After solution treatment, the 1420 Al-Li alloy samples were aged at different temperatures in an electric field with different intensity. The measurements made showed that the electric field increased the strength of ...After solution treatment, the 1420 Al-Li alloy samples were aged at different temperatures in an electric field with different intensity. The measurements made showed that the electric field increased the strength of the 1420 Al-Li alloy, and best properties were obtained when they were aged at 120 ℃ with E=4 kV/cm for 12 hrs. The electric field promoted the nucleation of δ′ phase, increased the quantity of the δ′ phase, and made the size of the δ′ phase particles smaller. The electric field restrained the formation and growth of PFZ, and increased the intensity of the electric field while the width of the PFZ was decreased.展开更多
The thermoelectric properties of Sr0.61Ba0.39Nb2O6-δ ceramics, reduced in different conditions, are investigated in the temperature range from 323 K to 1073 K. The electrical transport behaviors of the samples are do...The thermoelectric properties of Sr0.61Ba0.39Nb2O6-δ ceramics, reduced in different conditions, are investigated in the temperature range from 323 K to 1073 K. The electrical transport behaviors of the samples are dominated by the thermal-activated polaron hopping in the low temperature range, the Fermi glass behavior in the middle temperature range, and the Anderson localized behavior in the high temperature range. The thermal conductivity presents a plateau at high- temperatures, indicating a glass-like thermal conduction behavior. Both the thermoelectric power factor and the thermal conductivity increase with the increase of the degree of oxygen-reduction. Taking these two factors into account, the oxygen-reduction can still contribute to promoting the thermoelectric figure of merit. The highest ZT value is obtained to be -0.19 at 1073 K in the heaviest oxygen reduced sample.展开更多
The oxidative polycondensation reaction conditions of 2-[(2-hydroxyphenyliminomethylbenzylidene)amino- phenol](2-HPIMBAP)has been accomplished by using air O_2 and NaOCl oxidants in an aqueous alkaline medium between ...The oxidative polycondensation reaction conditions of 2-[(2-hydroxyphenyliminomethylbenzylidene)amino- phenol](2-HPIMBAP)has been accomplished by using air O_2 and NaOCl oxidants in an aqueous alkaline medium between 50-90℃.The optimum reaction conditions of the oxidative polycondensation and the main parameters of the process were established.At the optimum reaction conditions,yield of the products were found to be 67.72% and 61.49% for air O_2 and NaOCl oxidants respectively.The structures of the monomer ...展开更多
This article presents illustrations of an extended model of the electron to visualize how it spins and radiates in the external magnetic field. A time-varying magnetic field B produces a rotational induced electric fi...This article presents illustrations of an extended model of the electron to visualize how it spins and radiates in the external magnetic field. A time-varying magnetic field B produces a rotational induced electric field E which rotates (spins) the electron about its axis. In time-constant magnetic field: the electron radiates the cyclotron radiation. In time-varying magnetic field: synchrotron radiation is generated. The couplings between spin, acceleration and radiation will be discussed.展开更多
Sea surface electric field observations off the coast from Goa (15°25'N, 73°47'E) to Madras (13°04'N, 80°15'E) around Sri Lanka, in a distance range 25-135 km from coast, during 9-2...Sea surface electric field observations off the coast from Goa (15°25'N, 73°47'E) to Madras (13°04'N, 80°15'E) around Sri Lanka, in a distance range 25-135 km from coast, during 9-20 May 1983 were taken. In this paper we have examined the diurnal variation of electric field in the Arabian Sea, Indian Ocean and Bay of Bengal regions covered during the cruise of the research ship ORV Gaveshani. An aspect of electric field dependence on coastal distance and Aitken Nuclei concentration has also been studied. An attempt to examine the latitude dependence of field was also made. Results obtained in the above studies are presented and compared with those obtained elsewhere.展开更多
The optimum reaction conditions of the oxidative polycondensation of 2-(thien-2-yl-methylene)aminophenol (2-TMAP) has been accomplished by using air O_2,H_2O_2 and NaOCl oxidants in an aqueous alkaline medium between...The optimum reaction conditions of the oxidative polycondensation of 2-(thien-2-yl-methylene)aminophenol (2-TMAP) has been accomplished by using air O_2,H_2O_2 and NaOCl oxidants in an aqueous alkaline medium between 20℃and 90℃.The structures of the monomer and oligomer were confirmed by FT-IR,UV-Vis,~1H-NMR and ^(13)C-NMR and elemental analysis.TGA-DTA,size exclusion chromatography(SEC) techniques and solubility tests were applied for characterization.The ~1H-NMR and ^(13)C-NMR data show that the polymeriz...展开更多
The machine tool is one of the new products developed and produced by the Shanghai No.8 Machine Tool Plant. It adopts a lift adjustable wiretrame and molybdenum filament tensioning mechanism with large cutting thickne...The machine tool is one of the new products developed and produced by the Shanghai No.8 Machine Tool Plant. It adopts a lift adjustable wiretrame and molybdenum filament tensioning mechanism with large cutting thickness and high machining precision. It is equipped with an advanced IBM-PC 386 microcomputer-controlled system, with strong performance and CRT display. Man/展开更多
The variations noticed in the atmospheric electric field recorded at Pune (18°32'N, 73°51'E, 559 m ASL), a tropical inland station located in Dcccan Plateau, India, during the period 1930-1987, have ...The variations noticed in the atmospheric electric field recorded at Pune (18°32'N, 73°51'E, 559 m ASL), a tropical inland station located in Dcccan Plateau, India, during the period 1930-1987, have been examined in relation to the variations observed in the Angstrom turbidity coefficient (β) and selected meteorological parameters. The monthly and annual mean values of the atmospheric electric field. Angstrom turbidity coefficient (β), rainfall, temperature and relative humidity for the years 1930-1938, 1957-1958, 1964-1965, 1973-1974 and 1987 were considered in the study.The results of the above study indicated gradual increases in the atmospheric electric field over the period of study (1930-1987) which is statistically significant at less than 5%level. The increases noticed during different periods varied from 30 to 109%. The increase noticed during the period (1930-1938) and (1973-1974) was maximum (109%). The Angstrom turbidity coefficient also showed systematic increases during the period of study, which is consistent. The diurnal curve of the atmospheric electric field at the station by and large, showed a double oscillation, which is generally observed in the conlinental environments.展开更多
A series samples of La0.6M0.4FeO3-δ (M = Ca, Sr, process (GNP). FTIR, TG-DSC, XRD and TEM techniques Ba) perovskite-type oxides were prepared by glycine nitrate were used to characterize the chemical constitution...A series samples of La0.6M0.4FeO3-δ (M = Ca, Sr, process (GNP). FTIR, TG-DSC, XRD and TEM techniques Ba) perovskite-type oxides were prepared by glycine nitrate were used to characterize the chemical constitution, thermal stability and phase structure. The electrical conductivity of the samples was investigated by four-probe technique. With the increase of substituted-ionic radius, the temperature of phase formation increases, and the solid solubility decreases gradually, respectively. The La0.6Ca0.4FeO3-δ(LCF)powder is pure cubic perovskite-type crystalline after fired at 850℃ for 2 h. The XRD patterns of La0.6Sr0.4FeO3-δ(LSF) powder shows a small quantity of SrO peaks sintered at 1050℃ for 2 h. The electrical conductivity of LCF and LSF at 500 - 800℃ is over 100 S·cm^ - 1, and the value of LCF is 1170 S·cm^ - 1 at 800℃, which indicate that LCF and LSF may be used as a profitable cathode for IT-SOFCs. The characteristic of La0.6 Ba0.4FeO3-δ(LBF) is poor, and the electrical conductivity at intermediate temperatures is 1/20 less than that of LSF.展开更多
La0.8Sr0.2Co1-yFeyO3-δ (y=0.2, 0.4, 0.6, 0.8) powders were synthesized by ethylenediamine tetraacetic acid (EDTA) complexing sol-gel process. The powders were characterized via X-ray diffraction (XRD) and scanning el...La0.8Sr0.2Co1-yFeyO3-δ (y=0.2, 0.4, 0.6, 0.8) powders were synthesized by ethylenediamine tetraacetic acid (EDTA) complexing sol-gel process. The powders were characterized via X-ray diffraction (XRD) and scanning electron microscope and energy dispersive X-ray spectroscopy (SEM-EDS). The results showed that single-phased perovskite-type oxide powders with small particle size were obtained by the process, and the compositions of the productions agreed with the designed molar ratio. The electronic conductivity and ionic conductivity of La0.8Sr0.2Co1-yFeyO3-δ were investigated by DC four-terminal method and AC impedance spectroscopy, respectively. The electronic conductivity of La0.8Sr0.2Co1-yFeyO3-δ is approximately 2~4 orders of magnitude higher than the ionic conductivity. It was confirmed that the conductivities of the materials were strongly influenced by the composition anions, temperature and sample preparing process.展开更多
Objectives To investi-gate the effect of electrical stimulation during absolute refractory period on contraction and relaxation of ventricular myocytes from normal guinea - pigs. Methods The guinea - pig ventricular m...Objectives To investi-gate the effect of electrical stimulation during absolute refractory period on contraction and relaxation of ventricular myocytes from normal guinea - pigs. Methods The guinea - pig ventricular myocytes were obtained by enzyme digesting, and the extent of its contraction and relaxation and Ca2+ transient were recorded through the motion edge detection system. Results (1) The contracting extent of guinea - pig ventricular myocytes increased 15.45±6.48% , and the peak velocity of shorting (contraction) and the peak veloci ty of relengthening (relaxation) increased 15.97 ± 8.37% and 21. 63±8. 06% respectively (n = 10); (2) The extent of ventricular myocytes fluorescence ra tio(360/380) (F360/F380) increased 22. 55±9. 08%, and the peak velocity of ventricular myocytes F360 /F380 increased 36. 75 ± 9. 77% and 23. 62±4. 47% during shorting and relengthening respectively (n = 6) . Conclusions Appropriate electrical stimulation may strengthen the contracting and relaxing function of normal guinea - pig ventricular myocytes.展开更多
A good contact between the pantograph and catenary is critically important for the working reliability of electric trains, while the basic understanding on the electrical contact evolution during the pantograph--caten...A good contact between the pantograph and catenary is critically important for the working reliability of electric trains, while the basic understanding on the electrical contact evolution during the pantograph--catenary system working is still ambiguous so far. In this paper, the evolution of electric contact was studied in respects of the contact resistance, temperature rise, and microstructure variation, based on a home-made pantograph-catenary simulation system. Pure carbon strips and copper alloy contact wires were used, and the experimental electrical current, sliding speed, and normal force were set as 80 A, 30 km/h, and 80 N, respectively. The contact resistance presented a fluctuation without obvious regularity, concentrating in the region of 25 and 50 mf~. Temperature rise of the contact point experienced a fast increase at the first several minutes and finally reached a steady state. The surface damage of carbon trips in microstructure analysis revealed a complicated interaction of the sliding friction, joule heating, and arc erosion.展开更多
The present work investigates the effect of europium substitution on the (Bi, Pb)-2212 system in the concentration range 0.5 ≤ x ≤1.0. Phase analysis and lattice parameter calculations on the powder diffraction da...The present work investigates the effect of europium substitution on the (Bi, Pb)-2212 system in the concentration range 0.5 ≤ x ≤1.0. Phase analysis and lattice parameter calculations on the powder diffraction data and the elemental analysis of EDX show that the Eu atoms are successfully substituted into the (Bi, Pb)-2212 system. Resistivity measurements (64-300 K) reveal that the system exhibits superconductivity at x ≤ 0.5 and semiconductivity at x 〉 0.5. With the complete suppression of superconductivity which is known to be a quasi-two dimensional phenomenon in these materials, a metal to insulator transition takes place at x = 0.6 and the predominant conduction mechanism is found to be variable range hopping between localized states, resulting in macroscopic semiconducting behaviour. The results of electrical and structural properties of the doped (Bi, Pb)-2212 compounds suggest that the decrease of charge carrier concentration and the induced structural disorder are the more effective and dominant mechanisms in the origin of the metal to insulator transition and suppression of superconductivity due to Eu substitution at its Sr site.展开更多
The solid solutions Ce_(0.9)RE_(0.1)O_(2-δ)(RE=Pr, Nd,Sm, Gd, Dy) were prepared by sol-gel method. The XRD measurement shows that the solid solution is crystallized in cubic fluorite-type structure and the cell volum...The solid solutions Ce_(0.9)RE_(0.1)O_(2-δ)(RE=Pr, Nd,Sm, Gd, Dy) were prepared by sol-gel method. The XRD measurement shows that the solid solution is crystallized in cubic fluorite-type structure and the cell volume of Ce_(0.9)RE_(0.1)O_(2-δ) decreases with the increase of atomic number of RE. The ionic conduction for Ce_(0.9)RE_(0.1)O_(2-δ) was measured by impedance spectroscopy and Ce_(0.9)Pr_(0.1)O_(2-δ) has better conductivity. The linear thermal expansion of Ce_(0.9)RE_(0.1)O_(2-δ) decreases with the increase of atomic number of RE.展开更多
In recent years, the data collecting and processing of magnetotelluric sounding (MT) have progressed greatly. How to improve the quality of field surveyed data and obtain the high quality parameters such as apparent...In recent years, the data collecting and processing of magnetotelluric sounding (MT) have progressed greatly. How to improve the quality of field surveyed data and obtain the high quality parameters such as apparent resistivity and phase is the most important link during the overall flow. It is closely related to the signal-to-noise ratio of magnetic sensors, the resolution of data collecting units and relevant processing methods as well. Produced by Germany Metronix Measurement Instruments and Electronics Ltd., the new type multi-channel geophysical measurement system GMS-06 was already adopted and used by domeslic units such as Institute of Geology and Geophysics of Chinese Academy of Sciences and Tongji University. Based on the brief introduction of GMS-06, this paper will give the comparisons and analyses of the synchronous surveyed MT data by GMS-06, MMS-03 MT system which was also produced by Metronix and V5-2000 MT system produced by Canada Phoenix Geophysics Ltd.. Then the preliminary processing and interpretation results of the long period MT data observed by GMS-06 in the area of Shanghai and Zhejiang are also discussed in the paper.展开更多
Pr0.6-x NdxCa0.4 FeO3-δ ( x = 0.0, 0.2, 0.3, 0.4, 0.5, 0.6) were synthesized using Pechini method. A number of studies were conducted concerning composition, specific area, crystalline structure and microstructure ...Pr0.6-x NdxCa0.4 FeO3-δ ( x = 0.0, 0.2, 0.3, 0.4, 0.5, 0.6) were synthesized using Pechini method. A number of studies were conducted concerning composition, specific area, crystalline structure and microstructure of the samples by means of FT-IR, BET, XRD TG-DTA and SEM. The results show that all the samples with different doping amounts of Pr^3+ and Nd^3+ on A-site are fine dispersed, and mean particle size less than 100 nm. The powders have good sinterability, and the relative density is 95% after sintered at 1200 ℃ for 2 h. It is found that all specimens are entirely single phase solid solutions with orthorhombic perovskite structure, the stable perovskitetype phase is formed completely after calcination at 900 ℃.展开更多
文摘After solution treatment, the 1420 Al-Li alloy samples were aged at different temperatures in an electric field with different intensity. The measurements made showed that the electric field increased the strength of the 1420 Al-Li alloy, and best properties were obtained when they were aged at 120 ℃ with E=4 kV/cm for 12 hrs. The electric field promoted the nucleation of δ′ phase, increased the quantity of the δ′ phase, and made the size of the δ′ phase particles smaller. The electric field restrained the formation and growth of PFZ, and increased the intensity of the electric field while the width of the PFZ was decreased.
基金Project supported by the National Basic Research Program of China(Grant No.2013CB632506)the National Natural Science Foundation of China(Grant Nos.51202132 and 51002087)
文摘The thermoelectric properties of Sr0.61Ba0.39Nb2O6-δ ceramics, reduced in different conditions, are investigated in the temperature range from 323 K to 1073 K. The electrical transport behaviors of the samples are dominated by the thermal-activated polaron hopping in the low temperature range, the Fermi glass behavior in the middle temperature range, and the Anderson localized behavior in the high temperature range. The thermal conductivity presents a plateau at high- temperatures, indicating a glass-like thermal conduction behavior. Both the thermoelectric power factor and the thermal conductivity increase with the increase of the degree of oxygen-reduction. Taking these two factors into account, the oxygen-reduction can still contribute to promoting the thermoelectric figure of merit. The highest ZT value is obtained to be -0.19 at 1073 K in the heaviest oxygen reduced sample.
基金This work was supported by the Canakkale Onsekiz Mart University Scientific Research Projects Commission for financial support(No.2007/20).
文摘The oxidative polycondensation reaction conditions of 2-[(2-hydroxyphenyliminomethylbenzylidene)amino- phenol](2-HPIMBAP)has been accomplished by using air O_2 and NaOCl oxidants in an aqueous alkaline medium between 50-90℃.The optimum reaction conditions of the oxidative polycondensation and the main parameters of the process were established.At the optimum reaction conditions,yield of the products were found to be 67.72% and 61.49% for air O_2 and NaOCl oxidants respectively.The structures of the monomer ...
文摘This article presents illustrations of an extended model of the electron to visualize how it spins and radiates in the external magnetic field. A time-varying magnetic field B produces a rotational induced electric field E which rotates (spins) the electron about its axis. In time-constant magnetic field: the electron radiates the cyclotron radiation. In time-varying magnetic field: synchrotron radiation is generated. The couplings between spin, acceleration and radiation will be discussed.
文摘Sea surface electric field observations off the coast from Goa (15°25'N, 73°47'E) to Madras (13°04'N, 80°15'E) around Sri Lanka, in a distance range 25-135 km from coast, during 9-20 May 1983 were taken. In this paper we have examined the diurnal variation of electric field in the Arabian Sea, Indian Ocean and Bay of Bengal regions covered during the cruise of the research ship ORV Gaveshani. An aspect of electric field dependence on coastal distance and Aitken Nuclei concentration has also been studied. An attempt to examine the latitude dependence of field was also made. Results obtained in the above studies are presented and compared with those obtained elsewhere.
基金supported by the Government Planning Organization(GPO2002K120170-7)TUBITAK GrantsCommission for a research grant(No.TBAG-105T428).
文摘The optimum reaction conditions of the oxidative polycondensation of 2-(thien-2-yl-methylene)aminophenol (2-TMAP) has been accomplished by using air O_2,H_2O_2 and NaOCl oxidants in an aqueous alkaline medium between 20℃and 90℃.The structures of the monomer and oligomer were confirmed by FT-IR,UV-Vis,~1H-NMR and ^(13)C-NMR and elemental analysis.TGA-DTA,size exclusion chromatography(SEC) techniques and solubility tests were applied for characterization.The ~1H-NMR and ^(13)C-NMR data show that the polymeriz...
文摘The machine tool is one of the new products developed and produced by the Shanghai No.8 Machine Tool Plant. It adopts a lift adjustable wiretrame and molybdenum filament tensioning mechanism with large cutting thickness and high machining precision. It is equipped with an advanced IBM-PC 386 microcomputer-controlled system, with strong performance and CRT display. Man/
文摘The variations noticed in the atmospheric electric field recorded at Pune (18°32'N, 73°51'E, 559 m ASL), a tropical inland station located in Dcccan Plateau, India, during the period 1930-1987, have been examined in relation to the variations observed in the Angstrom turbidity coefficient (β) and selected meteorological parameters. The monthly and annual mean values of the atmospheric electric field. Angstrom turbidity coefficient (β), rainfall, temperature and relative humidity for the years 1930-1938, 1957-1958, 1964-1965, 1973-1974 and 1987 were considered in the study.The results of the above study indicated gradual increases in the atmospheric electric field over the period of study (1930-1987) which is statistically significant at less than 5%level. The increases noticed during different periods varied from 30 to 109%. The increase noticed during the period (1930-1938) and (1973-1974) was maximum (109%). The Angstrom turbidity coefficient also showed systematic increases during the period of study, which is consistent. The diurnal curve of the atmospheric electric field at the station by and large, showed a double oscillation, which is generally observed in the conlinental environments.
基金Project Supported bythe Natural Science Foundation of Bureau Education Anhui Province (N2004kj326)
文摘A series samples of La0.6M0.4FeO3-δ (M = Ca, Sr, process (GNP). FTIR, TG-DSC, XRD and TEM techniques Ba) perovskite-type oxides were prepared by glycine nitrate were used to characterize the chemical constitution, thermal stability and phase structure. The electrical conductivity of the samples was investigated by four-probe technique. With the increase of substituted-ionic radius, the temperature of phase formation increases, and the solid solubility decreases gradually, respectively. The La0.6Ca0.4FeO3-δ(LCF)powder is pure cubic perovskite-type crystalline after fired at 850℃ for 2 h. The XRD patterns of La0.6Sr0.4FeO3-δ(LSF) powder shows a small quantity of SrO peaks sintered at 1050℃ for 2 h. The electrical conductivity of LCF and LSF at 500 - 800℃ is over 100 S·cm^ - 1, and the value of LCF is 1170 S·cm^ - 1 at 800℃, which indicate that LCF and LSF may be used as a profitable cathode for IT-SOFCs. The characteristic of La0.6 Ba0.4FeO3-δ(LBF) is poor, and the electrical conductivity at intermediate temperatures is 1/20 less than that of LSF.
基金the National Natural Science Foundation of China (50204007)the Talent Foundation of Yunnan Province (2005PY01-33)Programfor New Century Excellent Talents in University (NCET-07-0387)
文摘La0.8Sr0.2Co1-yFeyO3-δ (y=0.2, 0.4, 0.6, 0.8) powders were synthesized by ethylenediamine tetraacetic acid (EDTA) complexing sol-gel process. The powders were characterized via X-ray diffraction (XRD) and scanning electron microscope and energy dispersive X-ray spectroscopy (SEM-EDS). The results showed that single-phased perovskite-type oxide powders with small particle size were obtained by the process, and the compositions of the productions agreed with the designed molar ratio. The electronic conductivity and ionic conductivity of La0.8Sr0.2Co1-yFeyO3-δ were investigated by DC four-terminal method and AC impedance spectroscopy, respectively. The electronic conductivity of La0.8Sr0.2Co1-yFeyO3-δ is approximately 2~4 orders of magnitude higher than the ionic conductivity. It was confirmed that the conductivities of the materials were strongly influenced by the composition anions, temperature and sample preparing process.
文摘Objectives To investi-gate the effect of electrical stimulation during absolute refractory period on contraction and relaxation of ventricular myocytes from normal guinea - pigs. Methods The guinea - pig ventricular myocytes were obtained by enzyme digesting, and the extent of its contraction and relaxation and Ca2+ transient were recorded through the motion edge detection system. Results (1) The contracting extent of guinea - pig ventricular myocytes increased 15.45±6.48% , and the peak velocity of shorting (contraction) and the peak veloci ty of relengthening (relaxation) increased 15.97 ± 8.37% and 21. 63±8. 06% respectively (n = 10); (2) The extent of ventricular myocytes fluorescence ra tio(360/380) (F360/F380) increased 22. 55±9. 08%, and the peak velocity of ventricular myocytes F360 /F380 increased 36. 75 ± 9. 77% and 23. 62±4. 47% during shorting and relengthening respectively (n = 6) . Conclusions Appropriate electrical stimulation may strengthen the contracting and relaxing function of normal guinea - pig ventricular myocytes.
基金supported by the National Natural Science Foundation of China (Nos. U1234202 and 51577158)the National Science Foundation for Distinguished Young Scholars of China (No. 51325704)the Fundamental Research Funds for the Central Universities (No. A0920502051505-19)
文摘A good contact between the pantograph and catenary is critically important for the working reliability of electric trains, while the basic understanding on the electrical contact evolution during the pantograph--catenary system working is still ambiguous so far. In this paper, the evolution of electric contact was studied in respects of the contact resistance, temperature rise, and microstructure variation, based on a home-made pantograph-catenary simulation system. Pure carbon strips and copper alloy contact wires were used, and the experimental electrical current, sliding speed, and normal force were set as 80 A, 30 km/h, and 80 N, respectively. The contact resistance presented a fluctuation without obvious regularity, concentrating in the region of 25 and 50 mf~. Temperature rise of the contact point experienced a fast increase at the first several minutes and finally reached a steady state. The surface damage of carbon trips in microstructure analysis revealed a complicated interaction of the sliding friction, joule heating, and arc erosion.
基金supported by Kerala State Council for Science,Technology and Environment,Council of Scientific and Industrial Researchthe University Grants Commission of India
文摘The present work investigates the effect of europium substitution on the (Bi, Pb)-2212 system in the concentration range 0.5 ≤ x ≤1.0. Phase analysis and lattice parameter calculations on the powder diffraction data and the elemental analysis of EDX show that the Eu atoms are successfully substituted into the (Bi, Pb)-2212 system. Resistivity measurements (64-300 K) reveal that the system exhibits superconductivity at x ≤ 0.5 and semiconductivity at x 〉 0.5. With the complete suppression of superconductivity which is known to be a quasi-two dimensional phenomenon in these materials, a metal to insulator transition takes place at x = 0.6 and the predominant conduction mechanism is found to be variable range hopping between localized states, resulting in macroscopic semiconducting behaviour. The results of electrical and structural properties of the doped (Bi, Pb)-2212 compounds suggest that the decrease of charge carrier concentration and the induced structural disorder are the more effective and dominant mechanisms in the origin of the metal to insulator transition and suppression of superconductivity due to Eu substitution at its Sr site.
文摘The solid solutions Ce_(0.9)RE_(0.1)O_(2-δ)(RE=Pr, Nd,Sm, Gd, Dy) were prepared by sol-gel method. The XRD measurement shows that the solid solution is crystallized in cubic fluorite-type structure and the cell volume of Ce_(0.9)RE_(0.1)O_(2-δ) decreases with the increase of atomic number of RE. The ionic conduction for Ce_(0.9)RE_(0.1)O_(2-δ) was measured by impedance spectroscopy and Ce_(0.9)Pr_(0.1)O_(2-δ) has better conductivity. The linear thermal expansion of Ce_(0.9)RE_(0.1)O_(2-δ) decreases with the increase of atomic number of RE.
基金National Natural Science Foundation of China (40104005) and National High Technical Research and Development Project (2004AA615010).
文摘In recent years, the data collecting and processing of magnetotelluric sounding (MT) have progressed greatly. How to improve the quality of field surveyed data and obtain the high quality parameters such as apparent resistivity and phase is the most important link during the overall flow. It is closely related to the signal-to-noise ratio of magnetic sensors, the resolution of data collecting units and relevant processing methods as well. Produced by Germany Metronix Measurement Instruments and Electronics Ltd., the new type multi-channel geophysical measurement system GMS-06 was already adopted and used by domeslic units such as Institute of Geology and Geophysics of Chinese Academy of Sciences and Tongji University. Based on the brief introduction of GMS-06, this paper will give the comparisons and analyses of the synchronous surveyed MT data by GMS-06, MMS-03 MT system which was also produced by Metronix and V5-2000 MT system produced by Canada Phoenix Geophysics Ltd.. Then the preliminary processing and interpretation results of the long period MT data observed by GMS-06 in the area of Shanghai and Zhejiang are also discussed in the paper.
文摘Pr0.6-x NdxCa0.4 FeO3-δ ( x = 0.0, 0.2, 0.3, 0.4, 0.5, 0.6) were synthesized using Pechini method. A number of studies were conducted concerning composition, specific area, crystalline structure and microstructure of the samples by means of FT-IR, BET, XRD TG-DTA and SEM. The results show that all the samples with different doping amounts of Pr^3+ and Nd^3+ on A-site are fine dispersed, and mean particle size less than 100 nm. The powders have good sinterability, and the relative density is 95% after sintered at 1200 ℃ for 2 h. It is found that all specimens are entirely single phase solid solutions with orthorhombic perovskite structure, the stable perovskitetype phase is formed completely after calcination at 900 ℃.