The kinetic characteristic of photolysis of cypermethrin (CPM) sensitized by acetophenone (AP) and the effect of probe substance 2,6-Di-tert-butyl-4-methylphenol and tetralin is studied in this report. It showed that ...The kinetic characteristic of photolysis of cypermethrin (CPM) sensitized by acetophenone (AP) and the effect of probe substance 2,6-Di-tert-butyl-4-methylphenol and tetralin is studied in this report. It showed that the photolysis rate of CPM increases slightly with the increase of AP concentration; photolysis rate of CPM has no relationship with [CPM] itself; The more dipolar moment the solvent has, the more the interaction between radical and solvent has, and the slower the photolysis of CPM is. The addition of radical probe substance confirms that ROO·is more than RO·. The steady-state concentration of ROO·is about 10?8 mol·L?1.展开更多
A low-pressure reactor(LPR) was developed for the measurement of ambient organic peroxy(RO2)radicals with the use of the laser-induced fluorescence(LIF) instrument.The reactor converts all the RO_(x)(=RO2+HO2+RO+OH) r...A low-pressure reactor(LPR) was developed for the measurement of ambient organic peroxy(RO2)radicals with the use of the laser-induced fluorescence(LIF) instrument.The reactor converts all the RO_(x)(=RO2+HO2+RO+OH) radicals into HO2 radicals.It can conduct different measurement modes through altering the reagent gases,achieving the speciated measurement of RO2 and RO2^#(RO2 radicals derived from the long-chain alkane,alkene and aromatic hydrocarbon).An example of field measurement results was given,with a maximum concentration of 1.88 × 10^(8) molecule/cm^(3) for RO2 and 1.18×10^(8) molecule/cm^(3) for RO2^(#).Also,this instrument quantifies the local ozone production rates directly,which can help to deduce the regional ozone control strategy from an experimental perspective.The new device can se rve as a potent tool for both the explo ration of frontier chemistry and the diagnosis of the control strategies.展开更多
文摘The kinetic characteristic of photolysis of cypermethrin (CPM) sensitized by acetophenone (AP) and the effect of probe substance 2,6-Di-tert-butyl-4-methylphenol and tetralin is studied in this report. It showed that the photolysis rate of CPM increases slightly with the increase of AP concentration; photolysis rate of CPM has no relationship with [CPM] itself; The more dipolar moment the solvent has, the more the interaction between radical and solvent has, and the slower the photolysis of CPM is. The addition of radical probe substance confirms that ROO·is more than RO·. The steady-state concentration of ROO·is about 10?8 mol·L?1.
基金the National Key R&D Program of China(No.2017YFC0209402)the Beijing Natural Science Foundation,China(No.JQ19031)。
文摘A low-pressure reactor(LPR) was developed for the measurement of ambient organic peroxy(RO2)radicals with the use of the laser-induced fluorescence(LIF) instrument.The reactor converts all the RO_(x)(=RO2+HO2+RO+OH) radicals into HO2 radicals.It can conduct different measurement modes through altering the reagent gases,achieving the speciated measurement of RO2 and RO2^#(RO2 radicals derived from the long-chain alkane,alkene and aromatic hydrocarbon).An example of field measurement results was given,with a maximum concentration of 1.88 × 10^(8) molecule/cm^(3) for RO2 and 1.18×10^(8) molecule/cm^(3) for RO2^(#).Also,this instrument quantifies the local ozone production rates directly,which can help to deduce the regional ozone control strategy from an experimental perspective.The new device can se rve as a potent tool for both the explo ration of frontier chemistry and the diagnosis of the control strategies.
