With ultrasonic assistant mixing way, an intercalated mixture of polyol/ organo reactive montmorillonite （ORMMT） was pretreated. The prepolymer composed MMT clay was prepared by reaction of polyol/ORMMT mixture with...With ultrasonic assistant mixing way, an intercalated mixture of polyol/ organo reactive montmorillonite （ORMMT） was pretreated. The prepolymer composed MMT clay was prepared by reaction of polyol/ORMMT mixture with toluene diisocyanate （TDI）. The resultant prepolymer reacted with extender （DMTDA） and then the polyur- ethane-urealorgano reactive montmorillonite （PUUIORMMT） nanocomposites were obtained. The structure, morphology and properties of PUU/ORMMT nanocomposites were characterized by FT-IR, TEM, AFM, strain-stress machine, TGA, and dynamic mechanical analysis （DMA）. The results showed that when tl-m OMMT content is 3%, the PUU/ORMMT nanocomposities performed super mechanical properties. Because of the presence of ORMMT, both Tg of the soft segment and tan5 of the PUU increased, and the decomposition temperature for the first step and the second step increased respectively. TEM images showed that the organophilic MMT particles in the PUU composite exhibit a high degree of intercalation and exfoliation.展开更多
文摘With ultrasonic assistant mixing way, an intercalated mixture of polyol/ organo reactive montmorillonite （ORMMT） was pretreated. The prepolymer composed MMT clay was prepared by reaction of polyol/ORMMT mixture with toluene diisocyanate （TDI）. The resultant prepolymer reacted with extender （DMTDA） and then the polyur- ethane-urealorgano reactive montmorillonite （PUUIORMMT） nanocomposites were obtained. The structure, morphology and properties of PUU/ORMMT nanocomposites were characterized by FT-IR, TEM, AFM, strain-stress machine, TGA, and dynamic mechanical analysis （DMA）. The results showed that when tl-m OMMT content is 3%, the PUU/ORMMT nanocomposities performed super mechanical properties. Because of the presence of ORMMT, both Tg of the soft segment and tan5 of the PUU increased, and the decomposition temperature for the first step and the second step increased respectively. TEM images showed that the organophilic MMT particles in the PUU composite exhibit a high degree of intercalation and exfoliation.
