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Organic electro-optic polymer materials and organic-based hybrid electro-optic modulators 被引量:1
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作者 Yan Wang Tongtong Liu +3 位作者 Jiangyi Liu Chuanbo Li Zhuo Chen Shuhui Bo 《Journal of Semiconductors》 EI CAS CSCD 2022年第10期28-38,共11页
High performance electro-optic modulator,as the key device of integrated ultra-wideband optical systems,have be-come the focus of research.Meanwhile,the organic-based hybrid electro-optic modulators,which make full us... High performance electro-optic modulator,as the key device of integrated ultra-wideband optical systems,have be-come the focus of research.Meanwhile,the organic-based hybrid electro-optic modulators,which make full use of the advant-ages of organic electro-optic(OEO)materials(e.g.high electro-optic coefficient,fast response speed,high bandwidth,easy pro-cessing/integration and low cost)have attracted considerable attention.In this paper,we introduce a series of high-perform-ance OEO materials that exhibit good properties in electro-optic activity and thermal stability.In addition,the recent progress of organic-based hybrid electro-optic devices is reviewed,including photonic crystal-organic hybrid(PCOH),silicon-organic hy-brid(SOH)and plasmonic-organic hybrid(POH)modulators.A high-performance integrated optical platform based on OEO ma-terials is a promising solution for growing high speeds and low power consumption in compact sizes. 展开更多
关键词 organic electro-optic materials MODULATOR organic-based hybrid modulator heterogeneous integration
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Femtojoule electro-optic modulation using a silicon– organic hybrid device 被引量:4
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作者 Sebastian Koeber Robert Palmer +13 位作者 Matthias Lauermann Wolfgang Heni Delwin L Elder Dietmar Korn Markus Woessner Luca Alloatti Swen Koenig Philipp C Schindler Hui Yu Wim Bogaerts Larry R Dalton Wolfgang Freude Juerg Leuthold Christian Koos 《Light(Science & Applications)》 SCIE EI CAS CSCD 2015年第1期483-490,共8页
Energy-efficient electro-optic modulators are at the heart of short-reach optical interconnects,and silicon photonics is considered the leading technology for realizing such devices.However,the performance of all-sili... Energy-efficient electro-optic modulators are at the heart of short-reach optical interconnects,and silicon photonics is considered the leading technology for realizing such devices.However,the performance of all-silicon devices is limited by intrinsic material properties.In particular,the absence of linear electro-optic effects in silicon renders the integration of energy-efficient photonic–electronic interfaces challenging.Silicon–organic hybrid(SOH)integration can overcome these limitations by combining nanophotonic silicon waveguides with organic cladding materials,thereby offering the prospect of designing optical properties by molecular engineering.In this paper,we demonstrate an SOH Mach–Zehnder modulator with unprecedented efficiency:the 1-mm-long device consumes only 0.7 fJ bit^(-1) to generate a 12.5 Gbit s^(-1) data stream with a bit-error ratio below the threshold for hard-decision forward-error correction.This power consumption represents the lowest value demonstrated for a non-resonant Mach–Zehnder modulator in any material system.It is enabled by a novel class of organic electro-optic materials that are designed for high chromophore density and enhanced molecular orientation.The device features an electro-optic coefficient of r33<180 pm V^(-1) and can be operated at data rates of up to 40 Gbit s^(-1). 展开更多
关键词 electro-optic materials electro-optic modulation nonlinear organic materials silicon-organic hybrid
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新型有机非线性光学分子MC-FTC的合成 被引量:4
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作者 尹冬冬 任宇 +2 位作者 翟剑峰 邱玲 沈玉全 《化学学报》 SCIE CAS CSCD 北大核心 2004年第5期518-522,共5页
设计和合成了一种新型的有机非线性光学分子 ,2 二氰基甲叉 3 氰基 4 [2 (N ,N 二 乙酰氧基乙基氨基苯乙烯基 ) 3 正丁基噻吩基 5 乙烯基 ] 5 ,5 二甲基 2 ,5 二氢呋喃 (MC FTC) .报道了它的详细合成方法 ,给出了反应路... 设计和合成了一种新型的有机非线性光学分子 ,2 二氰基甲叉 3 氰基 4 [2 (N ,N 二 乙酰氧基乙基氨基苯乙烯基 ) 3 正丁基噻吩基 5 乙烯基 ] 5 ,5 二甲基 2 ,5 二氢呋喃 (MC FTC) .报道了它的详细合成方法 ,给出了反应路线和产物及各个中间体的化学结构 ,并通过IR ,UV/Vis ,NMR 。 展开更多
关键词 有机非线性光学分子 2-二氰基甲叉—3—氰基4[2-(N N-二—乙酰氧基乙基氨基苯乙烯基)—3—正丁基噻吩基—5—乙烯基]—5 5—二甲基—2 5—二氢呋喃 合成 结构 有机电光材料
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金属有机骨架材料MOF-5上噻吩硫化物的吸附分离 被引量:11
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作者 代伟 庄海堂 +3 位作者 卢信清 陈晓 韩敏敏 郑宇 《燃料化学学报》 EI CAS CSCD 北大核心 2010年第5期626-630,共5页
将金属有机骨架材料应用于燃油深度脱硫研究。采用水热法合成了金属有机骨架材料MOF-5,利用XRD、N2吸附和SEM等技术对其结构进行了表征。通过测定固定床吸附穿透曲线,考察了模型燃油类型对MOF-5吸附分离噻吩效果的影响。结果表明,MOF-5... 将金属有机骨架材料应用于燃油深度脱硫研究。采用水热法合成了金属有机骨架材料MOF-5,利用XRD、N2吸附和SEM等技术对其结构进行了表征。通过测定固定床吸附穿透曲线,考察了模型燃油类型对MOF-5吸附分离噻吩效果的影响。结果表明,MOF-5对硫化物的吸附容量超过了文献报道;在脂肪油中其穿透容量和饱和容量质量分数分别为0.90%和1.92%,在芳香模型物质中其穿透容量和饱和容量质量分数分别为0.64%和1.72%。通过采用与活性炭分层填装吸附柱技术,解决了溶解水对脱硫的影响,为吸附脱硫技术提供了新思路。 展开更多
关键词 金属有机骨架材料 MOF-5 噻吩 吸附分离 燃油深度脱硫
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具有D-π-A结构的三苯胺衍生物的合成及其性能 被引量:2
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作者 张正垠 赵鑫 +3 位作者 戚裕 邵晶 何星 林朝阳 《石油化工》 CAS CSCD 北大核心 2014年第4期425-429,共5页
以三苯胺、5-醛基-2-噻吩硼酸、丙二腈为主要原料,合成了一种具有D-π-A结构的三苯胺衍生物2-[5-[4-(N,N-二苯氨基)苯基]噻吩基]亚甲基丙二腈(DPTM)。通过FTIR、1H NMR和元素分析对该化合物的结构进行了表征,考察了其UV-Vis光谱、荧光... 以三苯胺、5-醛基-2-噻吩硼酸、丙二腈为主要原料,合成了一种具有D-π-A结构的三苯胺衍生物2-[5-[4-(N,N-二苯氨基)苯基]噻吩基]亚甲基丙二腈(DPTM)。通过FTIR、1H NMR和元素分析对该化合物的结构进行了表征,考察了其UV-Vis光谱、荧光光谱、电化学行为和热稳定性。研究结果表明,DPTM具有溶液成膜性,DPTM的二氯甲烷溶液及其固态薄膜均显示出很强的红色荧光,荧光量子产率为79.15%;DPTM的HOMO能级为-5.51 eV,与正电极的功函数(-4.8 eV)相匹配,可有效降低空穴注入的能垒,有利于空穴的注入和传输;DPTM的热分解温度为182℃,具有良好的热稳定性。DPTM有望作为一种具有空穴传输性能和发光性能的新型红色发光材料。 展开更多
关键词 三苯胺衍生物 5-醛基-2-噻吩硼酸 丙二腈 D-π-A结构 有机发光材料
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噻吩盘状液晶研究进展 被引量:1
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作者 赵可清 《四川师范大学学报(自然科学版)》 CAS 北大核心 2019年第3期285-300,F0003,共17页
液晶半导体材料因为具有自组装有序、自修复缺陷、保留有序度和电荷传输性能、可溶液方式加工成为薄膜电子器件且成本低廉等优点,而广受关注.液晶半导体材料在有机电子器件领域,如:发光二极管、太阳能电池、场效应晶体管、分子传感器等... 液晶半导体材料因为具有自组装有序、自修复缺陷、保留有序度和电荷传输性能、可溶液方式加工成为薄膜电子器件且成本低廉等优点,而广受关注.液晶半导体材料在有机电子器件领域,如:发光二极管、太阳能电池、场效应晶体管、分子传感器等有广阔的应用前景.这些薄膜电子器件性能与其活性成分液晶半导体材料性能密切相关.重点介绍含噻吩单元的盘状液晶和柱状相液晶的分子结构、合成方法、光电性质,及其在薄膜电子器件中的性能.对噻吩盘状液晶未来发展方向进行展望. 展开更多
关键词 液晶 有机半导体材料 噻吩 盘状液晶 柱状介晶相 荧光 场效应晶体管 电荷迁移速率
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新型苯并二噻吩类聚合物供体材料合成及其光伏性能研究
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作者 谭华 谭弘毅 +2 位作者 于俊婷 郑祥均 朱卫国 《常州大学学报(自然科学版)》 CAS 2021年第5期35-42,共8页
以刚性平面结构的苯并二噻吩(BDT)为给电子单元和具有稳定醌类结构的氟(F)取代噻吩[3,4-b]噻吩单元(TT)为受电子单元设计合成了两种窄带隙的聚合物供体材料。系统研究了侧链取代单元结构对聚合物供体材料光物理性能,电化学性能,活性层... 以刚性平面结构的苯并二噻吩(BDT)为给电子单元和具有稳定醌类结构的氟(F)取代噻吩[3,4-b]噻吩单元(TT)为受电子单元设计合成了两种窄带隙的聚合物供体材料。系统研究了侧链取代单元结构对聚合物供体材料光物理性能,电化学性能,活性层形貌和光伏性能影响。研究表明:相对于基于6-取代苯并噻吩侧链的聚合物供体材料PBDTBTs-TT,2-取代苯并噻吩侧链的聚合物供体材料PBDTTBs-TT具有更宽的光子捕获范围和更强的吸光能力,这有利于提高光伏器件的短路电流。以IT-4F为受体材料,基于PBDTBTs-TT:IT-4F的光伏器件能量转换效率和短路电流分别为6.43%和14.21 mA·cm^(-2);而基于PBDTTBs-TT:IT-4F的光伏器件能量转换效率和短路电流提高到了7.06%和15.32 mA·cm^(-2)。 展开更多
关键词 有机太阳能电池 聚合物供体材料 苯并二噻吩 氟取代噻吩[3 4-b]噻吩单元
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Growth and Study of ADP Crystal Doped with Acridine Orange
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作者 R. Nandhakumar T. Radhakrishnan 《Open Journal of Applied Sciences》 2016年第3期177-181,共5页
Materials with large non-linear optical properties are good candidates for applications in the fields of telecommunications, solar energy conversion, laser treatment and so on. In the present study, a crystal of Ammon... Materials with large non-linear optical properties are good candidates for applications in the fields of telecommunications, solar energy conversion, laser treatment and so on. In the present study, a crystal of Ammonium Dihydrogen Orthophosphate doped with Acridine Orange, possessing excellent nonlinear optical properties were grown by the slow solvent evaporation technique at 25°C using a constant temperature bath. Ammonium dihydrogen orthophosphate doped with Acridine Orange were synthesized in a large quantity via solution growth method using aqueous mixtures of Ammonium Dihydrogen Orthophosphate and Acridine Orange. The morphological characteristics were studied by field emission scanning electron microscopy which revealed that the synthesized product possesses needle shaped microstructures. The mechanical properties are studied by Vicker’s micro hardness test. 展开更多
关键词 IMPURITIES NUCLEATION Supersaturated Growth from Solutions organic Compound non-linear Optical material
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聚噻吩类电致变色材料的研究进展 被引量:3
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作者 金珊珊 陈宏书 +2 位作者 王结良 胡志毅 朱贞 《高分子通报》 CAS CSCD 北大核心 2014年第3期65-74,共10页
电致变色材料广泛应用于显示屏、智能窗、国防军事伪装等各方面,得到了人们的广泛关注。本文介绍了聚噻吩及其衍生物的变色机理,综述了聚噻吩、PEDOT、D-A型材料、D-A-D型材料、噻吩共聚物及其有机/无机纳米复合材料的性能及其研究进展... 电致变色材料广泛应用于显示屏、智能窗、国防军事伪装等各方面,得到了人们的广泛关注。本文介绍了聚噻吩及其衍生物的变色机理,综述了聚噻吩、PEDOT、D-A型材料、D-A-D型材料、噻吩共聚物及其有机/无机纳米复合材料的性能及其研究进展,并简要介绍了噻吩类电致变色材料的应用前景,指出合成颜色变化丰富、稳定性和成膜性好、易加工、并有很好导电性能的D-A-D材料、共聚物及其有机/无机纳米复合材料是聚噻吩类电致变色材料发展的主要趋势。 展开更多
关键词 有机电致变色材料 聚噻吩衍生物 聚(3 4-乙撑二氧噻吩) 供体-受体 纳米复合材料
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Taking silicon photonics modulators to a higher performance level: state-of-the-art and a review of new technologies 被引量:10
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作者 Abdul Rahim Artur Hermans +4 位作者 Benjamin Wohlfeil Despoina Petousi Bart Kuyken Dries Van Thourhout Roel Baets 《Advanced Photonics》 EI CSCD 2021年第2期38-60,共23页
Optical links are moving to higher and higher transmission speeds while shrinking to shorter and shorter ranges where optical links are envisaged even at the chip scale.The scaling in data speed and span of the optica... Optical links are moving to higher and higher transmission speeds while shrinking to shorter and shorter ranges where optical links are envisaged even at the chip scale.The scaling in data speed and span of the optical links demands modulators to be concurrently performant and cost-effective.Silicon photonics(SiPh),a photonic integrated circuit technology that leverages the fabrication sophistication of complementary metal-oxide-semiconductor technology,is well-positioned to deliver the performance,price,and manufacturing volume for the high-speed modulators of future optical communication links.SiPh has relied on the plasma dispersion effect,either in injection,depletion,or accumulation mode,to demonstrate efficient high-speed modulators.The high-speed plasma dispersion silicon modulators have been commercially deployed and have demonstrated excellent performance.Recent years have seen a paradigm shift where the integration of various electro-refractive and electro-absorptive materials has opened up additional routes toward performant SiPh modulators.These modulators are in the early years of their development.They promise to extend the performance beyond the limits set by the physical properties of silicon.The focus of our study is to provide a comprehensive review of contemporary(i.e.,plasma dispersion modulators)and new modulator implementations that involve the integration of novel materials with SiPh. 展开更多
关键词 high-speed modulators silicon photonics plasma dispersion effect FERROELECTRICS graphene III-V on Si organic(electro-optic)materials.
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