Impact and mechanism of bisphosphonate depressant 1-hydroxypropane-1,1-diphosphonic acid on flotation decalcification of dolomite-rich magnesite ore

Given the depletion of high-quality magnesite deposits and the rising demand for high-end magnesium materials,the separation and utilization of high-calcium magnesite ores have become essential.However,the similar surface properties and solubility of semi-soluble salt-type minerals,pose significant challenges for the utilization of dolomite-rich magnesite resources.In this study,1-hydroxypropane-1,1-di phosphonic acid(HPDP)was identified for the first time as a high-performance depressant for dolomite.Various tests,including contact angle measurements,ζ potential analysis,X-ray photoelectron spectroscopy,and atomic force microscopy,were conducted to elucidate the interfacial interaction mechanisms of HPDP on the surfaces of the two minerals at different scales.Additionally,molecular modeling calculations were used to detail the spatial matching relationship between HPDP and the crystal faces of the two minerals.It was emphasized that HPDP specifically adsorbed onto the dolomite surface by forming calcium phosphonate,ensuring that the dolomite surface remained hydrophilic and sank.Moreover,it was found that the adsorption strength of HPDP on the mineral surfaces depended on the activity of the metal sites and their spatial distribution.These findings provide a theoretical foundation for the molecular design of flotation reagents for high-calcium magnesite ores.

Role of tannin pretreatment in flotation separation of magnesite and dolomite

Flotation separation of magnesite and its calcium-containing carbonate minerals is a difficult problem.Recently,new regulat-ors have been proposed for magnesite flotation decalcification,although traditional regulators such as tannin,water glass,sodium carbon-ate,and sodium hexametaphosphate are more widely used in industry.However,they are rarely used as the main regulators in research because they perform poorly in magnesite and dolomite single-mineral flotation tests.Inspired by the limonite presedimentation method and the addition of a regulator to magnesite slurry mixing,we used a tannin pretreatment method for separating magnesite and dolomite.Microflotation experiments confirmed that the tannin pretreatment method selectively and largely reduces the flotation recovery rate of dolomite without affecting the flotation recovery rate of magnesite.Moreover,the contact angles of the tannin-pretreated magnesite and dolomite increased and decreased,respectively,in the presence of NaOl.Zeta potential and Fourier transform infrared analyses showed that the tannin pretreatment method efficiently hinders NaOl adsorption on the dolomite surface but does not affect NaOl adsorption on the magnesite surface.X-ray photoelectron spectroscopy and density functional theory calculations confirmed that tannin interacts more strongly with dolomite than with magnesite.

Characteristics and main controlling factors of intra-platform shoal thin-layer dolomite reservoirs:A case study of Middle Permian Qixia Formation in Gaoshiti-Moxi area of Sichuan Basin,SW China

Based on the study of the distribution of intra-platform shoals and the characteristics of dolomite reservoirs in the Middle Permian Qixia Formation in the Gaoshiti–Moxi area of the Sichuan Basin,SW China,the controlling factors of reservoir development were analyzed,and the formation model of“intra-platform shoal thin-layer dolomite reservoir”was established.The Qixia Formation is a regressive cycle from bottom to top,in which the first member(Qi1 Member)develops low-energy open sea microfacies,and the second member(Qi2 Member)evolves into intra-platform shoal and inter-shoal sea with decreases in sea level.The intra-platform shoal is mainly distributed near the top of two secondary shallowing cycles of the Qi2 Member.The most important reservoir rock of the Qixia Formation is thin-layer fractured-vuggy dolomite,followed by vuggy dolomite.The semi-filled saddle dolomite is common in fracture-vug,and intercrystalline pores and residual dissolution pores combined with fractures to form the effective pore-fracture network.Based on the coupling analysis of sedimentary and diagenesis characteristics,the reservoir formation model of“pre-depositional micro-paleogeomorphology controlling shoal,sedimentary shoal controlling dolomite,penecontemporaneous dolomite benefiting preservation of pores,and late hydrothermal action effectively improving reservoir quality”was systematically established.The“first-order high zone”micro-paleogeomorphology before the deposition of the Qixia Formation controlled the development of large area of intra-platform shoals in Gaoshiti area during the deposition of the Qi2 Member.Shoal facies is the basic condition of early dolomitization,and the distribution range of intra-platform shoal and dolomite reservoir is highly consistent.The grain limestone of shoal facies is transformed by two stages of dolomitization.The penecontemporaneous dolomitization is conducive to the preservation of primary pores and secondary dissolved pores.The burial hydrothermal fluid enters the early dolomite body along the fractures associated with the Emeishan basalt event,makes it recrystallized into medium–coarse crystal dolomite.With the intercrystalline pores and the residual vugs after the hydrothermal dissolution along the fractures,the high-quality intra-platform shoal-type thin-layer dolomite reservoirs are formed.The establishment of this reservoir formation model can provide important theoretical support for the sustainable development of Permian gas reservoirs in the Sichuan Basin.

Facies-controlled prediction of dolomite reservoirs in the Middle Permian Qixia Formation in Shuangyushi,northwestern Sichuan Basin

The Middle Permian Qixia Formation in the Shuangyushi area,northwestern Sichuan Basin,develops shoal-facies dolomite reservoirs.To pinpoint promising reservoirs in the Qixia Formation,deep thin shoal-facies dolomite reservoirs were predicted using the techniques of pre-stack Kirchhoff-Q compensation for absorption,inverse Q filtering,low-to high-frequency compensation,forward modeling,and facies-controlled seismic meme inversion.The results are obtained in six aspects.First,the dolomite reservoirs mainly exist in the middle and lower parts of the second member of Qixia Formation(Qi2 Member),which coincide with the zones shoal cores are developed.Second,the forward modeling shows that the trough energy at the top and bottom of shoal core increases with increasing shoal-core thickness,and weak peak reflections are associated in the middle of shoal core.Third,five types of seismic waveform are identified through waveform analysis of seismic facies.Type-Ⅰ and Type-Ⅱ waveforms correspond to promising facies(shoal core microfacies).Fourth,vertically,two packages of thin dolomite reservoirs turn up in the sedimentary cycle of intraplatform shoal in the Qi2 Member,and the lower package is superior to the upper package in dolomite thickness,scale and lateral connectivity.Fifth,in plane,significantly controlled by sedimentary facies,dolomite reservoirs laterally distribute with consistent thickness in shoal cores at topographical highs and extend toward the break.Sixth,the promising prospects are the zones with thick dolomite reservoirs and superimposition of horstegraben structural traps.

Classification and rating of disintegrated dolomite strata for slope stability analysis

Although disintegrated dolomite,widely distributed across the globe,has conventionally been a focus of research in underground engineering,the issue of slope stability issues in disintegrated dolomite strata is gaining increasing prominence.This is primarily due to their unique properties,including low strength and loose structure.Current methods for evaluating slope stability,such as basic quality(BQ)and slope stability probability classification(SSPC),do not adequately account for the poor integrity and structural fragmentation characteristic of disintegrated dolomite.To address this challenge,an analysis of the applicability of the limit equilibrium method(LEM),BQ,and SSPC methods was conducted on eight disintegrated dolomite slopes located in Baoshan,Southwest China.However,conflicting results were obtained.Therefore,this paper introduces a novel method,SMRDDS,to provide rapid and accurate assessment of disintegrated dolomite slope stability.This method incorporates parameters such as disintegrated grade,joint state,groundwater conditions,and excavation methods.The findings reveal that six slopes exhibit stability,while two are considered partially unstable.Notably,the proposed method demonstrates a closer match with the actual conditions and is more time-efficient compared with the BQ and SSPC methods.However,due to the limited research on disintegrated dolomite slopes,the results of the SMRDDS method tend to be conservative as a safety precaution.In conclusion,the SMRDDS method can quickly evaluate the current situation of disintegrated dolomite slopes in the field.This contributes significantly to disaster risk reduction for disintegrated dolomite slopes.

Removal of dolomite and potassium feldspar from apatite using simultaneous flotation with a mixed cationic-anionic collector

This study aims to investigate the effect of a cationic-anionic mixed collector(dodecyltrimethyl ammonium bromide/sodium oleate(DTAB/NaOL)on the selective separation of apatite,dolomite,and potassium feldspar.Herein,several experimental methods,including flotation experiments,zeta-potential detection,microcalorimetry detection,XPS analysis and FTIR measurements,were used.The flotation tests showed that dolomite and potassium feldspar can be successfully removed from apatite simultaneously when the molar ratio of DTAB to NaOL was 2:1 with pH 4.5.Zeta-potential and microcalorimetry detection suggested that NaOL and DTAB were adsorbed on the surface of dolomite and potassium feldspar respectively,and part of NaOL and DTAB formed co-adsorption on the surface of potassium feldspar to enhance the floatability of potassium feldspar.The XPS and FTIR spectra analysis demonstrated that the cationic collector,DTAB,was first adsorbed on the surface of potassium feldspar through electrostatic attraction in the DTAB/NaOL mixture system.Subsequently,the anionic NaOL collector and cationic DTAB collector form an electron neutralisation complex,thereby resulting in co-adsorption on the surface of potassium feldspar.NaOL was chemically reacted and adsorbed on dolomite surface,but almost no collector was adsorbed on apatite surface.Finally,the adsorption models of different collectors on mineral surface were obtained.

Effect of depressants on flotation separation of magnesite from dolomite and calcite

The flotation separation of magnesite from calcium-containing minerals has always been a difficult subject in minerals processing.This work studied the inhibition effects of carboxymethyl cellulose(CMC),sodium lignosulphonate,polyaspartic acid(PASP)and sodium silicate on flotation behaviors of magnesite,dolomite and calcite,providing guidance for the development of reagents in magnesite flotation.The micro-flotation results showed that among these four depressants,sodium silicate presented the strongest selectivity due to the highest recovery difference,and the flotation separation of magnesite from dolomite and calcite could be achieved by using sodium silicate as the depressant.Contact angle measurement indicated that the addition of sodium silicate caused the largest differences in surface wettability of the three minerals,which was in line with micro-flotation tests.Furthermore,zeta potential test,the Fourier transform infrared(FT-IR)spectroscopy and atomic force microscope(AFM)imaging were used to reveal the inhibition mechanism of sodium silicate.The results indicated that the dominated component SiO(OH)3
of sodium silicate could adsorb on minerals surfaces,and the adsorption of sodium silicate hardly affected the adsorption of NaOL on magnesite surface,but caused the reduction of NaOL adsorption on dolomite and calcite surfaces,thereby increasing the flotation selectivity.

Origin of dolomites in the Permian dolomitic reservoirs of Fengcheng Formation in Mahu Sag,Junggar Basin, NW China

Origin of authigenic dolomites in the dolomitic reservoir of the Permian Fengcheng Formation in the Mahu Sag of Junggar Basin is unclear.Occurrence and genetic evolution of the authigenic dolomites in dolomitic rock reservoir of the Fengcheng Formation in the Mahu Sag were analyzed by polarized and fluorescence thin sections,scanning electron microscope(SEM),electron microprobe(EMP),C,O and Sr isotopes analysis,and other techniques.(1)Dolomites were mainly precipitated in three stages:penecontemporaneous-shallow burial stage(early stage of the Middle Permian),middle burial stage(middle stage of the Middle Permian),and middle-deep burial stage,with the former two stages in dominance.(2)Dolomitization fluid was high-salinity brine originating from alkaline lake.In the penecontemporaneous-shallow burial stage,Mg^(2+)was mainly supplied by alkaline-lake fluid and devitrification of volcanic glass.In the middle burial stage,Mg^(2+)mainly came from the transformation of clay minerals,devitrification of volcanic glass and dissolution of aluminosilicates such as feldspar.(3)Regular changes of Mg,Mn,Fe,Sr,Si and other elements during the growth of dolomite were mainly related to the alkaline-lake fluid,and to different influences of devitrification and diagenetic alteration of volcanic materials during the burial.(4)In the penecontemporaneous stage,induced by alkaline-lake microorganisms,the micritic-microcrystalline dolomites were formed by primary precipitation,replacement of aragonite and high-Mg calcite,and other processes;in the shallow burial stage,the silt-sized dolomites were formed by continuous growth of micritic-microcrystalline dolomite and replacement of calcites,tuffs and other substances;in the middle burial stage,the dolomites,mainly silt-and fine-sized,were formed by replacement of volcanic materials.The research results are referential for investigating the formation mechanism and distribution patterns of tight dolomitic reservoirs in the Mahu Sag and other similar oil and gas bearing areas.

Production of high-purity Mg metal from dolomite through novel molten salt electrolysis and vacuum distillation

In this study,a novel Mg production process for producing high-purity Mg metal from dolomite was developed.When the electrolysis of calcined dolomite was conducted using Cu cathode and C anode in MgF_(2)–LiF molten salt at 1083–1173 K by applying an average current of 1.42–1.46 A for 9.50–21.0 h,the current efficiency of 66.4–88.6%was obtained.The produced Mg alloys consisted of MgCu_(2)and Cu(Mg)or MgCu_(2)and CuMg_(2)phases,depending on the Mg concentration in the Mg alloy.When the electrolysis of calcined dolomite was conducted in MgF_(2)–LiF–CaF_(2)molten salt at 1083 K,the current efficiency was 40.9–71.4%,owing to undesired reactions such as electroreduction of Ca^(2+)or/and CO_(3)^(2−)ions.Meanwhile,the current efficiency increased from 40.9%to 63.2%by utilizing a Pt anode,because the occurrence of CO_(3)^(2−)ions in the molten salt was prevented.After vacuum distillation of the obtained Mg alloys at 1300 K for 10 h,Mg metal with a purity of 99.9996–99.9998%was produced.Therefore,the feasibility of this novel process for the production of high-purity Mg metal from dolomite was demonstrated.

Reservoir Characterization of Special Dolomite Rock of Fengcheng Formation in Junggar Basin, China

Dolomites and eruptive rocks are well-developed in the Permian Fengcheng Formation in Junggar Basin in China, in which oil and gas are accumulated extensively. Until now, high-yield industrial oil and gas flows have been obtained in the dolomitic tuff of the second unit of the Fengcheng Formation, which demonstrates the huge exploration potential of the thick layer of massive dolomitic tuff. The lithology of the second unit of the Fengcheng Formation in this area has gradually transformed from the dolomite, dolomitic tuff to siltstone from east to west. Moreover, the well testing shows that the reservoir is oil-saturated, and the production rate mainly depends on the reservoir’s physical properties and fracture development. In this study, different types of data including core data, well log and seismic data are used cooperatively to characterize the sedimentary, structure and fracture features of the Fengcheng Formation, and then characterize the promising target zone in the study area. The result indicates that hydrocarbons are most accumulated along the deep fault in the Wu-Xia fault zone, which will be the favorable zone for the next progressive exploration.

Impact of volcanism on the formation and hydrocarbon generation of organic-rich shale in the Jiyang Depression, Bohai Bay Basin, China

Globally,most organic-rich shales are deposited with volcanic ash layers.Volcanic ash,a source for many sedimentary basins,can affect the sedimentary water environment,alter the primary productivity,and preserve the organic matter(OM)through physical,chemical,and biological reactions.With an increasing number of breakthroughs in shale oil exploration in the Bohai Bay Basin in recent years,less attention has been paid to the crucial role of volcanic impact especially its influence on the OM enrichment and hydrocarbon formation.Here,we studied the petrology,mineralogy,and geochemical characteristics of the organic-rich shale in the upper submember of the fourth member(Es_(4)^(1))and the lower submember of the third member(Es_(3)^(3))of the Shahejie Formation,aiming to better understand the volcanic impact on organic-rich shale formation.Our results show that total organic carbon is higher in the upper shale intervals rich in volcanic ash with enriched light rare earth elements and moderate Eu anomalies.This indicates that volcanism promoted OM formation before or after the eruption.The positive correlation between Eu/Eu*and Post-Archean Australian Shale indicates hydrothermal activity before the volcanic eruption.The plane graph of the hydrocarbon-generating intensity(S1+S2)suggests that the heat released by volcanism promoted hydrocarbon generation.Meanwhile,the nutrients carried by volcanic ash promoted biological blooms during Es_(4)^(1 )and Es_(3)^(3) deposition,yielding a high primary productivity.Biological blooms consume large amounts of oxygen and form anoxic environments conducive to the burial and preservation of OM.Therefore,this study helps to further understand the organic-inorganic interactions caused by typical geological events and provides a guide for the next step of shale oil exploration and development in other lacustrine basins in China.

Kinetics of extracting magnesium from mixture of calcined magnesite and calcined dolomite by vacuum aluminothermic reduction

The vacuum aluminothermic reduction of the mixture of calcined magnesite and calcined dolomite was studied. An isothermal reduction method satisfying the vacuum aluminothermic reduction was proposed. The experiments were carried out at 4 Pa. The results indicate that the reduction rate is increased with increasing temperature, content of aluminum and pellet forming pressure. The XRD patterns of pellets at different reduction stages confirm that the reduction process can be roughly classified into three stages：the formation of MgAl2O4, and Ca12Al14O33 phases;the phase transformation from MgAl2O4 and C12A7 to CaAl2O4;the formation of CaAl4O7 phase. The experimental data were divided into three parts according to the kinetic models. The apparent activation energies of the three parts were determined to be 98.2, 133.0 and 223.3 kJ/mol, respectively.

Mechanism of extracting magenesium from mixture of calcined magnesite and calcined dolomite by vacuum aluminothermic reduction

The process of aluminothermic reduction of a mixture of calcined dolomite and calcined magnesite had been developed. The mechanism of the process was studied by SEM and EDS. The reduction process was divided into three stages:0≤ηt/ηf≤0.43±0.06, 0.43±0.06≤ηt/ηf≤0.9±0.02 and 0.9±0.02≤ηt/ηf<1, whereηt andηf are the reduction ratio at time t and the final reduction ratio obtained in the experiment at temperature T, respectively. The first stage included the direct reaction between calcined dolomite or calcined magnesite and Al with 12CaO·7Al2O3 and MgO·Al2O3 as products. The reaction rate depended on the chemical reaction. The CA phase was mainly produced in the second stage and the overall reaction rate was determined by both the diffusion of Ca2+ with molten Al and the chemical reaction. The CA2 phase was mainly produced in the third stage and the reaction process was controlled by the diffusion of Ca2+.

Behavior of REE Fractionation during Weathering of Dolomite Regolith Profile in Southwest China

REE fractionation during the weathering of dolomite has been recognized for decades.A regolith profile on dolomite in southwest Yunnan of China was selected to investigate the behaviors of REE during weathering.The weathering of dolomite is divided into two stages：the pedogenesis stage and soil evolution stage,corresponding to the saprolites and soils respectively in the regolith profile. SiO_2,TiO_2,P_2O_5,Zr,Hf,Nb and Ta were immobile components during the weathering by and large, while Al_2O_3,K_2O and Fe_2O_3 were lost during the soil evolution stage in the physical form（clay minerals probably）.REE were fractionated during the whole weathering of dolomite.The field weathering profile and the lab acid-leaching experiments on dolomite indicate that MREE were enriched clearly relative to other REE during the pedogenesis stage in a ＂capillary ascending-adsorption＂ mechanism, but they did not fractionate clearly in the soil evolution stage.REE were lost and accumulated in the weathering front of dolomite during the soil evolution stage in a ＂physical-chemical leaching＂ mechanism.

The relationship between dolomite textures and their formation temperature: a case study from the Permian-Triassic of the Sichuan Basin and the Lower Paleozoic of the Tarim Basin

Study of dolomite texture can contribute to understanding the process of dolomitization.This research reports textures and homogenization temperatures of dolomites from the Permian-Triassic strata in the Sichuan Basin and the Lower Paleozoic strata in the Tarim Basin,which provided insights into relationships between dolomite textures and their formation temperatures.Our results are summarized as follows：1） dolomites with well-preserved texture indicate low dolomitization temperature.However,in certain diagenetic environments,the hydrothermal dolomitization may completely or partially preserve the original texture of dolomites.2） The formation temperatures of non-planar dolomites are always higher than those of planar dolomites.3） The formation temperatures of dolomite cements are generally higher than those of replacive dolomites.4） Although the formation temperatures of saddle dolomite cements have a wide range,they show higher values than those of the planar subhedral to euhedral dolomite cements.Thus,saddle dolomites could generally be an indicator of high precipitation temperature.5） The fluid Mg/Ca ratio is another element controlling dolomite morphology.Micritic dolomites,which precipitate from hypersaline fluids with a high Mg/Ca ratio in a subaerial environment could also have features of non-planar anhedral crystal shape because of rapid nucleation and crystallization during dolomitization.

Geochemical characteristics and genetic model of dolomite reservoirs in the eastern margin of the Pre-Caspian Basin

The widespread Carboniferous KT-I dolomite in the eastern margin of the Pre-Caspian Basin is an important hydrocarbon reservoir. The dolomite lithology is dominated by crystalline dolomite. The δ18O values range from -6.71‰ to 2.45‰, and average 0.063‰, obviously larger than -2.5‰, indicating low-temperature dolomite of evaporation origin. Stable strontium isotope ratios （87Sr/86Sr） range from 0.70829 to 0.70875 and average 0.708365, very consistent with 87Sr/86Sr ratios in Carboniferous seawater. Chemical analysis of Ca and Mg elements shows that the dolomite has 9.1 mole% excess Ca or even higher before stabilization. The degree of order of dolomite is medium–slightly poor, varying in a range of 0.336-0.504 and averaging 0.417. It suggests that the dolomite formed under near-surface conditions. There are two models for the origin of the Carboniferous KT-I dolomite reservoir. These are 1） the evaporation concentration – weathering crust model and 2） the shoal facies – seepage reflux model. The former is mainly developed in restricted platforms – evaporate platforms of restricted marine deposition environments with a representation of dolomite associated with gypsum and mudstone. The latter mainly formed in platform edge shoals and intra-platform shoals and is controlled by dolomitization due to high salinity sea water influx from adjacent restricted sea or evaporate platform.

Hydrothermal Dolomite in the Upper Sinian (Upper Proterozoic) Dengying Formation, East Sichuan Basin, China

Hydrothermal Dolomite （HTD） is present in the Upper Sinian （Upper Proterozoic） Dengying Formation, east Sichuan Basin, China. The strata are comprised by primary dolomite. The HTD has various textures, including zebra dolomite, subhorizontal sheet-like cavities filled by saddle dolomite and breccias cemented by saddle dolomites as well occur as a fill of veins and fractures. Also co-occur MVT type lead-zinc ores in the study area. The δ13C and δ18O isotopes of HTD in the Upper Sinian Dengying Formation are lighter than those of the host rocks, while STSr/86Sr is higher. The apparent difference in carbon, oxygen and strontium isotopes, especially the large difference in S7Sr/S6Sr isotopes ratio indicate crystallization from hot basinal and/or hydrothermal fluids. Saddle dolomite was precipitated at temperatures of 270-320℃. The diagenetic parasequences of mineral assemblage deposited in the Dengying Formation are： （1） dolomite host rock →sphalerite-galena-barite-fluorite; （2） dolomite host rock →saddle dolomite →quartz; （3） dolomite host rock →saddle dolomite→bitumen; （4） dolomite host rock →saddle dolomite →barite. The mean chemical composition of the host dolomite matrix and HTD didn＇t change much during hydrothermal process. The fluids forming the HTDs in the Dengying Formation were mixtures of freshwater from the unconformity at the top of Sinian, fluids from diagenetic compaction and hydrocarbon generation ＆ expulsion from the Lower Cambrian Niutitang Formation mudstones or the Doushantuo Formation silty mudstones, and hydrothermal fluids from the basement. The hydrocarbon reservoirs associated with the HTD were mostly controlled by the basement faults and fractures and karsting processes at the unconformity separating Sinian and Cambrian strata. The hydrocarbon storage spaces of HTD included dissolved cavities and intercrystalline pores. Dissolution cavities are extensive at the top of Dengying Formation, up to about 46m below the unconformity between Sinian and Cambrian and were generated mainly during karstification. Hydrothermal alteration enhanced the reservoir property of the Dengying Formation dolomites with 3%-5% increase in porosity. No agreement has been reached why zebra dolomite occurs only in the Upper Sinian strata, which would indicate that HTD mineralization occurred during two different periods, each of them related to major extensional tectonic event. The early one related to the Xingkai taphrogenesis （Z2-C1） and the later one to the Emei taphrogenesis （D2-T2）. But, all the data from saddle dolomite suggest that the predominant crystallization occurred during the latter event.

Geochemical characteristics of the Permian Changxing Formation reef dolomites,northeastern Sichuan Basin,China

The recent discovery of deep and ultra-deep gas reservoirs in the Permian Changxing Formation reefs, northeastern Sichuan Basin is a significant development in marine carbonate oil ＆ gas exploration in China. Reef dolomites and their origins have been major research topics for sedimentologists and oil ＆ gas geologists. The petrography, trace element and isotope geochemistry of the reef dolomites indicated that the dolomites are characterized by low Sr and Mn contents, relatively low Fe contents, very similar δ13C and 6180 values and very different 87Sr/86Sr ratios. Although the calculated results of the fluid mixing suggested that a mixture with 85%-95% meteoric water and 50/o- 15% seawater seemed to be the dolomitizing fluids of the reef dolomites, the low Mn contents, relatively low Fe contents, high δ13c values and high homogenization temperatures of the dolomites did not support that there were large proportions of meteoric water in the dolomitization process, and the 87Sr/86Sr ratios which were close to coeval seawater also did not support the possibility of the mixture of deep-burial circulated fluids from clastic rocks. High temperature deep-burial circulated seawater with low Mn and Fe contents, high Sr content and high δ13C values from the dissolution of widely distributed Triassic evaporites during the burial diagenetic processes （including dehydration of water-bearing evaporites） could have been the dolomitizing fluids of the reef dolomites.

Geochemical characteristics and diagenetic systems of dolomite reservoirs of the Changxing Formation in the eastern Sichuan Basin, China

In order to discuss the relationship between dolomite reservoirs and diagenetic systems of the Changxing Formation, we studied carbon, oxygen and strontium stable isotopes, iron, manganese and strontium trace elements and the Mg/Ca （mol%） ratio, dolomite order degree, and determined that burial dolomitization is the key to controlling the distribution of high quality dolomite reservoir in the Changxing Formation in the eastern Sichuan Basin. The dolomite of the Changxing Formation is divided into four diagenetic systems： （1） penecontemporaneous stage syngenetic brine diagenetic system, （2） early diagenetic stage strata seal brine diagenetic system, （3） middle-late diagenetic stage mixed hot brine diagenetic system and （4） tectonic uplift stage mixed hydrothermal fluid diagenetic system. New understanding of the controlling factors and distribution of dolomite reservoir development is discussed. Reef shoal facies belts controlled regional reservoir distribution and the scale of development. Burial dolomitization of a strata seal brine diagenetic system is the foundation of reservoir development, mainly developing pore reservoir. Burial dolomitization of mixed hot brine diagenetic system expanded the reservoir distribution and improved the reservoir quality, mainly developing pore-vug reservoir. Fracturing and dissolution of a mixed hydrothermal fluid diagenetic system is the key to improving the reservoir quality, mainly developing pore-vug-crack complex reservoirs.

Ferroan dolomites in Miocene sediments of the Xisha Islands and their genetic model

Carbonate rocks are important reservoirs for global petroleum exploration.The largest oilfield in the South China Sea,Liuhua 11-1,is distributed in the massive carbonate reef area of the Zhujiang(Pearl)River Mouth Basin.Previous studies showed that one 802.17-m-long core from well Xichen-1 in the South China Sea mainly consisted of white and light gray-white organic reefs.Recently,a Miocene whole core(161.9 m long)of well Xiyong-2,near well Xichen-1,was found to contain six layers of yellowish brown,light yellowish gray,iron black,or light yellowish gray-white organic reefs.Scanning electron microscope images of these layers reveal a typical ferroan dolomite rich in Fe(up to 29%),with the high concentrations of Mn,Cu,W,Zn,Cr,Ni,and Co.Systematic X-ray powder diffraction analysis yields a 1.9–6.1 match in phase ratio with ankerite,5.4–26.9 with dolomite,and zero with calcite,which indicate that the samples can be classified as ferroan dolomite.The iron and heavy metals are inferred to be originated from multiple volcanic eruptions of Gaojianshi Island in the Dongdao Atoll during the middle-late Miocene.These elements were dissolved in seawater,likely as a sol,and carried to Yongxing Island in the Xuande Atoll by sea currents and tides enhanced by prevailing winds,and deposited as a part of the sedimentation process in the study area.The ferroan dolomite has Sr content of (125–285)×10^(-6),which is lower than the accepted Sr boundary value of dolomite.This finding suggests that dolomitization occurred during large-scale global glacial regression in the late Miocene.The isolated Xisha carbonate platform,exposed to air,underwent freshwater leaching and dolomitization induced by mixed water,and caused the extensive Fe-Mg exchange along the organic reef profile to form ankerite and ferroan dolomite.These results may help to understand paleoceanographic environmental changes in the South China Sea during the Miocene.