A novel 3-D inorganic bimetallic compound Ag2Mo2O7 has been hydrothermally synthesized and structurally characterized by X-ray diffraction. The compound crystallizes in monoclinic, space group P21/c with a = 6.1274（3...A novel 3-D inorganic bimetallic compound Ag2Mo2O7 has been hydrothermally synthesized and structurally characterized by X-ray diffraction. The compound crystallizes in monoclinic, space group P21/c with a = 6.1274（3）, b = 13.1836（6）, c = 7.8780（3）A, β= 110.673（3）°, V = 595.42（5）A3, Z= 4, Mr= 519.62, Dc = 5.797g/cm^3, F（000） = 936,μ（MoKα） = 10.579 mm^-1, F（000） = 936, the final R = 0.0204 and wR = 0.0477 for 1268 observed reflections with I〉 2σ（I）. In the title compound, the [Mo4O16]n^8n-chains are linked through O-Ag-O bridging bonds to form a 3D network. It represents an unprecedented linking mode between the isopolyoxomolybdate chain and the transition metal oxide cluster. IR, TGA and fluorescence properties of the title compound are also studied.展开更多
A novel open-framework vanadium(W) phosphate(H_3NCH_2CH_2NH_3)_3[(VO)_4(PP_4)_2(HPO_4)_4] (short for V_2P_3-en) has been prepared. It issynthesized hydrothermally in the presence of ethylenediamine (en) at 170 deg C f...A novel open-framework vanadium(W) phosphate(H_3NCH_2CH_2NH_3)_3[(VO)_4(PP_4)_2(HPO_4)_4] (short for V_2P_3-en) has been prepared. It issynthesized hydrothermally in the presence of ethylenediamine (en) at 170 deg C for 5 days byself-assembly from structurally simple precursors V_2O_5, H_3PO_4 and H_2O. The compound ischaracterized by means of Fourier transform-infrared spectroscopy (FT-IR),Thermogravimetry-differential thermal analysis (TG-DTA), X-ray powder diffraction analysis (XRD) andScanning electron microscopy (SEM). Furthermore, the composition-structure-thermal stabilityrelation of V_2P_3-en is explored in terms of crystal chemistry, and the potential approach to theenhancement of its thermal stability is proposed.展开更多
Using n-propylamine as a template,deioned water and secondary-butanol(butan-2-ol)as solvents,a three-dimensional(3D)open-framework aluminophosphate[C3NH10]·[HAl3P3O13](1)and a two-dimensional layered aluminophosp...Using n-propylamine as a template,deioned water and secondary-butanol(butan-2-ol)as solvents,a three-dimensional(3D)open-framework aluminophosphate[C3NH10]·[HAl3P3O13](1)and a two-dimensional layered aluminophosphate[C3NH10]3·[Al3P4O16](2)were crystallized from the initial mixtures with compositions of Al2O3:2.4 P2O5:5.0 n-propylamine:100 H2O/butan-2-ol,respectively.They are characterized by X-ray powder diffraction(XRD),thermogravimetric(TG),and elemental(CHN)analyses and structurally determined by single-crystal X-ray diffraction analysis.Compound 1 crystallizes in the monoclinic space group P21/c with a=0.85831(13)nm,b=1.7677(3)nm,c=1.04353(12)nm,=123.887(9)°,and V=1.3143(3)nm3.Compound 2 crystallizes in the monoclinic space group P21/c with a=1.1313(2)nm,b=1.4874(3)nm,c=1.8020(6)nm,=125.07(2)°,and V=2.4817(11)nm3.The results show that the properties of solvent have a significant influence on the structure-directing effect of n-propylamine in the crystallization of the open-framework aluminophosphates.展开更多
The crystallization behavior of the initial mixture with the composition of Al2O3：4.0P2O5：3.0 diethylenetriamine（DETA）：xHF：153H2O was investigated at 180 ℃, where 0≤x≤3. If x≤1.8, three-dimensional openframe...The crystallization behavior of the initial mixture with the composition of Al2O3：4.0P2O5：3.0 diethylenetriamine（DETA）：xHF：153H2O was investigated at 180 ℃, where 0≤x≤3. If x≤1.8, three-dimensional openframework aluminophosphate AIPO-CJ31 was obtained. If 2 ≤x≤3, a chain-like aluminophosphate（1） was obtained. The crystallization process of both compounds was investigated by means of powder X-ray diffraction（XRD） and the concentrations of A1 and P in the liquid product during the crystallization process were analysed by means of induc- tively coupled plasma atomic emission spectroscopy（ICP-AES）. The evolution of the coordination state of A1, P and F during the crystallization was monitored with 27A1, 31p and 19F MAS NMR technique. The influence of the fluoride ions and the source of fluoride ions on the structure-directing effect of DETA was discussed. It was found that the fluoride ions changed the crystallization direction of the initial mixture, i.e., the structure-directing effect of DETA, via altering the distribution or micro-structure of the inorganic fragments.展开更多
井眼轨道控制系统包括轨道设计、丛式井防碰以及测斜数据分析处理等多个功能模块,需要满足不同井型设计、施工与数据分析的需求,同时要考虑系统可维护性、可扩展性,以满足现场应用的新需求。采用传统设计方法会面临模块化不足、维护升...井眼轨道控制系统包括轨道设计、丛式井防碰以及测斜数据分析处理等多个功能模块,需要满足不同井型设计、施工与数据分析的需求,同时要考虑系统可维护性、可扩展性,以满足现场应用的新需求。采用传统设计方法会面临模块化不足、维护升级困难的窘境,因此提出一种基于可扩展框架的井眼轨道控制系统软件。该软件参考开放服务网关协议(Open Service Gateway initiative,OSGi)规范,采用插件式模块化的编程思想,将系统框架与功能模块相互分离,同时使模块以插件形式加载实现前后端分离。将设计系统成功推广应用于十余口井,结果表明,系统运行稳定,界面交互方便,数据响应快速,算法维护和版本更新方便快捷,满足了现场应用新需求。该设计思路可为油气领域同类系统的架构设计提供一种有效可靠的思路,对油气井领域系统开发具有借鉴作用。展开更多
The database of open-framework aluminophosphate(AlPO) syntheses has been established,which includes about 1600 synthetic records.Data analysis has been done on the basis of the framework composition,structure dimensio...The database of open-framework aluminophosphate(AlPO) syntheses has been established,which includes about 1600 synthetic records.Data analysis has been done on the basis of the framework composition,structure dimension,pore ring,and organic template.This database will serve as useful guidance for the rational synthesis of microporous functional materials.展开更多
Employing 4,4-trimethylenedipyridine as a template,a new two-dimensional zinc phosphite (4,4-(C5H4N)2(CH2)3)· [Zn3(HPO3)4 ] has been prepared at room temperature and characterized by single-crystal X-ray diffract...Employing 4,4-trimethylenedipyridine as a template,a new two-dimensional zinc phosphite (4,4-(C5H4N)2(CH2)3)· [Zn3(HPO3)4 ] has been prepared at room temperature and characterized by single-crystal X-ray diffraction,FTIR,elemental analysis,powder X-ray diffraction,and thermogravimetric analysis.The compound crystallizes in the monoclinic space group P2 1 /c,with cell parameters,a=9.3309(19),b=14.798(3),c=33.637(7),β=91.11(3),V=4643.8(16) nm 3 and Z=4.The connectivity of the ZnO4 tetrahedra and HPO 3 pseudo pyramids results in infinite corner-sharing 4-membered ring chains as second building units which are further linked by Zn O P bonds to form a 2-D layer that with interesting 8-membered ring channels along the [100] direction.The diprotonated 4,4-trimethylenedipyridine molecules sit in the middle of the layers along the [100] direction and interact with the framework via hydrogen bonds.展开更多
The open-framework iron phosphate IIIII21.543FeFe(PO) was hydrothermally synthesized and characterized by elemental analysis, IR, EPR, XPS and single crystal X-ray diffraction analysis. The title compound crystallized...The open-framework iron phosphate IIIII21.543FeFe(PO) was hydrothermally synthesized and characterized by elemental analysis, IR, EPR, XPS and single crystal X-ray diffraction analysis. The title compound crystallized in the triclinic, space group P1with a=0.64724(4) nm, b=0.79651(6) nm, c=0.94229(5) nm, =104.447(2)? =108.919(4)? =101.741(4)? V=0.42302(5) nm3, Z=1 and R1 (wR2)=0.0307 (0.0793). Crystal data were collected on a Rigaku R-AXIS RAPID IP diffractometer with Mo K?(=0.071073 nm) at 293(2) K in the range of 2.43埃迹?7.46? The structure of 1 consists of 19 non-hydrogen atoms including three and a half crystallographically in-dependent Fe and three P atoms. Fe(1) connects its symmetrical Fe(1A) through bridging oxygen forming a dimer and the dimers are connected by Fe(4) forming an infinite staircase-like chain. Fe(2) and Fe(3) connect the infinite chains into a layer with bridging oxygen. Layers are interconnected via Fe(4) forming the six-membered and eight-membered channel systems.展开更多
基金The project was supported by the National Natural Science Foundation of China (20171012) and the Natural Science Foundation of Fujian Province, China (E0110010).
文摘A novel 3-D inorganic bimetallic compound Ag2Mo2O7 has been hydrothermally synthesized and structurally characterized by X-ray diffraction. The compound crystallizes in monoclinic, space group P21/c with a = 6.1274（3）, b = 13.1836（6）, c = 7.8780（3）A, β= 110.673（3）°, V = 595.42（5）A3, Z= 4, Mr= 519.62, Dc = 5.797g/cm^3, F（000） = 936,μ（MoKα） = 10.579 mm^-1, F（000） = 936, the final R = 0.0204 and wR = 0.0477 for 1268 observed reflections with I〉 2σ（I）. In the title compound, the [Mo4O16]n^8n-chains are linked through O-Ag-O bridging bonds to form a 3D network. It represents an unprecedented linking mode between the isopolyoxomolybdate chain and the transition metal oxide cluster. IR, TGA and fluorescence properties of the title compound are also studied.
基金This research was kindly supported by the Research Fund for the Doctoral Program of Higher Education (RFDP) and the OpeningFou
文摘A novel open-framework vanadium(W) phosphate(H_3NCH_2CH_2NH_3)_3[(VO)_4(PP_4)_2(HPO_4)_4] (short for V_2P_3-en) has been prepared. It issynthesized hydrothermally in the presence of ethylenediamine (en) at 170 deg C for 5 days byself-assembly from structurally simple precursors V_2O_5, H_3PO_4 and H_2O. The compound ischaracterized by means of Fourier transform-infrared spectroscopy (FT-IR),Thermogravimetry-differential thermal analysis (TG-DTA), X-ray powder diffraction analysis (XRD) andScanning electron microscopy (SEM). Furthermore, the composition-structure-thermal stabilityrelation of V_2P_3-en is explored in terms of crystal chemistry, and the potential approach to theenhancement of its thermal stability is proposed.
基金supported by the National Natural Science Foundation of China(21171063)the Excellent Young Scientists Fund(21222103)+1 种基金the National Basic Research Program of China(2011CB808-703)the Specialized Research Fund for the Doctoral Program of Higher Education
文摘Using n-propylamine as a template,deioned water and secondary-butanol(butan-2-ol)as solvents,a three-dimensional(3D)open-framework aluminophosphate[C3NH10]·[HAl3P3O13](1)and a two-dimensional layered aluminophosphate[C3NH10]3·[Al3P4O16](2)were crystallized from the initial mixtures with compositions of Al2O3:2.4 P2O5:5.0 n-propylamine:100 H2O/butan-2-ol,respectively.They are characterized by X-ray powder diffraction(XRD),thermogravimetric(TG),and elemental(CHN)analyses and structurally determined by single-crystal X-ray diffraction analysis.Compound 1 crystallizes in the monoclinic space group P21/c with a=0.85831(13)nm,b=1.7677(3)nm,c=1.04353(12)nm,=123.887(9)°,and V=1.3143(3)nm3.Compound 2 crystallizes in the monoclinic space group P21/c with a=1.1313(2)nm,b=1.4874(3)nm,c=1.8020(6)nm,=125.07(2)°,and V=2.4817(11)nm3.The results show that the properties of solvent have a significant influence on the structure-directing effect of n-propylamine in the crystallization of the open-framework aluminophosphates.
基金Supported by the National Natural Science Foundation of China（Nos.21571075, 21320102001, 21621001）, the National Key Research and Development Program of China（No.2016YFB0701100） and the Programme of Introducing Talents of Discipline to Universities（the 111 Project）, China（No.B 17020）.
文摘The crystallization behavior of the initial mixture with the composition of Al2O3：4.0P2O5：3.0 diethylenetriamine（DETA）：xHF：153H2O was investigated at 180 ℃, where 0≤x≤3. If x≤1.8, three-dimensional openframework aluminophosphate AIPO-CJ31 was obtained. If 2 ≤x≤3, a chain-like aluminophosphate（1） was obtained. The crystallization process of both compounds was investigated by means of powder X-ray diffraction（XRD） and the concentrations of A1 and P in the liquid product during the crystallization process were analysed by means of induc- tively coupled plasma atomic emission spectroscopy（ICP-AES）. The evolution of the coordination state of A1, P and F during the crystallization was monitored with 27A1, 31p and 19F MAS NMR technique. The influence of the fluoride ions and the source of fluoride ions on the structure-directing effect of DETA was discussed. It was found that the fluoride ions changed the crystallization direction of the initial mixture, i.e., the structure-directing effect of DETA, via altering the distribution or micro-structure of the inorganic fragments.
文摘井眼轨道控制系统包括轨道设计、丛式井防碰以及测斜数据分析处理等多个功能模块,需要满足不同井型设计、施工与数据分析的需求,同时要考虑系统可维护性、可扩展性,以满足现场应用的新需求。采用传统设计方法会面临模块化不足、维护升级困难的窘境,因此提出一种基于可扩展框架的井眼轨道控制系统软件。该软件参考开放服务网关协议(Open Service Gateway initiative,OSGi)规范,采用插件式模块化的编程思想,将系统框架与功能模块相互分离,同时使模块以插件形式加载实现前后端分离。将设计系统成功推广应用于十余口井,结果表明,系统运行稳定,界面交互方便,数据响应快速,算法维护和版本更新方便快捷,满足了现场应用新需求。该设计思路可为油气领域同类系统的架构设计提供一种有效可靠的思路,对油气井领域系统开发具有借鉴作用。
基金Supported by the National Natural Science Foundation of China (Grant No. 20871051)the State Basic Research Project of China (2006CB806103)the Major International Joint Research Project of China (20720102039)
文摘The database of open-framework aluminophosphate(AlPO) syntheses has been established,which includes about 1600 synthetic records.Data analysis has been done on the basis of the framework composition,structure dimension,pore ring,and organic template.This database will serve as useful guidance for the rational synthesis of microporous functional materials.
基金supported by the National Natural Science Foundation of China (20701023 & 20971076)the State Key Laboratory of Inorganic Synthesis and Preparative Chemistry (2010-17)the Natural Science Foundation of Shandong Province,China (BS2010NJ004 & 2009ZRB019KH)
文摘Employing 4,4-trimethylenedipyridine as a template,a new two-dimensional zinc phosphite (4,4-(C5H4N)2(CH2)3)· [Zn3(HPO3)4 ] has been prepared at room temperature and characterized by single-crystal X-ray diffraction,FTIR,elemental analysis,powder X-ray diffraction,and thermogravimetric analysis.The compound crystallizes in the monoclinic space group P2 1 /c,with cell parameters,a=9.3309(19),b=14.798(3),c=33.637(7),β=91.11(3),V=4643.8(16) nm 3 and Z=4.The connectivity of the ZnO4 tetrahedra and HPO 3 pseudo pyramids results in infinite corner-sharing 4-membered ring chains as second building units which are further linked by Zn O P bonds to form a 2-D layer that with interesting 8-membered ring channels along the [100] direction.The diprotonated 4,4-trimethylenedipyridine molecules sit in the middle of the layers along the [100] direction and interact with the framework via hydrogen bonds.
基金the National Natural Science Foundation of China (No. 20171010).
文摘The open-framework iron phosphate IIIII21.543FeFe(PO) was hydrothermally synthesized and characterized by elemental analysis, IR, EPR, XPS and single crystal X-ray diffraction analysis. The title compound crystallized in the triclinic, space group P1with a=0.64724(4) nm, b=0.79651(6) nm, c=0.94229(5) nm, =104.447(2)? =108.919(4)? =101.741(4)? V=0.42302(5) nm3, Z=1 and R1 (wR2)=0.0307 (0.0793). Crystal data were collected on a Rigaku R-AXIS RAPID IP diffractometer with Mo K?(=0.071073 nm) at 293(2) K in the range of 2.43埃迹?7.46? The structure of 1 consists of 19 non-hydrogen atoms including three and a half crystallographically in-dependent Fe and three P atoms. Fe(1) connects its symmetrical Fe(1A) through bridging oxygen forming a dimer and the dimers are connected by Fe(4) forming an infinite staircase-like chain. Fe(2) and Fe(3) connect the infinite chains into a layer with bridging oxygen. Layers are interconnected via Fe(4) forming the six-membered and eight-membered channel systems.
