Bottom-emitting organic light-emitting diodes (BOLEDs), using AI/MoO3 as the semitransparent anode and LiF/Al as the reflective cathode and Alqa as the emitter, are fabricated. At the same time, the performance impr...Bottom-emitting organic light-emitting diodes (BOLEDs), using AI/MoO3 as the semitransparent anode and LiF/Al as the reflective cathode and Alqa as the emitter, are fabricated. At the same time, the performance improvement of the BOLEDs having a capping layer inserted between the semitransparent anode and the glass substrate is studied. The optimized microcavity BOLED shows a current efficiency (5.49cd/A) enhancement of 10% compared with a conventional BOLED based on ITO (5.0cd/A). Slight color variation is observed in 120° forward viewing angle with 5Onto BCP as the capping layer. Strong dependence of efficiency on A1 anode thickness and the thickness and refractor index of the capping layer is explained. The results indicate that the BOLEDs with the double-aluminum electrode have potential practical applications.展开更多
Characteristics of organic matter may affect the residual aluminum after the coagulation process. This study reported the results of a survey for one drinking water treatment plant and measured the concentration of re...Characteristics of organic matter may affect the residual aluminum after the coagulation process. This study reported the results of a survey for one drinking water treatment plant and measured the concentration of residual aluminum species with different molecular weights.Survey results indicated that humic acid or organic matter whose molecular weight was smaller than 1500 Da had significant effects on residual aluminum. All the treatment processes were ineffective in removing dissolved organic matter whose molecular weight was smaller than1500 Da. These results also indicated that the addition of sand or polyacrylamide in the coagulation process could greatly decrease the concentration of humic acid, and the concentration of residual aluminum also decreased. These results revealed that for all water samples after filtration, the majority of total residual aluminum existed in the form of total dissolved aluminum, accounting for 70%–90%. The concentration of residual aluminum produced in bovine serum albumin solutions indicated that when the DOC was larger than4.0 mg/L, there were still significant differences when the solution p H value varied from 4.0 to 9.0.展开更多
A simple, cost effective and rapid electrochemical method has been developed for the determination of micro level ortho nitrobenzaldehyde(ONB) based on outstanding properties of modified aluminum electrode tin nanor...A simple, cost effective and rapid electrochemical method has been developed for the determination of micro level ortho nitrobenzaldehyde(ONB) based on outstanding properties of modified aluminum electrode tin nanorods/anodic aluminum oxide/aluminum(SnNR/AAO/Al) for the first time. The SnNR/AAO/Al electrode was fabricated by a second step anodization, followed by electrodeposition and its electrochemical behavior was investigated in detail. The cyclic voltammetry results indicated that the SnNR/AAO/Al electrode exhibited efficient electrocatalytic activity toward reduction of ONB in the acidic solution. It provides an appreciable improvement of reduction peak for ONB at-0.721 V.Furthermore, various kinetic parameters such as transfer electron number, transfer proton number and standard heterogeneous rate constant were calculated from the scan rates.The electrocatalytic behavior was further exploited as a sensitive detection scheme for the ONB determination by differential pulse voltammetry. Under the optimized conditions, the concentration range and detection limit are 0.1-100 μmol/L and 0.05 μmol/L, respectively,for ONB. The analytical performance of this modified sensor has been evaluated for detection of real sample such as river water and recovery of ONB was achieved all-out up to102.3% under standard addition method.展开更多
基金Supported by the Nanjing University of Telecommunications and Posts under Grant Nos NY212010 and NY212034the National Natural Science Foundation of China under Grant Nos 91233117 and 51333007+2 种基金the Natural Science Fund in Jiangsu Province under Grant No BK2012834the National Basic Research Program of China under Grant No 2015CB932200the Priority Academic Program Development of Jiangsu Higher Education Institutions
文摘Bottom-emitting organic light-emitting diodes (BOLEDs), using AI/MoO3 as the semitransparent anode and LiF/Al as the reflective cathode and Alqa as the emitter, are fabricated. At the same time, the performance improvement of the BOLEDs having a capping layer inserted between the semitransparent anode and the glass substrate is studied. The optimized microcavity BOLED shows a current efficiency (5.49cd/A) enhancement of 10% compared with a conventional BOLED based on ITO (5.0cd/A). Slight color variation is observed in 120° forward viewing angle with 5Onto BCP as the capping layer. Strong dependence of efficiency on A1 anode thickness and the thickness and refractor index of the capping layer is explained. The results indicate that the BOLEDs with the double-aluminum electrode have potential practical applications.
基金supported by the National Natural Science Foundation of China(Nos.51608515,51025830,51008293,51578527,41201498,51138008,51138010,51308008,21677156)
文摘Characteristics of organic matter may affect the residual aluminum after the coagulation process. This study reported the results of a survey for one drinking water treatment plant and measured the concentration of residual aluminum species with different molecular weights.Survey results indicated that humic acid or organic matter whose molecular weight was smaller than 1500 Da had significant effects on residual aluminum. All the treatment processes were ineffective in removing dissolved organic matter whose molecular weight was smaller than1500 Da. These results also indicated that the addition of sand or polyacrylamide in the coagulation process could greatly decrease the concentration of humic acid, and the concentration of residual aluminum also decreased. These results revealed that for all water samples after filtration, the majority of total residual aluminum existed in the form of total dissolved aluminum, accounting for 70%–90%. The concentration of residual aluminum produced in bovine serum albumin solutions indicated that when the DOC was larger than4.0 mg/L, there were still significant differences when the solution p H value varied from 4.0 to 9.0.
基金CSIR (09/0810 (0021)/ 2012-EMR-I), Periyar University for providing fundUGC networking resource center for providing visiting fellowship
文摘A simple, cost effective and rapid electrochemical method has been developed for the determination of micro level ortho nitrobenzaldehyde(ONB) based on outstanding properties of modified aluminum electrode tin nanorods/anodic aluminum oxide/aluminum(SnNR/AAO/Al) for the first time. The SnNR/AAO/Al electrode was fabricated by a second step anodization, followed by electrodeposition and its electrochemical behavior was investigated in detail. The cyclic voltammetry results indicated that the SnNR/AAO/Al electrode exhibited efficient electrocatalytic activity toward reduction of ONB in the acidic solution. It provides an appreciable improvement of reduction peak for ONB at-0.721 V.Furthermore, various kinetic parameters such as transfer electron number, transfer proton number and standard heterogeneous rate constant were calculated from the scan rates.The electrocatalytic behavior was further exploited as a sensitive detection scheme for the ONB determination by differential pulse voltammetry. Under the optimized conditions, the concentration range and detection limit are 0.1-100 μmol/L and 0.05 μmol/L, respectively,for ONB. The analytical performance of this modified sensor has been evaluated for detection of real sample such as river water and recovery of ONB was achieved all-out up to102.3% under standard addition method.