We have reported that Cp<sub>3</sub>Ln/NaH （Cp=cyclopentadienyl） systems can reduce alkene s and catalyze the isomerization of olefins, and their reactivity depends on the radii of trivalent rare earth i...We have reported that Cp<sub>3</sub>Ln/NaH （Cp=cyclopentadienyl） systems can reduce alkene s and catalyze the isomerization of olefins, and their reactivity depends on the radii of trivalent rare earth ions; σ ligands in （C<sub>5</sub>H<sub>4</sub>CH<sub>2</sub>CH<sub>2</sub>CH<sub>2</sub>C<sub>5</sub>H<sub>4</sub>） LnX·THF/NaH systems also affect obviously the reducing activity of the systems. Herein, we wish to report the results of reduction of alkenes with L<sub>2</sub>YCl（THF）<sub>n</sub>/NaH (L:展开更多
基金Project supported by the National Natural Science Foundation of China
文摘We have reported that Cp<sub>3</sub>Ln/NaH （Cp=cyclopentadienyl） systems can reduce alkene s and catalyze the isomerization of olefins, and their reactivity depends on the radii of trivalent rare earth ions; σ ligands in （C<sub>5</sub>H<sub>4</sub>CH<sub>2</sub>CH<sub>2</sub>CH<sub>2</sub>C<sub>5</sub>H<sub>4</sub>） LnX·THF/NaH systems also affect obviously the reducing activity of the systems. Herein, we wish to report the results of reduction of alkenes with L<sub>2</sub>YCl（THF）<sub>n</sub>/NaH (L:
