On the basis of expounding the necessity of evaluation index system of farmers' cooperative economic organization,the three first level indexes including organization development index,member development index and...On the basis of expounding the necessity of evaluation index system of farmers' cooperative economic organization,the three first level indexes including organization development index,member development index and social development index and 13 second level indexes including aggregate capital of cooperative organization,annual profit share of cooperative organization,annual total income of cooperative organization,etc.,are established according to the principles of Systematics and the methods of Statistics and Quantitative economics.By using the analytical hierarchy process,the weight of each index is tested and the operation result and evaluation mode is established,as well as the index standard value and comprehensive value.As for the result of the evaluation,it is suggested that the government should support the farmers' cooperative organizations in hierarchy and targeted way according to local conditions.Though the construction of index system and comprehensive score,the government should establish the entry and exit mechanism of farmers' cooperative organizations to reasonably guild the rapid development of cooperators.展开更多
The organizational structures and the performances of the university procurement are rarely studied. Through the SCP perspective in the modem industrial economics, we can not only reveal the roles of the public organi...The organizational structures and the performances of the university procurement are rarely studied. Through the SCP perspective in the modem industrial economics, we can not only reveal the roles of the public organizational structures in the organizational performances, but also help to reflect the problems existing in the organizational structures from the performances, and improve the market performances by optimizing the organization structures. This paper tries to put forward the relationship between them, and makes an analysis of the future development trend.展开更多
[ Objective] The study aimed to supply important basis for developing environment-friendly pesticides with myricetin and crude extract of Myrica rubra leaves as effective components. [ Method] According to "Test guid...[ Objective] The study aimed to supply important basis for developing environment-friendly pesticides with myricetin and crude extract of Myrica rubra leaves as effective components. [ Method] According to "Test guidelines for environmental safety evaluation on chemical pesticides", the toxicity of myricetin and crude extract of M. rubra leaves on non-target organisms was determined and the safety evaluation was carried out. [Result] MyriceUn and crude extract of M. rubra leaves had low toxicity on non-target organisms, such as earthworm, silkworm and soil microbes. Myricetin showed low toxicity and the crude extract of M. rubra leaves showed middle toxicity on tadpole. The high-concentration crude extract of M. rubra leaves had some antifeedant effect on silkworm. [ Conclusion] Myricetin and crude extract of M. rubra leaves had low toxicity on non-tar- get organisms in environment and they were relatively safe.展开更多
With the increasing clinical use of cytostatic and novel biologic targeted agents,conventional morphologic tumor burden assessments,including World Health Organization criteria and Response Evaluation Criteria in Soli...With the increasing clinical use of cytostatic and novel biologic targeted agents,conventional morphologic tumor burden assessments,including World Health Organization criteria and Response Evaluation Criteria in Solid Tumors,are confronting limitations because of their difficulties in distinguishing viable tumor from necrotic or fibrotic tissue.Therefore,the investigation for reliable quantitative biomarkers of therapeutic response such as metabolic imaging or functional imaging has been desired.In this review,we will discuss the conventional and new approaches to assess tumor burden.Since targeted therapy or locoregional therapies can induce biological changes much earlier than morphological changes,these functional tumor burden analyses are very promising.However,some of them have not gone thorough all steps for standardization and validation.Nevertheless,these new techniques and criteria will play an important role in the cancer management,and provide each patient more tailored therapy.展开更多
[Objective] The aim was to explore soil quality and fertility of organic rice fields in Daizhuang Village. [Method] The analysis was made based on soil samples from different areas where planting methods varied after ...[Objective] The aim was to explore soil quality and fertility of organic rice fields in Daizhuang Village. [Method] The analysis was made based on soil samples from different areas where planting methods varied after harvest of organic rice. [Result] The content of organic matter improved generally in fields of organic rice in Daizhuang. Specifically, the contents of N, P and K were not high, and the contents of N and P declined in the fields with crop rotation of organic rice Astragalus sin# cus, but the content of K increased. [Conclusion] It is of great significance for soil fertility to develop and promote crop rotation of organic rice Astragalus sinicus, which also advances quality of organic rice.展开更多
Virtual organization is a new production patter and a principal part in advanced manufacturing systems such as agile manufacturing. Manufacturability evaluation is the necessary condition to form the virtual organizat...Virtual organization is a new production patter and a principal part in advanced manufacturing systems such as agile manufacturing. Manufacturability evaluation is the necessary condition to form the virtual organization. A new manufacturability evaluation approach is described in this paper, which is carried out based on every process feature under the double-layer model of manufacturing resources proposed by authors. The manufacturing resources that build up the virtual organization are selected according to the results of manufacturability evaluation.展开更多
The degradation coefficient is proposed to evaluate the degradation degree of organic coatings by directly anaIyzing the Bode plots of the electrochemical impedance spectroscopy (EIS) data. This paper investigated t...The degradation coefficient is proposed to evaluate the degradation degree of organic coatings by directly anaIyzing the Bode plots of the electrochemical impedance spectroscopy (EIS) data. This paper investigated the degradation of phenolic epoxy coating/tinplate system by EIS and the degradation coefficient value, which correlates well with the results of breakpoint frequency and variation of phase angle at 10 Hz. Furthermore, the degradation process was confirmed by scanning electron microscope (SEM) and scanning probe microscopy (SPM). It is concluded that degradation coefficient can be used for the fast evaluation of degradation degree of organic coatings in practical appli- cations.展开更多
Neomysis awatschensis was collected on the west coast of Jiaozhou Bay, Qingdao in 1992 and acclimated in the laboratory conditions. The acute toxicity method using 4~ 6 day juvenile mysid of this species is studied. T...Neomysis awatschensis was collected on the west coast of Jiaozhou Bay, Qingdao in 1992 and acclimated in the laboratory conditions. The acute toxicity method using 4~ 6 day juvenile mysid of this species is studied. The species is compared with M. bahia in taxonomy, geographic distribution, morphology, as well as the sensitivity to reference toxins. Based on the results, we recommend N. awatschensis to be a standard marine organism for toxicity test in China and the method to be applied in toxicity evaluation of drilling fluids. In this paper, we report the results of the above studies and the application of the method in the evaluation of several drilling fluid products.展开更多
A self-organizing fuzzy clustering neural network by combining the self-organizing Kohonen clustering network with the fuzzy theory is proposed. This network model is designed for the effectiveness evaluation of elect...A self-organizing fuzzy clustering neural network by combining the self-organizing Kohonen clustering network with the fuzzy theory is proposed. This network model is designed for the effectiveness evaluation of electronic countermeasures, which not only exerts the advantages of the fuzzy theory, but also has a good ability in machine learning and data analysis. The subjective value of sample versus class is computed by the fuzzy computing theory, and the classified results obtained by self-organizing learning of Kohonen neural network are represented on output layer. Meanwhile, the fuzzy competition learning algorithm keeps the similar information between samples and overcomes the disadvantages of neural network which has fewer samples. The simulation result indicates that the proposed algorithm is feasible and effective.展开更多
Based on the investigation for the 14 groundwater sources, the water quality of the groundwater sources had been analyzed, using the evaluation method of the combination of inorganic and organic index instead of the t...Based on the investigation for the 14 groundwater sources, the water quality of the groundwater sources had been analyzed, using the evaluation method of the combination of inorganic and organic index instead of the traditional method which was only based on inorganic index. The results showed that the quality of 12 groundwater sources satisfied class III standard of groundwater quality and other two exceeded class III standard. There were one groundwater source, whose water quality reached class 1 standard, and five groundwater sources, whose water quality reached class II standard. There were seven groundwater sources, in which the fluorine, an organic pollutant, was detected. The results showed that the groundwater resources in Yantai City were less polluted and the main pollutant in groundwater was nitrate. According to the analytical data and the environmental conditions of groundwater sources, the conclusion was drawn that the agriculture and rural non-point pollution were the main reasons of groundwater pollution.展开更多
The paper investigates the learner-focused English as a Foreign Langue(EFL) curricular innovation in China Agricultural University(referred to as CAU in the following text) from the perspectives of curricular formulat...The paper investigates the learner-focused English as a Foreign Langue(EFL) curricular innovation in China Agricultural University(referred to as CAU in the following text) from the perspectives of curricular formulation,implementation and evaluation of EFL learning & teaching in the one-year duration from Autumn semester of 2016 to Spring semester of 2017.A discussion of the effects of the curricular restructuring is presented.展开更多
Cyber physical system(CPS)provides more powerful service by cyber and physical features through the wireless communication.As a kind of social organized network system,a fundamental question of CPS is to achieve servi...Cyber physical system(CPS)provides more powerful service by cyber and physical features through the wireless communication.As a kind of social organized network system,a fundamental question of CPS is to achieve service self-organization with its nodes autonomously working in both physical and cyber environments.To solve the problem,the social nature of nodes in CPS is firstly addressed,and then a formal social semantic descriptions is presented for physical environment,node service and task in order to make the nodes communicate automatically and physical environment sensibly.Further,the Horn clause is introduced to represent the reasoning rules of service organizing.Based on the match function,which is defined for measurement between semantics,the semantic aware measurement is presented to evaluate whether environment around a node can satisfy the task requirement or not.Moreover,the service capacity evaluation method for nodes is addressed to find out the competent service from both cyber and physical features of nodes.According to aforementioned two measurements,the task semantic decomposition algorithm and the organizing matrix are defined and the service self-organizing mechanism for CPS is proposed.Finally,examinations are given to further verify the efficiency and feasibility of the proposed mechanism.展开更多
Organization intelligence is an important index for evaluating competition ability of organization. This paper applies the Entropy concept to evaluate the level of organization intelligence and set up the framework of...Organization intelligence is an important index for evaluating competition ability of organization. This paper applies the Entropy concept to evaluate the level of organization intelligence and set up the framework of entropy evaluation theory related to the environment, inter-structure and behavior fields.展开更多
We have collected 18 samples corresponding to 18 locations in the middle and lower reaches of the Huaihe River. The sediment samples were tested for their pH level,percentage of solids,organic matter and five heavy me...We have collected 18 samples corresponding to 18 locations in the middle and lower reaches of the Huaihe River. The sediment samples were tested for their pH level,percentage of solids,organic matter and five heavy metals (Cr,Cu,Zn,Cd and Pb). The average concentrations of Cr,Cu,Zn,Cd and Pb of the 18 sampling locations were re-spectively 56.1,22.2,70.0,0.17 and 20.4 μg/g. Compared with their background values,the average concentrations of Zn and Cu in sediment samples from the Huaihe River were slightly higher,while the average concentrations of Cr and Pb were slightly lower. The concentration of Cd in all sediment samples was higher than its background value,while the average concentration of Cd in all sediment samples was about twice the amount of the background value. The concen-tration of the five heavy metals was lower than that of the Yangtze River. A correlation analysis revealed that heavy metals have similar geochemical feautures. The geo-accumulation index (Igeo) was used to evaluate the degree of pollu-tion of the Huaihe River sediments. The index reveals that the sediment samples are largely ranked from zero pollution to no to medium pollution.展开更多
Dimethyldistearylammonium Bromide (DODMAB) is a bentonite modifier with good performance. In this experiment, 1-Bromooctadecane is the raw material, and completes tertiary amination and quaternization successively by ...Dimethyldistearylammonium Bromide (DODMAB) is a bentonite modifier with good performance. In this experiment, 1-Bromooctadecane is the raw material, and completes tertiary amination and quaternization successively by changing the condition of experiment. The result is that the productivity can achieve 78.94% in the synthesis of DODMAB. It has been used in the experiment of bentonite modification and achieves good results;compared with using trimethylstearylammonium bromide as the organic modifier, the synthetic organic bentonite has better performance than the common organic modifier when used in the oil base drilling fluid of oilfield operation.展开更多
An automated cumulative sampling system and a method that combines a two-step cryo-concentrated system and gas chromatography/mass spectrometry (CCS-GC/MS) are introduced. The method is evaluated by a set of special...An automated cumulative sampling system and a method that combines a two-step cryo-concentrated system and gas chromatography/mass spectrometry (CCS-GC/MS) are introduced. The method is evaluated by a set of special experiments and the results are presented. The lowest measurement detection limit was expanded from 10^-6 nmol mol^-1 to 10^-12 nmol mol^-1 by using CCS-GC/MS instead of the simpler method of gas chromatography/mass spectrometry (GC/MS), with the average responsible factor of 39 object compounds being 2.9 × 10^-12. When the volume of air sample reached 1000 cm^3, the lowest detection limit reached up to 7 × 10^-12-40 × 10^-12 nmol mol^-1. The CCS-GC/MS method can potentially identify all objective chemical species in an atmospheric sample, with an average 2.5 s bias error of retention time for 39 gas chromatography (GC) peaks. Within the range 0-400×10^-9 nmol mol^-1, the concentration of 39 kinds of objective compounds can be individually calculated very accurately by a standard curve [average r^2 (coefficient of determination) value of above 0.99]. The recovery efficiency was 88%-111%, with an average of 100.8% ±5.6%. The bias error of precision was 2%-14%, with an average of 6.6%.展开更多
An analytical procedure involving Rock-Eval pyrolysis of whole-rocks was adopted on fresh outcrop samples covering the three lithostratigraphic units in the Afikpo Basin of the Lower Benue Trough. Three petroleum syst...An analytical procedure involving Rock-Eval pyrolysis of whole-rocks was adopted on fresh outcrop samples covering the three lithostratigraphic units in the Afikpo Basin of the Lower Benue Trough. Three petroleum systems are present in the Cretaceous delta frame: the Asu-River Group, the Eze-Aku Group and proto-Niger Delta sequences. The Afikpo Basin has been correlated to three petroleum systems in the Lower Congo Basin, Niger Delta and the Anambra Basin. The organic geochemistry of the shales, carbonaceous mudstones and coal beds show relatively moderate to high total organic carbon contents. The best potential hydrocarbon source rocks are the Eze-Aku Group and proto-Niger Delta shales, carbonaceous mudstones and coal beds where maturation was attained. The high total organic contents, thermal maturity and terrigenous characters of the Asu-River Group, Eze-Aku Group and proto-Niger Delta sediments, suggest the presence of a large amount of natural gas with a small quantity of oil accumulation. Variations in source rock facies were observed from one lithostratigraphic unit to another, and initial HI values as a function of TOC were proposed for each lithostratigraphic unit. The results also show that TOC, HI, OI, S2 and Tmax vary from older to younger rocks. The Tmax values discriminate the rocks into immature and mature source rocks. Source rocks with high Tmax suggest high geothermal gradient/or recycled organic matter. Also high Tmax and S2 yield indicate late and post maturity. Recycled organic matter is characterized by low Tmax. The principal source rocks for gas in the Afikpo Basin are the Eze-Aku Group and proto-Niger Delta beds deltaic systems, consisting mainly of III to IV kerogens with a subordinate amount of type II organic matter. Based on the obtained results, it is concluded that the Cretaceous shales, carbonaceous mudstones and coals in the Afikpo Basin of the Lower Benue Trough are capable of generating and expelling hydrocarbons in the case of sufficient maturity.展开更多
基金Supported by Xi'an Social Science Fund(2010240)New Century Excellent Talents (NCET-05-0859)
文摘On the basis of expounding the necessity of evaluation index system of farmers' cooperative economic organization,the three first level indexes including organization development index,member development index and social development index and 13 second level indexes including aggregate capital of cooperative organization,annual profit share of cooperative organization,annual total income of cooperative organization,etc.,are established according to the principles of Systematics and the methods of Statistics and Quantitative economics.By using the analytical hierarchy process,the weight of each index is tested and the operation result and evaluation mode is established,as well as the index standard value and comprehensive value.As for the result of the evaluation,it is suggested that the government should support the farmers' cooperative organizations in hierarchy and targeted way according to local conditions.Though the construction of index system and comprehensive score,the government should establish the entry and exit mechanism of farmers' cooperative organizations to reasonably guild the rapid development of cooperators.
文摘The organizational structures and the performances of the university procurement are rarely studied. Through the SCP perspective in the modem industrial economics, we can not only reveal the roles of the public organizational structures in the organizational performances, but also help to reflect the problems existing in the organizational structures from the performances, and improve the market performances by optimizing the organization structures. This paper tries to put forward the relationship between them, and makes an analysis of the future development trend.
基金Supported by Major Program in Zhejiang Science and Technology Department(2008C22G2100038)Emerging Artists Project in Zhejiang Province(21000037)~~
文摘[ Objective] The study aimed to supply important basis for developing environment-friendly pesticides with myricetin and crude extract of Myrica rubra leaves as effective components. [ Method] According to "Test guidelines for environmental safety evaluation on chemical pesticides", the toxicity of myricetin and crude extract of M. rubra leaves on non-target organisms was determined and the safety evaluation was carried out. [Result] MyriceUn and crude extract of M. rubra leaves had low toxicity on non-target organisms, such as earthworm, silkworm and soil microbes. Myricetin showed low toxicity and the crude extract of M. rubra leaves showed middle toxicity on tadpole. The high-concentration crude extract of M. rubra leaves had some antifeedant effect on silkworm. [ Conclusion] Myricetin and crude extract of M. rubra leaves had low toxicity on non-tar- get organisms in environment and they were relatively safe.
文摘With the increasing clinical use of cytostatic and novel biologic targeted agents,conventional morphologic tumor burden assessments,including World Health Organization criteria and Response Evaluation Criteria in Solid Tumors,are confronting limitations because of their difficulties in distinguishing viable tumor from necrotic or fibrotic tissue.Therefore,the investigation for reliable quantitative biomarkers of therapeutic response such as metabolic imaging or functional imaging has been desired.In this review,we will discuss the conventional and new approaches to assess tumor burden.Since targeted therapy or locoregional therapies can induce biological changes much earlier than morphological changes,these functional tumor burden analyses are very promising.However,some of them have not gone thorough all steps for standardization and validation.Nevertheless,these new techniques and criteria will play an important role in the cancer management,and provide each patient more tailored therapy.
基金Supported by Circular Agriculture Technology Research,Integration and Demonstration Program of Planting and Raising in Qiugang(CX(12)3043)~~
文摘[Objective] The aim was to explore soil quality and fertility of organic rice fields in Daizhuang Village. [Method] The analysis was made based on soil samples from different areas where planting methods varied after harvest of organic rice. [Result] The content of organic matter improved generally in fields of organic rice in Daizhuang. Specifically, the contents of N, P and K were not high, and the contents of N and P declined in the fields with crop rotation of organic rice Astragalus sin# cus, but the content of K increased. [Conclusion] It is of great significance for soil fertility to develop and promote crop rotation of organic rice Astragalus sinicus, which also advances quality of organic rice.
文摘Virtual organization is a new production patter and a principal part in advanced manufacturing systems such as agile manufacturing. Manufacturability evaluation is the necessary condition to form the virtual organization. A new manufacturability evaluation approach is described in this paper, which is carried out based on every process feature under the double-layer model of manufacturing resources proposed by authors. The manufacturing resources that build up the virtual organization are selected according to the results of manufacturability evaluation.
基金Supported by Major State Basic Research Program of China ("973"Program,No. 2011CB610500)
文摘The degradation coefficient is proposed to evaluate the degradation degree of organic coatings by directly anaIyzing the Bode plots of the electrochemical impedance spectroscopy (EIS) data. This paper investigated the degradation of phenolic epoxy coating/tinplate system by EIS and the degradation coefficient value, which correlates well with the results of breakpoint frequency and variation of phase angle at 10 Hz. Furthermore, the degradation process was confirmed by scanning electron microscope (SEM) and scanning probe microscopy (SPM). It is concluded that degradation coefficient can be used for the fast evaluation of degradation degree of organic coatings in practical appli- cations.
基金The work is supported by National Basic Research Project No. 2001CB409709, NNSFC project (49906007, 39950001, 20177023, 40076030), CAS Innovation Project (KZCX2-206), Direct Project of CAS and Project of the Commission of Science, Shandong Province.
文摘Neomysis awatschensis was collected on the west coast of Jiaozhou Bay, Qingdao in 1992 and acclimated in the laboratory conditions. The acute toxicity method using 4~ 6 day juvenile mysid of this species is studied. The species is compared with M. bahia in taxonomy, geographic distribution, morphology, as well as the sensitivity to reference toxins. Based on the results, we recommend N. awatschensis to be a standard marine organism for toxicity test in China and the method to be applied in toxicity evaluation of drilling fluids. In this paper, we report the results of the above studies and the application of the method in the evaluation of several drilling fluid products.
文摘A self-organizing fuzzy clustering neural network by combining the self-organizing Kohonen clustering network with the fuzzy theory is proposed. This network model is designed for the effectiveness evaluation of electronic countermeasures, which not only exerts the advantages of the fuzzy theory, but also has a good ability in machine learning and data analysis. The subjective value of sample versus class is computed by the fuzzy computing theory, and the classified results obtained by self-organizing learning of Kohonen neural network are represented on output layer. Meanwhile, the fuzzy competition learning algorithm keeps the similar information between samples and overcomes the disadvantages of neural network which has fewer samples. The simulation result indicates that the proposed algorithm is feasible and effective.
文摘Based on the investigation for the 14 groundwater sources, the water quality of the groundwater sources had been analyzed, using the evaluation method of the combination of inorganic and organic index instead of the traditional method which was only based on inorganic index. The results showed that the quality of 12 groundwater sources satisfied class III standard of groundwater quality and other two exceeded class III standard. There were one groundwater source, whose water quality reached class 1 standard, and five groundwater sources, whose water quality reached class II standard. There were seven groundwater sources, in which the fluorine, an organic pollutant, was detected. The results showed that the groundwater resources in Yantai City were less polluted and the main pollutant in groundwater was nitrate. According to the analytical data and the environmental conditions of groundwater sources, the conclusion was drawn that the agriculture and rural non-point pollution were the main reasons of groundwater pollution.
文摘The paper investigates the learner-focused English as a Foreign Langue(EFL) curricular innovation in China Agricultural University(referred to as CAU in the following text) from the perspectives of curricular formulation,implementation and evaluation of EFL learning & teaching in the one-year duration from Autumn semester of 2016 to Spring semester of 2017.A discussion of the effects of the curricular restructuring is presented.
基金Supported by the National Natural Science Foundation of China(61103069,71171148)the National High-Tech Research and Development Plan of China(″863″ Plan)(2012BAD35B01)+2 种基金the Innovation Program of Shanghai Municipal Education Commission(13YZ052)the Shanghai Committee of Science and Technology(11DZ1501703,11dz12106001)the Program of Shanghai Normal University(DXL125,DCL201302)
文摘Cyber physical system(CPS)provides more powerful service by cyber and physical features through the wireless communication.As a kind of social organized network system,a fundamental question of CPS is to achieve service self-organization with its nodes autonomously working in both physical and cyber environments.To solve the problem,the social nature of nodes in CPS is firstly addressed,and then a formal social semantic descriptions is presented for physical environment,node service and task in order to make the nodes communicate automatically and physical environment sensibly.Further,the Horn clause is introduced to represent the reasoning rules of service organizing.Based on the match function,which is defined for measurement between semantics,the semantic aware measurement is presented to evaluate whether environment around a node can satisfy the task requirement or not.Moreover,the service capacity evaluation method for nodes is addressed to find out the competent service from both cyber and physical features of nodes.According to aforementioned two measurements,the task semantic decomposition algorithm and the organizing matrix are defined and the service self-organizing mechanism for CPS is proposed.Finally,examinations are given to further verify the efficiency and feasibility of the proposed mechanism.
文摘Organization intelligence is an important index for evaluating competition ability of organization. This paper applies the Entropy concept to evaluate the level of organization intelligence and set up the framework of entropy evaluation theory related to the environment, inter-structure and behavior fields.
文摘We have collected 18 samples corresponding to 18 locations in the middle and lower reaches of the Huaihe River. The sediment samples were tested for their pH level,percentage of solids,organic matter and five heavy metals (Cr,Cu,Zn,Cd and Pb). The average concentrations of Cr,Cu,Zn,Cd and Pb of the 18 sampling locations were re-spectively 56.1,22.2,70.0,0.17 and 20.4 μg/g. Compared with their background values,the average concentrations of Zn and Cu in sediment samples from the Huaihe River were slightly higher,while the average concentrations of Cr and Pb were slightly lower. The concentration of Cd in all sediment samples was higher than its background value,while the average concentration of Cd in all sediment samples was about twice the amount of the background value. The concen-tration of the five heavy metals was lower than that of the Yangtze River. A correlation analysis revealed that heavy metals have similar geochemical feautures. The geo-accumulation index (Igeo) was used to evaluate the degree of pollu-tion of the Huaihe River sediments. The index reveals that the sediment samples are largely ranked from zero pollution to no to medium pollution.
文摘Dimethyldistearylammonium Bromide (DODMAB) is a bentonite modifier with good performance. In this experiment, 1-Bromooctadecane is the raw material, and completes tertiary amination and quaternization successively by changing the condition of experiment. The result is that the productivity can achieve 78.94% in the synthesis of DODMAB. It has been used in the experiment of bentonite modification and achieves good results;compared with using trimethylstearylammonium bromide as the organic modifier, the synthetic organic bentonite has better performance than the common organic modifier when used in the oil base drilling fluid of oilfield operation.
文摘An automated cumulative sampling system and a method that combines a two-step cryo-concentrated system and gas chromatography/mass spectrometry (CCS-GC/MS) are introduced. The method is evaluated by a set of special experiments and the results are presented. The lowest measurement detection limit was expanded from 10^-6 nmol mol^-1 to 10^-12 nmol mol^-1 by using CCS-GC/MS instead of the simpler method of gas chromatography/mass spectrometry (GC/MS), with the average responsible factor of 39 object compounds being 2.9 × 10^-12. When the volume of air sample reached 1000 cm^3, the lowest detection limit reached up to 7 × 10^-12-40 × 10^-12 nmol mol^-1. The CCS-GC/MS method can potentially identify all objective chemical species in an atmospheric sample, with an average 2.5 s bias error of retention time for 39 gas chromatography (GC) peaks. Within the range 0-400×10^-9 nmol mol^-1, the concentration of 39 kinds of objective compounds can be individually calculated very accurately by a standard curve [average r^2 (coefficient of determination) value of above 0.99]. The recovery efficiency was 88%-111%, with an average of 100.8% ±5.6%. The bias error of precision was 2%-14%, with an average of 6.6%.
文摘An analytical procedure involving Rock-Eval pyrolysis of whole-rocks was adopted on fresh outcrop samples covering the three lithostratigraphic units in the Afikpo Basin of the Lower Benue Trough. Three petroleum systems are present in the Cretaceous delta frame: the Asu-River Group, the Eze-Aku Group and proto-Niger Delta sequences. The Afikpo Basin has been correlated to three petroleum systems in the Lower Congo Basin, Niger Delta and the Anambra Basin. The organic geochemistry of the shales, carbonaceous mudstones and coal beds show relatively moderate to high total organic carbon contents. The best potential hydrocarbon source rocks are the Eze-Aku Group and proto-Niger Delta shales, carbonaceous mudstones and coal beds where maturation was attained. The high total organic contents, thermal maturity and terrigenous characters of the Asu-River Group, Eze-Aku Group and proto-Niger Delta sediments, suggest the presence of a large amount of natural gas with a small quantity of oil accumulation. Variations in source rock facies were observed from one lithostratigraphic unit to another, and initial HI values as a function of TOC were proposed for each lithostratigraphic unit. The results also show that TOC, HI, OI, S2 and Tmax vary from older to younger rocks. The Tmax values discriminate the rocks into immature and mature source rocks. Source rocks with high Tmax suggest high geothermal gradient/or recycled organic matter. Also high Tmax and S2 yield indicate late and post maturity. Recycled organic matter is characterized by low Tmax. The principal source rocks for gas in the Afikpo Basin are the Eze-Aku Group and proto-Niger Delta beds deltaic systems, consisting mainly of III to IV kerogens with a subordinate amount of type II organic matter. Based on the obtained results, it is concluded that the Cretaceous shales, carbonaceous mudstones and coals in the Afikpo Basin of the Lower Benue Trough are capable of generating and expelling hydrocarbons in the case of sufficient maturity.