Process of crystal growth can be controlled by both surface kinetics and by volume transport as well.Although the complicated relation between the surface kinetics and volume transport exsits,generally,they are studie...Process of crystal growth can be controlled by both surface kinetics and by volume transport as well.Although the complicated relation between the surface kinetics and volume transport exsits,generally,they are studied seprately.Due to the mathematical complexity of heat and mass transport equations,the in depth studies of heat and mass transport process become difficult.Most of the studies on the transport were performed for the growth from melt.Most of the work on Surface kinetics has been done for crystal growth from aqueous solution because the in situ observation of crystal growth is easily carried out.In recent years,the surface kinetics studies on the nanometer scale,even atomic scale,are demonstrated by using AFM.展开更多
Over the past few decades, coordination polymers/metal organic frameworks （CPs/MOFs） have drawn a great deal of attention for diverse applications due to their advantages of intrinsically ttLnable chemical structure...Over the past few decades, coordination polymers/metal organic frameworks （CPs/MOFs） have drawn a great deal of attention for diverse applications due to their advantages of intrinsically ttLnable chemical structure, flexible architecture, high pore volume, high surface area, multifunctional properties, etc. To date, numerous CPs/MOFs have been developed and employed for the treatment and control of gaseous pollutants, such as volatile organic compounds （VOCs）, through capture, sorptive removal, and catalytic degradation. Nevertheless, there are also some key drawbacks and challenges for the practical application of these systems （e.g., poor selectivity, high energy （and fiscal） cost, high synthesis cost, low capacity, and difficulties in regeneration and recycling）. In this review, recent developments in CPs/MOFs research are described with their associated mechanisms for capture, sorptive removal, and catalytic degradation of VOCs. To this end, we discuss the key variables and challenges for afforded abatement of VOCs through CPs/MOFs technologies. Hopefully, this review will help the scientific community set future directions for the advancement of CPs/MOFs techniques for the effective management of diverse environmental issues.展开更多
文摘Process of crystal growth can be controlled by both surface kinetics and by volume transport as well.Although the complicated relation between the surface kinetics and volume transport exsits,generally,they are studied seprately.Due to the mathematical complexity of heat and mass transport equations,the in depth studies of heat and mass transport process become difficult.Most of the studies on the transport were performed for the growth from melt.Most of the work on Surface kinetics has been done for crystal growth from aqueous solution because the in situ observation of crystal growth is easily carried out.In recent years,the surface kinetics studies on the nanometer scale,even atomic scale,are demonstrated by using AFM.
文摘Over the past few decades, coordination polymers/metal organic frameworks （CPs/MOFs） have drawn a great deal of attention for diverse applications due to their advantages of intrinsically ttLnable chemical structure, flexible architecture, high pore volume, high surface area, multifunctional properties, etc. To date, numerous CPs/MOFs have been developed and employed for the treatment and control of gaseous pollutants, such as volatile organic compounds （VOCs）, through capture, sorptive removal, and catalytic degradation. Nevertheless, there are also some key drawbacks and challenges for the practical application of these systems （e.g., poor selectivity, high energy （and fiscal） cost, high synthesis cost, low capacity, and difficulties in regeneration and recycling）. In this review, recent developments in CPs/MOFs research are described with their associated mechanisms for capture, sorptive removal, and catalytic degradation of VOCs. To this end, we discuss the key variables and challenges for afforded abatement of VOCs through CPs/MOFs technologies. Hopefully, this review will help the scientific community set future directions for the advancement of CPs/MOFs techniques for the effective management of diverse environmental issues.
