MLA-Based Detection of Organic Matter with Iodized Epoxy Resin—An Alternative to Carnauba

Solid organic matter is an important constituent not only in coal, but also in black shale-hosted ore deposits. The reliable recognition and quantification of organic carbon—as well as its microfabric relation to associated inorganic minerals—plays a crucial role in characterization by scanning electron microscopy-based image analysis. However, the use of conventional epoxy resin in the preparation of grain mounts does not allow for recognition of solid organic carbon compounds. In this study we illustrate that the use of iodized epoxy resin readily overcomes this bottleneck. Best results are obtained with an addition of 15 wt% iodoform to the epoxy resin. With process samples of black shale-hosted polymetallic Kupferschiefer-type ore as a case study, it is shown that recognition and quantification of solid organic carbon are easily achieved and that tangible parameters such as particle and grain sizes, association and liberation for ore and gangue minerals can be determined in the presence of solid organic matter. Due to the inherent uncertainty of the exact chemical composition of the kerogen contained in Kupferschiefer, it was not possible to attain exact comparability between chemical Corg assays and assays calculated from MLA data. However, the results are still found to closely agree with one another. The strength of iodized resin lies in its ability to distinguish organic matter with high hydration ratios in addition to the easy integration in sample preparation. It could therefore be an attractive supplement in the analyses of other raw materials containing complex organic-matter.

Preparation of Silica Powder in Epoxy Resin Wear-Resistant Coating

Silicon powders possess good thermal stability and rub resistance and can be used as the filler of high temperature wear-resistant coating;it can possess good wettability and dispersibility in the organic polymer by surface modification of silane coupling agent. Organic silicon has good thermal stability, which can modify the frangibility and thermal stability of epoxy resin. A certain proportion of modified silica powder, curing agent and additives were dispersed to modified epoxy resin can compound wear-resistant coating. The results show that: the modification effect can be the best if the dosage of silane coupling agent is 1.5% of silicon powder. If the methyl triethoxy silane is 50 phr and modified silica powder is 200 phr, then various performances of coating tend to be the best.

焦磷酸哌嗪@COF阻燃剂的制备及其对环氧树脂的阻燃作用

通过溶液合成法制备了一种共价有机框架(COF),再将COF包覆在焦磷酸哌嗪(PAPP)上形成PAPP@COF杂化阻燃剂,并将其应用于EP中。通过氧指数测定仪、垂直燃烧测定仪和锥形量热仪分析了PAPP@COF杂化阻燃剂对EP的阻燃及消烟性能的影响。结果表明,加入2%(质量分数,下同)的PAPP@COF时,EP复合材料的氧指数达到了30.0%,热释放速率峰值为911.35 k W/m^(2),烟释放速率峰值为0.394 m^(2)/s,相比于纯EP分别降低了37.36%和34.27%。PAPP@COF杂化阻燃剂对EP有优异的阻燃和消烟作用,为COF类阻燃剂的研究提供了一定的基础。

水性丙烯酸涂层改性研究进展

简单阐述了水性丙烯酸树脂的单体结构、聚合方法以及应用现状;较为系统地总结了根据不同材料改性水性丙烯酸树脂的研究进展,改性材料可归纳为纳米材料、有机硅、有机氟、聚氨酯和环氧树脂以及一些新型材料等。重点论述了改性材料对水性丙烯酸树脂进行改性的反应机理、相应的微观结构及性能提高情况。展望了水性丙烯酸涂料发展的方向。

金属有机框架基阻燃剂在阻燃领域的研究进展

简述了近几年来金属有机框架(MOFs)及其衍生物在阻燃高分子材料领域的应用,重点介绍了MOFs阻燃剂的设计及其对环氧树脂(EP)、聚苯乙烯(PS)、聚氨酯等材料阻燃性能的影响,阐述了可能存在的阻燃机理,并对MOFs阻燃剂未来的发展方向进行了展望。

环氧树脂掺杂对地质聚合物木材胶黏剂性能的影响

【目的】为了解决地质聚合物木材胶黏剂的界面相容性差等问题,采用环氧树脂为有机掺杂剂构建有机–无机交联网络的方法,研究环氧树脂掺杂对地质聚合物木材胶黏剂综合性能的影响。【方法】将地质聚合物与环氧树脂、聚醚胺、硅烷偶联剂KH550共混制备地质聚合物基木材胶黏剂,分析不同有机掺杂剂对胶黏剂性能的影响作用,结合FTIR、XPS、SEM-EDS和锥形量热仪等分析有机掺杂剂的作用机制。【结果】不同有机物掺杂均会提高地质聚合物浆体的黏度,当环氧树脂和聚醚胺的质量分数分别为4.8%和1.2%(GECS6)时,地质聚合物浆体黏度较低,有利于均匀施胶。不同物质掺杂均会不同程度地提高地质聚合物基胶合板的胶合强度,GECS6的湿态胶合强度达到较优值0.87 MPa,相比于纯地质聚合物胶黏剂提高了248%。相较于纯地质聚合物,有机掺杂地质聚合物胶合板的热释放速率和总热释放量分别下降了7.01%和17.95%,阻燃性能得到一定程度的提高。【结论】环氧树脂与硅烷偶联剂协同作用,构建了有机–无机交联网络,提高了地质聚合物胶黏剂与木材的相容性及浆体的致密性,解决了地质聚合物木材胶黏剂的界面相容性差的问题,从而增强了胶合板的胶合强度和阻燃性能。

Nickel-based metal-organic framework-derived whisker-shaped nickel phyllosilicate toward efficiently enhanced mechanical,flammable and tribological properties of epoxy nanocomposites

Metal−organic framework-derived materials have attracted significant attention in the applications of functional materials.In this work,the rod-like nickel-based metal−organic frameworks were first synthesized and subsequently employed as the hard templates and nickel sources to prepare the whisker-shaped nickel phyllosilicate using a facile hydrothermal technology.Then,the nickel phyllosilicate whiskers were evaluated to enhance the mechanical,thermal,flammable,and tribological properties of epoxy resin.The results show that adequate nickel phyllosilicate whiskers can disperse well in the matrix,improving the tensile strength and elastic modulus by 13.6%and 56.4%,respectively.Although the addition of nickel phyllosilicate whiskers could not obtain any UL-94 ratings,it enhanced the difficulty in burning the resulted epoxy resin nanocomposites and considerably enhanced thermal stabilities.Additionally,it was demonstrated that such nickel phyllosilicate whiskers preferred to improve the wear resistance instead of the antifriction feature.Moreover,the wear rate of epoxy resin nanocomposites was reduced significantly by 80%for pure epoxy resin by adding 1 phr whiskers.The as-prepared nickel phyllosilicate whiskers proved to be promising reinforcements in preparing of high-performance epoxy resin nanocomposites.

ORGANIC/INORGANIC HYBRID EPOXY NANOCOMPOSITES BASED ON OCTA(AMINOPHENYL)SILSESQUIOXANE

Octa（aminophenyl）silsesquioxane （OAPS） was used as the curing agent of diglycidyl ether of bisphenol-A （DGEBA） epoxy resin. A study on comparison of DGEBA/OAPS with DGEBA/4,4＇-diaminodiphenyl sulfone （DDS） epoxy resins was achieved. Differential scanning calorimetry was used to investigate the curing reaction and its kinetics, and the glass transition of DGEBA/OAPS. Thermogravimetric analysis was used to investigate thermal decomposition of the two kinds of epoxy resins. The reactions between amino groups and epoxy groups were investigated using Fourier transform infrared spectroscopy. Scanning electron microscopy was used to observe morphology of the two epoxy resins. The results indicated that OAPS had very good compatibility with DGEBA in molecular level, and could form a transparent DGEBA/OAPS resin. The curing reaction of the DGEBA/OAPS prepolymer could occur under low temperatures compared with DGEBA/DDS. The DGEBA/OAPS resin didn＇t exhibit glass transition, but the DGEBA/DDS did, which meant that the large cage structure of OAPS limited the motion of chains between the cross-linking points. Measurements of the contact angle indicated that the DGEBA/OAPS showed larger angles with water than the DGEBA/DDS resin. Thermogravimetric analysis indicated that the incorporation of OAPS into epoxy system resulted in low mass loss rate and high char yield, but its initial decomposition temperature seemed to be lowered.

有机硅改性环氧树脂建筑涂覆材料制备及性能研究

使用二氯甲基硅烷对E44环氧树脂进行改性制备了有机硅水性改性树脂,研究了制备工艺对涂层疏水性以及乳化过程的影响,从耐蚀性、吸水率、抗紫外老化能力以及抗Cl^(-)渗透能力方面分析了Si-E44水性树脂涂层对混凝土结构的防护效果。结果表明,溶剂(乙酸乙酯)用量为15%,改性温度为50℃,改性时间为9 h。有机硅改性水性树脂乳液最佳制备工艺为分散速度2500 r/min,乳化温度为60℃,乳化剂用量为30%。与未改性水性树脂相比,改性后的水性树脂涂层具有更强的耐酸/碱性,更低的吸水率以及更强的抗紫外线老化能力,且表现出更强的抗Cl^(-)渗透能力。

水性环氧乳液的制备与防腐性能研究

以固体环氧(E20)和聚乙二醇(PEG4000)为基础原料,采用顺丁烯二酐、甲基丙烯酸缩水甘油酯(GMA)、有机氟单体改性合成了一种环氧乳化剂,并采用相反转工艺制备了固含为50%的E20环氧乳液。研究了聚乙二醇与丙烯酸酯类共聚物的配比、GMA的用量以及有机氟单体的用量对乳液性能的影响。结果表明:在乳化剂用量为固体环氧E20的15%、乳化温度70℃、乳化剪切速率1200r/min的工艺条件下,m(聚乙二醇)∶m(丙烯酸共聚物)为7∶3、GMA占丙烯酸单体量的20%、有机氟单体占丙烯酸单体量的5%,合成的环氧乳液具有良好的稳定性和防腐性。

有机硅改性双酚A型环氧树脂研究

采用二氯二甲基硅烷 (DMS) ,或DMS与α ,ω 二氯聚二甲基硅氧烷 (DPS)的混合物来改性双酚A型环氧树脂 ,通过对固化物的冲击强度、拉伸强度、断裂伸长率和玻璃化转变温度 (Tg)的测定 ,探讨了改性方法、有机硅组成与含量等对材料性能的影响 .结果表明 ,用 5 7phr的DMS改性时 ,树脂固化物的冲击强度达2 0 2kJ m2 ,拉伸强度达 6 7 0MPa ,断裂伸长率达 11 2 9% ,Tg 达 16 8 0℃ ;分别比未改性时提高了 9 4kJ m2 ,2 1 1MPa ,5 4 %以及 32 6℃ .而用 0 7phrDMS +10phrDPS共同改性时 ,除Tg 和拉伸强度略有上升外 ,冲击强度达到了 31 6kJ m2 ,断裂伸长率达到 81 6 % ,分别比纯环氧提高了 2 0 8kJ m2 和 75 7% .

有机硅改性环氧树脂研究进展

综述了有机硅改性环氧树脂的主要方法及改性物固化机理、固化物性能研究进展。结合聚合物材料的高性能、多功能化发展方向提出有机硅改性环氧树脂研究发展趋势。

丙烯酸酯乳液的改性研究与发展状况

丙烯酸酯乳液是一大类容易制备、性能优良、价格低廉、应用广泛,且符合环保要求的聚合物。丙烯酸酯乳液的改性研究已经得到了多方面的发展。介绍了丙烯酸酯乳液的基本特性,分析了有机硅、有机氟、聚氨酯和环氧树脂改性丙烯酸酯乳液的优缺点,综述了其改性方法及研究现状,对今后丙烯酸酯乳液改性的发展提出了建议。

有机蒙脱石增强环氧树脂纳米复合材料的研究

介绍以有机蒙脱石作为增强组分的环氧树脂纳米复合材料的制备及其性能表征。结果表明 ,十六胺处理的蒙脱石层离以 1～ 10 0nm尺度分散于环氧树脂基体中 ,复合材料的物性得到提高 ,当蒙脱石含量比在 3 %时 ,马丁耐热提高 9℃ ,冲击强度提高了 12 2 % ,但进一步增加蒙脱石的含量比 。

新型环氧树脂固化剂的性能

采用亲核取代反应合成了新型含有醚酮键的芳香胺固化剂(BADK),并对其结构进行了表征。选用BADK作为固化剂,对含有联苯结构的环氧树脂和通用型环氧树脂E-51的固化条件、固化物耐热性和吸湿性进行了研究。实验结果表明:新型固化剂的使用提高了通用型环氧树脂E-51的热性能;含联苯结构的环氧树脂固化物与E-51相比,无论是热性能还是耐湿性都有很大的提高。

A-172/丙烯酸酯接枝改性水性环氧树脂的制备与性能

通过环氧树脂与丙烯酸、甲基丙烯酸甲酯、丙烯酸丁酯及有机硅氧烷单体乙烯基三(β-甲氧基乙氧基)硅烷(A-172)的接枝共聚反应,向环氧树脂中引入亲水性基团,使环氧树脂水性化,并在改性环氧树脂骨架中引入有机硅氧烷单元,改进环氧树脂的柔韧性和耐候性,制备具有良好水分散性和优异综合性能的有机硅氧烷接枝改性水性环氧树脂;在采用红外光谱分析接枝产物结构的基础上,采用透射电镜(TEM)、原子力显微镜(AFM)以及差示扫描量热仪(DSC)对A-172含量不同的接枝产物的水分散体及其涂膜进行了详细表征,并结合对涂膜机械性能的测试结果,分析了A-172用量对水性环氧乳液固化涂膜的微观结构及宏观性能的影响。结果表明,当A-172的质量分数为环氧树脂的6%时,改性环氧树脂乳液具有良好的分散性能和储存稳定性,其固化涂膜的耐水性、柔韧性和抗冲击强度等性能得到很大改善。

有机蒙脱土/环氧树脂复合改性沥青的性能

以有机蒙脱土(OMMT)和环氧树脂为改性剂,采用反应性熔融共混法制备了OMMT/环氧树脂复合改性沥青。通过X射线衍射和荧光显微镜对复合改性沥青的微观结构进行了表征,对其物理力学性能、相容性和热贮存稳定性进行了考察。结果表明,当OMMT掺加量为1%~2%时,OMMT以剥离结构存在于复合改性沥青中,体系中环氧树脂分布更加均匀;复合改性沥青中OMMT掺量为1%时,拉伸强度与环氧树脂改性沥青相比提高了25%;随着OMMT掺量的增加,复合改性沥青软化点逐渐升高,25℃针入度缓慢减小,针入度指数(PI)先增大后减小。

环氧树脂化学改性有机硅树脂的方法综述

环氧改性有机硅树脂可提高有机硅树脂的力学性能和粘接性能,还可降低有机硅树脂的固化温度。归纳总结了环氧树脂化学改性有机硅树脂的4种反应类型:1)缩聚反应;2)环氧基的开环聚合反应;3)硅氢加成反应;4)引入环氧基的反应。对该领域的近期研究成果进行了简要的综述,并展望了该领域未来的发展方向。

环氧树脂/有机硅双重改性水性聚氨酯胶粘剂的合成及性能研究

以环氧树脂E44和有机硅KH55O作为水性聚氨酯(WPU)交联改性剂,合成了环氧树脂/有机硅双重改性WPU乳液。研究了环氧树脂和有机硅加入量对改性WPU结构性能的影响,并研究了改性WPU乳液对超高分子量聚乙烯(UHMWPE)纤维的粘结性能。结果表明,随着环氧树脂和有机硅加入量的增加,乳液粒径增大,黏度下降,但过量加入后乳液储存稳定性变差;加入有机硅改性可有效提高WPU乳液对UHMWPE纤维的粘结性能,并提高WPU胶膜的耐水性,而加入环氧树脂改性可进一步改善胶膜的耐水性,环氧树脂/有机硅双重改性可提高WPU的综合性能。

有机硅改性环氧树脂制备及热稳定性

采用二苯基硅二醇与双酚A型环氧树脂(E-44)反应,制备有机硅环氧树脂及其固化物.通过正交和单因素实验研究原料物质的量比、反应温度和时间对树脂热稳定性的影响,用热机械分析仪、热失重分析仪、傅立叶变换红外光谱仪和化学滴定分析等对改性树脂进行表征.结果表明,用二苯基硅二醇改性E-44,在催化剂为二丁基二月桂酸锡,二苯基硅二醇与E-44物质的量比1∶4,反应温度110℃,反应时间2 h时,得综合热稳定性能优异的有机硅改性环氧树脂,较未改性环氧树脂,其热膨胀系数下降33.2%,内应力参数下降36.3%,初始热分解温度提高15℃,而玻璃化转变温度无明显降低,有良好的热稳定性.