First,screw theory,product of exponential formulas and Jacobian matrix are introduced.Then definitions are given about active force wrench,inertial force wrench,partial velocity twist,generalized active force,and gene...First,screw theory,product of exponential formulas and Jacobian matrix are introduced.Then definitions are given about active force wrench,inertial force wrench,partial velocity twist,generalized active force,and generalized inertial force according to screw theory.After that Kane dynamic equations based on screw theory for open-chain manipulators have been derived. Later on how to compute the partial velocity twist by geometrical method is illustrated. Finally the correctness of conclusions is verified by example.展开更多
The geometry and the energy of conformers of PnHn+2(n=2-9) have been studied with PM3 method. It is concluded that gauche interaction between adjacent lone electron pairs and gauche interaction between P-H bond with a...The geometry and the energy of conformers of PnHn+2(n=2-9) have been studied with PM3 method. It is concluded that gauche interaction between adjacent lone electron pairs and gauche interaction between P-H bond with adjacent P-P bond are important for predicting the stable conformer of open-chain phosphoanes.展开更多
文摘First,screw theory,product of exponential formulas and Jacobian matrix are introduced.Then definitions are given about active force wrench,inertial force wrench,partial velocity twist,generalized active force,and generalized inertial force according to screw theory.After that Kane dynamic equations based on screw theory for open-chain manipulators have been derived. Later on how to compute the partial velocity twist by geometrical method is illustrated. Finally the correctness of conclusions is verified by example.
文摘The geometry and the energy of conformers of PnHn+2(n=2-9) have been studied with PM3 method. It is concluded that gauche interaction between adjacent lone electron pairs and gauche interaction between P-H bond with adjacent P-P bond are important for predicting the stable conformer of open-chain phosphoanes.