In nature, some molecules have broken conjugate symmetry configurations, which might result in a special optical phenomenon called negative refraction. Under such circumstances, both permittivity and permeability are ...In nature, some molecules have broken conjugate symmetry configurations, which might result in a special optical phenomenon called negative refraction. Under such circumstances, both permittivity and permeability are negative simultaneously. When light at certain frequency is transmitted through a transparent medium(e.g., slide glass) in which a psychoactive drug with negative indexes has been deposited, the refracted light is detected at different locations in the transparent medium. This is because the refracted light travels in a direction opposite to the expected path when it passes through material with a negative index. Using this method, it is possible to distinguish synthetic cannabinoids from other abusive psychoactive drugs in the UV-vis region. In this study, we use a tight-binding model to calculate the permittivity and permeability of pentagonal configurations with different broken symmetries. Furthermore, a qualitative analysis of the negative refraction with respect to heptagonal models is discussed.展开更多
基金supported by the National Natural Science Foundation of China(Grant No.11575125)
文摘In nature, some molecules have broken conjugate symmetry configurations, which might result in a special optical phenomenon called negative refraction. Under such circumstances, both permittivity and permeability are negative simultaneously. When light at certain frequency is transmitted through a transparent medium(e.g., slide glass) in which a psychoactive drug with negative indexes has been deposited, the refracted light is detected at different locations in the transparent medium. This is because the refracted light travels in a direction opposite to the expected path when it passes through material with a negative index. Using this method, it is possible to distinguish synthetic cannabinoids from other abusive psychoactive drugs in the UV-vis region. In this study, we use a tight-binding model to calculate the permittivity and permeability of pentagonal configurations with different broken symmetries. Furthermore, a qualitative analysis of the negative refraction with respect to heptagonal models is discussed.
