The selectivity of organosamarium(Ⅲ) hydride in reducing unsaturated carbonyl compounds has been studied. Dimeric organosamarium hydride[(C_9H_7)_2SmH]_2·4THF·NaCl prepared by the reaction of (C_9H_7)_2SmCl...The selectivity of organosamarium(Ⅲ) hydride in reducing unsaturated carbonyl compounds has been studied. Dimeric organosamarium hydride[(C_9H_7)_2SmH]_2·4THF·NaCl prepared by the reaction of (C_9H_7)_2SmCl·2THF with NaH in THF reacts with unsaturated carbonyl compounds to give the corresponding reduction products with a high selectivity. The carbonyl groups have been reduced while the carbon-carbon double bonds are not affected.展开更多
The construction of N-fused polycyclic compounds at room temperature via the combination of transition-metal catalyst and photocatalyst has been reported.This novel work has successfully realized LED irradiated C—H a...The construction of N-fused polycyclic compounds at room temperature via the combination of transition-metal catalyst and photocatalyst has been reported.This novel work has successfully realized LED irradiated C—H activation of iodonium ylides.The strategy shows wide substrate scope and ideal functional group tolerance.Our work would be useful for the construction of various heterocyclic compounds.展开更多
Sulphur-containing aromatic amines were prepared efficiently in good to excellent yields by reduction of the corresponding sulphur-containing aromatic nitro compounds with hydrazine hydrate in the presence of iron（Ⅲ...Sulphur-containing aromatic amines were prepared efficiently in good to excellent yields by reduction of the corresponding sulphur-containing aromatic nitro compounds with hydrazine hydrate in the presence of iron（Ⅲ） oxide-MgO catalyst. The catalyst exhibited high activity and stability for the reduction of sulphur-containing aromatic nitro compounds. The yields of sulphur-containing aromatic amines were up to 91-99 % at 355 K after reduction for 1-4 h over this catalyst.展开更多
Catalyzed by ytterbium（III） triflate hydrate [Yb（OTf）3.xH20], the Michael addition and cyclocondensation of α,β-unsaturated ketones with active methylene compounds to afford the 1,4-adducts and benzo[b]pyran der...Catalyzed by ytterbium（III） triflate hydrate [Yb（OTf）3.xH20], the Michael addition and cyclocondensation of α,β-unsaturated ketones with active methylene compounds to afford the 1,4-adducts and benzo[b]pyran derivatives, respectively were studied.展开更多
文摘The selectivity of organosamarium(Ⅲ) hydride in reducing unsaturated carbonyl compounds has been studied. Dimeric organosamarium hydride[(C_9H_7)_2SmH]_2·4THF·NaCl prepared by the reaction of (C_9H_7)_2SmCl·2THF with NaH in THF reacts with unsaturated carbonyl compounds to give the corresponding reduction products with a high selectivity. The carbonyl groups have been reduced while the carbon-carbon double bonds are not affected.
基金the support from Sichuan Science and Technology Program(No.2020YJ0221).
文摘The construction of N-fused polycyclic compounds at room temperature via the combination of transition-metal catalyst and photocatalyst has been reported.This novel work has successfully realized LED irradiated C—H activation of iodonium ylides.The strategy shows wide substrate scope and ideal functional group tolerance.Our work would be useful for the construction of various heterocyclic compounds.
文摘Sulphur-containing aromatic amines were prepared efficiently in good to excellent yields by reduction of the corresponding sulphur-containing aromatic nitro compounds with hydrazine hydrate in the presence of iron（Ⅲ） oxide-MgO catalyst. The catalyst exhibited high activity and stability for the reduction of sulphur-containing aromatic nitro compounds. The yields of sulphur-containing aromatic amines were up to 91-99 % at 355 K after reduction for 1-4 h over this catalyst.
基金the National Natural Science Foundation of China (No.20676123) for financial support.
文摘Catalyzed by ytterbium（III） triflate hydrate [Yb（OTf）3.xH20], the Michael addition and cyclocondensation of α,β-unsaturated ketones with active methylene compounds to afford the 1,4-adducts and benzo[b]pyran derivatives, respectively were studied.
