Effects of Primary Annealing Condition on Recrystallization Texture in a Grain Oriented Silicon Steel

The recrystallization texture in grain oriented silicon steel sheets, which were annealed at different primary annealingtemperatures with and without an electric field, was investigated. An automated electron backscattered diffraction(EBSD) technique was used to analyze the recrystallization texture. It was found that recovery and application ofelectric field in primary annealing lead to an increase of {001} component and a decrease of {111} component afterannealing at 900℃. The development of recrystallization texture can be explained in terms of the effects of electricfield and primary annealing temperature on recovery.

Balanced solubility product and enthalpies of formation of Nb compounds in 0.09 % oriented silicon steel

Balance solubility products and enthalpy of for- mation for NbC0.75, NbC0.85, NbC0.88, NbC and NbN in oriented silicon steels were calculated and compared quali- tatively. Meanwhile, the mixing enthalpies of these five Nb compounds were calculated based on Miedema Model. The results show that the solubility products of Nb compounds in ferrite and austenite meet the following relationship, NbC0.75 〉 NbC0.85 〉 NbC0.88 〉 NbC 〉 NbN and NbN has the minimum enthalpy of formation. It indicates that NbN easily precipitate out, but it is more difficult for NbC0.75.

STUDY ON REDUCING THE CORE LOSS OF GRAIN ORIENTED SILICON STEEL AND IMPROVING ITS AGING PROPERTY BY LASER NITRIDING TECHNIQUE IN ATMOSPHERIC AMBIENT

CW-CO2 laser nitriding technique was applied to improve the properties （such as aging property and the core loss） of grain oriented silicon steel. The samples were nitrided with regular space. Laser power density and scanning speed were chosen as 7.8×10^5W·cm^-2 and 100mm·min^-1. By some laser irradiation, Fe4N and Fe3N were formed in the nitrided zone. The nitrided samples were annealed at the temperatures ranged from 100 to 90℃. The core loss of some interested samples was tested. The results show that the core loss of the nitrided samples with different thickness of 0.23 and 0.30mm decreased by 14.9% and 9.4% respectively, and the aging property were improved up to 800℃. The mechanism of laser nitriding to improve the properties of grain oriented silicon steel is discussed.

Primary Recrystallization of Grain Oriented Silicon Steel Strip Rolled by CSR and Annealed in Magnetic Field

The magnetic properties and textures of grain oriented silicon steel with different thickness rolled by cross shear rolling （CSR） of different mismatched speed ratio （MSR） and annealed in magnetic field under hydrogen were presented.Effects of the factors such as thickness and mismatched speed ratio on the magnetic properties and recrystallization texture were analyzed and the recrystallization principles in magnetic field annealing were discussed. The study would provide a new route for mass production of high quality ultra-thin grain oriented silicon steel strip.

EFFECTS OF Sn AND Sb ON STRUCTURE AND MAGNETIC PROPERTIES OF HIGH INDUCTION ORIENTED SILICON STEEL

Effects of Sn and Sb on the structure and magnetic properties of high induction oriented silicon steel have been investigated.The heats with Sn or Sb possess rather fine primary and secondary gram sizes.Sn or Sb promotes the finer AlN particles,increases the amount of pre- cipitated AlN after normalizing and strengthens the ability of inhibition.After decarburizing annealing,the texture components of{110}〈115〉and〈110〉〈001〉tend to increase and form more secondary grain nuclei.

Texture Characteristics of Thin Grain Oriented Silicon Steel Sheet Produced by Cross Shear Rolling

Commercial grain oriented silicon steel was cold rolled to thickness from 0.06 to 0.10 mm by cross shear rolling, then annealed in vacuum or a hydrogen atmosphere furnace. Deformation textures of the sheets were researched by ODF method and reverse pole figure quantitative analyses. The results indicate that: in the condition of the cross shear rolling, the deformation texture of rolled sheet is generally similar to that of conventional rolled sheet, however, the texture distribution through the thickness is asymmetrical. With mismatch speed ratio increasing, the amount of Goss texture increases. With reduction ratio increasing, the intensity of γ-fiber becomes strong.

Recent Developments in the Study on Oriented Silicon Steel Sheets

Over the past several decades, the texture, properties and manufacture of quality silicon steels have been investigated for application in magnetic devices requiring magnetically soft materials, such as transformers, inductive devices, etc. Most recently, the factors effecting the texture and magnetic properties, e.g. impurities, rolling process and annealing process, have been greatly studied. The benefits of this study are that low core loss silicon steels with stable high-performance can be obtained through an economic production process. This review is intended to summarize the recent developments in the texture, properties, manufacture and application of oriented silicon steel sheets.

New process for production of ultra-thin grain oriented silicon steel

The Hi-B silicon steels were cold rolled by cross shear rolling (CSR) with different mismatch speed ratio(MSR)s and conventional rolling(CR) respectively, followed by primary recrystallization annealing. The effects of MSR and annealing temperature on magnetic properties of ultra-thin grain oriented silicon steel were analyzed. Experimental results show that, with the increase of MSR, the magnetic properties can be remarkably improved. The higher the annealing temperature is, the higher the magnetic induction and the lower the iron loss in ultra-thin silicon steel is.

Optimizing Domain Distribution of Grain Oriented Silicon Steel by Using Antimony as the Laser Surface Alloying Element

For reducing the core loss of grain oriented silicon steel and improving its aging property, a new method, the LLSA by using Sb as the laser surface alloying element, was investigated, and at proper technique conditions rather good result was obtained.

Goss Texture Evolution of Grain Oriented Silicon Steel by High-Energy X-ray Diffraction

High energy synchrotron diffraction offers great potential to study the recrystallization kinetics of metallic materials. To study the formation of Goss texture （{ [10}（001）） of grain oriented （GO） silicon steel during secondary recrystallization process, an in situ experiment using hi gh energy X-ray diffraction was designed. The results showed that the secondary recrystallization began when the heating temperature was 1,494 K, and the grains grew rapidly above this temperature. With an increase in annealing temperature, the large grains with 7 orientation [〈111〉//normal direction] formed and gradually occupied the dominant position. As the annealing temperature increased even further, the grains with Goss orientation to a very large size by devouring the 7 orientation grains that formed in the early annealing stage. A single crystal with a Goss orientation was observed in the GO silicon steel when the annealing temperature was 1,540 K.

Non-Oriented Fe-Si Thin Strip Produced from Grain Oriented Fe-Si Strip by CSR

The grain oriented silicon strip was rolled by cross shear rolling(CSR)and then annealed to manufacture non-oriented thin silicon strip of high quality.The recrystallization of rolled grain-oriented silicon steel into non-oriented silicon steel was studied.For this purpose,CSR is better than conventional rolling,and the higher the mismatched speed rate is,the better the properties of the non-oriented thin silicon strip are.The optimum annealing schedule is heating at 1 000 ℃for 1hin pure hydrogen atmosphere added with H2 S of 0.001 0 %.

Two-Dimensional Transient Temperature Field of Finish Rolling Section in Hot Tandem Rolling

The grain oriented silicon strip was rolled by cross shear rolling (CSR) and then annealed to manufacture non-oriented thin silicon strip of high quality. The recrystallization of rolled grain-oriented silicon steel into non-oriented silicon steel was studied. For this purpose, CSR is better than conventional rolling, and the higher the mismatched speed rate is, the better the properties of the non-oriented thin silicon strip are. The optimum annealing schedule is heating at 1 000 ℃ for 1 h in pure hydrogen atmosphere added with H 2S of 0.001 0 %.

Evaluation on the contribution of steel products to environmental improvement from LCA perspectives

High functionality given to steel products results in an increase of environmental loads in the steelmaking stage. However, at the stage of their utilization, the high-functional steel products prove to be more environmentally friendly than their conventional counterparts in many cases. In view of this contradiction, the evaluation on the contribution of steel products to environmental improvement requires a more integrated approach--Life Cycle Assessment （ LCA ）, which incorporates the effects over the products＇ entire life cycles. This paper discusses the relationship between the improvement of steel products＇ performance and the according environmental impact from the entire life cycle perspectives. How to evaluate and assess the contribution of high-functional steel products to environmental improvement using LCA method is explained in detail. Two case studies of Baosteel are given to substantiate the effectiveness of LCA as a scientific and systematic method for eco-material evaluation or eco-design： @ For a power transformer, by replacing silicon steel B30G130 with B30Pll0,the carbon dioxide emissions were reduced by 15.1% over the life cycle of the transformer. @ Tinplate steel of Baosteel used for two-piece steel cans experienced six reductions in thickness from 0.28 mm to 0.225 mm,which results in a 14.5% emission reduction over the life cycle of two-piece steel cans.

Effect of Electropulsing on Recrystallization and Mechanical Properties of Silicon Steel Strips

Electropulsing-induced recrystallization and its effect on mechanical properties of oriented silicon steel strips （Fe-3.0%Si） were studied by optical microscopy, scanning electron microscopy and electron back-scatter diffraction. The results indicated that electropulsing accelerated recrystallization, and decreased the temperature of recrystallization. Electropulsing favors refinement of the grain structure of the alloy. Effects of electropulsing on strength and elongation of the alloy were discussed from the point view of dislocation dynamics, microstructural changes, and electropulsing kinetics.

Preparation and properties of polycrystalline silicon seed layers on graphite substrate

Polycrystalline silicon（poly-Si） seed layers were fabricated on graphite substrates by magnetron sputtering. It was found that the substrate temperature in the process of magnetron sputtering had an important effect on the crystalline quality,and 700℃was the critical temperature in the formation of Si（220） preferred orientation. When the substrate temperature is higher than 700℃,the peak intensity of X-ray diffraction（XRD） from Si（220） increases distinctly with the increasing of substrate temperature.Moreover,the XRD measurements indicate that the structural property and crystalline quality of poly-Si seed layers are determined by the rapid thermal annealing （RTA） temperatures and time.Specifically,a higher annealing temperature and a longer annealing time could enhance the Si（220） preferred orientation of poly-Si seed layers.

Evaluation on Contribution of Steel Products to Environmental Improvement from Life Cycle Assessment Perspectives

High functionality given to steel products results in incremental environment loads at the steelmaking stage.However,at the stage of utilization,high-functional steel products prove more environment friendly than their conventional counterparts in many cases.Therefore,evaluation on contribution of steel products to environmental improvement requires an integrated approach that considers the product over its entire life cycle - life cycle assessment(LCA).This paper discusses the relationship between the improvement of steel products performance and environmental impact from the entire life cycle perspectives.The LCA method to calculate and assess contribution of high-functional steel products during the life cycle to environmental improvement is explained.Two case studies of Baoshan Iron & Steel Co.,Ltd.(Baosteel for short) are given to show that LCA is a scientific and systematic method for eco-materials evaluation or eco-design:in a power transformer,using silicon steel B30P110 to replace B30G130 can reduce carbon dioxide emissions in the region of 15.1% over the life cycle of the power transformer;tinplate steel of Baosteel for two-piece steel cans experienced six times thickness reduction from 0.280 to 0.225 mm,which results in 14.5% emission reduction over the life cycle of two-piece steel cans.It is a systematic and scientific method for evaluating on products environmental performance from life cycle perspective.