Synthesis and Characterization of Chiral Organogallium and Indium Complexes with Salen Ligands

Several new chiral organogallium and indium complexes with chiral Salen (1 and 2) as anxciliary ligands have been synthesized and characterized by elemental analysis, IR, 1H NMR and Mass spectroscopy. For the gallium, mono and bimetallic complexes were obtained, whereas ring closure complexes of indium were obtained.

稀散元素镓配合物的研究进展

近年来,镓的配位化学的研究发展迅速.对最近几年镓与主族元素、过渡元素及其他一些典型配体形 成的有机镓配合物的研究进展作一概述.

有机镓配合物的合成及其质谱

本文通过三环戊基镓与取代苯酚,有机酸,氨基酸反应合成了八个新的有机镓配合物,这些配合物经过元素分析、质谱、核磁共振谱或红外光谱鉴定;质谱研究表明这些配合物均以二聚体的形式存在。