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Thixotropic composite hydrogels based on agarose and inorganic hybrid gellants 被引量:2
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作者 Hongzhi Zhang Huiyan Guo +4 位作者 Yang Liu Chengxiang Shi Lun Pan Xiangwen Zhang Ji-Jun Zou 《Chinese Journal of Chemical Engineering》 SCIE EI CAS CSCD 2023年第2期240-247,共8页
Water can be used as oxidant in conjunction with metal particles to form metal-water propellant to increase the energy of propellant.For this application,water needs to be stored in form of solid and capable of becomi... Water can be used as oxidant in conjunction with metal particles to form metal-water propellant to increase the energy of propellant.For this application,water needs to be stored in form of solid and capable of becoming liquid when use.Stable and thixotropic hydrogel has good potential as water-retaining material and oxidant of metal-based propellant.In this study,we prepared organic/inorganic composite hydrogels by combining inorganic gellants hectorite and fumed silica with organic gellant agarose,respectively.The total content of the gellants can be reduced to less than 2%by adding agarose.The influence of agarose on water content,phase transition temperature,centrifugal stability and other basic physical properties of composite hydrogels were discussed.The results show that the composite hydrogels have better thixotropy and stability than pure inorganic hydrogels,and the gel-sol transformation can be realized by applying shear force or heating to the phase transition temperature.The composite hydrogels have good shear thinning ability and improved mechanical stability.Fumed silica/agarose hydrogels have better physical stability,while the thixotropy and shear thinning ability of hectorite/agarose hydrogels are better. 展开更多
关键词 Composite hydrogels organic gellant inorganic gellant Rheological properties
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Synergistic Optimization of Buried Interface by Multifunctional Organic-Inorganic Complexes for Highly Efficient Planar Perovskite Solar Cells 被引量:2
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作者 Heng Liu Zhengyu Lu +7 位作者 Weihai Zhang Hongkang Zhou Yu Xia Yueqing Shi Junwei Wang Rui Chen Haiping Xia Hsing-Lin Wang 《Nano-Micro Letters》 SCIE EI CAS CSCD 2023年第9期505-519,共15页
For the further improvement of the power conversion efficiency(PCE)and stability of perovskite solar cells(PSCs),the buried interface between the perovskite and the electron transport layer is crucial.However,it is ch... For the further improvement of the power conversion efficiency(PCE)and stability of perovskite solar cells(PSCs),the buried interface between the perovskite and the electron transport layer is crucial.However,it is challenging to effectively optimize this interface as it is buried beneath the perovskite film.Herein,we have designed and synthesized a series of multifunctional organic-inorganic(OI)complexes as buried interfacial material to promote electron extraction,as well as the crystal growth of the perovskite.The OI complex with BF4−group not only eliminates oxygen vacancies on the SnO_(2) surface but also balances energy level alignment between SnO_(2) and perovskite,providing a favorable environment for charge carrier extraction.Moreover,OI complex with amine(−NH_(2))functional group can regulate the crystallization of the perovskite film via interaction with PbI2,resulting in highly crystallized perovskite film with large grains and low defect density.Consequently,with rational molecular design,the PSCs with optimal OI complex buried interface layer which contains both BF4−and−NH_(2) functional groups yield a champion device efficiency of 23.69%.More importantly,the resulting unencapsulated device performs excellent ambient stability,maintaining over 90%of its initial efficiency after 2000 h storage,and excellent light stability of 91.5%remaining PCE in the maximum power point tracking measurement(under continuous 100 mW cm−2 light illumination in N2 atmosphere)after 500 h. 展开更多
关键词 Perovskite solar cells organic inorganic complexes Multifunctional interfacial material Buried interface layer
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4‑Terminal Inorganic Perovskite/Organic Tandem Solar Cells Offer 22%Efficiency 被引量:2
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作者 Ling Liu Hanrui Xiao +10 位作者 Ke Jin Zuo Xiao Xiaoyan Du Keyou Yan Feng Hao Qinye Bao Chenyi Yi Fangyang Liu Wentao Wang Chuantian Zuo Liming Ding 《Nano-Micro Letters》 SCIE EI CAS CSCD 2023年第2期172-181,共10页
After fast developing of single-junction perovskite solar cells and organic solar cells in the past 10 years,it is becoming harder and harder to improve their power conversion efficiencies.Tandem solar cells are recei... After fast developing of single-junction perovskite solar cells and organic solar cells in the past 10 years,it is becoming harder and harder to improve their power conversion efficiencies.Tandem solar cells are receiving more and more attention because they have much higher theoretical efficiency than single-junction solar cells.Good device performance has been achieved for perovskite/silicon and perovskite/perovskite tandem solar cells,including 2-terminal and 4-terminal structures.However,very few studies have been done about 4-terminal inorganic perovskite/organic tandem solar cells.In this work,semi-transparent inorganic perovskite solar cells and organic solar cells are used to fabricate 4-terminal inorganic perovskite/organic tandem solar cells,achieving a power conversion efficiency of 21.25%for the tandem cells with spin-coated perovskite layer.By using drop-coating instead of spin-coating to make the inorganic perovskite films,4-terminal tandem cells with an efficiency of 22.34%are made.The efficiency is higher than the reported 2-terminal and 4-terminal inorganic perovskite/organic tandem solar cells.In addition,equivalent 2-terminal tandem solar cells were fabricated by connecting the sub-cells in series.The stability of organic solar cells under continuous illumination is improved by using semi-transparent perovskite solar cells as filter. 展开更多
关键词 4-Terminal tandem solar cells inorganic perovskite solar cells organic solar cells SEMITRANSPARENT Drop-coating
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Preparation and Optical Patterning of Organic-Inorganic Hybrid Color-Filter Films Using Latent Pigments by Utilizing Photo-Acid-Generator and Microwave Irradiation
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作者 T. Ohishi S. Sugawara 《Materials Sciences and Applications》 2014年第14期1079-1090,共12页
Preparation and photo-patterning characteristics of organic-inorganic hybrid thin film containing latent pigment by using photo-acid-generator (PAG) and microwave irradiation have been investigated. The acrylic thin f... Preparation and photo-patterning characteristics of organic-inorganic hybrid thin film containing latent pigment by using photo-acid-generator (PAG) and microwave irradiation have been investigated. The acrylic thin film modified with methoxysilane containing PAG was formed on a glass substrate and irradiated with ultraviolet rays to promote sol-gel reaction by catalytic action of acid which was generated from PAG. And then the film was hardened with microwave irradiation, yielding organic-inorganic hybrid polymer film having hardness, highly transparency and strong adhesion with a glass substrate. Since this reaction only occurred in the optically (UV) irradiated regions, by exploiting the difference between the adhesivenesses of these regions photo-irradiated through photomask with a glass substrate, it was possible to form a patterned film with pitch of 100 to 50 μm by a simple lift-off method. A pigment-containing film using latent pigments (with subtractive three primary colors of coloring materials) and a patterned film were prepared, and it was possible to make these films multi-colored by varying the mixing ratio of the pigments. This multi-colored film-preparation method is effective for simply and efficiently forming a color-filter film by applying optical and microwave irradiation. 展开更多
关键词 organic-inorganic Hybrid Film Color Filter Photo-Patterning LATENT pigment Photo-Acid-Generator Microwave Lift-Off Method
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In Situ Formed Tribofilms as Efficient Organic/Inorganic Hybrid Interlayers for Stabilizing Lithium Metal Anodes
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作者 Shaozhen Huang Kecheng Long +6 位作者 Yuejiao Chen Tuoya Naren Piao Qing Xiaobo Ji Weifeng Wei Zhibin Wu Libao Chen 《Nano-Micro Letters》 SCIE EI CAS CSCD 2023年第12期320-333,共14页
The practical application of Li metal anodes(LMAs)is limited by uncontrolled dendrite growth and side reactions.Herein,we propose a new friction-induced strategy to produce high-performance thin Li anode(Li@CFO).By vi... The practical application of Li metal anodes(LMAs)is limited by uncontrolled dendrite growth and side reactions.Herein,we propose a new friction-induced strategy to produce high-performance thin Li anode(Li@CFO).By virtue of the in situ friction reaction between fluoropolymer grease and Li strips during rolling,a robust organic/inorganic hybrid interlayer(lithiophilic LiF/LiC_(6)framework hybridized-CF_(2)-O-CF_(2)-chains)was formed atop Li metal.The derived interface contributes to reversible Li plating/stripping behaviors by mitigating side reactions and decreasing the solvation degree at the interface.The Li@CFO||Li@CFO symmetrical cell exhibits a remarkable lifespan for 5,600 h(1.0 mA cm^(-2)and 1.0 mAh cm^(-2))and 1,350 cycles even at a harsh condition(18.0 mA cm^(-2)and 3.0 mAh cm^(-2)).When paired with high-loading LiFePO4 cathodes,the full cell lasts over 450 cycles at 1C with a high-capacity retention of 99.9%.This work provides a new friction-induced strategy for producing high-performance thin LMAs. 展开更多
关键词 Lithium metal anode organic/inorganic hybrid interlayers High current density Fluoropolymer grease Local desolvation environment
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Effect of Bio-Based Organic‒Inorganic Hybrid Hydrogels on Fire Prevention of Spontaneous Combustion of Coals
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作者 Hu Shi Wei Cai +2 位作者 Xin Wang Lei Song Yuan Hu 《Journal of Renewable Materials》 EI 2023年第12期3991-4006,共16页
To solve the fire accidents caused by coal combustion,this work prepared four hybrid hydrogel materials using bio-based polymers,flame retardants,and inorganic materials.Compared to pure water and 3.5 wt%MgCl_(2)solut... To solve the fire accidents caused by coal combustion,this work prepared four hybrid hydrogel materials using bio-based polymers,flame retardants,and inorganic materials.Compared to pure water and 3.5 wt%MgCl_(2)solution,the as-prepared hydrogel presents good fire prevention performance.In addition,it is found that CO and CO_(2)are not produced by coal when the pyrolysis temperature is lower than 200℃.During low-temperature pyrolysis,CO is more likely to be produced than CO_(2),indicating inadequate pyrolysis behavior.At the same time,the addition of fire-preventing hydrogel can not only decrease the maximum CO_(2)concentration before the critical temperature but also prolong the corresponding time.In addition,based on the cone calorimeter test,the inhibition effects of pure water,magnesium chloride solution,and four hybrid hydrogels on heat release behavior are evaluated.It is demonstrated that different dosages of different hydrogels affected the fire prevention effect.Phosphorous-modified cellulose/silica and carrageenan/DMMP/vermiculite composite hydrogels have the weakest fire prevention effect at 20 g,which is weaker than that of water.However,the fire prevention effect of carrageenan/DMMP/vermiculite composite hydrogels exceeded that of water at 40 and 60 g.Additionally,the fire prevention effect of the sodium alginate/sepiolite/ammonium polyphosphate composite hydrogel is most significant in common tests,attributed to the intumescent flame retardant system. 展开更多
关键词 organicinorganic hybrid hydrogels fire prevention coal combustion
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Effects of Integrated Organic and Inorganic Fertilizers on Yield and Growth Parameters of Rice Varieties 被引量:13
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作者 Kyi MOE Seinn Moh MOH +2 位作者 Aung Zaw HTWE Yoshinori KAJIHARA Takeo YAMAKAWA 《Rice science》 SCIE CSCD 2019年第5期309-318,共10页
We investigated the effects of integrated organic and inorganic fertilizers on the growth and yield of indica rice variety Manawthukha and japonica rice variety Genkitsukushi.In a split-plot design,the two rice variet... We investigated the effects of integrated organic and inorganic fertilizers on the growth and yield of indica rice variety Manawthukha and japonica rice variety Genkitsukushi.In a split-plot design,the two rice varieties were assigned as main plot factors,and the integrated treatments were the subplot factors,including no-N fertilizer(N0),50%chemical fertilizer(CF)(CF50),100%CF(CF100),50%CF+50%poultry manure(PM)(CF50PM50),50%CF+50%cow manure(CM)(CF50CM50),and 50%CF+50%compost(CP)(CF50CP50).CF100 was equivalent to N at 85 kg/hm2.Manure was applied based on the estimated mineralizable nitrogen(EMN)level,which is dependent on total N(%)of each manure type.Manawthukha rice plants were taller with higher tiller number and dry matter content.However,higher soil-plant analysis development(SPAD)values were measured in Genkitsukushi throughout the crop growth period,resulting in higher seed-setting rate(%)and greater yield.At the same N level,CF50PM50 application in both rice varieties resulted in higher SPAD values,plant height and tiller number than CF100.CF50PM50 containing total N more than 4%supplied synchronized N for the demands of the rice plants,resulting in maximum dry matter,yield and yield components.CF50CM50 and CF50CP50 treatments containing total N less than 4%resulted in lower yields which were similar to CF100.These results indicated that integrating organic and inorganic fertilizers enhanced growth parameters and yields of Manawthukha and Genkitsukushi,while reducing the dose of chemical fertilizer. 展开更多
关键词 estimated mineralizable nitrogen GROWTH parameter inorganic FERTILIZER organic MANURE RICE YIELD
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Effects of temperature and organic and inorganic nutrients on the growth of Chattonella marina (Raphidophyceae)from the Daya Bay,South China Sea 被引量:10
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作者 WANG Zhaohui YUAN Meiling +1 位作者 LIANG Yu LU Sollghui 《Acta Oceanologica Sinica》 SCIE CAS CSCD 2011年第3期124-131,共8页
The effects of temperature and different forms of nutrients on Chattonella marina growth have been investigated in strains isolated from the Daya Bay, the South China Sea. The strain of C. marina preferred high temper... The effects of temperature and different forms of nutrients on Chattonella marina growth have been investigated in strains isolated from the Daya Bay, the South China Sea. The strain of C. marina preferred high temperatures, with an optimal temperature of 25℃, and 18℃ was the minimum for its survival. Higher cell number and growth rate were obtained in high nitrogen and phosphorus concentrations (500 μg/L, 74μg/L) than under nutrient limitation. Nitrogen influenced the growth most, as the specific growth rate and maximum cell density were lower in nitrogen- limited cultures than noted under phosphorus limitation or under limitation from both. C. marina was capable of using many kinds of organic nitrogen sources including L-serine (L-Ser), glycine (Gly), alanine (Ala), L-threonine (L-Thr), glutamic acid (Glu) and urea, but could not utilize uric acid. Various forms of organic phosphorus compound such as glucose-6-phosphate (G6P), sodium glycerophosphate (GYP), adenosine triphosphate (ATP), adenosine monophosphate (AMP), cyti- dine monophosphate (CMP), guanosine monophosphate (GMP), uridine monophosphate (UMP), 4-nitrophenylphosphate (NPP) and triethyl phosphate (TEP) supported the growth as well. Algal cells had the ability to sustain growth under nitrogenand/or phosphorus-free conditions particularly under phosphorus depleted condition. These results led to the hypothesis that high loading of nitrogen has played an important role in frequent C. marina blooms in the past decade, and its capability for utilization of diverse forms of organic nutrients and growth in low nutrient conditions make this species a likely recurrent dominant in the Daya Bay phytoplankton assemblages, visible as more frequent blooms. 展开更多
关键词 Chattonella marina GROWTH inorganic and organic nutrients SALINITY TEMPERATURE
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An Explosive Organic/Inorganic Hybrid: Synthesis and Thermal Property of Octa(2,4-dinitrophenyl)silsesquioxane 被引量:6
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作者 CHENHong-Ji 《Chemical Research in Chinese Universities》 SCIE CAS CSCD 2004年第1期42-45,共4页
Octaphenylsilsesquioxane(OPhS) was prepared by a modifying method and a new core-shell nanocomposite, octa(2,4-dinitrophenyl)silsesquioxane, [(R_2PhSiO_ 1.5)_8, R=—NO_2, ODNPhS], was synthesized by nitration of OPh... Octaphenylsilsesquioxane(OPhS) was prepared by a modifying method and a new core-shell nanocomposite, octa(2,4-dinitrophenyl)silsesquioxane, [(R_2PhSiO_ 1.5)_8, R=—NO_2, ODNPhS], was synthesized by nitration of OPhS in a mixed acid solution of nitric and sulfuric acids at about 60 ℃. Their molecular structures were determined by DRIFTS, 1H NMR, 13C NMR spectra analysis. The thermal analysis shows that ODNPhS is an explosive that detonates at about 420 ℃. 展开更多
关键词 Core-shell nanocomposite organic/inorganic hybrid Octa(2 4-dinitrophenyl)silsquioxane Thermal property
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Combined Application of Organic and Inorganic Fertilizers on Black Soil Fertility and Maize Yield 被引量:5
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作者 ZHAO Jinwei ZHOU Lianren 《Journal of Northeast Agricultural University(English Edition)》 CAS 2011年第2期24-29,共6页
By two years (2007-2008) located fertilizer experiment, the effect of long-term combined application of organic and inorganic fertilizers on black soil fertility and crop yield was investigated in Shuangcheng City, ... By two years (2007-2008) located fertilizer experiment, the effect of long-term combined application of organic and inorganic fertilizers on black soil fertility and crop yield was investigated in Shuangcheng City, Heilongjiang Province. The results showed that the combined application of organic and inorganic fertilizers could increase the organinc matter, alkaline nitrogen, available phosphorus and available potassium. At the same time, the increasing application of organic fertilizer could reduce the soil bulk density and improve the field moisture capacity. Field moisture capacity and organic matter of the combined application of high quantities of organic manure and inorganic fertilizers AtB5 treatment increased the fhstest, organic matter increased by 3.33 g. kg and field moisture capacity increased by 11.25% than the beginning of the experiment. Under the same fertilization, the combined application of organic and inorganic fertilizers' increasing production range was higher than the single chemical fertilizers' which was from 0.8% to 9.4%. The results showed that the combined application of organic and inorganic fertilizers could increase the nutrient contents of soil and also was the highest productivity contribution to black soil fertility. It was the best fertilization structure of increasing productivity level and improving the soil fertility. 展开更多
关键词 black soil combined application of organic and inorganic fertilizers soil fertility maize yield
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Preparation and Conducting Behavior of Amphibious Organic/Inorganic Hybrid Proton Exchange Membranes Based on Benzyltetrazole 被引量:3
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作者 QIAO Li-gen SHI Wen-fang 《Chemical Research in Chinese Universities》 SCIE CAS CSCD 2012年第2期345-352,共8页
A series of novel amphibious organic/inorganic hybrid proton exchange membranes with H3PO4 doped which could be used under both wet and dry conditions was prepared through a sol-gel process based on acrylated triethox... A series of novel amphibious organic/inorganic hybrid proton exchange membranes with H3PO4 doped which could be used under both wet and dry conditions was prepared through a sol-gel process based on acrylated triethoxysilane(A-TES) and benzyltetrazole-modified triethoxysilane(BT-TES).The dual-curing approach including UV-curing and thermal curing was used to obtain the crosslinked membranes.Polyethylene glycol(400) diacrylate(PEGDA) was used as an oligomer to form the polymeric matrix.The molecular structures of precursors were characterized by 1 H,13 C and 29 Si NMR spectra.The thermogravimetric analysis(TGA) results show that the membranes exhibit acceptable thermal stability for their application at above 200 oC.The differential scanning calorimeter(DSC) determination indicates that the crosslinked membranes with the mass ratios of below 1.6 of BT-TES to A-TES and the same mass of H3PO4 doped as that of A-TES possess the-T g s,and the lowest T g(-28.9 ℃) exists for the membrane with double mass of H3PO4 doped as well.The high proton conductivity in a range of 9.4―17.3 mS/cm with the corresponding water uptake of 19.1%―32.8% of the membranes was detected at 90 oC under wet conditions.Meanwhile,the proton conductivity in a dry environment for the membrane with a mass ratio of 2.4 of BT-TES to A-TES and double H3PO4 loading increases from 4.89×10-2 mS/cm at 30 ℃ to 25.7 mS/cm at 140 ℃.The excellent proton transport ability under both hydrous and anhydrous conditions demonstrates a potential application in the polymer electrolyte membrane fuel cells. 展开更多
关键词 AMPHIBIOUS Benzyltetrazole organic/inorganic hybrid membrane Phosphorus acid Proton conductivity
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Development of multiple soft computing models for estimating organic and inorganic constituents in coal 被引量:7
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作者 M.Onifade A.I.Lawal +4 位作者 J.Abdulsalam B.Genc S.Bada K.O.Said A.R.Gbadamosi 《International Journal of Mining Science and Technology》 SCIE EI CAS CSCD 2021年第3期483-494,共12页
The distribution of the various organic and inorganic constituents and their influences on the combustion of coal has been comprehensively studied.However,the combustion characteristics of pulverized coal depend not o... The distribution of the various organic and inorganic constituents and their influences on the combustion of coal has been comprehensively studied.However,the combustion characteristics of pulverized coal depend not only on rank but also on the composition,distribution,and combination of the macerals.Unlike the proximate and ultimate analyses,determining the macerals in coal involves the use of sophisticated microscopic instrumentation and expertise.In this study,an attempt was made to predict the amount of macerals(vitrinite,inertinite,and liptinite)and total mineral matter from the Witbank Coalfields samples using the multiple input single output white-box artificial neural network(MISOWB-ANN),gene expression programming(GEP),multiple linear regression(MLR),and multiple nonlinear regression(MNLR).The predictive models obtained from the multiple soft computing models adopted are contrasted with one another using difference,efficiency,and composite statistical indicators to examine the appropriateness of the models.The MISOWB-ANN provides a more reliable predictive model than the other three models with the lowest difference and highest efficiency and composite statistical indicators. 展开更多
关键词 Multiple soft computing models COAL organic and inorganic constituents
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Difference in Number of Electrons in Inner Shells of Charged or Uncharged Elements in Organic and Inorganic Chemistry: Compatibility with the Even-Odd Rule 被引量:4
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作者 Geoffroy Auvert 《Open Journal of Physical Chemistry》 2017年第2期72-88,共17页
The recently introduced even-odd rule has been shown to successfully represent chemical structures of ions and molecules. While comparing available drawings in the scientific literature with the list of compounds pred... The recently introduced even-odd rule has been shown to successfully represent chemical structures of ions and molecules. While comparing available drawings in the scientific literature with the list of compounds predicted by the even-odd rule, it became however obvious that existing compounds are fewer than expected. Several predicted compounds involving many covalent bonds have apparently never been experimentally observed. Neutral oxygen for instance is expected to have 6 valence electrons, whereas oxygen can only build a maximum of two bonds, as in water. This specificity is observed for elements in the top-right corner of the periodic table. For compounds to contain only single covalent bonds, and thus follow the even-odd rule, further explanations are necessary. The present paper proposes that those specific elements experience a transfer of electrons from the valence shell into the inner shell, making them unavailable for further bonding. These elements will be described as organic, hereby providing a clear and hopefully unifying definition of the term. In opposition, inorganic elements have a constant inner shell no matter their electrical state or the number of bonds they maintain. More than 70 compounds involving 11 elements of the main group are studied, revealing a progression from fully inorganic elements at the left of the periodic table to fully organic elements. The transition between inorganic or organic elements is made of few elements that take an organic form when negatively charged;they are labelled semi-organic. The article concludes that the fully organic elements of the main group are Oxygen and Fluorine, whereas semi-organic elements are more numerous: C, N, S, Cl, Se, Br and I. Thus, the even-odd rule becomes fully compatible with scientific knowledge of compounds in liquid or gaseous phase. 展开更多
关键词 organic inorganic Element Chemistry Even-Odd RULE Inner Shell BOND Single BOND Charge State
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A Specific Periodic Table for Chemistry of Organic, Semi-Organic and Inorganic Elements: Compatibility with the Even-Odd Rule,the Number of Electrons and the Isoelectronicity Rule 被引量:3
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作者 Geoffroy Auvert 《Open Journal of Physical Chemistry》 2018年第2期57-66,共10页
Following the introduction of the new even-odd and isoelectronic rules and definitions affecting the understanding of electronic structure and bonds, the author has thought necessary to summarize understandings in the... Following the introduction of the new even-odd and isoelectronic rules and definitions affecting the understanding of electronic structure and bonds, the author has thought necessary to summarize understandings in the form of a table. The classical periodic table, a simple tool used by generations of physicists, is here extended to become a useful tool aimed specifically at chemists. In chemistry, position and number of covalent bonds of each atom are needed, as well as the exact location of charges. The table gives the number of possible bonds for each element and reveals how it is affected by charges. Additionally, the specific table indicates for each atom its isoelectronic elements and highlights the distinction between organic and inorganic elements. Discussion is led on the first two rows of the table by successfully comparing its statement with more than 50 well-known liquid and gaseous compounds. 展开更多
关键词 CHEMISTRY Periodic Table organic inorganic Semi-organic Even-Odd RULE Inner Shell
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Effect of Organic Ligands on Biological Availability of Inorganic Phosphorus in Soils 被引量:43
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作者 FENGKe LUHai-Ming SHENGHai-Jun WANGXiao-Li MAOJian 《Pedosphere》 SCIE CAS CSCD 2004年第1期85-92,共8页
Citrate, oxalate, tartrate and malate were added into soils during the growth period of ryegrass to study the effect of different organic ligands on the release various inorganic P (Pi) fractions in a yellow-brown soi... Citrate, oxalate, tartrate and malate were added into soils during the growth period of ryegrass to study the effect of different organic ligands on the release various inorganic P (Pi) fractions in a yellow-brown soil and a paddy soil. The results showed that oxalate was most effective in promoting the release of total Pi in the yellow-brown soil and tartrate in the paddy soil. The dominant Pi fractions released from the yellow-brown soil were calcium phosphate (Ca-P) and aluminum phosphate (Al-P) and those from the paddy soil were iron phosphate (Fe-P) and reductant soluble phosphate (O-P) mobilized by tartrate. Phosphorous-mobilizing capability of organic acids in the yellow-brown soil revealed the following order: oxalate > citrate > malate > tartrate. In the paddy soil, the order was tartrate > citrate ≈ oxalate > malate. It was demonstrated that organic ligands were different in their capabilities of mobilizing Pi and the same organic ligand showed also a discrepancy in mobilizing P in different soils. Although the addition of organic ligands into soils could increase the amount of P taken up by ryegrass, the more uptake of P, however, was not only due to the more release of Pi, but also partly from organic P. In many cases, organic ligands promoted the release of the total of the total Pi, while different fractions showed different trends: some increased and others decreased. 展开更多
关键词 生物学 柠檬酸盐 草酸盐 酒石酸盐 苹果酸盐 黑麦草 配合基 无机物
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DISTRIBUTIONS OF TOTAL, INORGANIC AND ORGANIC PHOSPHORUS IN THE SEDIMENTS NEAR THE HUANGHE RIVER ESTUARY 被引量:1
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作者 林荣根 吴景阳 《Chinese Journal of Oceanology and Limnology》 SCIE CAS CSCD 1992年第3期204-214,共11页
For some hundred surface sediment samples from five cores taken in two cruises near the Huanghe River Estuary, total phosphorus (TP (.inorganic phosphorus (IP (and organic phosphorus (OP)were determined.On the average... For some hundred surface sediment samples from five cores taken in two cruises near the Huanghe River Estuary, total phosphorus (TP (.inorganic phosphorus (IP (and organic phosphorus (OP)were determined.On the average, 527×10-6, 455×10~6 and 72×10-6 were found for TP,IP and OP for the surface sediments taken in the two cruises. The distribution of OP and IP was controlled by the sample particle size: OP content increased with the decreasing of the sample particle size, while the maximal value of IP was found in the silt fraction due to the existence of apatite in our samples. Vertical distributions reflected well the channel change of the Huanghe River. Results from the multiple regressions between the three forms of phosphorus and the percentages of different particle size agreed well with the analytical data. 展开更多
关键词 distribution TOTAL phosphorus- inorganic PHOSPHORUS organic PHOSPHORUS SEDIMENTS
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Organic/inorganic nanocomposite polymer electrolyte 被引量:1
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作者 Li Qi Shao Jun Dong 《Chinese Chemical Letters》 SCIE CAS CSCD 2007年第2期185-188,共4页
The organic/inorganic nanocomposites polymer electrolytes were designed and synthesized. The organic/inorganic nanocomposites membrane materials and their lithium salt complexes have been found thermally stable below ... The organic/inorganic nanocomposites polymer electrolytes were designed and synthesized. The organic/inorganic nanocomposites membrane materials and their lithium salt complexes have been found thermally stable below 200 °C. The conductivity of the organic/inorganic nanocomposites polymer electrolytes prepared at room temperature was at magnitude range of 10(?6) S/cm. 展开更多
关键词 organic/inorganic nanocomposites Polymer electrolyte Polymer lithium battery CONDUCTIVITY Characterization Thermal stability
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Pitfalls of acid leaching method for determining organic and inorganic carbon contents in marine sediments 被引量:2
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作者 Chen Ling Zhifei Liu +3 位作者 Jingwen Zhang Yulong Zhao Yanwei Zhang Adrian RFernandez 《Acta Oceanologica Sinica》 SCIE CAS CSCD 2020年第8期96-102,共7页
Organic and inorganic carbon contents of marine sediments are important to reconstruct marine productivity,global carbon cycle, and climate change. A proper method to separate and determine organic and inorganic carbo... Organic and inorganic carbon contents of marine sediments are important to reconstruct marine productivity,global carbon cycle, and climate change. A proper method to separate and determine organic and inorganic carbons is thus of great necessity. Although the best method is still disputable, the acid leaching method is widely used in many laboratories because of its ease-of-use and high accuracy. The results of the elemental analysis of sediment trap samples reveal that organic and inorganic carbon contents cannot be obtained using the acid leaching method, causing an infinitely amplified error when the carbon content of the decarbonated sample is 12%±1% according to a mathematical derivation. Acid fumigation and gasometric methods are used for comparison, which indicates that other methods can avoid this problem in organic carbon analysis. For the first time, this study uncovers the pitfalls of the acid leaching method, which limits the implication in practical laboratory measurement, and recommends alternative solutions of organic/inorganic carbon determination in marine sediments. 展开更多
关键词 marine sediments organic carbon inorganic carbon acid leaching method LIMITATION
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Relative effectiveness of organic and inorganic nutrient sources in improving yield, seed quality and nutrient uptake of canola 被引量:2
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作者 S. S. Malhi C. L. Vera S. A. Brandt 《Agricultural Sciences》 2013年第12期1-18,共18页
The proper use of organic and inorganic nutrient sources is important to sustain high levels of crop production, while maintaining or enhancing soil and environmental quality. A 4-year (2009 to 2012) field experiment ... The proper use of organic and inorganic nutrient sources is important to sustain high levels of crop production, while maintaining or enhancing soil and environmental quality. A 4-year (2009 to 2012) field experiment was established in spring 2009 on a Gray Luvisol (Typic Haplocryalf) loam soil at Star City, Saskatchewan, Canada, to determine the effectiveness of organic/biological (compost, wood ash [fine and granular], alfalfa pellets, distiller grain, thin stillage, glycerol, fish food additive, Penicillium bilaiae), inorganic/mineral (granular-gypsum, rapid release elemental S [RRES], rock phosphate [granular and fine]) and chemical/synthetic (granular-ammonium nitrate, triple super phosphate and potassium sulphate) nutrient sources (amendments/chemicals) in improving seed yield, straw yield, seed quality and nutrient uptake (N, P, K and S) in seed + straw of canola. Combined application of N, P and S chemical fertilizers (NPS) produced considerably greater seed yield, straw yield and nutrient uptake of canola compared to the unamended control in all four years. In treatments receiving only organic amendments, thin stillage produced the greatest seed yield, straw yield and nutrient uptake in all years, and it was similar to the NPS balanced fertilizer treatment, while fish food additive and distiller grain dry of wheat in 2009, 2011 and 2012, distiller grain dry of corn in 2009 and 2012, and compost and alfalfa pellets in 2011 and 2012 produced significantly greater seed yield, straw yield and nutrient uptake, when compared to the control. In treatments where chemical fertilizers were also applied, in addition to organic amendments, ap- plication of N fertilizer increased seed yield, straw yield and nutrient uptake substantially when combined with wood ash fine in 2009, 2010, 2011 and 2012, wood ash granular in 2009, 2011 and 2012, and glycerol in 2009 and 2012 (moderate increase in 2012). In the chemical fertilizer treatments, there was a reduction in seed yield, straw yield and nutrient uptake of canola when only N fertilizer was applied compared to the control (significant in 2010 and 2011). Application of P along with N (NP) increased seed yield, straw yield and nutrient uptake of canola compared to N alone treatment, but was less than the NPS treatment in all years. Application of S along with N (NS) increased seed yield, straw yield and nutrient uptake of canola further compared to the NP treatment, but it was still lower than the NPS treatment in 2010 and 2011. In treatments receiving inorganic/mineral amendments in addition to chemical fertilizers, application of N + P fertilizers substantially increased seed yield, straw yield and nutrient uptake in treatments receiving gypsum and RRES in 2009, 2010, 2011 and 2012. This suggests the potential of gypsum and RRES in preventing S deficiency in organic crops when grown on S-deficient soils, provided other nutrients are not limiting in the soil for crop growth. Seed yield, straw yield and nutrient uptake with application of N and S fertilizers in combination with rock phosphate and/or Penicillium bilaiae were similar to N + S treatment in most cases, except in 2011 when application of finely-ground or powder rock phosphate in a combination with N + S produced significantly greater yield and nutrient uptake than N + S with granular rock phosphate. This suggests little contribution of rock phosphate and/or Penicillium bilaiae in improving yield and nutrient uptake of canola, and improves the performance of fine rock phosphate only evident in the third growing season in 2011, after three consecutive applications, but not in 2012. In conclusion, some organic amendments showed potential for improvement in organic crop production, and in some other cases highest yield and nutrient uptake were 展开更多
关键词 inorganic NUTRIENT Sources NUTRIENT Uptake organic Seed Quality YIELD
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Combined Effect of Organic Manures and Inorganic Fertilizers on the Growth and Yield of Hybrid Rice (Palethwe-1) 被引量:1
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作者 Kyi Moe Kumudra Win Mg +1 位作者 Kyaw Kyaw Win Takeo Yamakawa 《American Journal of Plant Sciences》 2017年第5期1022-1042,共21页
We investigated the effect of combining organic and inorganic fertilizers on the growth and yield of hybrid rice (Palethwe-1) in the dry and wet seasons of 2015. Four quantities of inorganic fertilizer were used in th... We investigated the effect of combining organic and inorganic fertilizers on the growth and yield of hybrid rice (Palethwe-1) in the dry and wet seasons of 2015. Four quantities of inorganic fertilizer were used in the main plot [0%, 50%, 75%, and 100% nitrogen, phosphorus, and potassium (NPK)] based on the recommended amounts of 150 kg N ha-1, 70 kg P2O5 ha-1, and 120 kg K2O ha-1, while different organic manures were applied to subplots [no organic manure (O0), cow manure (Oc), poultry manure (Op), and vermicompost (Ov);all at 5 t·ha-1] as part of a split-plot experimental design with three replicates. In both seasons, significant differences in growth parameters including number of tillers hill-1, soil-plant analysis development (SPAD) values, total dry matter, yield, and yield components were observed in plants supplied with different inorganic fertilizers. The 100% NPK (I100) fertilizer produced the maximum yield but similar yields were achieved in plots supplied with 50% NPK (I50) and 75% NPK (I75). Significant differences in growth and yield parameters were also found in crops supplied with organic manures. Although identical quantities were supplied, Op produced the best growth parameters in both seasons including total dry matter, yield, and yield components. Oc also performed well. Combining inorganic and organic fertilizers demonstrated that I50 together with Op (5 t·ha-1) provided similar growth, total dry matter, and yield parameters to I100 in both seasons. Oc (5 t·ha-1) plus I75 also achieved similar yields to I100. This study demonstrates that the combined application of inorganic fertilizers and organic manures has the potential to reduce chemical fertilizer usage without decreasing the yield of hybrid rice, and can enhance the growth, yield, and yield components of Palethwe-1. 展开更多
关键词 Growth Parameter inorganic Fertilizers organic MANURES Rice YIELD
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