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Integrating Levels of Hierarchical Organization in Porous Organic Molecular Materials
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作者 Jesus Ferrando‑Soria Antonio Fernandez 《Nano-Micro Letters》 SCIE EI CAS CSCD 2024年第5期134-153,共20页
Porous organic molecular materials(POMMs)are an emergent class of molecular-based materials characterized by the formation of extended porous frameworks,mainly held by non-covalent interactions.POMMs represent a varie... Porous organic molecular materials(POMMs)are an emergent class of molecular-based materials characterized by the formation of extended porous frameworks,mainly held by non-covalent interactions.POMMs represent a variety of chemical families,such as hydrogen-bonded organic frameworks,porous organic salts,porous organic cages,C-H···πmicroporous crystals,supramolecular organic frameworks,π-organic frameworks,halogen-bonded organic framework,and intrinsically porous molecular materials.In some porous materials such as zeolites and metal organic frameworks,the integration of multiscale has been adopted to build materials with multifunctionality and optimized properties.Therefore,considering the significant role of hierarchy in porous materials and the growing importance of POMMs in the realm of synthetic porous materials,we consider it appropriate to dedicate for the first time a critical review covering both topics.Herein,we will provide a summary of literature examples showcasing hierarchical POMMs,with a focus on their main synthetic approaches,applications,and the advantages brought forth by introducing hierarchy. 展开更多
关键词 Porous organic molecular materials HIERARCHY Hydrogen-bonded organic frameworks Porous cages FULLERENE
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How can we improve the stability of organic solar cells from materials design to device engineering?
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作者 Mingpeng Li Leilei Tian Feng He 《Aggregate》 EI CAS 2024年第5期109-134,共26页
Among a promising photovoltaic technology for solar energy conversion,organic solar cells(OSCs)have been paid much attention,of which the power conversion efficiencies(PCEs)have rapidly surpassed over 20%,approaching t... Among a promising photovoltaic technology for solar energy conversion,organic solar cells(OSCs)have been paid much attention,of which the power conversion efficiencies(PCEs)have rapidly surpassed over 20%,approaching the threshold for potential applications.However,the device stability of OSCs including storage stability,photostability and thermal stability,remains to be an enormous challenge when faced with practical applications.The major causes of device instability are rooted in the poor inherent properties of light-harvesting materials,metastable mor-phology,interfacial reactions and highly sensitive to external stresses.To get rid of theseflaws,a comprehensive review is provided about recent strategies and meth-ods for improving the device stability from active layers,interfacial layers,device engineering and encapsulation techniques for high-performance OSC devices.In the end,prospectives for the next stage development of high-performance devices with satisfactory long-term stability are afforded for the solar community. 展开更多
关键词 device engineering materials design organic solar cells stability
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Advances in anode interfacial materials for organic solar cells
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作者 Menglan Lv Junhua Huang +6 位作者 Xuanyan Luo Shan Yu Xu Wang Zhuo Wang Fei Pan Bin Zhang Liming Ding 《Aggregate》 EI CAS 2024年第4期74-95,共22页
Organic solar cells(OSCs)have attracted much interest in the past few decades because of their advantages,such as being lightweight,low cost,simple preparation process,and environmental friendliness.While researchers ... Organic solar cells(OSCs)have attracted much interest in the past few decades because of their advantages,such as being lightweight,low cost,simple preparation process,and environmental friendliness.While researchers have made significant progress on the active layer materials of OSCs,the interface engineering is another entry point for upgrading the photovoltaic performance of OSCs.Significantly,the interface modification materials,including anode interfacial materials and cathode interfacial materials,are two essential parts of interfacial layers for OSCs,in which the excellent interfacial materials can realize the very high-performance photovoltaic cells.Among these interfacial materials,the anode interfacial layers(AILs)play a crucial role in improving photovoltaic performance.This review expresses a detailed conclusion of the development of anode interfacial materials and an outlook on future trends for OSCs. 展开更多
关键词 anode interfacial materials organic solar cells power conversion efficiency
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Effects of Functional Organic Materials on Morphological Indexes,Quality and Yield of Watermelon
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作者 Kun CHEN Shuying CHEN +1 位作者 Tao JIANG Pan ZHANG 《Agricultural Biotechnology》 2024年第3期8-10,共3页
[Objectives]This study was conducted to explore suitable organic compound application models for watermelon growth.[Methods]With watermelon hybrid material"M22×P18"as the test material,the effects of fo... [Objectives]This study was conducted to explore suitable organic compound application models for watermelon growth.[Methods]With watermelon hybrid material"M22×P18"as the test material,the effects of four functional organic materials,namely garlic straw treatment(T_(1)),onion straw treatment(T_(2)),garlic straw+sheep manure treatment(T_(3))and onion straw+chicken manure treatment(T_(4)),on the morphological indexes,yield and quality of watermelon were investigated.[Results]Different functional organic materials had different effects on morphological indexes,yield and quality of watermelon.The morphological indexes,nutritional quality indexes and yield of watermelon treated with garlic straw and sheep manure compound(T_(3))and onion straw and chicken manure compound(T_(4))were significantly higher than those treated simply with garlic straw(T_(1))and onion straw(T_(2)),and T_(3)performed relatively better.Compared with treatment T_(2),T_(3)showed a stem diameter,vine length and leaf number increasing by 43.05%,46.69%and 40.77%respectively,central sugar and side sugar contents increasing by 11.72%and 21.90%respectively,and a yield increasing by 42.91%,with significant differences from T_(2).[Conclusions]This study provides technical support for high-quality and high-yielding cultivation of watermelon. 展开更多
关键词 organic materials WATERMELON Morphological index QUALITY YIELD
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Effects of Functional Organic Materials on Fresh Weight,Quality,Single-melon Weight and SPAD Value of Watermelon
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作者 Kun CHEN Yuefeng ZHAO +5 位作者 Xiaoxue REN Mingda YANG Mingjun ZHAO Yumei WANG Xinhua HUANG Hao LIU 《Agricultural Biotechnology》 2024年第4期54-56,共3页
[Objectives]This study was conducted to explore a functional organic material formula suitable for watermelon cultivation with high quality,high yield and high efficiency.[Methods]Four treatments were set in the exper... [Objectives]This study was conducted to explore a functional organic material formula suitable for watermelon cultivation with high quality,high yield and high efficiency.[Methods]Four treatments were set in the experiment,namely four functional organic materials,garlic straw treatment(T_(1)),onion straw treatment(T_(2)),garlic straw+sheep manure treatment(T_(3))and onion straw+chicken manure treatment(T_(4)),to investigate the effects of different functional organic materials on fresh weight,quality,single-melon weight and SPAD value of watermelon.[Results]The effects of different functional organic materials on fresh weight,quality,single-melon weight and SPAD value of watermelon were quite different.The fresh weight,quality,single-melon weight and SPAD value of watermelon were higher in treatment T_(3)applying garlic straw and sheep manure and treatment T_(4)applying onion straw and chicken manure than in treatment T_(1)applying garlic straw and treatment T_(2)applying onion straw.Specifically,the fresh weight of whole plant was the highest in treatment T_(3),followed by treatment T_(4),and the values of the two treatments increased by 12.83%and 5.94%respectively compared with treatment T_(1);the weight of single melon was the highest in treatment T_(3),followed by treatment T_(4),and the values of the two treatments increased by 42.45%and 31.77%respectively compared with treatment T_(2);and the SPAD values of treatments T_(3)and T_(4)were significantly higher than those of treatments T_(1)and T_(2),and the value of treatment T_(3)was the largest.[Conclusions]This study provides theoretical support for the popularization and application of fertilization techniques combining organic fertilizers and reduced chemical fertilizers for watermelon. 展开更多
关键词 WATERMELON organic materials Fresh weight QUALITY Single-melon weight SPAD value
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Towards green asphalt materials with lower emission of volatile organic compounds: A review on the release characteristics and its emission reduction additives
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作者 Xiwen Chang Feng Wang +2 位作者 Rui Wu Chen Wang Yue Xiao 《Journal of Road Engineering》 2024年第3期292-317,共26页
Recently, researchers in the road field are focusing on the development of green asphalt materials with loweremission of volatile organic compounds (VOCs). The characterization methodology of asphalt VOCs and theinflu... Recently, researchers in the road field are focusing on the development of green asphalt materials with loweremission of volatile organic compounds (VOCs). The characterization methodology of asphalt VOCs and theinfluencing factors on VOCs release have always been the basic issue of asphalt VOCs emission reduction research.Researchers have proposed a variety of asphalt VOCs characterization methodologies, which also have mutuallyirreplaceable characteristics. Asphalt VOCs volatilization is affected by many factors. In this study, asphalt VOCscharacterization methodologies were summarized, including their advantages, disadvantages, characteristics andapplicable requirements. Subsequently, the influencing factors of VOCs release, such as asphalt types and environment conditions, are summarized to provide theoretical support for the emission reduction research. Theclassification and mechanism of newly-development asphalt VOCs emission reduction materials are reviewed. Thereduction efficiencies are also compared to select better materials and put forward the improvement objective ofnew materials and new processes. In addition, the prospects about development of VOCs release mechanism ofasphalt materials during the full life cycle and feasibility research of high-efficiency composite emission reductionmaterials in the future were put forward. 展开更多
关键词 Asphalt VOCs Volatile organic compounds Green asphalt materials Reduction efficiency Hazardous emission
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Outstanding Lithium Storage Performance of a Copper-Coordinated Metal-Covalent Organic Framework as Anode Material for Lithium-Ion Batteries
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作者 Derong Luo Huizi Zhao +5 位作者 Feng Liu Hai Xu Xiaoyu Dong Bing Ding Hui Dou Xiaogang Zhang 《Energy & Environmental Materials》 SCIE EI CAS CSCD 2024年第5期29-36,共8页
Metal-covalent organic frameworks(MCOF)as a bridge between covalent organic framework(COF)and metal organic framework(MOF)possess the characteristics of open metal sites,structure stability,crystallinity,tunability as... Metal-covalent organic frameworks(MCOF)as a bridge between covalent organic framework(COF)and metal organic framework(MOF)possess the characteristics of open metal sites,structure stability,crystallinity,tunability as well as porosity,but still in its infancy.In this work,a covalent organic framework DT-COF with a keto-enamine structure synthesized from the condensation of 3,3'-dihydroxybiphenyl diamine(DHBD)and triformylphloroglucinol(TFP)was coordinated with Cu^(2+)by a simple post-modification method to a obtain a copper-coordinated metal-covalent organic framework of Cu-DT COF.The isomerization from a keto-enamine structure of DT-COF to a enol-imine structure of Cu-DT COF is induced due to the coordination interaction of Cu^(2+).The structure change of Cu-DT COF induces the change of the electron distribution in the Cu-DT COF,which greatly promotes the activation and deep Li-storage behavior of the COF skeleton.As anode material for lithium-ion batteries(LIBs),Cu-DT COF exhibits greatly improved electrochemical performance,retaining the specific capacities of 760 mAh g^(-1)after 200 cycles and 505 mAh g^(-1)after 500 cycles at a current density of 0.5 A g^(-1).The preliminary lithium storage mechanism studies indicate that Cu^(2+)is also involved in the lithium storage process.A possible mechanism for Cu-DT COF was proposed on the basis of FT-IR,XPS,EPR characterization and electrochemical analysis.This work enlightens a novel strategy to improve the energy storage performance of COF and promotes the application of COF and MCOF in LIBs. 展开更多
关键词 anode material copper-coordination lithium-ion batteries metal-covalent organic frameworks
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Organic cathode materials for rechargeable magnesium-ion batteries:Fundamentals, recent advances, and approaches to optimization
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作者 Xiaoqian He Ruiqi Cheng +6 位作者 Xinyu Sun Hao Xu Zhao Li Fengzhan Sun Yang Zhan Jianxin Zou Richard M.Laine 《Journal of Magnesium and Alloys》 SCIE EI CAS CSCD 2023年第12期4359-4389,共31页
Rechargeable magnesium-ion batteries(MIBs) are favorable substitutes for conventional lithium-ion batteries(LIBs) because of abundant magnesium reserves, a high theoretical energy density, and great inherent safety. O... Rechargeable magnesium-ion batteries(MIBs) are favorable substitutes for conventional lithium-ion batteries(LIBs) because of abundant magnesium reserves, a high theoretical energy density, and great inherent safety. Organic electrode materials with excellent structural tunability,unique coordination reaction mechanisms, and environmental friendliness offer great potential to promote the electrochemical performance of MIBs. However, research on organic magnesium battery cathode materials is still preliminary with many significant challenges to be resolved including low electrical conductivity and unwanted but severe dissolution in useful electrolytes. Herein, we provide a detailed overview of reported organic cathode materials for MIBs. We begin with basic properties such as charge storage mechanisms(e.g., n-, p-, and bipolartype), moving to recent advances in various types of organic cathodes including carbonyl-, nitrogen-, and sulfur-based materials. To shed light on the diverse strategies targeting high-performance Mg-organic batteries, elaborate summaries of various approaches are presented.Generally, these strategies include molecular design, polymerization, mixing with carbon, nanosizing and electrolyte/separator optimization.This review provides insights on exploring high-performance organic cathodes in rechargeable MIBs. 展开更多
关键词 Mg-organic batteries organic cathode materials Energy storage Charge storage mechanism Electrochemical optimization approaches
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Low-cost and stable SFX-based semiconductor materials in organic optoelectronics
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作者 Chen-Sheng Li Bao-Yi Ren Ya-Guang Sun 《Resources Chemicals and Materials》 2023年第1期100-109,共10页
In the progress of realizing the commercialization of organic optoelectronic materials,the four basic coherent factors are stability,cost,performance,and processability,all which determine the results of device applic... In the progress of realizing the commercialization of organic optoelectronic materials,the four basic coherent factors are stability,cost,performance,and processability,all which determine the results of device applications.Spiro[fluorene-9,9′-xanthene](SFX)has been becoming the robust building-block that fulfilling the practical requirements due to its key features of non-planarity,one-pot facile availability,well-defined quality assurance as well as performance behaviors.In this review,we introduce the SFX and its analogues,including synthesis,molecular design,device performance,and structure-property relationship,in the applications of organic light-emitting diodes(OLEDs),organic photovoltaics,perovskite solar cells(PSCs)and others.Furthermore,emitters or hosts for OLED and hole transport materials for PSCs are highlighted at the level of molecular configuration and film morphology.Tracing the thread from intrinsic photoelectric properties,molecular packing to optoelectronic application,the advantage of stability and low-cost of SFX-based materials are illuminated,and an outlook is given providing orientation for bring SFX into the fields of catalysis and energy chemistry in view of its binary conjugation and three-dimensional configuration. 展开更多
关键词 organic optoelectronic materials Spiro[fluorene-9 9′-xanthene](SFX) Synthesis Application
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Decomposition of Different Organic Materials and Variation of Active Organic Carbon and Nitrogen Contents in Tobacco-planted Soil 被引量:4
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作者 鲁耀 郑波 +4 位作者 段宗颜 李祖红 解燕 邱学礼 王建新 《Agricultural Science & Technology》 CAS 2015年第1期107-111,共5页
The oilseed cake, vetch, rapeseed straw, wheat straw and corn straw were buried in tobacco-planted soil. The decomposition rates, the variation of active organic C and N contents in the residues and the relationship b... The oilseed cake, vetch, rapeseed straw, wheat straw and corn straw were buried in tobacco-planted soil. The decomposition rates, the variation of active organic C and N contents in the residues and the relationship between active organic C and N contents and decomposition rate were investigated. The results showed the decomposition rates of different organic materials were all high in the early period and then low in the late period. Among the organic materials, the decomposition rates ranked as oilseed cake 〉 vetch 〉 wheat straw and rapeseed straw 〉 corn straw. The decomposition rate was positively related to total N content (P〈0.01), but was negatively related to the active organic C/N ratio (P〈0.01). However, there was no significant relationship between decomposition ratio and active organic C content. With the proceeding of decomposition, the active organic C content and the total N content in rapeseed straw, vetch, wheat straw and corn straw all trended to increase, but the active organic C/N ratio trended to decrease. However, the variation of active organic C content, total N content and active organic C/N ratio in oilseed cake was on the contrary. 展开更多
关键词 organic material Decomposition rate Active organic C C/N ratio
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Effects of Combined Application of Water Retaining Agents and Organic Materials on Water Holding Characteristics of Yellow Brown Soils in Hilly Areas 被引量:1
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作者 唐玉邦 虞利俊 +4 位作者 徐磊 罗佳 王东升 范如芹 裴勤 《Agricultural Science & Technology》 CAS 2015年第9期1985-1988,共4页
[Objective] The aim was to reduce fertilizer and water losses caused by surface runoffs in rainy season and provide scientific references for soil moisture in arid season. [Method] The application proportion of comple... [Objective] The aim was to reduce fertilizer and water losses caused by surface runoffs in rainy season and provide scientific references for soil moisture in arid season. [Method] The application proportion of complex water-holding organic materials was determined by multi-factor mixture experiment and the curve changes of soil moisture characters were tested to analyze water-holding capacity and water availability of soils. [Result] The initial moisture content of soil with different mixture proportions improved in varying degrees. For example, when water-retention agents reached 0.4% and 0.6% of soil weight, soil moisture contents were 69.0% and70.5%, respectively, which showed significant differences with the control(S0.0). Soil dehydration terms in different treatments all extended, prolonging in the range of4.6-14 d. [Conclusion] The applications of water-retention agent and organic material would improve water-holding capacity of hills and low mountains, and initial moisture content and dehydration cycle tend to be volatile upon mixture proportion. Therefore,it is necessary to adjust soil fertility, crop species, and irrigation to meet crop demands on fertilizer and water. 展开更多
关键词 Water retaining agents organic materials Soils of hilly areas Water characteristics
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A Review of Anode Materials for Dual‑Ion Batteries
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作者 Hongzheng Wu Shenghao Luo +6 位作者 Hubing Wang Li Li Yaobing Fang Fan Zhang Xuenong Gao Zhengguo Zhang Wenhui Yuan 《Nano-Micro Letters》 SCIE EI CAS CSCD 2024年第11期618-674,共57页
Distinct from"rockingchair"lithium-ion batteries(LIBs),the unique anionic intercalation chemistry on the cathode side of dual-ion batteries(DIBs)endows them with intrinsic advantages of low cost,high voltage... Distinct from"rockingchair"lithium-ion batteries(LIBs),the unique anionic intercalation chemistry on the cathode side of dual-ion batteries(DIBs)endows them with intrinsic advantages of low cost,high voltage,and ecofriendly,which is attracting widespread attention,and is expected to achieve the next generation of large-scale energy storage applications.Although the electrochemical reactions on the anode side of DIBs are similar to that of LIBs,in fact,to match the rapid insertion kinetics of anions on the cathode side and consider the compatibility with electrolyte system which also serves as an active material,the anode materials play a very important role,and there is an urgent demand for rational structural design and performance optimization.A review and summarization of previous studies will facilitate the exploration and optimization of DIBs in the future.Here,we summarize the development process and working mechanism of DIBs and exhaustively categorize the latest research of DIBs anode materials and their applications in different battery systems.Moreover,the structural design,reaction mechanism and electrochemical performance of anode materials are briefly discussed.Finally,the fundamental challenges,potential strategies and perspectives are also put forward.It is hoped that this review could shed some light for researchers to explore more superior anode materials and advanced systems to further promote the development of DIBs. 展开更多
关键词 Dual-ion batteries ANODE Carbonaceous materials Metallic materials organic materials Optimization strategies
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Progress in the research on organic piezoelectric catalysts for dye decomposition
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作者 Zhaoning Yang Xiaoxin Shu +3 位作者 Di Guo Jing Wang Hui Bian Yanmin Jia 《International Journal of Minerals,Metallurgy and Materials》 SCIE EI CAS CSCD 2024年第2期245-260,共16页
Organic contaminants have posed a direct and substantial risk to human wellness and the environment.In recent years,piezo-electric catalysis has evolved as a novel and effective method for decomposing these contaminan... Organic contaminants have posed a direct and substantial risk to human wellness and the environment.In recent years,piezo-electric catalysis has evolved as a novel and effective method for decomposing these contaminants.Although piezoelectric materials offer a wide range of options,most related studies thus far have focused on inorganic materials and have paid little attention to organic materi-als.Organic materials have advantages,such as being lightweight,inexpensive,and easy to process,over inorganic materials.Therefore,this paper provides a comprehensive review of the progress made in the research on piezoelectric catalysis using organic materials,high-lighting their catalytic efficiency in addressing various pollutants.In addition,the applications of organic materials in piezoelectric cata-lysis for water decomposition to produce hydrogen,disinfect bacteria,treat tumors,and reduce carbon dioxide are presented.Finally,fu-ture developmental trends regarding the piezoelectric catalytic potential of organic materials are explored. 展开更多
关键词 piezoelectric catalysis piezoelectric material dye decomposition organic materials
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A review of anode materials for sodium ion batteries
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作者 Syed Ali Riza XU Ri-gan +6 位作者 LIU Qi Muhammad Hassan YANG Qiang MU Dao-bin LI Li WU Feng CHEN Ren-jie 《新型炭材料(中英文)》 SCIE EI CAS CSCD 北大核心 2024年第5期743-769,共27页
Lithium-ion batteries(LIBs)are used in electric vehicles and portable smart devices,but lithium resources are dwindling and there is an increasing demand which has to be catered for.Sodium ion batteries(SIBs),which ar... Lithium-ion batteries(LIBs)are used in electric vehicles and portable smart devices,but lithium resources are dwindling and there is an increasing demand which has to be catered for.Sodium ion batteries(SIBs),which are less costly,are a promising replacement for LIBs because of the abundant natural reserves of sodium.The anode of a SIB is a necessary component of the battery but is less understood than the cathode.This review outlines the development of various types of anodes,including carbonbased,metallic and organic,which operate using different reaction mechanisms such as intercalation,alloying and conversion,and considers their challenges and prospects.Strategies for modifying their structures by doping and coating,and also modifying the solid electrolyte interface are discussed.In addition,this review also discusses the challenges encountered by the anode of SIBs and the solutions. 展开更多
关键词 Sodium ion batteries ANODE Carbon material Metallic compound organic
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A review of ultra-high temperature heat-resistant energetic materials
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作者 Rongzheng Zhang Yuangang Xu +4 位作者 Feng Yang Pengcheng Wang Qiuhan Lin Hui Huang Ming Lu 《Defence Technology(防务技术)》 SCIE EI CAS CSCD 2024年第8期33-57,共25页
Heat-resistant energetic materials refer to a type of energetic materials that possess a high melting point,high stability and operational safety. By studying the structures of these energetic materials has showed tha... Heat-resistant energetic materials refer to a type of energetic materials that possess a high melting point,high stability and operational safety. By studying the structures of these energetic materials has showed that the thermal stability can be enhanced by introducing amino groups to form intra/inter-molecular hydrogen bonds, constructing conjugate systems and designing symmetrical structures. This article aims to review the physical and chemical properties of ultra-high temperature heat-resistant energetic compounds and provide valuable theoretical insights for the preparation of ultra-high temperature heatresistant energetic materials. We also analyze the selected 20 heat-resistant energetic materials with decomposition temperatures higher than 350℃, serving as templates for the synthesis of various highperformance heat-resistant energetic materials. 展开更多
关键词 Heat-resistant energetic materials organic synthesis CONJUGATED Hydrogen bond Symmetrical structure STABILIZATION
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Cation-Anion Redox Active Organic Complex for High Performance Aqueous Zinc Ion Battery
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作者 Lilin Zhang Yining Chen +5 位作者 Zongyuan Jiang Jingwei Chen Cong Wei Wenzhuo Wu Shaohui Li Qun Xu 《Energy & Environmental Materials》 SCIE EI CAS CSCD 2024年第1期60-67,共8页
Organic redox compounds are attractive cathode materials in aqueous zinc-ion batteries owing to their low cost,environmental friendliness,multiple-electron-transfer reactions,and resource sustainability.However,the re... Organic redox compounds are attractive cathode materials in aqueous zinc-ion batteries owing to their low cost,environmental friendliness,multiple-electron-transfer reactions,and resource sustainability.However,the realized energy density is constrained by the limited capacity and low voltage.Herein,copper-tetracyanoquinodimethane(CuTCNQ),an organic charge-transfer complex is evaluated as a zinc-ion battery cathode owing to the good electron acceptation ability in the cyano groups that improves the voltage output.Through electrochemical activation,electrolyte optimization,and adoption of graphene-based separator,CuTCNQ-based aqueous zinc-ion batteries deliver much improved rate performance and cycling stability with anti-self-discharge properties.The structural evolution of CuTCNQ during discharge/charge are investigated by ex situ Fourier transform infra-red(FT-IR)spectra,ex situ X-ray photoelectron spectroscopy(XPS),and in situ ultraviolet visible spectroscopy(UV-vis),revealing reversible redox reactions in both cuprous cations(Cu^(+))and organic anions(TCNQ^(x-1)),thus delivering a high voltage output of 1.0 V and excellent discharge capacity of 158 mAh g^(-1).The remarkable electrochemical performance in Zn//CuTCNQ is ascribed to the strong inductive effect of cyano groups in CuTCNQ that elevated the voltage output and the graphene-modified separator that inhibited CuTCNQ dissolution and shuttle effect in aqueous electrolytes. 展开更多
关键词 cathode materials cyano groups electrochemical activation organic charge-transfer complex zinc-ion battery
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Modeling and Simulation of an Organic Photovoltaic Cell: ITO/MoO3/CARAPA/PCBM/Alq3/Al with SCAPS
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作者 Donafologo Soro Adama Sylla +5 位作者 Aboudramane Gbané Bamba Abdoulaye Franck Julia Mari Guaita Amal Bouich Siaka Toure Bernabé Marí 《Modeling and Numerical Simulation of Material Science》 2024年第3期79-96,共18页
Renewable energies are of major interest due to their inexhaustible and clean nature, with minimal impact on the environment. Numerous technological pathways exist in this field, each distinguished by the materials us... Renewable energies are of major interest due to their inexhaustible and clean nature, with minimal impact on the environment. Numerous technological pathways exist in this field, each distinguished by the materials used and their implementation principles. However, the cost-efficiency ratio remains a significant challenge for researchers. Currently, organic materials are gaining popularity due to their relatively low cost. However, their performance, particularly in terms of conversion efficiency, still requires improvements. This study focuses on optimizing the organic photovoltaic cell ITO/MoO3/CARAPA/PCBM/Alq3/Al using SCAPS. Several parameters were considered, such as layer thickness, recombination center density, and doping, to improve the cell’s performance. The optimal parameters obtained include an efficiency of 3%, a fill factor of 81.67%, an open-circuit voltage of 1610 mV, and a short-circuit current of 2.28 mA/cm2. The study also revealed that doping the phenyl-C61-butyric acid methyl ester (PCBM) layer has a significant impact on efficiency and short-circuit current, improving these parameters up to a certain point before causing degradation due to increased recombination. Furthermore, high doping of the tri (8-hydroxyquinoline) aluminum (Alq3) layer improves performance up to a critical threshold, after which degradation is also observed. In contrast, doping the molybdenum trioxide (MoO3) layer does not have a notable impact on cell performance. Regarding the thickness of the active Carapaprocera (CARAPA) and PCBM layers, non-optimal values lead to a decrease in performance. Similarly, an optimal thickness of the Alq3 layer significantly improves efficiency. These results highlight the importance of parameter optimization to maximize the efficiency of organic solar cells. 展开更多
关键词 Renewable Energie Solar Cells SIMULATION organic materials PERFORMANCE
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Investigating the Potential of Quasi-One-Dimensional Organic Crystals of TTT(TCNQ)2 for Thermoelectric Applications
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作者 Silvia Andronic Ionel Sanduleac 《Advances in Materials Physics and Chemistry》 CAS 2024年第1期1-14,共14页
The purpose of this paper is to present the results of investigations on quasi-one-dimensional organic crystals of tetrathiotetracene-tetracyanoquinodi- methane (TTT(TCNQ)<sub>2</sub>) from the prospective... The purpose of this paper is to present the results of investigations on quasi-one-dimensional organic crystals of tetrathiotetracene-tetracyanoquinodi- methane (TTT(TCNQ)<sub>2</sub>) from the prospective of thermoelectric applications. The calculations were performed after analytical expressions, obtained in the frame of a physical model, more detailed than the model presented earlier by authors. The main Hamiltonian of the model includes the electronic and phonon part, electron-phonon interactions and the impurity scattering term. In order to estimate the electric charge transport between the molecular chains, the physical model was upgraded to the so-called three-dimen- sional (3D) physical model. Numeric computations were performed to determine the electrical conductivity, Seebeck coefficient, thermal conductivity, thermoelectric power factor and thermoelectric figure-of-merit as a function on charge carrier concentrations, temperatures and impurity concentrations. A detailed analysis of charge-lattice interaction, consisting of the exploration of the Peierls structural transition in TCNQ molecular chains of TTT(TCNQ)<sub>2</sub> was performed. As result, the critical transition temperature was determined. The dispersion of renormalized phonons was examined in detail. 展开更多
关键词 organic materials Tetrathiotetracene-Tetracyanoquinodimethane Thermoelectric Figure of Merit Renormalized Phonon Spectrum Peierls Tran-sition
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Decomposition characteristics of organic materials and their effects on labile and recalcitrant organic carbon fractions in a semi-arid soil under plastic mulch and drip irrigation 被引量:9
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作者 hu juan wu jinggui qu xiaojing 《Journal of Arid Land》 SCIE CSCD 2018年第1期115-128,共14页
Labile organic carbon (LC) and recalcitrant organic carbon (RC) are two major fractions of soil organic carbon (SOC) and play a critical role in organic carbon turnover and sequestration. The aims of this study ... Labile organic carbon (LC) and recalcitrant organic carbon (RC) are two major fractions of soil organic carbon (SOC) and play a critical role in organic carbon turnover and sequestration. The aims of this study were to evaluate the variations of LC and RC in a semi-arid soil (Inner Mongolia, China) under plastic mulch and drip irrigation after the application of organic materials (OMs), and to explore the effects of OMs from various sources on LC and RC by probing the decomposition characteristics of OMs using in-situ nylon mesh bags burying method. The field experiment included seven treatments, i.e., chicken manure (CM), sheep manure (SM), mushroom residue (MR), maize straw (MS), fodder grass (FG), tree leaves (TL) and no OMs as a control (CK). Soil LC and RC were separated by Huygens D's method (particle size-density), and the average soil mass recovery rate and carbon recovery rate were above 95%, which indicated this method was suitable for carbon pools size analysis. The LC and RC contents significantly (P〈0.01) increased after the application of OMs. Moreover, LC and RC contents were 3.2%-8.6% and 5.0%-9.4% higher in 2016 than in 2015. The applications of CM and SM significantly increased (P〈0,01) LC content and LC/SOC ratio, whereas they were the lowest after the application of TL. However, SOC and RC contents were significantly higher (P〈0.01) after the applications of TL and MS. The correlation analysis indicated the decomposition rate of OMs was positively related with LC content and LC/SOC ratio. In addition, lignin, polyphenol, WOM (total water-soluble organic matter), WHA (water-soluble humic acid), HSL (humicdike substance) and HAL (humic acid-like) contents in initial OMs played important roles in SOC and RC. In-situ nylon mesh bags burying experiment indicated the decomposition rates of CM, SM and MS were significantly higher than those of MR, FG, and TL. Furthermore, MS could result in more lignin derivatives, WHA, and HAL polymers in shorter time during the decomposition process. In conclusion, the application of MS in the semi-arid soil under a long-term plastic mulch and drip irrigation condition could not only improve soil fertility, but also enhance soil carbon sequestration. 展开更多
关键词 organic materials labile organic carbon recalcitrant organic carbon decomposition characteristics plasticmulch drip irrigation Inner Mongolia
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Selective extraction and separation of Fe,Mn oxides and organic materials in river surficial sediments 被引量:6
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作者 LI Feng-mei WANG Xiao-li +2 位作者 LI Yu GUO Shu-hai ZHONG Ai-ping 《Journal of Environmental Sciences》 SCIE EI CAS CSCD 2006年第6期1233-1240,共8页
In order to investigate the adsorption mechanism of trace metals to surficial sediments (SSs), a selective extraction procedure was improved in the present work. The selective extraction procedure has been proved to... In order to investigate the adsorption mechanism of trace metals to surficial sediments (SSs), a selective extraction procedure was improved in the present work. The selective extraction procedure has been proved to selectively remove and separate Fe, Mn oxides and organic materials (OMs) in the non-residual fraction from the SSs collected in Songhua River, China. After screening different kinds of conventional extractants of Fe and Mn oxides and OMs used for separation of heavy metals in the soils and sediments, NH2OH .HCl (0.1 mol/L) + HNO3 (0.1 mol/L), (NH4)2C2O4 (0.2 mol/L) + H2C2O4 (pH 3.0), and 30% of H2O2 were respectively applied to selectively extract Mn oxides, Fe/Mn oxides and OMs. After the extraction treatments, the target components were removed with extraction efficiencies between 86.09%--3.36% for the hydroxylamine hydrochloride treatment, 80.63%- 101.09% for the oxalate solution extraction, and 94.76%-102.83% for the hydrogen peroxide digestion, respectively. The results indicate that this selective extraction technology was effective for the extraction and separation ofFe, Mn oxides and OMs in the SSs, and important for further mechanism study of trace metal adsorption onto SSs. 展开更多
关键词 surficial sediments selective extraction iron oxides manganese oxides organic materials
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