traditional process respectively.The experimental results show that the thermal conductivity coefficients of aluminum foams prepared by two different infiltration methods have similar increasing trend with the increase of particle size;along with the reducing porosity,the thermal conductivity coefficients will be enhanced oppositely.However,with the same particle size,the open-celled aluminum foam prepared by the former method has a higher thermal conductivity coefficient obviously.It is largely because that the sample prepared by counter-gravity infiltration casting has a lower void content and better dense crystallization of metal-matrix after the constant pressure process.展开更多
Based on the elongated Kelvin obtained to investigate the tensile behavior Kelvin model's periodicity and symmetry in model, a simplified periodic structural cell is of anisotropic open-cell elastic foams due to the ...Based on the elongated Kelvin obtained to investigate the tensile behavior Kelvin model's periodicity and symmetry in model, a simplified periodic structural cell is of anisotropic open-cell elastic foams due to the whole space. The half-strut element and elastic deflection theory are used to analyze the tensile response as done in the previous studies. This study produces theoretical expressions for the tensile stress-strain curve in the rise and transverse directions. In addition, the theoretical results are examined with finite element simulation using an existing formula. The results indicate that the theoretical analysis agrees with the finite element simulation when the strain is not too high, and the present model is better. At the same time, the anisotropy ratio has a significant effect on the mechanical properties of foams. As the anisotropy ratio increases, the tensile stress is improved in the rising direction but drops in the transverse direction under the same strain.展开更多
Metal foams are a new kind of materials with low densities and novel physical, mechanical, thermal, electrical and acoustic properties. They can be divided into closed and open cell structures. In this paper the open ...Metal foams are a new kind of materials with low densities and novel physical, mechanical, thermal, electrical and acoustic properties. They can be divided into closed and open cell structures. In this paper the open cell structures, called sponges, were treated. A new technique to manufacture sponges by plaster investment casting was described. Experimental results show that it is essential to make a sound plaster mould by casting plaster slurry into the polyurethane foams and infiltrate the open channels of the baked plaster mold by molten metal. The optimal processes include plaster slurry preparation, plaster mold baking, and molten metal infiltration. The sponge sample with porosity of 97% is presented.展开更多
Based on the elongated Kelvin model, the effect of microstructure on the uniaxial strength asymmetry of open-cell foams is investigated. The results indicate that this asymmetry depends on the relative density, the so...Based on the elongated Kelvin model, the effect of microstructure on the uniaxial strength asymmetry of open-cell foams is investigated. The results indicate that this asymmetry depends on the relative density, the solid material, the cell morphology, and the strut geometry of open-cell foams. Even though the solid material has the same tensile and compressive strength, the tensile and compressive strength of open-cell foams with asymmetrical sectional struts are still different. In addition, with the increasing degree of anisotropy, the uniaxial strength as well as the strength asymmetry increases in the rise direction but reduces in the transverse direction. Moreover, the plastic collapse ratio between two directions is verified to depend mainly on the cell morphology. The predicted results are compared with Gibson and Ashby's theoretical results as well as the experimental data reported in the literature, which validates that the elongated Kelvin model is accurate in explaining the strength asymmetry presented in realistic open-cell foams.展开更多
Foamed zinc was prepared by infiltration casting process.The mechanical properties and corrosion resistance of the samples were studied,and the feasibility of the foamed zinc as a bone implant material was discussed.A...Foamed zinc was prepared by infiltration casting process.The mechanical properties and corrosion resistance of the samples were studied,and the feasibility of the foamed zinc as a bone implant material was discussed.All the compression stress-strain curves of open-cell zinc foams with various cell size(1-4 mm)and porosity(55%-67%)show three stages:elastic stage,plastic stage,and densification stage.The compression strength increases with decreasing density.The smooth stress-strain response indicates a progressively deformation of open-cell zinc foam.In addition,the cell wall or edge bending and fracture are the dominated mechanisms for failure of open cell zinc foam.The immersion test for determining the corrosion rate of open cell zinc foam was conducted in simulated body fluid.It was found that zinc foam with a small cell size and high porosity showed a higher corrosion rate.In addition,open-cell zinc foams can effectively induce Ca-P deposition in immersion tests,showing good bioactivity.Therefore,the open cell zinc foam prepared in this experiment has a good potential application as a human bone substitute material.展开更多
The objective of this study is to find an effective method to improve Voc without Jsc loss for Cu2ZnSnSe4 (CZTSe) thin film solar cells, which have been fabricated by the one step co-evaporation technique. Surface s...The objective of this study is to find an effective method to improve Voc without Jsc loss for Cu2ZnSnSe4 (CZTSe) thin film solar cells, which have been fabricated by the one step co-evaporation technique. Surface sulfurization of CZTSe thin films is carried out by using one technique that does not utilize toxic H2S gas; a sequential evaporation of SnS after CZTSe deposition and the annealing of CZTSe thin films in selenium vapor. A Cu2ZnSn(S, Se)4 (CZTSSe) thin layer is grown on the surface of the CZTSe thin film after the annealing. The conversion efficiency of the completed device is improved due to the enhancement of Voc, which could be attributed to the formation of a hole-recombination barrier at the surface or the passivation of the surface and grain boundary by S incorporation.展开更多
This paper identifies the contributions of p-a-SiC:H layers and i-a-Si:H layers to the open circuit voltage of p-i-n type a-Si:H solar cells deposited at a low temperature of 125℃. We find that poor quality p-a-Si...This paper identifies the contributions of p-a-SiC:H layers and i-a-Si:H layers to the open circuit voltage of p-i-n type a-Si:H solar cells deposited at a low temperature of 125℃. We find that poor quality p-a-SiC:H films under regular conditions lead to a restriction of open circuit voltage although the band gap of the i-layer varies widely. A significant improvement in open circuit voltage has been obtained by using high quality p-~SiC:H films optimized at the "low-power regime" under low silane flow rates and high hydrogen dilution conditions.展开更多
The effect of the parameters on the open-circuit voltage, V_(OC) of a-Si:H/c-Si heterojunction solar cells was explored by an analytical model. The analytical results show that V_(OC) increases linearly with the logar...The effect of the parameters on the open-circuit voltage, V_(OC) of a-Si:H/c-Si heterojunction solar cells was explored by an analytical model. The analytical results show that V_(OC) increases linearly with the logarithm of illumination intensity under usual illumination. There are two critical values of the interface state density(D_(it)) for the open-circuit voltage(V_(OC)), D_(it)^(crit,1) and D_(it)crit,2(a few 1010 cm^(-2)·e V^(-1)). V_(OC) decreases remarkably when D_(it) is higher than D_(it)^(crit,1). To achieve high V_(OC), the interface states should reduce down to a few 1010 cm^(-2)·e V^(-1). Due to the difference between the effective density of states in the conduction and valence band edges of c-Si, the open-circuit voltage of a-Si:H/c-Si heterojunction cells fabricated on n-type c-Si wafers is about 22 mV higher than that fabricated on p-type c-Si wafers at the same case. V_(OC) decreases with decreasing the a-Si:H doping concentration at low doping level since the electric field over the c-Si depletion region is reduced at low doping level. Therefore, the a-Si:H layer should be doped higher than a critical value of 5×10^(18) cm^(-3) to achieve high V_(OC).展开更多
AIM: To evaluate the patterns of macular ganglion cell-inner plexiform layer(GCIPL) loss in normal tension glaucoma(NTG) and primary open angle glaucoma(POAG) in a detailed, disease severity-matched way;and to assess ...AIM: To evaluate the patterns of macular ganglion cell-inner plexiform layer(GCIPL) loss in normal tension glaucoma(NTG) and primary open angle glaucoma(POAG) in a detailed, disease severity-matched way;and to assess the diagnostic capabilities of GCIPL thickness parameters in discriminating NTG or POAG from normal subjects.METHODS: A total of 157 eyes of 157 subjects, including 57 normal eyes, 51 eyes with POAG and 49 eyes with NTG were enrolled and strictly matched in age, refraction, and disease severity between POAG and NTG groups. The average, minimum, superotemporal, superior, superonasal, inferonasal, inferior, and inferotemporal GCIPL thickness, and the average, superior, temporal, inferior, and nasal retinal nerve fiber layer(RNFL) thickness were obtained by Cirrus optical coherence tomography(OCT). The diagnostic capabilities of OCT parameters were assessed by area under receiver operating characteristic(AUROC) curves. RESULTS: Among all the OCT thickness parameters, no statistical significant difference between NTG group and POAG group was found(all P>0.05). In discriminating NTG or POAG from normal subjects, the average and inferior RNFL thickness, and the minimum GCIPL thickness had better diagnostic capabilities. There was no significant difference in AUROC curve between the best GCIPL thickness parameter(minimum GCIPL) and the best RNFL thickness parameter in discriminating NTG(inferior RNFL;P=0.076) and indiscriminating POAG(average RNFL;P=0.913) from normal eyes.CONCLUSION: Localized GCIPL loss, especially in the inferior and inferotemporal sectors, is more common in NTG than in POAG. Among all the GCIPL thickness parameters, the minimum GCIPL thickness has the best diagnostic performance in differentiating NTG or POAG from normal subjects, which is comparable to that of the average and inferior RNFL thickness.展开更多
文摘The effect of fluidity on open cell AZ31 metal foam samples fabricated using a solid state space holder method was investigated.Granule was fabricated by plaster powder and perlite powder.Granules were sieved which compacted layer by layer in casting mold.Preforms which made by granules were then heated to 200℃,300℃,400℃,500℃ under a rough(mechanical)vacuum before pressure infiltration with AZ31 Mg alloy.Samples were infiltrated using vacuum pressure values range of 8-14 KPa.The conditions of pressure and temperature were performed in order to get different fluidity on manufacturer of open cell AZ31 metal foam specimen quantity.It is found that the fluidity plays significant role to determine the open cell AZ31 alloy foam.The fluidity is affected by preheat temperature and infiltration vacuum pressure.The macrostructure,the distribution of the pores,microstructure,infiltration length,and porosity were investigated.
文摘The aluminum open cell foams have been prepared by the conventional precision casting method to investigate the thermal and acoustic properties.A water heating system and silencers were organized as a first step for its applications.The temperature increase between the top and bottom of the foam became larger as the cell size increased in the heat transfer measurement.Sound absorption ratio of the close cell foams was 60%-100%, whereas the open cell aluminum foam showed only 10%-20% of sound absorption at low frequency.When the prototype electric water heater manufactured by combining aluminum open cell foam with a heater was heated to 100-400℃,the highest temperature of water was in the range of 16-46~C.This suggests that there could be potential for this type of heater to be used as a commercial electric water heater.Sound silencer made with the aluminum open cell foam was applied to exit of exhaustion side at air pressure line.Sound silencing effect of open-celled aluminum foam showed that the noise level went down by introducing smaller cell size foam.
文摘This manuscript deals with the electro-deposition of Cu on aluminum foams. Metallic foams are highly porous materials which present complex structure of three-dimensional open cells. This aspect causes strong limitations in mass transport due to electro-deposition technology. Experimental tests were performed to study the influence of the operational parameters on the overall performance of the coated aluminum foams. The experimental findings revealed that the manufactured metal foams were characterized by a high thermal conductivity and low process costs, making these materials very promising in many technological fields. On the basis of the experimental results, analytical models are proposed to predict the quantity and the quality characteristics of the coating.
文摘The monocrystalline silicon is a promising material that could be used in solar cells that convert light into electricity. Although the cost of ordinary silicon (Si) solar cells has decreased significantly over the past two decades, the conversion efficiency of these cells has remained relatively high. While solar cells have a great potential as a device of renewable energy, the high cost they incur per Watt continues to be a significant barrier to their widespread implementation. As a consequence, it is vital to conduct research into alternate materials that may be used in the construction of solar cells. The heterojunction solar cell (HJSC), which is based on n-type zinc oxide (n-ZnO) and p-type silicon (p-Si), is one of the numerous alternatives of the typical Si single homojunction solar cell. There are many deficiencies that can be found in the published research on n-ZnO/p-Si heterojunction solar cell. Inconsistencies in the stated value of open circuit voltage (V<sub>oc</sub>) of the solar cell are one example of deficiency. The absence of a full theoretical study to evaluate the potential of the solar cell structure is another deficiency that can be found in these researches. A lower value of experimentally obtained V<sub>OC</sub> in comparison to the theoretical prediction based on the band-gap between n-ZnO and p-Si. There needs to be more consensus among scientists regarding the optimal conditions for the growth of zinc oxide. Many software’s are available for simulating and optimizing the solar cells based on these parameters. For this purpose, in this dissertation, I provide computational results relevant to n-ZnO/p-Si HJSC to overcome deficiencies that have been identified. While modeling and simulating the potential of the solar cell structure with AFORS-HET, it is essential to consider the constraints that exist in the real world. AFORS-HET was explicitly designed to mimic the multilayer solar cell arrangement. In AFORS-HET, we can add up to seven layers for solar cell layout. By using this software, we can figure out the open circuit voltage (V<sub>OC</sub>), the short circuit current (J<sub>SC</sub>), the quantum efficiency (QE, %), the heterojunction energy band structure, and the power conversion efficiency (PCE).
基金National Natural Science Foundation of China (10572013) ECB Foundation (XK100060522)
文摘The random models of open-cell foams that can reflect the actual cell geometrical properties are constructed with the Voronoi technique. The compression process of elastic open-cell foams is simulated with the nonlinear calculation module of finite element analysis program. In order to get the general results applicable to this kind of materials, the dimensionless compressive stress is used and the stress-strain curves of foam models with different geometrical properties are obtained. Then, the influences of open-cell geometrical properties, including the shape of strut cross section, relative density and cell shape irregularity, on the compressive nonlinear mechani- cal performance are analyzed. In addition, the numerical results are compared with the predicted results of cubic staggering model. Nu- merical results indicate that the simulated results reflect the compressive process of foams quite well and the geometrical properties of cell have significant influences on the nonlinear mechanical behavior of foams.
基金Project(51304254) supported by the National Natural Science Foundation of ChinaProject(2013GK4064) supported by the Strategic Emerging Industry Program of the Ministry of Science and Technology of Hunan Province,China
文摘Contrastive research was carried out to study the thermal properties of open-celled aluminum foams prepared by counter-gravity infiltration casting system and the traditional process respectively.The experimental results show that the thermal conductivity coefficients of aluminum foams prepared by two different infiltration methods have similar increasing trend with the increase of particle size;along with the reducing porosity,the thermal conductivity coefficients will be enhanced oppositely.However,with the same particle size,the open-celled aluminum foam prepared by the former method has a higher thermal conductivity coefficient obviously.It is largely because that the sample prepared by counter-gravity infiltration casting has a lower void content and better dense crystallization of metal-matrix after the constant pressure process.
基金Project supported by the National Natural Science Foundation of China(Nos.11472025 and 11272030)
文摘Based on the elongated Kelvin obtained to investigate the tensile behavior Kelvin model's periodicity and symmetry in model, a simplified periodic structural cell is of anisotropic open-cell elastic foams due to the whole space. The half-strut element and elastic deflection theory are used to analyze the tensile response as done in the previous studies. This study produces theoretical expressions for the tensile stress-strain curve in the rise and transverse directions. In addition, the theoretical results are examined with finite element simulation using an existing formula. The results indicate that the theoretical analysis agrees with the finite element simulation when the strain is not too high, and the present model is better. At the same time, the anisotropy ratio has a significant effect on the mechanical properties of foams. As the anisotropy ratio increases, the tensile stress is improved in the rising direction but drops in the transverse direction under the same strain.
文摘Metal foams are a new kind of materials with low densities and novel physical, mechanical, thermal, electrical and acoustic properties. They can be divided into closed and open cell structures. In this paper the open cell structures, called sponges, were treated. A new technique to manufacture sponges by plaster investment casting was described. Experimental results show that it is essential to make a sound plaster mould by casting plaster slurry into the polyurethane foams and infiltrate the open channels of the baked plaster mold by molten metal. The optimal processes include plaster slurry preparation, plaster mold baking, and molten metal infiltration. The sponge sample with porosity of 97% is presented.
基金Project supported by the National Natural Science Foundation of China(Nos.11472025 and 11272030)
文摘Based on the elongated Kelvin model, the effect of microstructure on the uniaxial strength asymmetry of open-cell foams is investigated. The results indicate that this asymmetry depends on the relative density, the solid material, the cell morphology, and the strut geometry of open-cell foams. Even though the solid material has the same tensile and compressive strength, the tensile and compressive strength of open-cell foams with asymmetrical sectional struts are still different. In addition, with the increasing degree of anisotropy, the uniaxial strength as well as the strength asymmetry increases in the rise direction but reduces in the transverse direction. Moreover, the plastic collapse ratio between two directions is verified to depend mainly on the cell morphology. The predicted results are compared with Gibson and Ashby's theoretical results as well as the experimental data reported in the literature, which validates that the elongated Kelvin model is accurate in explaining the strength asymmetry presented in realistic open-cell foams.
基金Key Research and Development Program of Liaoning Province(2019JH2/10100008)the Plan for Innovative Talents in Liaoning Higher Education Institutions(LR2018011)the Plan for Young and Middle-aged Science and Technology Innovation Talent of Shenyang(RC170204).
文摘Foamed zinc was prepared by infiltration casting process.The mechanical properties and corrosion resistance of the samples were studied,and the feasibility of the foamed zinc as a bone implant material was discussed.All the compression stress-strain curves of open-cell zinc foams with various cell size(1-4 mm)and porosity(55%-67%)show three stages:elastic stage,plastic stage,and densification stage.The compression strength increases with decreasing density.The smooth stress-strain response indicates a progressively deformation of open-cell zinc foam.In addition,the cell wall or edge bending and fracture are the dominated mechanisms for failure of open cell zinc foam.The immersion test for determining the corrosion rate of open cell zinc foam was conducted in simulated body fluid.It was found that zinc foam with a small cell size and high porosity showed a higher corrosion rate.In addition,open-cell zinc foams can effectively induce Ca-P deposition in immersion tests,showing good bioactivity.Therefore,the open cell zinc foam prepared in this experiment has a good potential application as a human bone substitute material.
基金Supported by the Specialized Research Fund for the Doctoral Program of Higher Education under Grant No 20120031110039
文摘The objective of this study is to find an effective method to improve Voc without Jsc loss for Cu2ZnSnSe4 (CZTSe) thin film solar cells, which have been fabricated by the one step co-evaporation technique. Surface sulfurization of CZTSe thin films is carried out by using one technique that does not utilize toxic H2S gas; a sequential evaporation of SnS after CZTSe deposition and the annealing of CZTSe thin films in selenium vapor. A Cu2ZnSn(S, Se)4 (CZTSSe) thin layer is grown on the surface of the CZTSe thin film after the annealing. The conversion efficiency of the completed device is improved due to the enhancement of Voc, which could be attributed to the formation of a hole-recombination barrier at the surface or the passivation of the surface and grain boundary by S incorporation.
基金Project supported by the National High Technology Research and Development Program of China (Grant No. 2009AA05Z422), the National Basic Research Program of China (Grant Nos. 2011CBA00705, 2011CBA00706, and 2011CBA00707), and the Natural Science Foundation of Tianjin (Grant No. 08JCZDJC22200).
文摘This paper identifies the contributions of p-a-SiC:H layers and i-a-Si:H layers to the open circuit voltage of p-i-n type a-Si:H solar cells deposited at a low temperature of 125℃. We find that poor quality p-a-SiC:H films under regular conditions lead to a restriction of open circuit voltage although the band gap of the i-layer varies widely. A significant improvement in open circuit voltage has been obtained by using high quality p-~SiC:H films optimized at the "low-power regime" under low silane flow rates and high hydrogen dilution conditions.
基金Project(11374094)supported by the National Natural Science Foundation of ChinaProject(2013HZX23)supported by Natural Science Foundation of Hunan University of Technology,ChinaProject(2015JJ3060)supported by Natural Science Foundation of Hunan Province of China
文摘The effect of the parameters on the open-circuit voltage, V_(OC) of a-Si:H/c-Si heterojunction solar cells was explored by an analytical model. The analytical results show that V_(OC) increases linearly with the logarithm of illumination intensity under usual illumination. There are two critical values of the interface state density(D_(it)) for the open-circuit voltage(V_(OC)), D_(it)^(crit,1) and D_(it)crit,2(a few 1010 cm^(-2)·e V^(-1)). V_(OC) decreases remarkably when D_(it) is higher than D_(it)^(crit,1). To achieve high V_(OC), the interface states should reduce down to a few 1010 cm^(-2)·e V^(-1). Due to the difference between the effective density of states in the conduction and valence band edges of c-Si, the open-circuit voltage of a-Si:H/c-Si heterojunction cells fabricated on n-type c-Si wafers is about 22 mV higher than that fabricated on p-type c-Si wafers at the same case. V_(OC) decreases with decreasing the a-Si:H doping concentration at low doping level since the electric field over the c-Si depletion region is reduced at low doping level. Therefore, the a-Si:H layer should be doped higher than a critical value of 5×10^(18) cm^(-3) to achieve high V_(OC).
基金Supported by National Natural Science Foundation of China(No.81800879)Natural Science Foundation of Guangdong Province(No.2017A030310372)+2 种基金Fundamental Research Funds of the State Key Laboratory of Ophthalmology,China(No.2018KF04 No.2017QN05)Sun Yat-Sen University Clinical Research 5010 Program(No.2014016)
文摘AIM: To evaluate the patterns of macular ganglion cell-inner plexiform layer(GCIPL) loss in normal tension glaucoma(NTG) and primary open angle glaucoma(POAG) in a detailed, disease severity-matched way;and to assess the diagnostic capabilities of GCIPL thickness parameters in discriminating NTG or POAG from normal subjects.METHODS: A total of 157 eyes of 157 subjects, including 57 normal eyes, 51 eyes with POAG and 49 eyes with NTG were enrolled and strictly matched in age, refraction, and disease severity between POAG and NTG groups. The average, minimum, superotemporal, superior, superonasal, inferonasal, inferior, and inferotemporal GCIPL thickness, and the average, superior, temporal, inferior, and nasal retinal nerve fiber layer(RNFL) thickness were obtained by Cirrus optical coherence tomography(OCT). The diagnostic capabilities of OCT parameters were assessed by area under receiver operating characteristic(AUROC) curves. RESULTS: Among all the OCT thickness parameters, no statistical significant difference between NTG group and POAG group was found(all P>0.05). In discriminating NTG or POAG from normal subjects, the average and inferior RNFL thickness, and the minimum GCIPL thickness had better diagnostic capabilities. There was no significant difference in AUROC curve between the best GCIPL thickness parameter(minimum GCIPL) and the best RNFL thickness parameter in discriminating NTG(inferior RNFL;P=0.076) and indiscriminating POAG(average RNFL;P=0.913) from normal eyes.CONCLUSION: Localized GCIPL loss, especially in the inferior and inferotemporal sectors, is more common in NTG than in POAG. Among all the GCIPL thickness parameters, the minimum GCIPL thickness has the best diagnostic performance in differentiating NTG or POAG from normal subjects, which is comparable to that of the average and inferior RNFL thickness.